03 WB 1K and 2K Furniture Coatings

1K & 2K WB
Furniture coatings
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Outline
• Introduction
• Product description
 Dispersions overview
 Polyisocyanates overview
• Systems for wood coatings
 Dispersions for woodcoatings
 Bayhydrol ® A 2427: pigmented
 Bayhydrol ® A 2651 / Bayhydur ® XP 2655
 Bayhydrol ® A 2846
 Bayhydrol ® U XP 2755
• Special applications
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Wood coatings sector
Industrial Wood Coatings DIY
Furniture Decorative
Joinery Joinery
Parquet
Professional
Furniture (workshops)
Joinery
Parquet on-site
Decorative
Demands on industrial furniture coatings
Mechanical properties
Scratch resistance
Mar resistance
Chemical properties
Water resistance
Stain resistance
Domestic compounds
Appearance properties
Transparency / Wood warmth
Matt / Gloss
✔ Resistance responsible for durability and appearance for attractiveness of the coating
Demands on industrial furniture coatings
Product & application properties
Storage stability
Easy to apply
Competitive price
Drying & curing time
Stackability
Sandability
Blocking resistance
Laws and regulations

e.g.: SED 1999/13
National regulations
Film formation in waterborne systems
Drying speed of wb. systems

determined by:
Dispersion • Humidity
• Curing Temperature
• Formulation/solvents
Substrate
• Polymer
Enlarged (dispersion)
What is important in WB systems?
Binder:
• film properties
Coating formulation:
• drying and curing of the coating
• adjusted crosslinking ratio
• the final gloss of the film
• optimised additives
• the robustness in application
• adjusted viscosity for easy mixing of
hardener solution
• robustness
Polyisocyanate:
• chemical resistance of the film Application and drying conditions:
• mixing process of hardener solution • final optical appearance
• final gloss achieved in film • chemical resistance
• robustness in application and film
properties
PUD in wood coatings
Why do we need a PU dispersion in wood coatings?
• to provide WB systems with very low environmental impact, meeting most of regulatory
and labeling requirements
• to achieve films with final polyurethane level, regarding film resistance
• to provide 1K, 2K coatings with very good aspect on wood, high hardness and fast
drying.
• to reach best mechanical properties and film resistances:
• elasticity
• abrasion resistance
• scratch resistance
Outline
• Introduction
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PU and WB wood coatings
Polyurethane technology (SB, WB and UV) dominates the wood coatings market
• Hardness and flexibility: high mechanical resistance
• High chemical resistance
• Fast drying and curing
Waterborne polyurethane systems for wood coatings
PAC Bayhydrol® A
1K
PUD Bayhydrol ® UH
PAC Bayhydrol ® A
WB 2K PUD Bayhydrol ® U
PIC Bayhydur ®
UV PUD Bayhydrol ® UV
WB polyurethane systems
Bayhydrol ® : polyol dispersions
Page 16 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

WB polyurethane systems
Bayhydrol ® UH / UA: polyurethane dispersions

Bayhydrol A for wood coatings
OH functional polymer dispersions are necessary for top chemical resistance
Higher OH content in the polyol tends to lead to better chemical resistance
PAC emulsion Primary dispersions

polymer long-chain OH bearing polymer
OH functional high molecular weight
for fast drying
Secondary
PAC dispersion
OH functional
Secondary dispersions
short-chain OH bearing polymer
PU
dispersion lower molecular weight
OH functional for high gloss
Primary vs. secondary dispersions
Emulsion polymerisation:
water + surfactants Primary dispersion
Strong physical drying
High Mw: ~106
Secondary dispersion
Multistep process:
High gloss and
Polymerization in solvent transparency
Neutralization +
Dispersion Low Mw: ~ 104
Primary and secondary dispersions to meet all wood coating requirements

Binders for 1K and 2K woodcoatings
OH functional PAC (polyol PAC)
High performance OH
OH Bayhydrol A
OH
Best in chemical resistance
A 2651
Solvent like aspect possible
A 2427
OH OH A 2846 XP
Polyurethane dispersion (PUD)
Hardness and flexibility Bayhydrol UH
UH 2558
UH XP 2719
FA/alkyd modified PUDs
Improved chemical resistance UH 2342
High hydrophobicity UH 2557
UH 2593/1
UH XP 2592
OH functional PUDs (polyol PUD)
For 2K, with PU crosslinking mechanism Bayhydrol U
OH OH
Best chemical resistance
U XP 2755, U XP 2766
OH U XP 2757
OH
U XP 2750
Bayhydrol for 2K wood and furniture
Highest
chemical
Resistance
Anti-graffity
A Faster version of
2695 A 2470: Faster version of
Lower cosolvent A 2470:
content Internal activation
Chemical resistance
High chemical
resistance
Body build up A 2470 A 2770 A 2601
Primer / Topcoat Fast drying + Mechanical
Clear and properties
pigmented (hg, Standar for
Primer / Topcoat Clear
sg) 2K WB Wood:
and Pigmented coatings
SB like aspect
(hg, sg)
All purporse U XP
A 2651
A 242 2755
Fast drying + Chemical
Anti knot- resistance
bleeding Mainly for mat or semigloss
pigmented.
2427
primary acrylic emulsion
Fast drying, self X-linking
secondary: high gloss & transparency 2846 XP 1K and 2K with good chemical
resistances
polyester based PU dispersion
Drying speed
2K polyurethane: high class systems
Polyol Polyisocyanate Solventborne 2K polyurethane

(component A) (component B) systems:
• high-class coatings
• highest chemical resistance
• reliable and robust processing
• no special investment required
+
the easiest way to water
Waterborne 2K
polyurethane systems:
• high-class coatings
• low to zero VOC technology
• light fast, non-yellowing
• just slightly more demanding in
formulation and application
Reactive Reactive • no special equipment required
hydroxy group isocyanate group • most “natural” shift from SB to
WB
2K - WB systems
PAC emulsion
polymer
OH functional
2K
furniture,
Secondary plastic,
PAC dispersion
OH functional
+ PIC
= construction
and general
industrial
systems
PU
dispersion
OH functional
2K
PUR dispersion
parquet
OH free!!
+ PIC
= and plastic
systems
Polyurethane systems
Bayhydur®: hydrophillic polyisocyanates

