SS-41-Chem. | vadtentbat & fre area Prget : GENERAL INSTRUCTIONS TO THE EXAMINEES : (1) veer elven srr wer aC arate: arfrareia: fer | L Candidates must write Virst his / her Roll No. on the question paper compulsorily. Q) wie we sifted 1 All the questions are compulsory. @) rete waa a Tae SG Te gfReeHT HF fers | Write the answer to each question in the given answer-book only. sS-41-Chem. [Turn over@) So) © M (8) 2 fret ome ws far ahd an ws aera ed | For questions having more than one part, the answers t written together in continuity. ‘0 those parts are to be wea & fect @ sist waiaer F feet waar A aR/siac/federare sere ah eT | SEER If there is any error / difference / contradiction in Hindi & English version of the question paper, the question of Hindi version should be treated valid, we or Sur fore @ a wer aor sorties area Fer | Write down the serial number of the question before attempting it, weiter sie ae erga? | Weightage of marks for the question is as follows. we yaden wetter Sea yes WA) Het i A uS-31(A) | 1 (tox), 2to ll (29° 1 20 we-a(B) 12015 “ea 2 8 wwe-a (C) 16 to 195% 4 3 2 ws-<(D) 20,to 21. 3 4 8 waus-4 (E) 2216 23 2 4 8 RAHAT 16S 23 ew stiches Prewed g | Question No. 16 to 23 have internal choice. $S-41-Chem.3 qs —H SECTION-A 1. Bair weet Fea ma at Rapes cor ae at eR fea Ft feiflae — ee Write the answer of following multiple choice questions in the given answer book. @ Pefetaa ta safe sere (31) NaCi(s) (@ CHS) (@) SiO,(s) (@) CCi,(s) onic solid among the following is~ 1 | (A) NaCKs) () CH,(s) (©) Si0,fs) @) CCi(s) Gi) Wace Rar a aor fran weft Het are SraTeRt faery (&) Bria + Ger (a) thas + Wier (a) Basie + ae Sgacitags (@) Fe + eelaRTis ar ‘The pair of non-ideal solution exhibiting negatiye/deviation from Raoult’s law is - 1 (B) Acetone + Ethanoke. (©) Methanol + Cafbbi tetrachloride (D) Water + Hydrochloric acid thanol + We (A) Methanol + Water ace (iii) fre aH HTT 2 (#) Sm! (@) stm (&) stmt @ Sm ‘The unit of specific conductance is - ; (a) Seu ®) stm © sim! ) sm (ivy Peter atte saftefinar & Ser fresh gang & (a) mol L-1s* @ st! (@) mot! ist (@) mol L* ‘The unit of rate constant of second order reaction is - 7 (A) mol L's @®) sI (©) mort Ls! () mol Lt SS-41-Chem. [ Turn over4 (vy) Prefaftas 3 8 aoratind siege aie 2 (a) freee © (@) wrt (a) TiO, (®)AL,0,xH,0 Negative charged colloidal sol among the following is : 1 oJ (A) methylene blue (B) starch , (©) Tio, () AL,0;xH,0 (vi) Falftrs Pagaesonercna ater Ta a (@) F (@) cl (@) Br @ 1 ‘The element having maximum electronegativity is - 1 (A) F (@) Cl (C) Br @) 1 (vii) Peafertiad 4 2 sfergachia ara : (3) Mn?* (a) cu A, (a) cul (@) Fe Diamagnetic ion among the following is») ” 1 (A) Mn?" (B)_ Cu : (©) cult WY Fe (viii) K,[Fe(C,0,)5] a4 Feat arian aren ® é (@) 42 * (a) 43 (@) +4 . (@) +6 Oxidation state of Fe in complex K3[Fe(C,0,)s] is - 1 , 2 @®) 3 © +4 @) +6 (ix) seit 3 Reto sear & af ars TTY oH apts ae 2 (H) sp? (@) sp? (@) sp (2) sp3a2 Hybridized state of carbon at ty ridized state of carbon atom bonded to halogen atom in chlorobenzene a» ®) sp : (C) sp (D) sp3a2 go-41-Chem. a5 @ Prafiftaa da as a aire satire aeraaaa caters ? (a) 2-Sfreniita (@) =g-1-84 (@) #R-2- (@) site Which of the following compound shows geometrical isomerism ? (A) 2-methylpropene (B)_ but-1-ene (©) but-2-ene (D)_propene we 2S 8 Hae Ue laa ahhre | Q.2—8 : Answer the following questions in one line : | 2, ferracianes recat da & fore srefia sao 3 a ferflae | | Write the value of axial angles for orthorhombic crystal system. 