Presión 495 mmHg ∆T 0.

25744888 (18 DATOS)

CONSTANTES DE ANTOINE
SUSTANCIA A B C T sat [oC]
Etanol 8.2133 1652.05 231.48 67.8752026
Tetracloruro
de carbono 6.8941 1219.58 227.17 63.2411227 Más volátil

DATOS DEL SISTEMA Fracciones en el líquido Fracciones en el vapor

T[oC] P sat1 [mmHg] Psat2[mmHg]
63.2411227 495 405.351138
63.4985716 499.2576697 409.943203
63.7560205 503.5443283 414.579144
64.0134694 507.8601146 419.259297
64.2709182 512.2051677 423.983997
64.5283671 516.5796271 428.753583
64.785816 520.9836325 433.568394
65.0432649 525.4173239 438.428774
65.3007138 529.8808418 443.335064
65.5581626 534.3743267 448.287611
65.8156115 538.8979197 453.286762
66.0730604 543.451762 458.332866
66.3305093 548.0359952 463.426274
66.5879582 552.6507613 468.567339
66.845407 557.2962024 473.756416
67.1028559 561.972461 478.993861
67.3603048 566.6796799 484.280033
67.6177537 571.4180022 489.615292
67.8752026 576.1875713 495
x1 x2
1 9.547918E-15
0.95232945 0.0476705494
0.90395874 0.0960412592
0.85485332 0.1451466806
0.80497688 0.1950231173
0.75429125 0.245708745
0.70275626 0.2972437424
0.65032957 0.3496704314
0.59696657 0.4030334306
0.54262018 0.457379821
0.48724067 0.5127593263
0.43077549 0.5692245098
0.37316901 0.6268309881
0.31436234 0.6856376649
0.25429301 0.7457069857
0.19289478 0.8071052175
0.13009725 0.8699027543
0.06582555 0.9341744526
0 1
y1 y2
1 7.771561E-15
0.96052077 0.0394792277
0.91956222 0.080437784
0.87706243 0.1229375662
0.8329562 0.1670437995
0.78717474 0.2128252621
0.73964547 0.2603545296
0.69029176 0.3097082392
0.63903262 0.3609673772
0.58578241 0.4142175903
0.53045048 0.4695495244
0.47294081 0.5270591936
0.41315162 0.5868483822
0.35097492 0.6490250832
0.28629602 0.7137039774
0.21899304 0.7810069583
0.14893629 0.851063706
0.07598768 0.9240123177
0 1

Ya vs Xa
1.2
Ya

0.8

0.6

0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Xa
 ^

T vs Xa
69
T [oC]

68
67
66
65
64
63
62
61
60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Xa

Pi vs Xa
600
Pi [mmHg]

580
560
540
520
500
480
460
440
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Xa
 Constantes de Antoine

componentes Comp A B
Tetracloruro de carbono 1 6.8941 1219.58
Etanol 2 8.2133 1652.05

Determinación de las constantes de Van Laar para el azeótropo

T= 67 °C γ1 = 5.40939
P= 495.0 mmHg γ2 = 11.09153
x1 = 0.4 ln γ1 = 1.68814
x2 = 0.6 ln γ2 = 2.40618
P1⁰ = 91.51 mmHg A12 = 12.96876
P2⁰ = 44.63 mmHg A21 = 2.61940

T vs Xa
69
68
67
66
65
64
63
62
61
60
0 0.2 0.4 0.6 0.8 1 1.2

Ya vs Xa
1.2000

1.0000

0.8000

0.6000

0.4000
1.0000

0.8000

0.6000

0.4000

0.2000

0.0000
0.00E+00 2.00E-01 4.00E-01 6.00E-01 8.00E-01 1.00E+00 1.20E+00
C Tmin Tmax
227.17 -23 76.5
231.48 -114.1 78.37

x1 x2 T [°C] γ1 γ2 P1 [mmHg] P2 [mmHg]

