Topic Name : Atomic Structure

1. The mass of a proton is equal to _______ .

(2) the electron is an unstable particle
(1) 0.0055 u (2) 1.00727 u
(3) the electron has very high kinetic energy
(3) 1.6000 u (4) 1.672 u
(4) an accelerated electron in an orbit emits
2. Cathode rays are made up of _______ . radiation
(1) positively charged particles 9. The SI unit of frequency of radiation is
(2) negatively charged particles (1) cm–1 (2) Hertz
(3) neutral particles (3) nm (4) metre
(4) equal amount of positively and negatively 10. _______ is the number of wavelengths per unit
charged particles length.
3. An -particle is represented as _______. (1) Amplitude (2) Velocity
(1) 1
(2) 4 (3) Wavenumber (4) Frequency
1 2
11. The value of Rydberg constant for hydrogen atom
2 1
(3) 2 (4) 0  is _______.
4. The mass number and atomic number of an (1) 109677 m–1 (2) 109677 cm–1
element are A and Z respectively. The number of (3) 109 6 77 × 107 cm–1 (4) 109677 × 10–7cm–1
neutrons in the atom of that element is calculated 12. The emission spectrum of hydrogen in the
as _______ . ultraviolet region of electromagnetic radiation
(1) A (2) Z forms _______ series.
(3) A + Z (4) A - Z (1) Pfund (2) Lyman
5. The nuclide having 6 protons and 8 neutrons is (3) Balmer (4) Brackett
represented as _______ . 13. The spectral line obtained when an electron jumps
14 8 from n = 6 to n = 3 level in hydrogen atom belongs
(1) 6 X (2) 6X to the _______ series.
6 (1) Balmer (2) Lyman
8X
14
(3) 6 X (4)
(3) Paschen (4) Pfund
6. The number of protons, neutrons and electrons
14. Which of the following is INCORRECT regarding
231
in a neutral atom of the element 89 X are _______ different series observed in hydrogen spectrum?
respectively. (1) For Balmer series, n1 = 2.
(1) 89,89,242 (2) 89,142,89 (2) For Brackett series, n1 = 4.
(3) 89,71,89 (4) 89,231,89 (3) For Lyman series, n1 = 1.
7. Which of the following pairs represent isobars? (4) For Pfund series, n1 = 3.
3 15. According to Bohr ’s model for the hydrogen
(1) 2 He and 42 He (2) 24
12 Mg and 25
12 Mg atom, when electrons revolve in the stationary
40 40 40 39 orbits, _______ .
(3) 19 K and 20 Ca (4) 19 K and 19 K
(1) the energies of the electrons remain constant
8. Rutherford’s model of an atom is unstable
(2) they become stationary
because_______.
(3) they gain potential energy
(1) the proton is an unstable particle
(4) there is increase in energies of the electrons
16. When an electron jumps from K to L shell, energy 25.. Maximum number of electrons that can be
is _______ . accommodated in ‘M’ shell is _______ .
(1) absorbed (1) 18 (2) 32
(2) released (3) 2 (4) 8
(3) sometimes absorbed and sometimes released 26. The value l = 1 represents _______ subshell.
(4) neither absorbed nor released (1) s (2) p
17. According to Bohr ’s theory, the angular (3) d (4) f
momentum of an electron in the fourth Bohr’s
27. The quantum numbers n = 5,l = 3 represent the
orbit is _______.
_______ orbital.
h 2h (1) 5s (2) 5f
(1) (2)
2  (3) 5d (4) 5p
28. The total number of subshells in the N shell is
3h 3h _______ .
(3) (4)
2 
(1) 3 (2) 4
18. The ratio of radii of second and first Bohr ’s (3) 5 (4) 7
orbits of H-atom is _______ .
29. The number of orbitals in a subshell is equal to
(1) 2 : 1 (2) 1 : 3 _______ .
(3) 4 : 1 (4) 2 : 3 (1) n 2 (2) 2l
19. The phenomenon of splitting of atomic spectral (3) (2l + 1) (4) 2(n – l)
lines under the influence of the external magnetic
30. The maximum number of electrons in s, p and d-
field is known as _______ effect.
subshells are _______ respectively.
(1) photoelectric (2) Stark
(1) 2, 2 and 4 (2) 2, 4 and 6
(3) Zeeman (4) spectral
(3) 2, 6 and 10 (4) 2, 6 and 12
20. Which of the following represents the de Broglie
31. The maximum number of electrons that can be
relation?
accommodated in f-subshell is _______ .
(1) mv = hc/ (2) mv = h/
(1) 2 (2) 8
h (3) 14 (4) 32
(3) mv = /h (4)  
mvc 32. Which of the following orbitals does NOT exist?
21. The de Broglie wavelength () associated with a (1) 3d (2) 3f
material particle is _______ . (3) 5p (4) 7s
(1) directly proportional to its mass 33. Which of the following is CORRECT?
(2) directly proportional to its momentum (1) Azimuthal quantum number (l) can have
(3) inversely proportional to h only positive values between 0 and – l.
(4) inversely proportional to its momentum (2) Electron spin quantum number describes the
22. In the Schrodinger wave equation,  represents shape of the orbital that is occupied by the
_______ . electron.
(1) orbit (3) Principal quantum number describes the
relative spatial orientation of the orbitals in a given
(2) wave function
subshell.
(3) energy of an electron
(4) Magnetic orbital quantum number has values
(4) radial probability from – l to + l through zero.
23. How many quantum numbers are required to 34. 2px and 2py orbitals differ in their _______ .
fully specify an electron in an atom?
(1) orientation (2) energy
(1) One (2) Three
(3) shape (4) ‘l’ value
(3) Two (4) Four
(3) px-orbital (4) pz-orbital
24. The number of allowed orbitals in any principal
35. Hund’s rule deals with the distribution of
shell is given by _______ .
electrons in _______ .
(1) (2l +1) (2) 2n2
(1) a principal shell
(3) (2n + 1) (4) n 2
(2) different subshells
 (3) orbitals with slightly different energies 45. If m l has seven values, the value of azimuthal
(4) degenerate orbitals quantum number should be _______ .
36. Which of the following electronic configuration (1) 1 (2) 2
is CORRECT for iron? (3) 3 (4) 4
(1) 1s 2s 2p 3s 3p 3d
2 2 6 2 6 5
46. Which of the following sets of quantum numbers
(2) 1s 2s 2p 3s 3p 4s 3d
2 2 6 2 6 2 5 is NOT permitted?
(3) 1s2 2s2 2p6 3s2 3p6 4s23d7 1
(4) 1s2 2s2 2p6 3s2 3p6 4s23d6 (1) n = 3, l = 3, ml = 0, ms = +
2
37. The CORRECT orbital diagram for beryllium atom
in ground state is _______ . 1
(2) n = 3, l = 2, ml = +2, ms = –
2
   
