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https://doi.org/10.1038/s41586-023-06939-z Fernando Vidal1,2, Eva R. van der Marel3,4, Ryan W. F. Kerr1, Caitlin McElroy5, Nadia Schroeder5,
Celia Mitchell5, Gloria Rosetto1, Thomas T. D. Chen1, Richard M. Bailey6, Cameron Hepburn5 ✉,
Received: 2 November 2021
Catherine Redgwell3 ✉ & Charlotte K. Williams1 ✉
Accepted: 5 December 2023
Plastics are extraordinarily useful materials. They play key roles across vision of the entire life cycle, as well as an economic and legal perspec-
the global economy in important areas such as food production and tive on what stimulates (or hampers) change.
preservation, transport, insulation, clothing, healthcare and medi- In November 2020, several members of the World Trade Organiza-
cine. Since their discovery more than a century ago, we have mastered tion (WTO) launched an informal dialogue to explore the role of trade
their mass production at a phenomenal annual rate, exceeding 460 cooperation in reducing plastics pollution and transitioning to a more
megatonnes (Mt) in 2019 (ref. 1). Driven by their low cost, light weight, circular and environmentally sustainable global plastics economy,
stability, longevity and high performance across various economic complementing discussions in other forums32. Moreover, following
sectors, our consumption of plastic has greatly accelerated2. However, a resolution adopted unanimously at the fifth session of the United
plastics pollution is correspondingly pervasive and only expected to get Nations Environment Assembly (UNEA) in May 2022, countries have
worse3–5, with serious consequences for the environment and human started negotiating a legally binding international treaty on plastic
health6–9. Moreover, the greenhouse gas (GHG), and in particular carbon pollution, addressing the full life cycle of plastics, with the ambition of
dioxide (CO2), emissions associated with plastics production, use and completing negotiations by the end of 2024 (refs. 33–35). In line with
end-of-life (EoL) remain a substantial barrier to keep global warming the resolution, the treaty could include provisions to promote sustain-
below 1.5 °C (ref. 10). able production and consumption of plastics through, among other
Globally, awareness of these challenges has grown in recent years, things, product design and environmentally sound waste management
providing scope for new research on mapping the problems and provid- (Supplementary information sections 4.2 and 4.4). If successful, the
ing solutions. A growing body of academic literature has also emerged, new treaty will provide legal certainty on key sustainability approaches
offering important insights into the problems associated with the cur- and bring greater coherence to international law, which—at present—
rent economic model, including plastics life-cycle carbon emissions11–13, addresses aspects of the plastics life cycle in a fragmented manner
dependence on fossil resources14–16, inadequate recycling techniques (chemicals, wastes, pollution etc.)34–39.
and infrastructure17–19, the implications of plastic waste exports and In light of these continuing international discussions, this perspec-
mismanagement20–23, ecosystem pollution20,24,25 and health risks26,27. tive aims to propose a vision for a future circular carbon and plastics
Although these studies often include mitigation strategies2,28–31, a future economy. This circular system can only be attained if four interlinked
sustainable plastics economy requires a multidisciplinary and holistic targets, centred on consumption reduction, uptake of renewable
1
Department of Chemistry, University of Oxford, Oxford, UK. 2POLYMAT, University of the Basque Country (UPV/EHU), Donostia-San Sebastian, Spain. 3Faculty of Law, University of Oxford, Oxford,
UK. 4Faculty of Law, UiT The Arctic University of Norway, Tromsø, Norway. 5Smith School of Enterprise and the Environment, University of Oxford, Oxford, UK. 6School of Geography and the
Environment, University of Oxford, Oxford, UK. ✉e-mail: cameron.hepburn@smithschool.ox.ac.uk; catherine.redgwell@law.ox.ac.uk; charlotte.williams@chem.ox.ac.uk
Photosynthesis
Polymerization
Cleavable
Mechanical polymer chains
recycling (for example, PET, PUR)
Anaerobic Polymers
Energy Controlled digestion
incineration Industrial
with carbon Conversion
composting Reuse
capture and
energy
Biodegradable Recoverable
recovery Products
(for example, PLA, thermoplastics
PHAs, TPS)
Discard
Intractable,
Renewables
non-recyclable Waste
Fig. 1 | The circular carbon and plastics life cycle. In the current system, which (last resort and only with carbon capture). The recycling streams replace
features linear flows of production and disposal (black pathway), demand for the need for more virgin raw materials for the plastics industry (polymers,
plastics is satisfied by consuming fossil resources, while the lack of perceived monomers or unprocessed feedstock) and avoid extraction of petrochemicals.