Polyurethane systems
Desmodur® : aliphatic polyisocynates

Desmodur ® / Bayhydur ® :
The choice of polyisocyanate
• Hydrophilisation level: easiness of mixing, film appearance, chemical resistance

Mixing energy required to
achieve optimal final properties
Low viscosity, hydrophobic
0 100
Hydrophillic
0 100
Highly hydrophillic
0 100
• Hydrophillisation type: chemical resistance

External emulsifier
Highest
PET modified chemical
resistance
Anionic modified

Bayhydur toolbox
Perfect „Bayhydur-in-Water Emulsion“

Anionic PIC:
best in chemical resistance
Anionic polyisocyanates
• top chemical resistance
• easy mixing in the waterphase
• extremely easy-mixing is possible

• no special 2K spray equipment is required for
the easy mixing polyisocyanates
• wide application frame: no change in chemical
resistance under different mixing processes
• high gloss easily achieved
• chemical resistance requirements for DIN 1B conventional
hydrophilic
Anionically modified
HDI-trimer for
or IOS-MAT-066 fulfilled even in white isocyanate highest chemical
pigmented coatings resistance

NCO/OH ratio:
a key parameter
Optimizing the crosslinking NCO/OH ratio is crucial to achieve the highest film properties
Optimal NCO/OH ratio depends on:
specific coating formulations
drying and curing conditions
Typical croslinking ratios for a high-class 2K WB system

Drying conditions
23ºC, 50% Hr 50ºC
Coating
clear 1,5 1,3
pigmented 2,0 1,7
Mild drying conditions require higher NCO/OH ratio

Overcrosslinking in 2K waterborne systems
O
Primary R R´
reaction R-N=C=O + R´-OH N O
H
Polyisocyanate Polyol- Polyurethane

dispersion
1. R-N=C=O + H2O R-NH2 + CO2
O
R R
Secondary 2. R-N=C=O + R-NH2 N N
reaction H H
O
R R
1.+ 2. 2 R-N=C=O + H2O N N + CO2
H H
Carbon-
Polyisocyanate Water Polyurea
dioxyd
Bayhydur product landscape
PET hydrophilized IPDI based Anionic hydrophilized IPDI based

Combination partnerwith HDI types Combination partnerwith HDI types
Physical drying, high hardness XP
Physical drying, high hardness
2759
401
Desmodur Faster drying speed

N 3600 or Anionic hydrophilized HDI based
N 3900 For high gloss and high chemical
XP resistance in clear and pigmented
XP
Hardness
Anionic hydrophilized HDI based Specially for high-gloss

For high gloss and high chemical
2487/1 2655 High robustness
resistance in clear and pigmented Mainly for furniture application
(mainly furniture application)
Better chemical
resistance Ready to use for
furniture and parquet
2858 XP
PET hydrophilized HDI based
Bubble size: For high gloss and high chemical
chemical resistance 304 resistance in clear.
3100 Elastifying properties.
Mainly for parquet application
HDI based XP
305
IPDI based 2700
Ready to use
Easy mixing
*:solvent free mixable

Bayhydur® XP
2759
IPDI for fast drying and high
hardness
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Bayhydur XP 2759:
IPDI PIC for faster drying
 Combination partner for HDI based polyisocyanates

 Fast drying polyisocianate
 Higher final hardness, faster hardness development
 Increased popping limit Clear coating based on HDI PIC
HDI PIC / IPDI PIC
PAC polyol (7:3)
 Higher reliability
Dust drying 35’ 27’
 Longer potlife Total drying 4h 55’ 3h 05’
Haze 15 9
Gloss 20º/60º 83/90 83/90
Hardness 16 hs 50ºC 131” 168”
Hardness ev.RT 2h/4h/6h 12”/50”/77” 32”/79”/104”

1d/7d 130”/134” 158”/172”
Coffee 16 h 5 5
Wine 16 h 5 5
Water 16 h 5 5
EtOH 1h 5 5
Bayhydur® XP 2759: The perfect partner to increase hardness and drying speed

Bayhydur® 2858
XP
New universal hydrophilic hardener
- The key to make 2K waterborne
polyurethane coatings easier
Product presentation
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Bayhydur® 2858 XP
When ready to use crosslinker and performance matter
Bayhydur® 2858 XP is a universal

crosslinker providing broad compatibility
with different dispersions for high-
performance 2K waterborne polyurethane
coatings
You can increase your production efficiency
with this ready-to-use crosslinker and
reduce your material positions without
compromising your sales portfolio
Satisfy your customers need for low odor
and robust coating materials!
Page 35 • CAS AD General Industrial • WB Woodcoatings • Customer Seminar • June 2016

Bayhydur® 2858 XP
Ready to use anionic hydrophillic HDI / IPDI based polyisocyanate
• Supplied in a ready to use form: Bayhydur® 305
70% in PGDA, 500 mPa·s
• Easy mixability in waterborne systems

Bayhydur® XP 2655, Bayhydur® 2858 XP
• Mild odor
• Long pot-life in 2K coatings
• Higher blisterfree film thickness possible Mixability
•
5
High chemical resistance even in 4
Chemical
pigmented system Hardness
3
resistance
2
• High hardness 1
• Suitable for indoor air quality complaint

systems Fast drying Low Odour
• Versatility: for parquet and furniture

Abrasion
Bayhydur XP 2858 (PGDA)
Bayhydur 305 (DMM)
Bayhydur XP 2655 (MPA)

Excellent miscibility, also with PUD
Bayhydur® XP 2858 is an ideal crosslinker for flooring coatings
Glossy 2K parquet formulation based on Bayhydrol® UH 2593/1 (fatty-acid modified PUD)

Mixing ratio: 10% of B component on A component.
Bayhyhdur Bayhydur® 305 Bayhydur® 2858 XP Bayhydur® XP 2655
Crosslinker dilution 70% in DPGDME 70% in PGDA (s.f) 70% in PGDA