1 3. gafterft aciigs aor as ws saree fee | Write any one example of lyophobic cite EY 1 4. Malar (Z = 64) Tae fetter, | Write correct electronic cétffiguration of Gadolinium (Z= 64). 1 5. srgefira acer TUPAC 774 ferfre | Write IUPAC name of diethyl ether. 1 6, Siardargs ar Tae ae fafa | Write chemical formula of semicarbazide. i! 7. aafietets aiftiiren ar carafe aettecor ferftrg | Write chemical equation of carbylamine reaction. 1 8. sits avira ‘B’ sect sara aati ce al cals aren fara ear | Draw a diagram showing plane of symmetry present in the letter “B’ of English 1 alphabet. SS-41-Chem. [Turn over6 far: seen a 1 da, wee yeni fafac | Note: — Write answers of question nos. 9 to 11 in answer book. 9. aaa a atte varate veel ar aah fem weed 1 Homogeneous mixture of two or more chemical substances is called 10. frrafafaa carafe after faa eons aft of Aire ; C¢H,OH + CCl, + 4KOH —> +4KCI+2H,0 Fill in the blank in the following chemical equation : CgH5OH + CCl, + 4KOH —> +4KCI+2H,0 LL, wal Bete area wt 140 °C wen! faba sen 8 at ae Psfettgpa ata wan? When maleic acid is heated at 140 °C then on deilavon it forms we - 4 SECTION -B 12, Seber het fara A aera BAT | Explain Frenkel defect withthe help of diagram. 2 13. 5.0 g eifeam aeitags Bt et Fate 250 mL Ae aE aT | faery Fears whee ata AIT | 250 ml. solution is prepared by dissolving 5.0 g of sodium chloride in-war Calculate the mass — volume percentage of the solution, werd 14. (1) 3d-Dehh Ss sry oat Ht ger Cr Cu fad sme Safa a a sera are? (a) f-seites aril ot goin ger cea wel sper TT z 2 (a) Why the value of second ionization enthalpy of Cr ang ¢ : cs compared to other elements of 3d series ? mere: higher as (b) Why block elements are called rare earth element 9 : 1+1=2 S-41-Chem- i7 15. (&) war Sar 2 wa arggasie ar ste Zn Ua Veslelfers NaOH St saferfa F (a) @ (b) (@) @) @ (b) (© (a) (a) (@) (a) (b) © SS-41-Chem, SUT Ses 2 Taras alee ATT | Uicia Ht ape aos ART | ‘What happens when reduction of nitro-benzene is carried out in presence of Zn and alcoholic NaOH ? Give chemical equation. Draw resonating structures of aniline. 1+1=2 ws-a SECTION -C Write definition of adsorption, What happens when electric current is passed through a colloidal sol ? Draw a labelled diagram of electro-dialysis method. wa1/OR srasiteor A afore ferftee 1 gar thar 8 xe Bee Blot Bega araerea freer Ta 8 ? aiden a areata 1TH Fer war | Write definition of absorption, ‘What happens when an electrolyte is added to colloidal sol 2 Draw a labelled diagram of Cottrell smoke precipitator. [Turn over8 17. (3) [Co(NH,),JC/, Hye wt TUPAC ATH ferfare | (@) reise Gd arate den 8 fate Ahr | (a [Ni(CN),)> 4a Ser ar Safire fea saree | (@)_ Write IUPAC name of complex [Co(NH;),]Cly. (©) Differentiate between coordination sphere and ionic sphere, (©) Draw the geometrical diagram of complex ion [Ni(CN),?-, Bities waaA/OR ( K4[Fe(CN)¢] age #1 IUPAC a4 faftae | (=) drtdfen wi hen doc ike (@) [Co(NH,).)