ACA A ue 34 (NS) (English Version) Instructions: 1. The question paper has four parts. All the four parts are compulsory. 2. Part-A carries 20 marks. Each question carries 1 mark. Part-B carries 8 marks. Each question carries 2 marks. Part-C carries 12 marks. Each question carries 3 marks. Part-D carries 30 marks. Each question carries 5 marks. 3. Write balanced chemical equations and draw diagrams wherever necessary. 4. Use log table and simple calculators if necessary. (Use of scientific calculator is not allowed) PART-A |. Select the correct option from the given choices : (15 x 1 = 15) 1) Which kind of defect is introduced by doping intrinsic semiconductors? a) Dislocation defect b) Electronic defect c) Interstitial defect d) Schottky defect 2) Abinary liquid mixture that forms maximum boiling azeotrope at a specific composition is a) Ethanol + Water b) n-Hexane + n-Heptane c) Benzene + Toluene d) Nitric acid + Water 3) The value of Van't Hoff factor (i) for ethanoic acid in benzene is nearly a) 2 b) 1 c) 05 d) 0 4) Oncharging the Lead storage battery, PbSO,(s) on cathode is converted into a) PbO, b) Pb c) PbO d) Nochange34 (NS) 5) 6) 8) 9) 10) 1 a AON In the Arrhenius equation the factor e tf corresponds to a) Collision frequency b) Proper orientation c) The fraction of molecules with kinetic energy > Ea d) Threshold energy Which one of the following is not applicable to the phenomenon of adsorption? a) AG=-Ve b) AS=-Ve c) AH=-Ve d) AH=+Ve What is the role of NaCN in the separation of ZnS and PbS by froth floatation method? a) depressant b) froth stabiliser c) collector d) reductant On complete hydrolysis of XeF, with water, the product formed is a) XeF, b) XeO3 c) Xe0,F, d) XeOF, Which of the following elements is not regarded as transition element? a) Fe b) Mn c) Sc d) Zn M-—C bond in metal carbonyls possesses . a) lonic character b) Both wand xzcharacters c) _-character only d) lon-dipole forces Identify chiral molecule in the following compounds, a) 2-Bromobutane b) 1-Bromobutane c) 2-Bromopropane 4) 2-Bromo-2-methyl-PropaneUIT L & 34 (NS) 12) When CH,ONa reacts with (CH), CBr, it gives exclusively a) f-Butylmethyl ether b) 2,2-Dimethyl propane c) 2-Methyl propene d) 2-Methyl Propan-2-ol 13) lodoform reaction with NaOl can be used for the detection of the compound a) CHgCOC,Hs b) CH,CHO c) CH,CH,CH,OH d) (CH,)3COH 14) Nitration of aniline in the strongly acidic medium at 288 K yields a) 2,4,6-Trinitroaniline b) oand p-Nitroanilines c) m-Nitroaniline d) 0, mand p-Nitroanilines 15) Which hormone is an iodinated derivative of aminoacid tyrosine? a) Insulin b) Epinephrine c) Thyroxin d) Glucagon Fill in the blanks by choosing the appropriate word from those given in the brackets : (5x1=5) [Radium-226, Anoxia, Norethindrone, Pseudo first order, Diphenyl] 16) Because of low concentration of O, in the blood and tissues of people living at high altitudes, suffer from a disease called 17) Inversion of cane sugar is an example of ——————— reaction. 18) Radon is obtained as a decay product of 49) When Chlorobenzene is treated with sodium in dry ether ———____ ig formed, 20) —___— is a synthetic progesteron derivative, most widely used as an antifertility drug. .34 (NS) ae AOE MU. PART-B Answer any four of the following. Each question carries 2 marks : (4x2 =8) 21) Give any two differences between Frenkel defect and Schottky defect. 22) A'm for NaCl, HCl and NaAc (Sodium acetate) are 126.4 Scm*mol”', 425.9 Scm’mol' and 91.0 Scm?mol™ respectively. Calculate A°m for HAc (acetic acid). 23) What are the two criteria for the effective collisions between molecules in a chemical reaction? 24) Give reason: a) Actinoids exhibit a greater range of oxidation states b) Zr and Hf have the almost identical atomic radii. 25) What happens when Phenol is heated with Zinc dust? Write equation. 26) How is Benzoylchloride converted into Benzaldehyde? Name _ the reaction. 27) What is the role of following chemicals in food? a) Sodium benzoate b) Butylated Hydroxy Anisole (BHA). 