owe SS" EE Figure 2: PED for Unit 300 — Acrylic Acid from Propylene cates ors € al DESIGN OF AN ACRYLIC ACID PRODUCTION PROCESS. (Comey of te Depa f Cheic Fapeeig Wet Vp Uae) Introduction emo-40, 20.0, +00, Aci Aid , 300, +38.0 ‘Tiere pal ces itp cos of to eae stn theca ‘pata seperti cote 5 os to mae he rotion of AN The Sane peas epee per wpe an eeAsya is rotted tata parta eidsion of prope nthe pesence of eam [x devae taperae sh sect pes We th to pia the Sig 03 proces 1 [rose 75, 000m ns of aye pt ar Nee patos NOT eet {is deep. Process Description Fei ema ses ow apa PPD) ee ar pee ce a als ae ppv and oye Sta ede poe nal ball. ‘Bopene eda oe stined pre apr st HOLD Thea eed wish aye coded {conan onyoryacn vopen td we ikaw H6Pa. The seam ated a 16 Ba Te eee tuted and sero Ge rector (R01 in hich say hdie med. The ‘cts wich ac ae shown bom. The reco et set 0 separ a(S 501) wach al i ses (onypn top cron uel rope) espe {svg Steam 7. Seas 7 eo Seams Band 9. Seam 8 2 eye seam ‘rami popvine oxy atom andcton Goude A puny equ ean Sa wen toe Soca 9s eae! Scan 1, coy wae a eye Sento detain cnn (301) patie prise aid The eed aye Sd ‘odie te 73.000 metic as Process Details Sea: propyee pre apr 29°C and H6P2 Seam: srs 21°C nd 46 P2 (as been conpesed fom Seam 9: wate pr steam oir, cet ay bee fo LV of fe Seam wae water seam teaes co $50010¢ al il fa il il il Process Flow Diagram for Acrylic Acid Production Figure 1.Cling Water siwer salable 2 5161 and 30°C en pesze = 508 LPs ‘aru onpertae igher han 45°C Retigeted Water sieoor alia S16s a 10% ‘rem pee 2308 KPa ‘hen emperate fe igher thn 20°C Retigenion woo References 1. ele KM and RW. Rasen, Hlomonty Prins of Chal Process (nb), Wiley New Yor, 1986 2 Rory R HL sa D. Gree, ee, Pery's hemi Engng HandBok NeGro it New Yo 888 3. Kur, 1). snd DB. Brat. "Stipbous Potmerzton of Ari Adi” Pat Operates Pros, 64, 203-207(1987) Soke Eee nt st Tae desig fhe ae extn i nr ana ead te ope fe ee jer Howe he fling sccm fos hae for ge proiy pees wae Co of. ~ 1.010 mee of wer Sm dof ‘pertig eon of 01 = 071m wea See 15 ana” ‘oe above peti oid te sot fl lies aby th ipl tho of tenting ‘Ge waa Ste dt est make sles Seta 12 Heat Zacuges For et excmge,wte elowing prin fr hn ne etc al oul deemabe ie be ete Seam 2: anye a pr 999 pty Equipment Reser 01) ‘De ftonag ences oc Gly + 150, + Ga, + 140 Sete an coment vious gerne ven in Tale These aes [zee theeaer pong ona of Pr sn erp he sa of ‘Sipe pos ag a pepe whe ning tat eee ‘Sielrenetic toate caper Select and Comers a DierentTemperaaes Tapers ‘Sei Coneion of Fropear to) ‘oes arte nes CO.) co 730 03 0, 190 050, 350. ‘O81 ‘076. Sporanr (80) ‘ts sparta congener han ey edn wate nin Sean 7. Te ‘Sis Sand watr apr ae puto Seams Pl 1 score ‘Bop sol ou cheat of ous so terme he apes ape ‘Sifweoe fi a separ The oat peste nat bee HOKE Destaton Ct (01) 1 is sttnion com te wae and ay i in Steam 10a sented. Te chmn operas at acusncafcs, Specs ae flows Te cok [Besar ern he tng poo yao» mann some Sempre, °C This ao he npr o Steam 12 The ep ofSem 1 e Dig pot of water hep of he clan. ees soperacson Gnsel tah i ketene pga. at xchange (30) 1 tis teat excanae,you may atme tt cea of he Sow of Sees 12 fre ad vapeur om Stes gd aed apa SOC The fot Stim oe pee seam aesp e cey oe a Bxhage (E02) {eis teat cong, ters conde om sted oper egi at ‘Be tie tase ow eam 10 The con fe soo eng et ‘Seeder ae eoaeny ey. Des of eae Exchanges E201 and E02 deat sgn of E01 aE 2 segues ca coats sub sand ‘atcocog wes sale tte conan speed oe Agent ft ree ‘Steno Fortes acne deg he flowy frase ele ponds Date ot Eulpneat Co Factors Prone <104m. 09 doeast apo aines cserenen see ‘sos)10-0aim 08 psig ty oat Sc a So ego 1010s 3c Tet Cost = Puchaed Cos 4 teri ete = preset) Polen se ete) (rain asard gr 270) se Chica Nahe Raper Aeic ALS mt) Chic ane Beer Metin Prue Seam (11SSRPH ted) 731/10 ‘igh ee Stn (37RD tes) sess00ty tay sooanw Dis Dsoized Water 1.01048 2a yt med tat pies nd ves ae inate in teen ot fact, Location fhe aes tl eet on te PPD.Cost Data Equipment Cons (Perchase’) Pansps $630 (power, kW) Hat Exchages $1030 (an. 0.6 $770 (power W996 + 400 (poner, kW)0S Tubine ——_$2:18¢108geer ouput MS se 6% foe Fiedler $635 (ay. LS seme $s themalefieacy ‘sume ca be designed 0 use my orpinic compound as fel evel S{167(0989 + 00817-83+10-P2)-10° 2=(617 + 0.20 +05 biol +021 log30l2) De dimetem 03m design fas secon ofthe pla. Tas part ofthe design wl be coutacted out o antes eunpany The ori ase aang X30, Sweam IS couaus 9 "athe AA and seh din Seam 13 and essentially no water or eer componeats. Tis is Seat the acd ificaa colum, 1302, whee 95% by mole aeic acid byproducts profaced overhead 4090 % by mole AAs produced as 3 boom prodct and cooled pe fe being Sa! 0 storage ‘Teague pase om he extractor, Sem 14 seta easter teste plat. whee sts decontammted por beg eure oe enoaneat ‘Reaction Kinetics and Reactor Configuration ‘he reactons taking place ae aleve. The ection kntis forthe cata wed in is ces are given below: Heat Exchangers Forbes exchanges ht do ot ave be designed in etal seh following ppestons ‘rea anfer nefits allo You detemie the beat aster aes andbeat exchanger aston Wim C) ‘onde en tt soadening rpc ee Teng we 780 ‘ling aie 1068 owing Td ca owing a @2 Ow Flow of Downer Aden) Pump Curve for the Dowtherm A Pump Gites30,+00,-1,0 Raia domi ted Cif $0 CHO; CO; +H:0Rersion? sete Aid 6¢+20,7300, +300 Reon} where - - hse poeta Pal resus in KPa ant be ataton ens an pengonnl es for eaions ig by Jalna molester (hPa) 118000 19.20" 2 mom sssst0"tthe explosion mis (LEL and UEL) is stony ecommended fra packed ed eat. The ‘exgonon lf propven aa 225% re LEL = 0 mel propyiene tod UEL= 11.1 ‘bots propylene Ateevatedtenpertasadbsing 4 sea pope ead) ‘te feed te tower explosion at LEL) hanged sips Tas aes esr 0 fefge 2 minim oxen conceataten (MOC) for te steam. Below he MOC. dane ‘ropagaon and beac cxploses a ot possible Fo te pcked bed eto Jou Cn ste En eage ale of MOC 5 6 mols oxygen The UEL at tye empertics wed fo tis ‘eachon 153 ol propvlene The second fey concen tat sacated Wh ely ‘ioernepolymezaon Of A wich occur int ways Fas if ened sed trite apropate aves ten eae tate of pymetton can cu Ths teal casos smaton ascssedby Kurland and Bryan [3} Secondly. AA denies ‘hea a igh concertos a teperats greater ha 90°C. Taree process coniions ‘ie eparan secon (C01 sad T 300) sould never enced us empertae Final Comments As wih ay pen ended prblen ea problem with ge comet aswer, he poem Sane above is deteraely vague You may need oil mvone msing a Wy dong 2 nate seach, nee seach of alan asunpts. The possi ess fa 5 900 ‘we on tas problem ou questions wl eae enon andr canis of be probles atone Vou shuld be aretha ewe reson cancion mye foricomng Moreover. ia seme aes (¢¢ sizing costing you ae sven more dat 24 ifort tan tat aeted You mst carceenguceingjpnea sot Gciewtdata fo ae Alo Jou ‘Boul so seek ana on fa te lnm or neato vey some of he ta the pcs of rosa ant a mates. Additional Data PulPa 10° volumetr flowrate (nh) ‘Compressor Curve for C-301