ENERGETICS

weat always from higher temp to lover temp until thermal equlibulum

Kinetic energy
lugher temp-high average

Enthalpy : the heat absorbed or released in a chemical reaction (the heat content

Exothermic reactions : combustion + neutralization Endothenic reactions thermal decomposition :

↑
-reactants

L
I
-

AH = negative

are more
In 1-hilpy Products -
-
C

stable
↳
energetically more energetically
than reactant stable
Reaction
Progen

heat mass neat

↑↑ apauty

S
calculating enthalpy change using a = mcD+

1st : m (methand) = 80 .
55-80 . 03 = 0 .
529

2nd : n(methand) = m =
Mr = 0 S2. = 32 05 .
= 0 016
. ma Systematic errors

· heat loss
3rd :
9 = mcDT
· incomplete combustion

q
↳ = 20 00x4 . 18 x
.
(56 . 3 - 19 . S) o not all heat thansferred
to water

9 = -
30805

↳th : -
3080 = 0 016 .
=
-1925005
+

5th : comment to
Julgoul/mol---1 - .
93x10 1) mol-

STANDARD ENTHALGY CHANGE OF FORMATION STANDARD ENTHALGY CHANGE OF COMPUSTION

(H8 + 50z - 3(z + 4420 City + Hz CHg

AM =
DHf(product) -

DHL creactant) DM =
AHcCreactants) -
DMc (products)

Ar = 3( -
3a4) + 4) -
286) -
c -
10) DH = ( -
1411 + -
286) - ( -
1561)

DH = ( -
2326) -
( -

10s) = -

222/rjmol- AH=-136 by und-

or

2 .

90g of butale is lumed in excen Oxygen releary 143 Sky of heat

.

1 . 2 .

90/58 .
14 = 0 . O had mot

0 . 0499 mol produces 143 .

5 KI heat

bitare=S=-28
1 mol et