>* aaa ser aa Sakina fea serge | (a) Write IUPAC naine of complex K4[Fe(CN),] (b) De homoleptic and heteroleptic complexes, (©) Draw the geometrical diagram of complex ion [Co(NH)¢)>* 18. (3) feat ar deen aa fefiar | @) Preafercn carats eet et aol fife ee per erg ar aH fea ; ; a @ CH,-CH,-oH "> 573K (ii) CH; —CH, -1+ Na-O- CH,~CH,—> s-41-Chem- iNSS-41-Chem. » (a) Write structural formula of glycerol. (b) Complete the following chemical equations and write the name of major product : (i) CH;—CH)~ a 73 K (i) CH; -CH, ~I+Na~O- CH,-CH; —> 14253 aaat/OR (a) Urata rergciiet aor eer Ferhat | (a) reafeaa craraies aoftarcit at got fre we ere seme sr a Feet cH. >\cH-on > @ CH;/ 573K ce 0" (ii) 2C,H eae (a) Write structural formula of ~ lene glycol. Complete the following chemical equations and write the name of major (b) product : CH. cee Sou <_<" _s CH; 573K AbOs (i) 2CH;OH (any wrens ane ars rar fr Bases Ager Has raat wit eta @ 7 (a) eared SA er eae ee HT TTR RHT | [ Turn over10 (a) Why formaldchyde is more reactive than acetaldehyde towards nucleophilic addition reactions ? (b) Explain Hell — Volhard — Zelinsky reaction with the help of chemical equation. 142=3 ¢ sea /OR (a) Wers seer aro Bhlfesergs sat al saeT ST EAT 7 (a) he aftGean at Taras anttrn At aeeKT a SAAT | (a) Why formaldehyde cannot be prepared by Rosenmund reduction ? | (b) Explain Schmidt reaction with the help of chemical equation. wWE-e SECTION -D 4. 20, (oH) aren tire Hate oe a aroha a rear ween Pa | (@) a zn wags ® fore ars sage fee wa — 0.76 V Bare ae artaeoweo Fara ot ora aS |” (@) 298K % 0.010 M KO) fee 3 arene 0.00141 S cm! @ | $a tite -arerapar $1 TFT HAAR | (@) Write the chemical equation of reaction taking place on the anode in the process of corrosion. (b) If the value of standard reduction potential for Zn electrode is — 0.76 V then calculate its standard oxidation potential. (©) The conductivity of 0.010 M KCI solution is 0.00141 § cm-! at 298 K. Calculate its molar conductivity. 14142=4 weaT/OR gg-41-Chem.21. u (@) darren At weer Halts we ata arett sabre ar Tera etter ferry | (a) af Mg saadts & fore are srraen fare apr a — 2.37 V @ al ae aati fae A or Ase | (@) 298 K WO. M KCI faere @ Ht area Set aor wf 100 SiH e 1 Bet feria ar after Ahire | (Rare — Kcr Perera ft Tea = 0.0129 S cme!) (a) Write the chemical equation of reaction taking place on the cathode in the process of corrosion. (b) If the value of standard reduction potential for Mg electrode is ~ 2.37 V then calculate its standard oxidation potential. (c) The resistance of a conductivity cell filled with 0.1 M KCI solution is 100 ohm at 298 K. Calculate the cell constant. (Given that — conductivity of KC/ solution = 0.0129 § em!) (a) ri \ (@) CH,CHO()—> cng aq an fram 1 =k [(CH,CHOP? aver sare 3s Fre afte ot ine et Se Frei ot wars Fea 1 (a) WAAR saffron Ra athens: A aries ATTA 0,02 mol Lot 8 TAT Rares aA 2 x 10-3 mol L-Is-! Rat ga ral ATT HIATT | a a-x (a) Draw a graph between log =~ and t for first order reaction. (b) For the reaction CH,CHO(g) —> CH,(g) + CO(g), rate law is rate = k [CH,CHOP? Write the order of reaction and unit of rate constant for the above reaction. (©) The initial concentration of reactant for zero order reaction is 0.02 mol L+ and ‘value of rate constant is 2x 10 mol L~!s™ then calculate its half life. 1+1+2=4 wat/OR SS-41-Chem. [Tora over: 2 (a) sem sie siftiBrar% fore log (ax) wi theme sHite AEE | (3) _2N0s(8) —> 4NO,(g) + 0,(g), sifiBren Bq Se Prem ‘1 =k [N,0,]! ac ata shes win ieee \ (a) aerate atiinar 2g sitters A sities wigat 0.2 mol L-! 