Miscibility 5 4-5 2
Sand dry (T1) approx. 15' approx. 15' approx. 15'
Fully dry (T4) approx. 45' approx. 42' approx. 45'
Pendulum hardness (s,König),
85 / 130 105 / 170 100 / 165
1 / 7d at RT
Water resistance 24 h 5 5 5
Ethanol resistance 5' / 30' 5 5 5
Black heel mark resistance (BHMR) 5 4 4-5
Abrasion Taber CS10
37 mg loss 35 mg loss 35 mg loss
mg loss after rev (10 N load)
5=very good, 1=very bad
Bayhydur ® XP 2858 is also suitable in 2K WB coatings for PVC formulation based on

Bayhydrol ® UH 2606 improving:
- chemical resistance
- adhesion

Complaint indoor air quality systems easier
Bayhydur® 2858 XP helps to fulfill indoor air quality regulations
Indoor air quality test according AgBB Scheme 2012

2K WB parquet coating based on Bayhydrol® UH 2593/1 and Bayhydur® 2858 XP
3 layers on oak 120 g/m2 wet, 6 h between layers, without sanding, 3 d preconditioning
TVOC Sum R
Limits 3 d TVOC ≤ 10 mg/m3, 28 d TVOC ≤ 1,0 mg/m3 Limits 28 d R≤ 1
1400
1,4
1200
1,2
1000
1,0
800 PGDA
mg/m3
0,8
600 BDG
0,6
DPM
400 0,4
TEA
200 0,2
0 0,0
3d 28d
Bayhydur 2858 XP
Additional to low emissions you benefit from mild odor

Very high chemical resistance
Bayhydur® 2858 XP in furniture coatings
White pigmented 2K formulation for furniture based on Bayhydrol® A 2651

NCO:OH ratio: 1,5
Bayhyhdur Bayhydur® 305 Bayhydur® 2858 XP Bayhydur® XP 2655
Crosslinker solution 70% in PGDA 70% in PGDA (s.f) 70% in PGDA

Miscibility 5 5 5
Sand dry (T1) approx. 40' approx. 25' approx. 35'
Fully dry (T4) approx. 6 h approx. 4 h 40' approx. 5 h 30'
Pendulum hardness (s,König),
90 / 125 135 / 160 110 / 130
1 / 7d at RT
Water resistance - 24h 5 5 5
Coffee resistance - 16h 2 5 5
Red wine resistance - 6h 2 5 5
Ethanol resistance - 1h 2 5 5
5=very good, 1=very bad
Chemical resistances according DIN 12720, 120 g/m2 wet on melamine, dried overnight at 50ºC
Bayhydur ® XP 2858 being an anionic polyisocyanate allows best chemical resistance

even in white pigmented systems

Higher film thickness with great surface
Bayhydur® 2858 XP in more robust industrial coatings
Film (diffusion barrier) Craters and pinholes

Clear glossy 2K formulation based on Bayhydrol® A 2651, RT drying
Wet film Bayhydur® 2858 XP Bayhydur® XP 2655 Bayhydur® XP 2655

thickness
70% in PGDA (s.f) 70% in MPA 70% in PGDA
200 μm 0 1 S1 0
300 μm 0 2 S1 0
Incomplete release Surface defects in
of entrapped air the coating layer 400 μm 1 S1 3 S1 1 S1
500 μm 3 S1 4 S1 3 S1
No diffusion
barrier ISO 4628-2: 0= no bubbles, 5=many bubbles; S1=small bubbles; S5= big bubbles
Coating layer is able Perfect surface,

to release entrapped air without surface defects
Bayhydur® 2858 XP
Bayhydur® XP 2655
Bayhydur® XP 2858 improves blister free thickness

Metal coatings at a glance
Bayhydur® 2858 XP for excellent optical and high performance
Bayhydrol® A 2695 Bayhydrol® A 2470

In a DTM coating In a white topcoat
Coating formulated as KYL 0602 REYE 533-2
Sand dry (T1) 1h 1,5 h
Fully dry (T4) 5h 7h
Pendulum hardness (s, König), 1 / 7d at RT 55 / 80 78 / 134
Glanz 20°/ 60° 38 / 5 78/ 87
Adhesion Gardobond OC / Q-Panels / Alu 0/0/2 0/0/1
Water resistance 1d / 3 d 0/0 0/0
Acetone resistance 5 min 0 0
H2SO4, 38% 1 (1h) 2 (24 h)
NaOH, 10% 0 (1h) 2 (24 h)
Condensed water / OA / 480 h ok -
Salt spray test / OC / 480 h 1 mm -
Bayhydur® XP 2858 is also suitable in 2K WB metal coatings when a ready to use

hardener is needed

Bayhydur® 2858 XP is a cost saver
Ready to use and convenient for parquet and furniture coatings
Packaging Market
Application Raw materials Production in cans product
Furniture
skip
PARQUET PARQUET PARQUET
Parquet
production

Bayhydur® 2858 XP
Summary
Recommended:
• Whenever a ready to use form is an advantage
• Robust industrial coatings with good optical appereance and film
performance:
• Furniture coatings
• Metal coatings
• Plastic coatings
• Flooring on-site:
• Specially recommended for parquet coatings
• Suitable for flooring, if solvents are accepted

Outline
• Introduction
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Bayhydrol ® for 2K wood and furniture
Highest
chemical
Resistance
Anti-graffity
A Faster version of
2695 A 2470: Faster version of
Lower cosolvent A 2470:
content Internal activation
Chemical resistance
High chemical
resistance
Body build up A 2470 A 2770 A 2601
Primer / Topcoat Fast drying + Mechanical
Clear and properties
pigmented (hg, Standar for
Primer / Topcoat Clear
sg) 2K WB Wood:
and Pigmented coatings
SB like aspect
(hg, sg)
All purporse U XP
A 2651
A 242 2755
Fast drying + Chemical
Anti knot- resistance
bleeding Mainly for mat or semigloss
pigmented.
A2427
primary acrylic emulsion
Fast drying, self X-linking
secondary: high gloss & transparency A2846 XP 1K and 2K with good chemical
resistances
polyester based PU dispersion
Drying speed

