a C- 1h, 44,64 99100450 eR TET] Calculate the radius of the first Bohr orbit from given data and hence find radius of 3% Bohr orbit. Dat m = 9x 10kg, © = 16x 10-%C, ho = 6.63x10- Js, €9" 8.85 x 10-1? C2/ Nm? Solution : 85 x 10° x (6.63 x 10") n = 3142 x9 x 10 x (1.6 x 10" ny = $374x 10-1 ry = 05374 Ingeneral r, = rym? 1x) ty = 0.537x9 3 ry = 4837 (2) The energy of an excited hydrogen atom is Angular momentum = 34 eV. Find the angular momentum of the ve 4 ne 2 oh on 26.63 x 10" 2x 3.142 = 2.11 x 10™ joule-second = joule-second 305 Energy of electron in 2" Bohr orbit is -3.4 eV. Find the energy of electron in 3% Bohr orbit and 1 Bohr orbit. Data: E)=-3.4eV, B=? and Ey=? Solution: We have, E, 4 1 1 Therefore, B, 01 3% and Ey 037 o Ba beg ow = (f)xe E, = (§)xca4ew E, = -151eV Similarly, Ey = (f)xe = " 4 B a @ < iiergy of electron in 2“ Bohr orbit is -3.4 eV. Calculate its K.E. and PE. in the 3% orbit. Data: EB, =-3.4eV Solution : = 24 =F =9 or E, = (#)xe, BE, = (3) x(-3.4eV) E, = -1.5leV (total energy) TE. = PE.+KE. If total energy is (=x), then K.E. = x; and 2x; i. = (TB) (-1,51 eV)= +151 eV PB. = 2x(T.E) PB, = 2x(-1.5leV)= EB Wehave Since .02 eVvr (5) Anelectron is orbiting in 4* Bohr orbit. Find the a 9 Oe ionization energy for this atom if the ground Paschen series limit y= “R” = 9M, state energy is -13.6eV. [since = 4] Data: Given E, =-13.6eV, E4=? dye 99122 = 8208 A 2 Solution: Wehave E = br =7k 7 \ Similarly, Brackett series limit is - The ionisation energy = E,-E, ie R G-3) = OC O85) Hence, Brackett series limit is - = +0.85eV 16 dg = RaNXAL (© On the basis of classical electromagnetic theory ° ° find the frequency of ‘light emitted by an dg = 16x912A = 14592 A electron revolving around proton in hydrogen atom. ° (8) An electron beam has wavelength of 05 A. Data :1, = 0.537 A. Find its velocity and accelerating voltage Solution : The speed of electron in 1" orbit is ee that ity. given by — Data: 2, = 05x 10m i é 9x10 kg, : € =16x10-9C, aii (1.6 x 1079? h = 6.63 x 10-*Js, * 2xB85x 10" x 6.63 x10 x1 Solution: ™ = 218% 10%nv/s and We have, a 5 Aim, aee pr pezneAl” iceman sac? ab 6.63 x 10 23142 x0.537 x10" oe mee v = 14733 x 107 ms, Also, mv? = eV, my? _ 9x10! < (1.473 x 10” or Ve oe 2xLexio® VY V = 6.102 102 volt V = 610.2 volt (9) What is de Broglie wavelength of an electron accelerated through 25000 volt ? (neglect relativistic effects), Data; V =25000 voit Solution : Weave, 4 = 42228 ‘du = 0.0776 A (10) Calculate the de Broglie wavelength of electron ‘moving with one fourth of the speed of light. (neglect relativistic effects.) Data:v -(3) xe . = 210) < 0.75x10" mis, Solution : ch ___ 6.6310 R= iw = 9107" x0.75 x1 A = 0.982210" m A = 0.09822 A (Ans.) (1) State the postulates of Bohr's theory of hydrogen atom. (2) Obtain the expression for radius of n™ Bohr orbit and show that the radius is proportional to square of the principal quantum number. (3) Show that angular speed of electron in n™ Bohr orbit is equal to - atmet_ OG 2ehin? me’ or frequeney of revolution, f= 75 in (4) Derive the expression for total energy of electron in n® Bohr orbit and show that - Rog (S) Using expression for energy of electron, obtain the Bohr’s formula for hydrogen spectral line, (©) Define (&)_Bohr’s orbit or stationary orbit (ii) Binding energy of electron Tonisation energy or ionization potential of atom (7) Draw a neat labelled energy level diagram and explain the different series of spectral lines for hydrogen atom. (® With the help of neat diagram, describe the Geiger-Marsden experiment. (9) Explain the concept of de Broglie wave (matter wave). (10) Explain the Rutherford's model of an atom. (11) On the basis of de Broglie hypothesis, obtain the relation’ for wavelength of an electron accelerated by a p.d of *V’ volt. (12) State importance of Davisson and Germer experiment. (13) Describe the Davisson and Germer experiment. Find the ratio of diameter of electron in 1" Bohr ‘orbit to that in 4* bohr orbit (Ans : 1:16) Calculate the change in angular momentum of electron when it jumps from 3# orbit to 1* orbit in hydrogen atom. » (Ans : 2,111 x 104s or kgm?s-!) Find the longest wavelength in Paschen series. (Given R= 1.097 x 10’m™) 7) (Ans : 18752 A) yy Find the frequency of revolution of electron in 2 Bohr orbit, if the radius and the speed of electron in that orbit are 2.14 x 10-! m and 1.09, X 108 m/s respectively. (Ans : 8.11 x 10!4Hz ) Find the value of Rydberg’s constant if the energy of electron in second orbit in hydrogen atom is -3.4 eV. (Ans: 1.095 x 107 m=!) 307v—" (6)/ Find the shortest wavelength in Paschen series , the longest wavelength in Balmer series is 8 6563 A. (Ans : 82037 A ) (1) Find the ratio of longest to shortest wavelength in Paschen series. (Ans : 2.286:1 ) (8) The moving electron and a photon has same de Broglie wavelength. Show that the electron possesses more energy than carried by the photon. °) monochromatic radiation of wavelength is incident on an hydrogen atom that lifts it to 3% orbit from ground level. Find the wavelength and frequency of incident photon, (Given : E; =-1.51 eV, E, =-13.6 eV) (Ans. : 1028 A ; 2.9176 x 10" Hz) An electron in hydrogen atom stays in 2" orbit for 10 s. How many, revolutions will it make jumps to the ground state ? (Ans. : 8.23 x 10°) (11) Find momentum of the electron having de Broglie wavelength of 0.5 A (Ans: 1.326 x 10-23 kgms-!) (12) Find the wavelength of a proton accelerated by a potential difference of SOV. [Given m, = 1.673 x 10-27 kg] (Ans: 0.04.) (13) A cracker of mass M at rest explodes in two parts of masses my’ and m, with non-zero velocities. Find the ratio of the de Broglie wavelength of two particles (Ans: 1) me