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Semester- I

Practical (physical Chemistry)

(Core Course_ IV)


Full Marks_ 50
Credits_S
Any one experiment- 30 Marks

1. Water equivalent of calorimeter


and determination of
(i) Heat ofsolution ofpotassium nitrate
(ii) Heat of neutralization ofstrong
acid and strong base.
(iii) Basiciry ofpolybasic acids.
2' Determination of rate constant
of hydrolysis of methyl acetate
in acid medium.
3. The study ofsaponification ofethyt
acetate by sodium hydroxide
and
determination of rate constant.
4. To determine the distribution
coefficient of
(i) Acetic acid
(iD Benzoic acid
Between water and benzene
by partition method.
5. Determination of specific and molar
rotation of sucrose in different
concentrations and to determine
the concentration ofgiven
solution.
6' Determination of rate constant by inversion
of cane sugar by polarimetrically
7. Determination of
(0 Dissociation constart ofacetic
acid.
(ii) Acid-basetitration.
(iii) Solubiliry product of sparingly
soluble salt.
Viva- voce- 15
Note books-S

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