2K WB PU systems for fast drying.
Internal activation in PAC polyol
Curing time Pot-life
but
better
better
Reference conventional external catalyst Internal activation with PAC Dispersion
• Internal activation of Bayhydrol® A speeds up curing without loosing pot-life

• Fast drying even at low temperature
• Increase process productivity

Bayhydrol® A 2427
The perfect partner for
pigmented system
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Bayhydrol ® A 2427:
2K-WB pigmented coatings
Manual incorporation of hardener

20º 60º
Pigmented coatings
100
% gloss
80
Bayhydrol ® A 2427
60
Bayhydur ® XP 2487/1 or XP 2655 40
20
0
Bayhydrol A 2427 / Bayhydrol A 2427 /
Bayhydur XP 2655 Bayhydur XP 2487/1
Unique chemical resistance manual dissolver
Fast drying % gloss at 60º

100
80
Blocking 60
40
20
0
Bayhydur XP 2655 Bayhydur XP 2487/1

Bayhydrol® A 2651
Standard resin for 2K
waterborne wood coatings
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Bayhydrol ® A 2651:
Standard for wood with best aspect
Solvent like appearance High chemical resistance
DIN 68861 1b
High gloss
Broad application opportunities
90
80
70
Clear coatings with:
60 solvent like aspect, wood warmth
50 20º
40
from high gloss to matt
60º
30 high mechanical and chemical properties
20
10
0 Pigmented systems with:
Bayhydur XP 2655 Bayhydur XP 2655
High chemical resistance
High gloss
Bayhydrol® A 2651 / Bayhydur ® XP 2655
Bayhydrol® A 2651: secondary PAC dispersion
Excellent grain warmth, transparency and gloss

High reactivity
High compatibility
Bayhydur® XP 2655: anionically mod. HDI polyiocyanate
Excellent chemical resistance

Simple incorporation
Bayhydrol ® UH 2593/1 for furniture
Bayhydrol® UH 2593/1: PUD, NMP-free, physical drying
Addition of 10-20% Bayhydrol® UH 2593/1 to Bayhydrol® A 2651 provides

• faster drying of the coating
• easier down-glossing
• better wood wetting Drying of coating (200 micron)
• improved popping limit 3
tack free (h)

2
keeping:
• chemical resistance 1
• grain attenuation (Anfeuerung)
0
• transparency 0 10 20
Mixing ratio
(% of UH 2593/1 on A 2651)

Popping limit: addition of UH 2593/1
Clear coating formulations:
application viscosity approx. 30 s DIN cup 4
applied on glass at different wet film thickness
NCO/OH = 1,5
Assessment of bubble content in dried film (coating applied on glass at different wet film thickness)
A 2651 / A 2651 /
Bayhydrol A 2651 A 2651
UH 2593/1 8:2 UH 2593/1 8:2
80% 80% 60% 60%

Bayhydur XP 2655
MPA MPA Butoxyl Butoxyl
wet film thickness [µm], applied on glass

120 0 0 0 0
200 0 0 0 0
300 1S1 0 0 0
400 2S2 0 2S2 0
500 3S2 / 1S4 2S2 3S2 2S2
ISO 4628-2: 0= no bubbles, 5=many bubbles

S1=small bubbles; S5= big bubbles
Addition of 20% Bayhydrol® UH 2593/1 improves popping limit

Addition of Bayhydur® XP 2759 in 2K
Clear coating based on Bayhydrol® A 2651; NCO / OH =1.5
XP 2655 / XP 2759
XP 2655
Crosslinker (7:3)
Dust drying 35’ 27’
Total drying 4h 55’ 3h 05’
Haze 15 9
Gloss 20º/60º 83/90 83/90
Hardness 16 hs 50ºC 131” 168”
Hardness ev.RT 2h/4h/6h 12”/50”/77” 32”/79”/104”
1d/7d 130”/134” 158”/172”
Coffee 16 h 5 5
Wine 16 h 5 5
Water 16 h 5 5
Mustard 16 h 3 3
EtOH 1h 5 5
Bayhydur® XP 2759: The perfect partner to increase hardness and drying speed
Bayhydrol ® UH 2593/1:
popping limit and down-glossing
Semi-gloss formulation, containing 1.5% TS100
Bayhydrol A XP
Bayhydrol A XP
2770 /
2770
UH 2593/1 7:3
200µm 0 0
250µm 0 0
Popping limit
300µm 0 0
400µm 2S1 0
% gloss 60/85º 52 / 80 13 / 30
ISO 4628-2: 0= no bubbles, 5=many bubbles

S1=small bubbles; S5= big bubbles
Addition of 20% Bayhydrol UH 2593/1 improves popping limit and improves down-glossing

Bayhydrol® A 2651: Formulations
Clear coatings with:

 solvent like aspect, wood warmth
 high gloss
 easy down glossing and nice matting effect
 high mechanical and chemical properties
Pigmented systems with:

 High chemical resistance
 High gloss
Bayhydrol® A 2846
XP
Self cross-linking acrylic
dispersion for 1K and 2K
waterborne wood coatings
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Bayhydrol® A 2846 XP
When versatility and performance

matter:
self cross-linking acrylic dispersion
for 1K and 2K wood coatings
• Product useful both for 1K as well as 2K coatings, giving maximal flexibility

and versatility to formulators and painters.
• Self-crosslinking mechanism present in its structure provides enough
resistance to the polymer to deliver high performance also in 1K coatings.
• More economical and simpler 2K systems possible

Application opportunities
Furniture Parquet Joinery
1K 2K
Clear Pigmented
Glossy Matt
Single binder Combination partner

Product highlights
• High versatility, very broad application Bayhydrol A 2846 XP