economic value in plastic waste leads to unsustainable rates of landfilling, Any remaining production of virgin polymers uses carbon from captured CO2
incineration or, worse, environmental leakage. In this future system (grey box), or indirectly from (waste) biomass. The carbon-recirculation system must be
a recirculation pathway hierarchy helps to maximize material recycling and powered using only renewable energy. Acronyms refer to common polymer
carbon recirculation by prioritizing (1) reuse of products, (2) physical recycling classes, for example: PET, poly(ethylene terephthalate); PHAs, poly(hydroxy
and (3) (bio)chemical recycling (including depolymerization to monomer, alkanoates); PLA, poly(lactic acid); PUR, poly(urethane); TPS, thermoplastic
pyrolysis and gasification) over (4) biodegradation and (5) energy recovery starch.
downstream and upstream cycles. This future system cannot operate biodegradation in order for the system to reach net zero: a very tough
using only biomass as the feedstock, but carbon capture and utilization challenge.
(CCU) technologies are also essential66. Estimates to reach climate
targets situate the efforts to scale current carbon-removal capacity, Evaluating carbon emissions and other metrics
including CCU, by a factor of 1,300 by 2050, an increase of 4.8 GtCO2 Addressing the impacts and biosphere burdens of the materials, pro-
per year from 2020 values67. Captured CO2 must be catalytically trans- cesses and energy requirements for this future circular plastics econ-
formed into chemical intermediates, for example, syngas, alkenes, omy requires careful life-cycle assessments accompanied by notable
naphtha, aromatics, carbonates and alcohols68–70. In nature, CO2 is technological breakthroughs in the coming decades. GHG emissions
captured and converted into biochemicals by photosynthesis. Plant are essential metrics to evaluate the effect on climate change, but there
metabolic pathways can be exploited, or even enhanced, to eventu- will be other negative environmental trade-offs that require careful
ally produce more complex monomers, including those from lignin, consideration and minimization. A useful metric for comparing impacts
carbohydrates, triglycerides and terpenes71,72. These combined syn- is the global planetary boundary framework73–75. This defines bound-
thetic and natural CO2 use pathways must offset all GHG emissions ary limits for human activities and sets a safe operating space against
from plastic production, manufacturing, recycling and any eventual nine Earth-system processes, including biosphere integrity through
Such plastics include new synthetic polymers produced by or contaminated plastic wastes that cannot be treated through
chemical transformations of biomass, for example, polylactic other forms of recycling. Although energy is recovered, this option
acid from starch, and drop-in polymers, analogous to sits at the bottom of the recirculation pathway hierarchy because
existing petrochemical plastics but biomass-derived, such it requires capture of carbon emissions and destroys the material
as biopolyethylene from bioethanol. Bio-based plastics need structure and value.
notable developments in five main areas: competitive economics, ● Smart design refers to innovations in plastic production,
efficient transformations from sustainable resources, optimized manufacturing and recycling that are underpinned by material
performance characteristics, establishment of clear EoL options applications, EoL retrievability and any environmental impacts
(including recycling) and global standardization. throughout the life cycle of the product.
● Reuse extends the life of plastic products by reintroducing them ● Service lifespan of plastic products indicates the length of time
to the economy after use. In combination with other ‘r strategies’ a particular material retains its function and is used, reused,
(redistribute, repair, refurbish, repurpose and remanufacture), repaired, refurbished or remanufactured. Long-lived plastics
reuse is an appealing approach to reduce consumption of virgin retain their properties for years and even decades (for example,
polymers, as it requires minimal energy compared with recycling, in construction and automotive) and thus show high durability,
and prevents waste. These strategies benefit from effective repairability and adaptability. Short-lived plastics are disposed
business models, such as refills for packaging. of within months or a few years (for example, packaging),
● Physical recycling applies mechanical and/or thermal energy to contributing substantially to projected increases in demand for
recycle waste plastic into new products (for example, through plastics.