28) Why do soaps not work in hard water? PART-C Answer any four of the following. Each question carries 3 marks : (4x 3 = 12) 29) Explain the extraction of ‘blister copper’ from copper matte. Write the balanced equations for the reactions taking place in the convertor, (3) 30) Write the balanced chemical equations with reaction conditions involved in the manufacture of nitric acid by Ostwald's process. (3)ENE " 34 (NS) 34) Comploto the following chernical equations : a) Pb8440,--—-» + 40, b) 550, 4+ 2MnO; +2H,0———»5SO% + 4H" + ©) CygHyy Oy, —Ce Se, —__ 4 44H,0, (14141) 32) a) How is chlorine manufactured by Deacon's process? Give equation. (2) b) Write the structure of Chlorous acid. (1) 33) a) The transition metals and their compounds are known for their catalytic activity. Give two reasons. (2) b) What is Mischmetall? (1) 24) Explain the preparation of Potassium permanganate from MnO, with equations. . (3) 25) Out of the following two coordination entities ; cis — [PtCl,(en),]** and trans — [PtCl,(en),]**. a) Which is Chiral (optically active)? (1) b) Draw the structures of its enantiomers. (2) 26) According to Valence Bond Theory (VBT), explain hybridization, geometry and magnetic property of [CoF,]°~ ion. (Atomic No. of Co = 27) (3)34 (NS) Vv. Answer any three of the following. Each question carries 5 marks : 37) 38) 39) 2) b) a) b) “ M000 PART-D (3x5 = 15) Calculate the packing efficiency in Face Centred Cubic (FCC) Lattice. (3) Potassium metal crystallises in a bcc unit cell with edge length 542 pm. Calculate the density of potassium metal. (2) [Atomic mass of K = 39 g mol”', Na = 6.022 x10**mol™] 450 cm® of an aqueous solution of a protein contains 1.0 g of the protein. The osmotic pressure of such a solution at 310 K is found to be 3.1x10™ bar. Calculate the molar mass of the protein. (R = 0.083 L bar mol™ K~"). (3) State Raoult's law of relative lowertig of vapour pressure. Write its mathematical form. (2) Calculate the standard Gibb's energy (ArG’) for the reaction at 298 K: Zn(S8)+ 2AGiag > 2 Ag(s)+ Znieay [Given : Eten =-0.76V, Ehg'ng = +0-80 VF = 96,500 C mol}, (3) Write the balanced equations for the reactions taking place at anode and cathode during rusting of iron. (2)UENCE TAL AT 40) a) b) 41) a) b) AT 34 (NS) Derive an integrated rate equation for the rate constant of a first order reaction. (3) Draw a graph of potential energy V/s reaction coordinate showing the effect of catalyst on the rate of a reaction. Explain Bredig's Arc method for the preparation of metal sols.’ (3) Write two steps involved in the mechanism of enzyme catalysed reaction. (2) VI. Answer any three of the following. Each question carries 5 marks : 42) a) b) 43) a) b) (3x 5=15) Explain S,1 mechanism of conversion of tert-butyl bromide to tert-butyl alcohol. (3) Give any two reasons for the less reactivity of arylhalides towards nucleophilic substitution reactions (2) Write the mechanism of the following reaction : (3) Conc. H,SO, | 2 t 5 CHp = CHa +H2O C,H,OH 443K » CH2 lo + Ha Identify ‘ an ‘B' in the following equations : (44#4) oe (1) COn (i) (CHs),C-OC,H, Hc, H,0H +B34 (NS) 44) 45) 46) 47) a) b) c) b) a) b) °) a) ¢) 7 WAVE A How is ketone prepared from Grignard reagent and nitrile? Explain with an example. . (2) Explain Hell-Volhard-Zelinsky reaction. Give equation. (2) What is the role of dry HCI gas in the addition of alcohols to aldehydes? (1) Write the equations of reactions involved in the Gabriel Phthalimide synthesis of a primary amine. (3) Complete the following reactions by giving major products. . NaNO,+2HCl 1) OHeNHe —o73K 78K N3CIT NH, P Ht ii) + + (1 #1) Write the Haworth’s structure of Lactose. (2) What is denaturation of proteins? Which level of structure remains intact during denaturation of globular proteins? (2) Name the sugar moiety present in DNA. (4) How is Buna-N prepared? Give equation. (2) Name the monomers of the biodegradable polymer Nylon-2-nylon-6 (2) Write the partial structure of Dacron. (1)