Solid content approx. 40%
opportunities
Viscosity (23ºC) approx. 50 mPa·s
• Fast drying %OH on solids approx. 1,5%
pH approx. 7
• VOC content < 130 g/l possible
• Good chemical resistance in 1K Low VOC

5
Pot-life 2K 4 Stains Resistance
3
• Excellent chemical resistance in 2K 2
1
• Excellent adhesion on melamine Anfeuerung 0 Solvent Resistance
• Long pot-life in 2K coatings Blocking Fast Drying
• More economical 2K formulations possible Sandability
A 2846 XP competitors

Chemical resistance
Self-crosslinking OH functional PAC dispersion
Bayhydrol®
A 2846 XP
1K 2K
Clear Pigmented Clear Pigmented
IKEA IOS-MAT-0066(7)-R2
   
DIN 68861-1B
  

Positioning in 2K WB systems
Comparing Bayhydrol® A 2651, A 2427 and A 2846 XP in 2K WB coatings
Pot-life
5
A 2651 Low coating cost 4 Low VOC
3
2
Coating cost
A 2427 1
Anfeuerung 0 Stains Resistance
A 2846 XP
Stackability Fast Drying

A 2846 XP
Sandability
A 2846 XP A 2427 A 2651

Film performance

Clear glossy 1K / 2K coating
Clear coating 1K / 2K
Starting point formulation TERO 0200 2K clear
1K clear
(10 % PIC)
Pendulum hardness (König)
% 1 / 3 / 7 d at RT 35 / 60 / 65” 55 / 65 / 70”
16 h at 50ºC 110” 120”
Bayhydrol® A 2846 XP 91,00 Sand dry (T1) approx. 35’ approx. 45’
Dowanol DPM / PnB 1:1 7,40 Total dry (T4) approx. 70’ Approx. 100’
1K Byk 093 0,50 Gloss 20º / 60º / Haze (%) 84 / 91 /20 81 / 90 / 45
Surfynol 110 C 0,50 Chemical resistance on Birch Melamine Birch Melamine
TegoTwin 4100 0,30 Water resistance - 16 h 5 5 5 5
Tafigel PUR 45 0,30 Coffee resistance - 1h / 16 h 5/5 5/3 5/5 5/5
Total 100,00 Red wine resistance - 6 h 5 3 5 5

American mustard resistance - 6 h 5 5 5 5
Bayhydur XP 2655 Ethanol 48% resistance - 1 h 5 5 5 5

2K 5,00
at 80% in MPA Acetone resistance – 10” 5 5 5 5
Component A viscosity: approx. 35”
Viscosity A + B adjusted with 5% of water to 40” Drying and pendulum hardness measured over glass (120 mm wet) at 23ºC and 50% RH.
Solid content 1K formulation: approx. 38% Chemical resistance evaluated on coated birch panel and on white melamine (5=very good; 1=very bad)
Solid content 2K formulation: approx. 40%

Clear glossy 1K / 2K coating
Starting point formulation TERO 0200
Blocking Resistance Sandability
5 5
4 4
3 3
1K formulation
2 2
2K formulation
1 1
0 0
0 2 4 6 8 0 2 4 6 8
Drying time (h) at 40ºC Drying time (h) at RT
Test details: Test details:
- Application: 120 g/m2 wet on leneta foil Application: 120 g/m2 wet on Sapelly wood
- Drying: 15’ flash-off at RT before drying at 40ºC Drying: RT
- Stacking: Face to face for 1h at 40ºC, 100 g/cm2 Sanding: 320 grit sand paper
- Evaluation 5: Best, 0: Worse Evaluation 5: Best, 0: Worse
 No anti-blocking additives/waxes have been used in this test No sanding aids have been used in this test

Pigmented matt 2K coating
Pigmented matt 2K
Starting point formulation TERO 0208
% 2K pigmented matt
Bayhydrol® A 2846 XP 65,40 Pendulum hardness (König), 1 / 3 / 7 d at RT 60 / 100 / 100”

DPM / PnB 1:1 6,00 16 h at 50ºC 110”
Airex 902W 0,60 Sand dry (T1) approx. 40’

Byk 349 0,20 Total dry (T4) approx. 5h 30’
Aquis white 0062 20,00 Gloss 60º / 85º 25 / 40
Ceraflour 1000 2,50 Water resistance - 16 h 5
Aquamat 272 5,00 Coffee resistance - 16 h 5
Tafigel PUR 45 0,30 Red wine resistance - 6 h 5
Total 100,00 American mustard resistance - 6 h 5
Ethanol 48% resistance - 1 h 4
Bayhydur XP 2655 at
20,00
80% in MPA Acetone resistance - 1 min 5
Coating viscosity: approx. 35” (adjusted with 15% of water) Drying and pendulum hardness measured over glass (120 mm wet) at 23ºC and 50% RH.
Solid content 2K formulation: approx 47% Chemical resistance evaluated on coated birch panel (5=very good; 1=very bad).

Blends to adjust properties
Bayhydrol UH 2593/1 is the perfect blending partner:
Down-glossing (30% of silica saving is possible) Drying, hardness and blocking resistance
Formulations based on Bayhydrol A 2846 XP with 1% Acematt TS 100 Formulations based on Bayhydrol A 2846 XP
A 2846 XP /
% Bayhydrol UH 2593/1 0% 10% 20% 30% A 2846 XP
UH 2593/1 (7:3)
20° 23 20 12 10 Acematt TS 100 [%] 1 0,7
% Gloss at 60° 56 52 44 39 % Gloss 60° / 85º 50 / 82 43 / 74
85° 86 84 78 72 Drying T1 / T4 (min) 48 / 90 41 / 80
Pendulum hardness (s)

RT 1d / 4d / 7d 21 / 34 / 38 31 / 52 / 62
Increasing the 16h 50ºC 51 69
amount of Bayhydrol
UH 2593/1, lower Blocking 100 g/cm2 at 40 ºC;
1 5
gloss values are 3.0 h drying at 40ºC
obtained Pencil hardness 4B 2B
5: Best, 0: Worse
Addition of Bayhydrol UH 2593/1 improves down-glossing, hardness, drying and blocking resistance