(1) (2)
1s 2s 1s 2s 1
(3) n = 4, l = 1, ml = —l,ms = –
2
   
(3) (4)
1s 2s 1s 2s
1
(4) n = 3, l = 0, ml = 0, ms = +
38. Which of the following electronic configurations 2
is NOT possible in the ground state of an atom?
47. Which d-orbital does NOT have four lobes?
(1) 1s2 2s2 (2) 1s2 2s2 2p6
(3) 1s2 2s2 2p5 (4) 1s2 2s22p2 3s1 (1) d x2 y2 (2) dxy
39. The total number of unpaired electrons in the d-
orbitals of an atom of the element with atomic (3) d yz (4) d 2
z
number 29 is _______ . 48. In a multi-electron atom, which of the following
(1) 10 (2) 1 orbitals described by the three quantum numbers
(3) 0 (4) 5 will have the same energy in the absence of
magnetic and electric fields?
40. Which of the following is isoelectronic with K+?
(1) n = 1, l = 0, m = 0
(1) Ar (2) Ca
(2) n = 2, l = 0, m = 0
(3) Sc+ (4) S4–
(3) n = 3, l = 2, m = 0
41. What is the energy in joules produced when an
electron moves from n = 4 to n = 3 level in a (4) n = 3, l = 2, m = 1
hydrogen atom? (1) (1) and (2) (2) (2) and (3)
(1) – 3.13 × 10 –18
J (2) – 2.18 × 10 –18
J (3) (1) and (3) (4) (3) and (4)
(3) – 1.06 × 10 –19
J (2) – 4.36 × 10 –18
J 49. The number of unpaired electrons in chromium
42. If wavelength of photon is 2.2 × 10 m, –11 (Z = 24) is _______ .
h = 6.6 × 10–34 J s, then momentum of photon is (1) 3 (2) 5
(1) 3 × 10–23 kg m s–1 (2) 3 × 1022 kg m s–1 (3) 6 (4) 8
(3) 1.5 × 10–44kgms–1 (4) 6.9 × 1043 kg m s–1 50 4d, 5p, 5f and 6p orbitals are arranged in the order
43. If uncertainty in position and momentum are of decreasing energy. The CORRECT option is
equal, then uncertainty in velocity is _______ . _______ .
[NEET (UG) 2019]
1 h h (1) 6p > 5f > 5p > 4d (2) 6p > 5f > 4d > 5p
(1) (2)
m   (3) 5f > 6p > 4d > 5p (4) 5f > 6p > 5p > 4d

1 h h
(3) (4)
2m  2
(3) 1 × 109 cm s–1 (4) 1 × 106 cm s–1
44. The value of azimuthal quantum number (l) for
electrons present in 4p subshell is _______ .
(1) 1 (2) 2
(3) 3 (4) 4