Printed Pages: 03 ‘Sub Code: BAS- 102 Paper ta: [233014 Roll No. Lit 1 B. TECH. (SEM I) THEORY EXAMINATION 2022-23 ENGINEERING CHEMISTRY Time: 3 Hours Total Marks: 70 ‘a 03 wee te: 70 Note: 1. Attempt all Sections. If require any missing data; then choose suitably. 2. The question paper may be answered in Hindi Language, English Language or in the mixed language of Hindi and English, as per convenience. shes 1. wit wet or Gere ATT fA wer A, rae Ser wr Teta 7 a TI Refer ¥ Sagar Set KAT: APTA WEA BY Ect BE 2. met or aR BF og Braga fx an, aiteh are sear fea wd ofttohy DY fatter arar eor eT feet oT wera BH SECTION A 1. Attempt aif questions in brief. 2x7=14 Pret eh wet or dads 4 aR AI 9 (a) On the basis of MO theory cage ont order of NO. Will NO be paramagnetic or diamagnetic? tio rain arr No Tue Ara AE No BT 6 vfrgerata . (b) What are Chiral Drugs?’ See Drugs. a fre grr ae ea shih cere ae Vv (©) Give important apni is of electrochemical series. Cow Regge cra IR ree agree FAA XN (® A water sample? found to contain 40.5 mg/L Say 14.6 mg/L mg/L. NaCl. Mg(HCO3); 22.2 mg/L CaCl; 24 mg/L MgSO, Calculate the temporary and permanent hardness of, Ser sample. ‘WH UF Ba A 40.5 mg/L Ca(HCOs)2; 14.6 my 1COs)p; 22.2 mg/L. CaCly; 24 mg/L MgSO, and 18mg/L NaCl meat ST ST ore TR RU GSA SATO BE Ss (©) Discuss the preparation and uses of PTF, Pree #1 Prafer wfarar srevaede (Q) How does Gross Calorific Value gi@}i¥om Net Calorific Value? aoa Seah on, Ya Batt ay eine (g) What are Chromophores an hromes? Give examples. sito ae ota eT a A‘ section a 2. Attempt any three of the following: 7x3=21 Pa Pret de wel or vere SET (a) Describe different types of liquid crystals. Discuss the applications of Liquid crystals. fafa mere a freee ar eka a Ps freee ay orga aa wk QP23DP2_010 | 20-03-2023 [Link] | [Link](©). What is Atropisomerism? Give five examples of compounds showing optical ial earns par ate cna aa — Sulasaemae — Explain the a and hardening of cement with relevant chemical reactions involved during the process. vim dhe a ae rea ara 5 aT AS eT SH HANT warerst Explain the stages involved in production of biogas from cattle dung. Compare the impact of use of biogas and coal onthe environment. the tarda gare a tha eet A aren aif ofa aT SBA soe wad geri © ( (©) What are organo metallic compounds? Discuss the preparation of Grignard Reagent Predict the final product obtained when CaHsMgBr reacts with CH GR [Link] (Hn (HCO? 5 seniors aa era can qoarcece ees ifm see () HCHO (i CHSCHO Gi (CH1),C0? SECTION C Attempt any one part ofthe following: 9 Tx197 Fra a feet cw oer ar oan aie) NS (@) Describe the structure and. sone ‘of Graphite and Fullerenes. Explain gu” ams for electical and Iu Properties of graphite, +) er preg nf ala ae Hore bea © ee ao N, Discus the ea te apnea fran on we one rear fees Tx1=7 Fre Pet We Se oT Ga fie @ (@) Why is TMS used as an intemal standard in NI scopy? Th ‘compounds A and B have molecular fen ‘The NMR reat these isomers gave the following data: : Isomer A:6 130(9119); 57.28 (SHi,s) Isomer B: 6 0.88 (6H, d); 81,86 (1H, ¥ Giving reasons assign the ee ie in on oe ian ee) Reamer US goeiret tama ratte a Ta RRR A: 1 ns be ) Stn tags baie ‘SH, s) MRT B: 50.88 (61 i weg wees B87 26H,5) (6) G) Explain the bas Bs Se Figen con NR seater © troscopy. What isthe significance of (li) Identify the chromo, phi roups a Sa Bo en (0 RESTON eRe ahora ate heh Are arma (ii) UV ® HEARN Meena eg wpa cma teats QP230P2_010 | 20-03-2023 [Link] | [Link]5. Attempt any one part of the following: Pra 42 fart UH wer FT aR ATT (@) _ Discuss the mechanism of electrochemical theory of corrosion by absorption of oxygen. What effect will increased oxygen supply have on such corrosion? How can corrosion be minimized by proper design? iti Be orestton rer deren Bs fg rea Farha a farenraea aA aa AIT Qa Gre asters ef at eae ra SMT GPa PETE GTI we wy BS oT fearen eae? (b) Discuss the differences between anodic and cathodic metallic coatings. Explain the processes of Galvanizing and Electroplating? What will happen if an iron ship travelling in the sea is attached through an insulated metallic wire toa Tx1=7 small sheet of magnesium? te she tafe ute dt seg crate Acree AR Ta woot oresa wy ee, OR aI TA Tee ene ETA surg are Bre a Hehe aA Uw Ore ae @ wig Fea TE? 6. Attempt any one part of the following: qx1=7 fr 48 fret ww wet aT aR STL (@) Explain the zeolite process of water softening. What are the advantages and limitations of this process? Calculate the amount of lime and soda required for the treatment of 10,000 litres of water whose analysis is as follows (in mg/L): Mg(HCO3)=73; CaSO,=102; MgCh=95; MgSO.=24; Ca(HCOs).=121.5; NaCl= 55. re or gee aA Paste Biter a: Fa ARPT By st ag ae S 10,000 tee arf ee Fa he eer eA a a OTA Frere FART TA WERE (mel Fy: Ve ® Mg(HCO3),=73; CaSO4=) QQ igCl=95; MgSO.=24; caconsy NaCl= 55. (b) Explain the different pf pen that are determined in the proxi SLératysis of coal. On burning (92 of a solid fuel in a bomb calorimeters ‘mperature of 3300g of warpRereased by 2.42°C. Water equivalent dNMlorimeter and Intent heat of steam ae 385.0g and 587. Dea, respectyay NC the fuel cntins 0.7% hydrogen, calculate its GCV and NCV. aoe a a hg es oe ew eben 0.92 IT Bea SUA ATA Ty 3300 BA OFA aT ATT, aq FIT Bl Ser ST ore Grate oh 4g FA TI GIT HAT: 385.08. cally & aratO1 are fer A 0.7% BES, ch Us GCV SIRNCV Bt 1 7. Attempt any one part of the following: SV ax1-7 Pre AA POAA aH me a eee A YY (a) (i) Differentiate between Cigig-Growth and Step Growth polymerization. ir «uttanization of rubber. Describe the preparation, (ji)Outline the process 4 important properties aff ‘or W roar. 1 ote eae FHT iy, THR Beare Apo BA VTA Tega BHAA Bye TAT aT HTT BT eT, seagate oe TAT wT (b) (i) Differentiate between Thermosetting and Thermoplastic polymers. Gi)Giving examples write a brief note on conducting polymers. aetna aan evr da Src wt iy * Tepe agereeT Ue TUTE AA BR UH Uifesea Fecha QP23DP2_010 | 20-03-2023 [Link] | [Link]