Results on parquet coating
Bayhydrol A
Bayhydrol Bayhydrol Bayhydrol UH 2557
2846 XP 2K
A 2846 XP UH 2557 / A 2846 XP 7:3
10 % Bayhydur
1K 1K 1K
305
Pendulum hardness (s,König), 1 / 7d at RT 30 / 65 80 / 100 54 / 57 67 / 70

16 h at 50ºC 100 110 60 73
Sand dry (T1) approx. 30’ approx. 40’ approx. 40’ approx. 40’
Total dry (T4) approx. 60’ approx. 80’ approx. 105’ approx. 90’
Gloss 20º / 60º / Haze (%) 80 / 89 / 40 68 / 83 / 40 82 / 89 / 7 84 / 90 / 11
Water resistance - 4 h / 24 h 3/3 5/5 5/5 5/5
Scratch water resistance - 4h / 24 h 5/5 5/5 5/5 5/5
EtOH resistance – 5’ / 30’ 5/5 5/5 5/3 5/3
Scratch EtOH resistance - 5’ / 30’ 5/4 5/5 5/3 5/3
Black Heel Mar Resistance 3 5 3 3
Abrasion Taber CS10 / CS17 –

83 / 91 80 / 90 15 / 4 21 / 20
mg lost after 1000 rev (10N load)
Drying and pendulum hardness measured over glass (200 mm wet) at 23ºC and 50% RH.
Chemical resistance evaluated on coated oak panel (3 x 120 mm wet) ( 5=very good; 1= very bad).
Product not assessed in VOC emission tests
Bayhydrol A 2846 XP could be used in parquet coating:

• in 1K primer
• in 2K topcoat
• as combination partner with a PUD in 1K or 2K systems

Bayhydrol® A 2846 XP / UH XP 2719
Economic parquet coating
Bayhydrol UH Bayhydrol UH 2719
Bayhydrol Bayhydrol
2719 / A 2846 XP 1:1
A 2846 XP UH 2719
/ A 2846 XP 1:1 +10% Bayhydur
1K 1K
1K 2858XP
Pendulum hardness (s,König), 1 / 7d at RT 30 / 65 49 / 83 60 / 110 60/100
16 h at 50ºC 100 85 120 105
Sand dry (T1) approx. 30’ approx. 40’ approx. 37’ approx. 37’
Total dry (T4) approx. 60’ approx. 70’ approx. 55’ approx. 75’
Gloss 20º / 60º / Haze (%) 80 / 89 / 40 84 / 88 / 17 84 / 89 / 21 85 / 90 / 12
Water resistance - 4 h / 24 h 4/2 5/4 5/5 5/5
Scratch water resistance - 4h / 24 h 5/5 5/3 5/5 5/5
EtOH resistance – 5’ / 30’ 5/4 3/3 4/4 5/5
Scratch EtOH resistance - 5’ / 30’ 5/5 2/2 1/1 5/5
Black Heel Mar Resistance 1 1 1 5
Abrasion Taber CS17 –

91 12 37 30
mg lost after 1000 rev (10N load)
Drying and pendulum hardness measured over glass (200 mm wet) at 23ºC and 50% RH.
Chemical resistance evaluated on coated oak panel (3 x 120 mm wet) ( 5=very good; 1= very bad).
Product not assessed in VOC emission tests
Bayhydrol UH 2719 / Bayhydrol A 2846 XP could be used for economic parquet coating, having
better mechanical properties than an acrylic based system.
With addition of hardener excellent properties are obtained.

Outdoor resistance
Artificial weathering resistance according to EN 927-6:2007, 2016 h test, UV and water spray
Natural weathering resistance according to DIN EN 927-3:2007, 12 months exposition in Barcelona
1K Pigmented coating
1K white pigmented 5
1K clear coating
coating
4
Natural Artificial Natural Artificial 3

weathering weathering weathering weathering 2
Gloss retention at 60º 81% 60% 84% 88% 1
0
Yellowing (DE)* 1,9 1,2 13 18
Chalking
Flacking 5 5 5 5 Adhesion
Gloss retention
Cracking 5 5 5 4 Yellowing ∆E 5 – Best
Flaking
Chalking 5 4 - - Cracking 0 – Worst
Not Not 1K clear coating
Adhesion 5 5 5
measured measured
4
Formulation containing HALS. Application: 3 x 150g/m2 on massive pinewood
3
Testing conditions: 24h of condensation / 48 cycles of 3h consisting of 2,5h UV + 0,5h water spray
Total length of the test: 2016 hours (12 weeks) 2
*DE on clear coating is coming mainly from wood discoloration
1
5=very good; 1= very bad
0
Cracking
Bayhydrol A 2846 XP shows good weather stability in 1K
Adhesion
coatings
Gloss retention
Flaking

and further applications
Bayhydrol A 2846 XP can be considered for further application and

substrates in 1K or 2K formulation
Some examples:
• Decopaper foils
• Wall paints
• Plastic coatings: formulated as 1K or 2K shows good adhesion on certain plastics
with Bayhydur XP 2655
• Pocan S 1506
• Makrofol clear
• Plexiglas (only as 2K)
• Composites (depending on specific grade)

Bayhydrol® A 2846 XP in plastic coatings
Waterborne primer and basecoat for composites
 Good direct adhesion to numerous

composites grades
 Low temperature drying and curing: from
Bayhydrol A 2846 XP / UH 650
RT- to 60-80°C
1K WB Primer Adhesion
 Two-coat system and even 2K monocoat
PC/ABS 5B (good)
possible
PC/GF 5B (good)
 Waterbased PU: no solvent attack, no fiber
PC/CF 5B (good)
rising up
PA/GF 5B (good)
PPS/GF 5B (good)

Starting point formulations available
Starting point formulations available for furniture and parquet coatings:
• TERO 0200: 1K/2K clear glossy for furniture

