+ INTRODUCTION
(Transition elements
2 transition element is defined os the one which has
incompletely filled d orbitals in ity
arwnd chee orn ay one of He oridetion tales
3 ZnCd Hy
4 nDdllOns!-2
5 SeTiV Ge Mn Fe Co NiCu Zn [Trick - Repeat
SET: VGrMn FeCONi Cale 0 tes for
this series it is betHer than any mnemonic)
6.¥ Zr Nb Mo Te Ru Rh Pd Ag Cd (Trick - Yor
Zoruri Nhi Mohbbat Twine Rulati Rhe, Par
gor Cdo Ke Lipton]
T La Hf Ta W Re Os Ir PH Au Hg [Trick - La Hatta
Varna Re Os Irritating Popta (ke saath)
ur Maja
& he RF Db Sq Bh He Mt Ds Rg [Trick - Rutherford
Dooba Son Bohr (ko bhi le dooda), (Ex
girlfriend jab hasti hoi toh) - Has Mt Rs Rhid
qT
+ TRENDS AND PROPERTIES
10. Trick - Groupwise lattice ix - BH, BH, B, BH, H,
€.C.€ (BHEB2H2C3)
IF, first increase then decrease
12 Mn ond Te
BT
1, Density
6
16.7
M1 Middle
BT
MF
20.Se
Mn
mr
23 Postve
24, MOS, M207
25, CoPB
16. VES ond GoF6
2G
10. Lattice Structures of Transition Metals
CS u v a Ce en ee
hep hep bee. bee, =x bee cep cep, ccp SX
(bec) (bee (bee, cep) (hep) hep) (hep)
3 a Nb Cos CT a ee)
| hep hep bee bec hep hep cep, ep, cep, X.
| (bec) (heey (hep)
| hep hep bee. bec hep hep cep cep, cep X,
| (eep,bec} (bee) |
82
QUESTIONS 1
Scanned with CamScannerQUESTIONS 1
30, Fel03 + 02
aur
32 Poramagnatism
ee
| Bh, SoBe, Th, Zale
35.V2s, Cr3s, MrBs
36. VBe, Fels, Nido
57. Vbs, Gr2s, CoB, Cals
38 Yellow
34 Purple
40. Pink
4 V205 in contact process. finely died Fe in Haber's
Process Ni in Catalytic Hydrogenation
42 | Feds + > Feds + 2
I Feds « (S208)2- > Fe3s + (SO42-
BF
4b, High
45.F
46. () They have high meling points
(i) They are very hard some borides approach diamond
in hardness
(id They retain metalic conduchvty
(i) They are chemical inert
ws
48. Cur2n
44. CuSn
+ POTASSIUM DICHROMATE |
50. Se, ionic
51, Green
52. HMnO4, H2CrO4 and H2Cr201
53. VO2+
54, (VOUI3- and VO2+
QUESTIONS 2
55 Basix amphoteric
56. Feb
ST Na2CrO4 + 2 Fe208 + 8 C02
58
54, NoZGrZ01 + 2 Now + H20
60. Orange
OF
62. K2Gr201 + 2 NaCl
63. Orange
64.7
(65, [Gr2071 2 + H20
66. [GrO4] 2- + H2O
61.52
68. Dichromates
64. Grd
10.Snle « Gr3s
POTASSIUM PERMANGANATE
TL Mn02, alkal metal hydroxide, KNO3
TL Dark green permanganate
1B. KIMaOls «2420
Th, Mrs = + MnO? « 2H20
5 | alkaline eidative futon of Mr2
I clctroyfic oxidation in alain sliion
6. Mil = + S04 2~ + He
T1 Green, purple
TE KIMaOh + MoO? + 02
7A Poramagnetism
80, Paramagnatic
81 Diamagnetic
82 Onalate, Fell, trates I2
aT
BU, L Mads « 52
Meds + 5Fe3s
ML 2Mnde « 0C02
QUESTIONS 3
Scanned with CamScannerQUESTIONS 2 QUESTIONS 3
‘THE D-BLOCK ELEMENTS 7
eae ign Q3-Trerds in enthlpies of alomiaton ofthe
Wunceese Aransition elements
B51 Mo? « 20H- » 103 ~ Diga @. Chromatin
1 MnO? 6506 2~ + 20H- Dig @5.Dichromate ion
MnO? » He ATM pm
+ DigaQs B16
babe in the melting points of transition C 163 pm
Dig 0 Tren loi ri ran cement] Die 6 Teoh prmangenae on ‘purple
iga 1 Tetrahadeal manganate in gree)
rasmus
QUESTIONS 4 i
Scanned with CamScanner