_ Saliey) jee + (meade suweoh) ip. Ys § for position Westone - eG s ee CN _ * doll ppl for posikon [eA her Wormne | aul gr 33 phenone cinnamnaldehude Carnmarmod) JUPAC, ~ carbaldehyde afor fing hr] ee, * alRan¢ + al JUurRAC * a\kan¢ + one % numbering fron) the carbon near tO CO FFP SWATHY'STuDy PLANETWroclore oF carbs rOUI Om 2 Te cloold Nes ps () 0. 4 forms 3 T bonds ray ihr bord euth OnJ9 ) aweve € belbw plane’ 5 ih p praital overlapping +02 hes 2° non bonding 6 pars abA- 120° + Hrigoral coplanar str) ° or ener aylorised due {0 high Pnegatvity oF 02 i woe” eyectrophilic (Leis aad) neo Dipolar 9 =e nexteophilié (Lee's bec) Preparation j RCH20H oxidation {C403 ReHo alcohol Pee oe 2c20¥ _W/ SIBRy RHO ‘\ [Rosenmund, “cl ta pd eno reac: » Oo Sear: os Hsot Stephen» RCN + SnCcl2 + act Ror lene RcHO ALDEHYDE a reac: Imine gcn —pbiBAL_——r_ReHO oe Y) Ho diisobuly aluminiur hydride euatena)g—0- OE DmBal—y csCoreda o-H aster H20 . Etard) rex ona Lan (ocroncale ~ 0 tae GIO acroace 2, (oh ar) chromy! 5 *Moride cA(ococs)2 7 Ons os "4 403 + (CH3CO) 0 2a (of Sat becetey CC) voio Br (oJ tant, OY ‘ OAS Sue < oy -sulhv © > yo 5 G cae 313k S ch\orind Hon One Os.> 2RMg X + Cdcla —y Rad + 2Hg (earl Ny? Ricocl + Racd —> AWC -R + CAC2 draiwylcadmiven a Sgr 0 Ren + Corstger Sherr Rel te0T, pf GHe Scous RETONE ° » Co 4 Ar[R-o-Cl -Anbyd— of ~R/Ar le auylalkon ‘Physical Prop F Intermol: Chertfical “Rect¢ BPN Gricominia ADDITION): REA d) Hechasiem Yow hw Felcal __slou— wht / ‘ow f ae aT [oj “step 4 ee ‘shep2 [oy ou/ preter Nonide, AddiHon produck \ntermediate SWATHY' STUDY PLANET) Reachvily Aldehyde 7 Ketone [Reactivity | ‘Reason : stearic hinderance - i) Yaamples (A) AppiTion OF HCN NIG Oe on™ +1120 ee \ ae a C Ne= N cro + CNT : 1” Son Wrohedral \ntormetiate SULPHATE (B) Am TION oF soDIUH HYPROGE + equilibriom 4owards — right (aldehude) —left (yelore) (c) ADDTION OF GRIGNARD REAGIENTS Rl \ RcHO+ R'Mgk —> RecN ONG Saar (©) ADDITION OF ALCOHOLS r oR! F Pe = pon vow. p-c § rare gps Sou aes + prokrates 02 hermiacetal #A ereckophilo } or date OVO — Syogyatcord oro} _Wel gos \ ee cn208 aN A R 0 Phy get . Acer) [Rela 182 —> alde| Retore mineral add k 2R of Ketone 4 clectrophillicity oF c” & provides (to 4 reac rale ) Sic Gypnohydrin Se ——— Nie c=0 +(Ngnsoa == 7° , a Sa. SEE 7 Sa . BisvIprite addilon product (soluble nH20) sroversad by heating eoith al : minera jou Son osoana — coniy nethy! fayctic petones) vat / on + Hg (OH) + 20 on! Aceta\/ Gem —aioRoy +20 Brrylene Glycol Reta}(E) ADDITION OF AHHONIA € 15 DERIVATIVES \ fols} Nexo + WaN-2 = ee | T: Repuction mC! 7 nrtz| dehydraton / (A) REDUCTION TO ALCOHOLS pcao+ Ha Pd —> RcH2041 peop) NaBHy > RoR! ou (8) REpuction To HC Clernmensen Reduction WolFF—Rishner Reduchon Ye =o NraNi2» “TT oxipaTion ol RcHO mato Racr209] BHU) < © Nz +120 (zeaiy) fary\ (oH Juve [cor N¥) ss Nc <0 ZnaHg > YH + #20 g Hel -W20 RCOOH R- HNO3 GTOuen's Test (Anmmenoniacal silver nitrate) pewo-+ 2] Ag (wHada* + 30H ——> ROO” + 2Aq + 220 + NHS carpowlde — si\ver mirror anion Drerune's Test RENO + 2¢u2t +EOH™ —> RCoO™ + Cv20 + 320 Red- brown ppt Ac: Se ont Re i) R—c- Hs (sodiury, tet Revone — pypohalile) Nv Rec -ONa + OHS / Bod LA —y Seno + No etrylene gyol / \ igh bating salv = NNH2 : Lol > econ + ReH2coH Ob“ Fagniene a esh ondist R2coOH + RI CCOH geht Nok for aromatic aldehyde. (even \W the presence of = bond) SINATHY' STUDY PLANETTW REACTION DOF TO w= HYpROGEN acidity of U-H dveato sltong 2© withdrawing ef feck oF co er resonance. s\abilisa Hon (AVADOL CONDENSATION aNd & Rot having ciileast 1 w-H undergo r pors-cro ALNOOA cacy cco —B—> cHa-cH = CHCHO ' = oH “420 dol Ado\ condensalon product (1 B-unsatvrated. carbonyl cH30H tH ¢ foraideryse methanol Ok ‘Potassium formate je carboxy lic derek sat}273 -283R oN f + acetone ~ solvent sNic ¥y Pavenll Benzaldchyde — —yerfomne dye CarBoxyiic ACID & cobonul grp +hydxyl grp —> carbosuhe aad bony! arp + hydronyl gi ‘i “ ' . ROO AyCOOH *O2oCis higher aliprakc carboxylic aod —> Fatty aad vag COOH . on VUPAC “soft ~\c aad #alkand +o0ic aad | HCOOH — Formic oad —red ont + numbonng From corkosslic cotton —acekic oad — vinegcir + manu coon =aPreparation carboxylic aad RCH2OH. wall Wet RCOOH ® alde cHa(cra)s CH 20 _ cHa(c2)8 COOH ee s Ragen!) Reno 22.0207 LRH p cooH HNoal fo] benzene, oH oe ee Oo sea ae oy “Hao (o From nitriles > pony antlow — RE! Syn wiles, RCOCOH amides 5 come Amite, cooH ~7 COOH ne + NHS. WOT RcooH i Bote 0 =C=0 bey reagent (dry ice) eter pong’ a H20., pcooH + Cl | Ag) RCOCI - Preanndede pcoo7 4ci> Had*, eco ae aadity H20 + 9 (645 (00H L&esco)20 pninydride CO CooL aot oye one NadHs cria(cHa)2cOONO * \psor vy + @2H450H aden) 60 G50 CH3(cH2)2 CCOH\cal Properties « Aliphatic (Ca) — colaxtess bq, 1 unpleasant door ahaher ores —> cAourless less voile aux like solids x» High bp oY alde +¥et. deatols 2 ----H-0 dste wteunealte Wad —s paw” < O=H==--0) Dimer © reysable I) H20 — Form HA bond, a soubilily W as C atoms Lgher ones — hydrophehic interachon of HC aslute in less polar solv — CcHe + crcis , alcoho! 4 (ESCO —IMsolvble I cold crater Chemical Reachons T. GEAVAME oF 0-H BONP DRLoOW + Na ——> IRCOOING * Ha. > Ni roatat aioe’ - nat +420 ReooH + Nao —r RCO Reeptt + NaHcos —> ROT nat + H20+Co2 + 120 Carboxylic oat \__—=» Acibt AciDi? where Ka = Req {mol Liodistingvish ~ coo a > H30t +]R—c. <— > H30t +]R—<. im wapesrale / ayo solv + Pa = —logka pamatier pla —Sttnger aad ( proten donor) proce = alton \ Rcocl * pocls + Hcl | PLB PCI3/S OCI phosproony chloride BRcoor+ PCS. —>3R COC) + H3PU3 proophoraus acid Srcoorr+Sihia, 7 RCOCI * S02 +HCl Fence with cool *NHa === RCO NHUT Roar Reon F areeno- amide | co cOONHYY A a , CO NH2 | (6) sn) | Om, coo" NH miiagg nt Phibalic oad strong Ral) yea tes ° NH nea \ ° pihalimide SWATHY' STupyY PLANETWV. SUBSTITUTION REAC IN HYDROCARBON PART D ReH2con Dre Red P_, a : Wiao Rid ca - coo X Xt -halocarboxyl acid Zeling Ry reac: For cavboylic aud with & — hydrogen Xx =c\ (Br carborylic pou oe COOH one Ha fo NOS Nor u ee FeBra ° ~ Br = — Uses oF cool No Friedel —GroFts reacHon 5 ceo —deachualing IP + catalyst Acts onds wath c=0 4rP | + qubber Jeatile Indes + eltemec aad — solvent Lauivegar + Hexanedionc acid — nylon —6«6 4 sodium wenzecte — foo dA preserva veFormaldehyde / Formalin (407) meee re \ ope : preserve biO =| Urea: form spedmen | -aidenyde bake like poly Aceraldehy de CH3COOH /CAPacho2coH vIn, \ polyp avela\e drugs 7