• TERO 0201: 2K clear semi-matt for furniture
• TERO 0202: 1K primer for wood
• TERO 0206: 1K pigmented glossy for furniture
• TERO 0207: 2K pigmented glossy for furniture
• TERO 0208: 1K pigmented matt furniture
• TERO 0209: 2K pigmented matt furniture
• TERO 5460: 1K semi-matt combined with Bayhydrol UH 2593/1 for furniture
• TERO 5461: 1K glossy combined with Bayhydrol UH 2557 for parquet
• TERO 5505: 2K glossy for parquet
• TERO 5600-2: 1K glossy economic parquet coating with Bayhydrol UH XP 2719

Bayhydrol® U XP
2755
Fast drying and high
hardness
covestro.com
Bayhydrol ® U XP 2755:
2K WB PU systems for fast drying
Solvent-free aqueous PES-PUD polyol

 Suited for 2K-WB systems, clear and
Solid content approx. 38%
pigmented, glossy and matt.
Viscosity (23ºC) approx. 3000 mPa·s  Clear dispersion (low particle size)
pH approx. 8
 High reactivity: fast drying and fast
hardness evolution
OH-content [wt.% on solids] approx. 3%  High chemical resistance
Particle Size approx. 30 nm  Good wood grain enhancement
Neutralizing agent DMEA
 Good mechanical properties
 Long pot life
Appearance clear
 Very low VOC formulations possible
 Excellent compatibility with PAC, PUD
 Competitive price
Application fields:
2K waterborne coatings (furniture and parquet)
Especially suited for 2K-WB industrial wood coatings

Bayhydrol® U XP 2755 : coating properties
Coating based on Bayhydrol® U XP 2755 + Bayhydur® XP 2655 (200mm wet film)
Clear formulation Semigloss formulation Pigmented formulation

ALGU 0238 ALGU 0239 ALGU 0240
NCO/OH ratio* 1.5 1.7 2.0
Solid content 37% 37% 45%
T1: Dust drying time RT (200 mm, glass) 48’ 44’ 46’
T4: Total drying time RT (200 mm, glass) 2 h 40’ 3 h 15’ 4 h 45’
Haze 7 - 10
Gloss 20º / 60º 86 / 91 16 / 53 85 / 91
Hardness after 16 h at 50ºC 219” 185” 208”
Hardness evolution RT 2/4/6h 70” / 146” / 167” 26” / 83” / 144” 12” / 84” / 127”
(200 mm, König) 1/3/7d 195” / 202”/ 207” 166” / 166” / 178” 179” / 189” / 186”
Coffee 16 h 5 5 5
Wine 16 h 5 4 5
Water 16 h 5 5 5
Mustard 16 h 5 5 5
Ethanol (48%) 1h 5 4 5
Chemical resistance tested on white melamine panel (5=very good; 1= very bad)
* Starting point formulations optimised for mild drying conditions. Drying at forced temperature allows NCO/OH ratio reduction keeping
same chemical resistance
Drying evolution at different NCO/OH ratios
200mm clear coating based on Bayhydrol® U XP 2755 and

Bayhydur® XP 2655 at different NCO/OH ratios
300
Total drying time at RT (min)
 Increasing NCO/OH ratio

250
involves longer drying time.
200
 Final film properties depend not
150 only on crosslinking ratio but
also on curing conditions.
100
50
0
1,2 1,4 1,6 1,8
NCO/OH ratio
Bayhydrol ® U XP 2755 :
Abrasion CS10 König Hardness
90 250
(mg after 1000 r CS10 10N)
80
70 200
König Hardness (s)

Taber abrasion
60
150
50
40
100 Black Heel Mar Resistance is perfect after
30
3 days of drying at room temperature
20 50
10
0 0
U XP 2755 PAC
Good abrasion due to the whole polyurethane

structure
Product also suitable for parquet application

Self Healing effect
Curing of 2K PU S-H system (RT or forced drying at 50ºC) increases crosslink density with
flexible net bows
C
R O C N Scratching
hydrogen O H
bondings
H O
R N C O
“Plastic Deformation”
urethane groups
Self-healing
60-70°C
H-Bondings generate a
second network with
switchable properties

Scratch Resistance and Gloss
SW 0000
recovery
Steel Wool 0000
100
SW 0000
100 90
90 Initial gloss at 20º
80
80
10 double rubs
% Gloss retention (20º)
70 70
%Gloss Retention (20º)
50 double rubs
60 60
50
50 Reflow 10' hair dryer
40
30
40
20 30
Scotch Brite
10
20 Scotch Brite
0 100
Bayhydrol A 2651 10
Bayhydrol U XP Bayhydrol U XP Bayhydrol U XP
90
2750 2755 2750 / Bayhydrol U
%Gloss Retention (20º)

0 XP 2755 80
PAC 450 / PIC 75 PAC 365 / PIC 75 PAC 76870/ PIC679
60
PUDs have better scratch resistance and
50
reflow ability. 40
New WB S-H system based on Bayhydrol U 30
XP 2750 / 2755 recovers almost the initial 20

10
gloss after 10’ of heating with hair-dryer. 0
Bahydrol A 2651 Bahydrol U XP Bahydrol U XP Bahydrol U XP
2750 2755 2750 / Bahydrol U
XP 2755
Before scratching
Page 91 • CAS ADScratch (50 dr SW0000)
General Industrial Reflow (10’
• WB Woodcoatings • Octhair
2015dryer)
Bayhydrol® U XP 2755
Starting formulations:
ALGU 0237: parquet clear coating
ALGU 0238: glossy clear coating
ALGU 0239: semiglossy clear coating
ALGU 0240: glossy white pigmented coating
ALGU 0241: deep matt white pigmented coating
ALGU 0220: self-healing formulation
Outline
• Introduction
covestro.com
Bayhydrol ® A 242 / Bayhydur:
Knot bleeding isolation primer
Anti-Bleeding primer
Stops knot bleeding
Stops bleeding of redwood, oak, etc
Bayhydrol® A 242 + Bayhydur® 3100

Waterborne easy-to-clean PU coatings:
2K WB based on Bayhydrol ® A 2695
Easy-to-clean: extrem high chemical resistance