2 wer geht meg, 10 s 8h safwer 35 Ser Frei ot ora aE | (a) Draw a graph between log (a — x) and t for first order reaction (b) For the reaction 2N,O5(2)—+ 4NO,(g) + Op(g), rate law is — rate = k [N,Os]} Write the order of reaction and unit of rate constant for the above reaction. (©) The initial concentration of reactant for zero order reaction is 0.2 mol L~! and its half life is 10 s then calculate the rate constant for the reaction, WE-q section=E 22. (af) faean aor arate aa feta | >" (a) Brrad: sepe AS aad aor Hastert & | as wa TET AAT | (a) Prete create enteric: (@ NaNO, +180, (i) H,S+Ch—> (@) Write chemical formula of gypsum. (0) Generally noble gases are least reactive. Give any one reason. (©) Complete the following chemical equations @ NaNO, +H,S0,—> (i) Hys+Ch— 14142=4 3aT/OR 56-41-Chem.13 (@) War can ar carats ag fear | (a) aeh-1g 35 aed a seq Aa Baer eT TAT R | ET ATE | (a) Preaferttac rearates enftarctl at yet fee : oO pay ii) Cl, +H,O— (a) Write chemical formula of Epsom salt. (b) Elements of group — 18 are known as noble gases. Give reason. (©). Complete the following chemical equations : (i) Bags) Temperature hyo (i) Ch+H,0— amie en @ 9g, 00% @ mee Be eat met (a) arate creas eae at eet =I aw () 2NaN,—— : CuCl ay ATTCEE (ii) 4HC/+ 02 Ee (a) Write chemical formula of copper pyrites. (b) The value of ionization enthalpy of noble gases are very high. Give reason, (©) Complete the following chemical equations = Temperature, (i) 2NaN3 . 5 CuCl, (ii) 4HCI+ 92" 993K SS-41-Chem, | Turn over23. ss-4 14 (a) Bera aeitags ar eT ga Patan | (@) Prafafasd after a si attire & vfs afiraticn & aed aa F craters fire : CH, w CH; — CH, ~C/, CH; -CH-CH;, CH,- C -CH; by br . (a) Refer aafirtaeer a Terai, eefiesr A aera a AAT | 1+14+2=4 (a) Write structural formula of allyl chloride. (b) Arrange the following compounds in increasing order of reactivity towards Syl reaction : ‘he CH, -CH)-Cl, CH, — fe CH, CH; - Cy CH, J cL kr (©) Explain Fittig’s reaction with the help of chemical equation. wT /OR, (a) auger actrees reer Ferre 7 (@) Prafefan atest a s.2 oifirar a ft aftearetcrat 3 eat am H arafera ahi : ‘ed cH; CH, —CHi,~ Br: CH ~ CH CH, CH — c -CH, Br Br (a) Sesrren afi Br Terabe, after Ht ere a AAT | (a) Write structural formula of vinyl chloride. (b) Arrange the following compounds in increasing order of reactivity towards ‘Sy2 reaction : CH; i CH, - CH, -Br, CH; -CH~CH,, CH, - i -CH, | Br Br j-Chem.15 (c) Explain Sandmeyer’s reaction with the help of chemical equation. aaa1/OR (a) SPreractags ar eer a fafa | (a) Pratt atfrat at airerea steers sii Brersit & sfe oaftefararetterar agit an t crafera shite : CH,-CH,-Ci, (©)-Cl, (©) CH,CI (a) Rest ar a ee (a) Write structural formula of benzyl chi iS (b) Arrange the following components order of reactivity towards nucleophilic substitution reactions : CH,-CH,-Ch (©)-Cl,’ (©) CH,CI (©) Explain Finkelstein reaction with the help of chemical equation. SS-41-Chem.go-at-chem