1 9.55E-15 63.2411227 1.0000 13.7274 495.00 36.06
0.95232945 0.04767055 63.4985716 1.0013 13.7237 494.34 36.07
0.90395874 0.09604126 63.7560205 1.0060 13.7109 492.05 36.10
0.85485332 0.14514668 64.0134694 1.0154 13.6852 487.52 36.17
0.80497688 0.19502312 64.2709182 1.0315 13.6418 479.90 36.29
0.75429125 0.24570875 64.5283671 1.0575 13.5733 468.09 36.47
0.70275626 0.29724374 64.785816 1.0985 13.4694 450.61 36.75
0.65032957 0.34967043 65.0432649 1.1632 13.3146 425.55 37.18
0.59696657 0.40303343 65.3007138 1.2671 13.0865 390.65 37.83
0.54262018 0.45737982 65.5581626 1.4410 12.7510 343.52 38.82
0.48724067 0.51275933 65.8156115 1.7517 12.2579 282.58 40.38
0.43077549 0.56922451 66.0730604 2.3687 11.5331 208.97 42.92
0.37316901 0.62683099 66.3305093 3.8140 10.4752 129.78 47.25
0.31436234 0.68563766 66.5879582 8.2292 8.9682 60.15 55.19
0.25429301 0.74570699 66.845407 29.0215 6.9527 17.06 71.20
0.19289478 0.80710522 67.1028559 222.1396 4.6092 2.23 107.39
0.13009725 0.86990275 67.3603048 4343.0187 2.5284 0.11 195.78
0.06582555 0.93417445 67.6177537 104987.2875 1.3287 0.00 372.54
9.55E-15 1 67.8752026 428806.5985 1.0000 0.00 495.00
 y1 y2 y1 + y 2
1.0000 0.0000 1.0000
0.9511 0.0035 0.9545
0.8986 0.0070 0.9056
0.8419 0.0106 0.8525
0.7804 0.0143 0.7947
0.7133 0.0181 0.7314
0.6397 0.0221 0.6618
0.5591 0.0263 0.5854
0.4711 0.0308 0.5019
0.3766 0.0359 0.4124
0.2781 0.0418 0.3200
0.1819 0.0494 0.2312
0.0978 0.0598 0.1577
0.0382 0.0765 0.1147
0.0088 0.1073 0.1160
0.0009 0.1751 0.1760
0.000029955 0.3441 0.3441
0.000000627 0.7031 0.7031
0.000000000 1.0000 1.0000
 Presión 495 mmHg ∆T 0.51489776 (9 DATOS)

CONSTANTES DE ANTOINE
SUSTANCIA A B C T sat [oC]
Etanol 8.2133 1652.05 231.48 67.8752026
Tetracloruro 68

T [oC]
de carbono 6.8941 1219.58 227.17 63.2411227 Más volátil 66

64
DATOS DEL SISTEMA Fracciones en el líquido Fracciones en el vapor
T[oC] P sat1 [mmHg] Psat2[mmHg] x1 x2 y1 y2 62
60 443.821069 351.156879 1 0 0.89660822 0.10339178 60
61 459.140253 367.180488 0.9 0.1 0.83480046 0.16519954
61.5 466.955835 375.421548 0.8 0.2 0.7546761 0.2453239 58

62.5 482.903955 392.373824 0.7 0.3 0.68289448 0.31710552 56

63 491.038498 401.089776 0.6 0.4 0.59519818 0.40480182
54
65 524.670151 437.608776 0.5 0.5 0.52996985 0.47003015
67 560.100498 476.895573 0.4 0.6 0.45260646 0.54739354 52
61 459.140253 367.180488 0.3 0.7 0.27826682 0.72173318 50
66 542.156363 456.89606 0 1 0 1 0 0.1 0.2

Y vs X / CCl4
1
Y

0.9

0.8

0.7

0.6

0.5 Ytetrac vs Xtetrac

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X
 T vs composición
68
T [oC]

66

64

62

60
T vs Xa
58 T vs Ya

56

54

52

50
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Composición

P vs Xi
600
P [mmHg]

550

500

Pi vs Xi
450
Column B

400

350

300
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Xi
 Constantes de Antoine

componentes Comp A B C
Tetracloruro de carbono 1 6.8941 1219.58 227.17
Etanol 2 8.2133 1652.05 231.48

Determinación de las constantes de Van Laar para el azeótropo

T= 67 °C γ1 = 5.40939
P= 495.0 mmHg γ2 = 11.09153
x1 = 0.4 ln γ1 = 1.68814
x2 = 0.6 ln γ2 = 2.40618
P1⁰ = 91.51 mmHg A12 = 12.96876
P2⁰ = 44.63 mmHg A21 = 2.61940
 Tmin Tmax
-23 76.5
-114.1 78.37

x1 x2 T /°C γ1 γ2 P1 /mmHg P2 /mmHg y1 y2

1.00 0.00 60 1.0000 13.7274 443.82 0.00 0.8966 0.1034
0.90 0.10 61 0.9450 44.6256 390.49 1638.56 0.8348 0.1652
0.80 0.20 61.5 0.8662 75.6298 323.59 5678.61 0.7547 0.2453
0.70 0.30 62.5 0.8721 75.6576 294.80 8905.81 0.6829 0.3171
0.60 0.40 63 1.0919 50.5822 321.70 8115.20 0.5952 0.4048
0.50 0.50 65 1.9249 25.5897 504.96 5599.14 0.5300 0.4700
0.40 0.60 67 5.4094 11.0915 1211.92 3173.70 0.4526 0.5474
0.30 0.70 61 27.4394 4.6635 3779.56 1198.64 0.2783 0.7217
0.00 0.00 66 1.0000 1.0000 0.00 0.00 0.0000 1.0000
y1 + y 2
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
 Tetracloruro de carbono - Etanol (P = 495 mmHg)
1.0

y1
0.8

0.6 Ideal

Margules

Van Laar

0.4 y=x

0.2

0.0
0.0 0.2 0.4 0.6 0.8 1.0

x1