Diagramas de Equilibrio

SISTEMA BINARIO n-PENTANO/n-HEXANO PT(atm) 1
SISTEMA BINARIO ETANOL-AGUA PT(atm) 1

CpAl(cal/mol) 26.83
log10Pvap= A-[B/(C+T)] CpAg(cal/mol) 15.586
CONSTANTES DE ANTOINE CpBl(cal/mol) 18
Compuesto A B C CpBg(cal/mol) 8.026
Etanol 78.37 5.33675 1648.22 230.918 HvA 9216
Agua 100 5.11564 1687.537 230.17 HvB 9718
n Teb( ͦC) P ͦa(bar) P ͦa(atm) P ͦb(bar) P ͦb(atm) Xa Ya

1 78.37 1.0178214534 1.00475958 0.44280552 0.43712292 1 1
2 80.533 1.1083618905 1.0941381 0.48338054 0.47717723 0.40269884627 0.44060815
3 82.696 1.2055384102 1.19006753 0.52703423 0.52027071 0.20912326089 0.2488708
4 84.859 1.3097261348 1.2929182 0.57394839 0.56658282 0.14519615855 0.18772676
5 87.022 1.4213142638 1.4030743 0.62431215 0.61630024 0.09686785094 0.13591279
6 89.185 1.5407062491 1.52093411 0.678322 0.66961698 0.06709665885 0.1020496
7 91.348 1.6683199582 1.64691013 0.73618198 0.72673443 0.04642589668 0.07645928
8 93.511 1.8045878267 1.78142925 0.79810374 0.78786154 0.03599690409 0.06412594
9 95.674 1.949956999 1.92493287 0.86430665 0.85321486 0.01819135024 0.03501713
10 97.837 2.1048894583 2.07787706 0.93501789 0.92301865 0.00826157224 0.01716653
11 100 2.2698621432 2.24073262 1.01047254 0.99750497 0 0
SISTEMA BINARIO METANOL-AGUA PT(atm) 1

CpAl(cal/mol) 26.83
log10Pvap= A-[B/(C+T)] CpAg(cal/mol) 15.586
CONSTANTES DE ANTOINE CpBl(cal/mol) 18
Compuesto A B C CpBg(cal/mol) 8.026
Metanol 78.37 5.20277 1580.08 239.5 HvA 9216
Agua 100 5.11564 1687.537 230.17 HvB 9718
n Teb( ͦC) P ͦa(bar) P ͦa(atm) P ͦb(bar) P ͦb(atm) Xa Ya

1 64.54 1.0134964457 1.00049007 0.24521473 0.24206785 1 1
2 68.095 1.1638190462 1.14888356 0.28694289 0.2832605 0.76842065441 0.88282586
3 71.64 1.3317202091 1.31463002 0.33438853 0.33009727 0.56371284367 0.74107383
4 75.185 1.519224193 1.49972773 0.3882972 0.38331412 0.39341649608 0.59001763
5 78.73 1.7280494294 1.70587308 0.44935257 0.44358595 0.26578550961 0.45339635
6 82.275 1.9600086873 1.93485556 0.51828783 0.51163656 0.17745556818 0.34335089
7 85.82 2.2170100602 2.1885588 0.59588717 0.58824005 0.11693533302 0.25591985
8 89.365 2.5010577314 2.46896124 0.68298724 0.67422235 0.07419398124 0.18318206
9 92.91 2.8142525144 2.77813674 0.78047849 0.77046247 0.04286414868 0.11908247
10 96.455 3.1587921711 3.11825486 0.88930637 0.87789375 0.01901704313 0.05929999
11 100 3.5369715059 3.49158095 1.01047254 0.99750497 0 0
1
0.9
0.8
0.7
0.6
0.5
Y
0.4
0.3
0.2
0.1
0
0 0.1 0.2
0.9
0.8
0.7
0.6
0.5
Y
0.4
0.3
0.2
0.1
0
0 0.1 0.2
0.2
0.1
0
0 0.1 0.2
0.9
0.8
0.7
0.6
0.5
Y
0.4
0.3
0.2
0.1
0
0 0.1 0.2
0.9
0.8
0.7
0.6
0.5
Y
0.4
0.3
0.6
0.5
Y
0.4
0.3
0.2
0.1
0
0 0.1 0.2
A12 1.6383
A21 0.9419
0.9
αAB Hl Hg δ1 δ2 Xa(supuesta)
2102.6671 10437.4748 1 2.5648 1 0.8
1.1682865 1735.95572 10411.4278 1.42089 1.312 0.4
0.7
1.2530424 1641.23099 10412.3744 2.216 1.09 0.2
1.36061535 1636.2582 10425.2726 2.6094 1.05333 0.15 0.6
1.46647409 1640.82967 10437.6255 3.16 1.025 0.1
0.5
1.58013684 1658.16886 10451.3757 3.6 1.0127 0.07
Y
1.70046736 1681.71126 10465.5786 3.955 1.00665 0.05 0.4
1.83497265 1712.92072 10481.6615 3.6 1.0127 0.04
1.95849667 1737.50008 10493.6287 4.6085 1.00111 0.02 0.3
2.09670365 1768.20318 10507.3193 4.919 1.00018 0.008
0.2
1800 10520.6 5.1464 1 0
0.1
0
0 0.1
0.9
A12 1.6383
A21 0.9419 1
0.9
0.8
0.7
αAB Hl Hg δ1 δ2 Xa(supuesta)
1731.6082 10221.9204 1 1.7435 1 0.6
2.27061787 1687.74509 10275.8291 1.0224 1.4848 0.77
2.21513408 1646.11415 10322.328 1.0987 1.29 0.56 0.5
Y
2.21890054 1614.51274 10360.6112 1.2388 1.1573 0.4 0.4
2.2913801 1601.91034 10392.143 1.4305 1.079 0.27
2.42367599 1609.86939 10419.5409 1.6402 1.038 0.18 0.3
2.59735319 1633.3725 10444.3601 1.8422 1.0175 0.12
0.2
2.79839493 1667.11595 10467.0438 2.0263 1.0074 0.075
3.01850533 1707.54555 10487.5597 2.1894 1.0025 0.04 0.1
3.25178572 1752.38677 10505.6208 2.3334 1.0005 0.02
0
1800 10520.6 2.463 1 0 0 0.1
Sistema npentano-nhexano
1 atm
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Curva de Equilibrio Linea de Referencia
Sistema nhexano-nheptano
1 atm
100
95
90
85
T
80
75
70
65
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
X
70
65
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
Sistema nheptano-noctano
1 atm
130
125
120
115
T
110
105
100
95
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
Sistema benceno-tolueno
1 atm
115
110
105
100
95
T
90
85
100
95
T
90
85
80
75
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
Sistema etanol-agua
1 atm
0.9
0.8
0.7
0.6
0.5
Y
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Sistema metanol-agua
1 atm
0.9
1 atm
0.9
0.8
0.7
0.6
0.5
Y
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