Chemical resistance against professional cleaning agents
• Staining resistance similar to

highly crosslinked solventborne
2K PU systems
• Highly resistant to aggressive

liquids
Bayhydrol A 2695 Desmophen 651

5% OH 8% OH
waterborne solventborne

Haptic coatings
Waterborne Soft-touch Coating
 Key Features
 Excellent touch (warm, soft and comfort)
 Matt effect, high value and luxurious feel
 Low odor and environmentally friendly
 Scratch & abrasion resistance
 Applications: Automotive, Industrial, Packaging,...
 PUDs are used in 1K and 2K WB soft touch formulations to improve soft touch

Natural touch wood coating
Highlights
 Natural touch and appearance on wood

 Deep matt coating
 Excellent adhesion
 Excellent chemical and mechanical resistance
 UV protection
 Broad application opportunities: furniture, parquet, interior joinery
 Fast drying, high reactivity and long pot-life
 High wet film thickness is possible: up to 500 g/m2

Natural touch wood coating
Coating properties
OH bearing PES-PUR dispersion for soft touch

OH bearing PAC for high adhesion and chemical resistance
Anionically modified polyisocyante for high chemical resistance
Technical data: Mechanical resistance

NCO/OH ratio: 1.5 BHMR: excellent after 3 d at RT
Solid content: approx. 46% Adhesion: excellent
Pot-life: approx. 7 h Abrasion CS 10, 1kg: 20 mg after 500 rev
38 mg after 1000 rev
Application conditions:
On wood up to 500 g/m2 Optical appearance
Gloss at 60º : < 10%
Drying conditions:
On glass, 45 min sand dry
200 micron wet, RT: 3 h tack free
Parquet
Chemical resistance:
On beech 1b DIN EN 68861 Furniture

Summarizing…
Toolbox of polyols and polyisocianates availables for WB

2K systems for wood coating has been presented.
Different systems:
 Bayhydrol® A 2427
 Bayhydrol® A 2651 / Bayhydur ® XP 2655
 Bayhydrol® U XP 2755/ Bayhydur ® XP 2655
 Bayhydrol® UH 2593/1
 Bayhydur® XP 2655, 305, XP 2759
 Isolation primer, Natural Touch, Soft Touch, Easy-to-clean
Thank you for
your attention
covestro.com

03 WB 1K and 2K Furniture Coatings

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03 WB 1K and 2K Furniture Coatings

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1K & 2K WB

Industrial Wood Coatings DIY

Laws and regulations

Drying speed of wb. systems

Waterborne polyurethane systems for wood coatings

Page 16 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

Page 17 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

PAC emulsion Primary dispersions

Primary and secondary dispersions to meet all wood coating requirements

Polyol Polyisocyanate Solventborne 2K polyurethane

Page 24 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

Page 25 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

• Hydrophilisation level: easiness of mixing, film appearance, chemical resistance

• Hydrophillisation type: chemical resistance

Page 26 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

Perfect „Bayhydur-in-Water Emulsion“

• extremely easy-mixing is possible

Page 28 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

Typical croslinking ratios for a high-class 2K WB system

clear 1,5 1,3

pigmented 2,0 1,7

Mild drying conditions require higher NCO/OH ratio

Page 29 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

Polyisocyanate Polyol- Polyurethane

1. R-N=C=O + H2O R-NH2 + CO2

PET hydrophilized IPDI based Anionic hydrophilized IPDI based

Desmodur Faster drying speed

Anionic hydrophilized HDI based Specially for high-gloss

Page 31 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

 Combination partner for HDI based polyisocyanates

Hardness ev.RT 2h/4h/6h 12”/50”/77” 32”/79”/104”

Page 33 • CAS AD General Industrial • WB Woodcoatings • Oct 2015

Bayhydur® 2858 XP is a universal

Page 35 • CAS AD General Industrial • WB Woodcoatings • Customer Seminar • June 2016

• Supplied in a ready to use form: Bayhydur® 305

70% in PGDA, 500 mPa·s

• Easy mixability in waterborne systems

High chemical resistance even in 4

• Suitable for indoor air quality complaint

• Versatility: for parquet and furniture

Page 36 • CAS AD General Industrial • WB Woodcoatings • Customer Seminar • June 2016

Glossy 2K parquet formulation based on Bayhydrol® UH 2593/1 (fatty-acid modified PUD)

Bayhyhdur Bayhydur® 305 Bayhydur® 2858 XP Bayhydur® XP 2655

Crosslinker dilution 70% in DPGDME 70% in PGDA (s.f) 70% in PGDA

Bayhydur ® XP 2858 is also suitable in 2K WB coatings for PVC formulation based on

Page 37 • CAS AD General Industrial • WB Woodcoatings • Customer Seminar • June 2016

Indoor air quality test according AgBB Scheme 2012

Additional to low emissions you benefit from mild odor

Page 38 • CAS AD General Industrial • WB Woodcoatings • Customer Seminar • June 2016

White pigmented 2K formulation for furniture based on Bayhydrol® A 2651

Bayhyhdur Bayhydur® 305 Bayhydur® 2858 XP Bayhydur® XP 2655

Crosslinker solution 70% in PGDA 70% in PGDA (s.f) 70% in PGDA

Bayhydur ® XP 2858 being an anionic polyisocyanate allows best chemical resistance

Page 39 • CAS AD General Industrial • WB Woodcoatings • Customer Seminar • June 2016

Film (diffusion barrier) Craters and pinholes

Wet film Bayhydur® 2858 XP Bayhydur® XP 2655 Bayhydur® XP 2655

Coating layer is able Perfect surface,

Bayhydur® XP 2858 improves blister free thickness

Page 40 • CAS AD General Industrial • WB Woodcoatings • Customer Seminar • June 2016

Bayhydrol® A 2695 Bayhydrol® A 2470

Coating formulated as KYL 0602 REYE 533-2

Sand dry (T1) 1h 1,5 h

Fully dry (T4) 5h 7h

Pendulum hardness (s, König), 1 / 7d at RT 55 / 80 78 / 134