1 atm
70
65
60
55
50
T
45
40
35
30
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X,Y
Punto de Burbuja Punto de Rocio
1 atm
100
95
90
85
T
80
75
70
65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X,Y
70
65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X,Y
1 atm
130
125
120
115
T
110
105
100
95
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X,Y
Sistema benceno-tolueno
1 atm
115
110
105
100
95
T
90
85
100
95
T 90
85
80
75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X,Y
Sistema etanol-agua
1 atm
100
95
90
T
85
80
75
1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
X,Y
1 atm
100
95
1 atm
100
95
90
85
80
T
75
70
65
60
1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
X,Y

1 atm
10000
9000
8000
7000
6000
Entalpia
5000
4000
3000
2000
1000
0
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
X,Y
Liquido Vapor
1 atm
12000
11000
10000
9000
8000
Entalpia
7000
6000
5000
4000
3000
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
X,Y
5000
4000
3000
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
X,Y
Liquido Vapor
1 atm
15000
14000
13000
12000
11000
Entalpia
10000
9000
8000
7000
6000
5000
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
X,Y
Liquido Vapor
Sistema benceno'tolueno
1 atm
12000
11000
10000
9000
8000
Entalpia
7000
6000
5000
4000
8000
Entalpia
7000
6000
5000
4000
3000
2000
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
X,Y
Liquido Vapor
Sistema benceno'tolueno
1 atm
11000
10000
9000
8000
7000
Entalpia
6000
5000
4000
3000
2000
1000
0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0
X,Y
Liquido Vapor
1 atm
11000
10000
1 atm
11000
10000
9000
8000
7000
Entalpia
6000
5000
4000
3000
2000
1000
0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0
X,Y
Liquido Vapor
xano
0.6 0.7 0.8 0.9 1
Vapor
tano
0.6 0.7 0.8 0.9 1

0.6 0.7 0.8 0.9 1
Vapor
tano
0.6 0.7 0.8 0.9 1
Vapor
eno
0.6 0.7 0.8 0.9 1
Vapor
a benceno'tolueno
1 atm
0.4 0.5 0.6 0.7 0.8 0.9 1
X,Y
quido Vapor
ma metanol-agua
1 atm
ma metanol-agua
1 atm
0.4 0.5 0.6 0.7 0.8 0.9 1
X,Y
quido Vapor

Diagramas de Equilibrio

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Diagramas de Equilibrio

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SISTEMA BINARIO n-PENTANO/n-HEXANO PT(atm) 1

SISTEMA BINARIO ETANOL-AGUA PT(atm) 1

n Teb( ͦC) P ͦa(bar) P ͦa(atm) P ͦb(bar) P ͦb(atm) Xa Ya

SISTEMA BINARIO METANOL-AGUA PT(atm) 1

n Teb( ͦC) P ͦa(bar) P ͦa(atm) P ͦb(bar) P ͦb(atm) Xa Ya

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Curva de Equilibrio Linea de Referencia

Curva de Equilibrio Linea de Referencia

Curva de Equilibrio Linea de Referencia

Curva de Equilibrio Linea de Referencia

Curva de Equilibrio Linea de Referencia

Curva de Equilibrio Linea de Referencia

Punto de Burbuja Punto de Rocio

Punto de Burbuja Punto de Rocio

Punto de Burbuja Punto de Rocio

Punto de Burbuja Punto de Rocio

Punto de Burbuja Punto de Rocio

Punto de Burbuja Punto de Rocio

0.6 0.7 0.8 0.9 1

0.6 0.7 0.8 0.9 1

0.6 0.7 0.8 0.9 1

0.4 0.5 0.6 0.7 0.8 0.9 1

0.4 0.5 0.6 0.7 0.8 0.9 1

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