melting, extrusion and moulding technologies). These methods ● Recoverability of plastic wastes describes the feasibility to collect,
are expected to be the dominant EoL treatment for thermoplastic sort, process and recycle a plastic after use. Recoverable plastics
materials, which constitute 86% of the global plastics market, are used in applications and in geographies in which recovery
owing to the low energy requirements and economic feasibility. and separations are physically and economically feasible and are
However, challenges include deterioration in material properties best recycled. Irretrievable plastics describe products that are
after repeated recycles and the need to separate and purify mixed distributed in the environment after use; for example, uncollected
or contaminated wastes. wastes in rural areas of the developing world, waste fishing gear,
● Chemical recycling involves the controlled breakdown of plastics agricultural mulch film plastics, microplastic sources, including
into monomers or precursors suitable for recycling to polymers from tyre dust and textile fibres, and formulated products. These
using existing manufacturing processes. It is, at present, most cannot be recycled and are best designed to biodegrade.
(in)direct land-use change, balanced nitrogen/phosphorus cycles and polymers77 or application of crops that grow rapidly in marginal lands
atmospheric aerosol loading10. or increase the soil organic carbon content78. By comparison, the direct
It is essential to work together to articulate clear and commonly use of CO2 to make monomers and polymers does not usually result
understood international sustainability criteria76 and accelerate in burdens on arable lands and habitats, which are great concerns in
research, including to efficiently use and transform biomass feed- any increased-biomass-consumption model1,10. Nonetheless, CCU in
stocks that avoid habitat loss, overconsumption of freshwater and polymer production may increase demand for renewable energy and
fertilizers, and limits other adverse environmental impacts. Provid- green hydrogen, particularly if reduced molecules such as methanol or
ing solutions will not be easy, but priority fields for research include syngas are the primary feedstocks10. Increased renewable energy pro-
methods to transform organic wastes and agricultural by-products to duction has planetary footprints, including increases to atmospheric
Bio-based
Plastic industry scenarios in 2050 Net GHG emissions in 2050 (GtCO2) Carbon recirculation
a Baseline
1,100 100 0 0.8 1.6 2.4 3.2 4.0 4.8
EoL (share, %)
70
(GtCO2)
0%
0 4.5
0
b Business as usual
1,100 100 0 0.8 1.6 2.4 3.2 4.0 4.8
EoL (share, %)
(MMT plastic)
(GtCO2)
670 57
39%
0 4.1
0
c Conservative commitments
EoL (share, %)
(MMT plastic)
825 100
(GtCO2)
528 64 36%
40
0 0
2.2
d Bold system change
EoL (share, %)
(GtCO2)
550 100
86%
Fig. 2 | Plastic industry scenarios and GHG emissions for 2050 based on an of fossil-based plastic and intermediate deployment of renewable energies).
estimated global production of 1.1 Gt. a, Baseline scenario (all plastic waste is d, Bold system change (cut plastic demand in half, full-scale introduction of
discarded through a combination of landfilling and incineration). b, Business- bio-based plastics and recycling technologies up to 95%, plus complete
as-usual scenario (projected growth from current levels in recycling, up to 43%, decarbonization of the energy system). In the left column, the dashed frames
and incineration, up to 50%). c, Conservative commitments scenario (only highlight the projected size of manufacturing and EoL in the 2050 baseline
partially deploying key interventions: 25% demand reduction, 50% substitution scenario. MMT, million metric tonnes.
aerosol loading and impacts on P-cycles. Hence, the implementation waste infrastructure (where it exists) and recycling options. Another
of larger-scale CCU technologies and biomass uptake must be care- challenge associated with estimating the effects of increased use of
fully balanced10. Notably, plastic recirculation by physical and (bio) renewable plastics is the earlier market stage of such materials, which
chemical recycling replaces the need for extracting virgin renewable affects manufacturing-process efficiency with knock-on consequences
resources, avoiding notable burden shifting and, therefore, represents for GHG emissions. In the four scenarios, the current data for the top
a promising approach to reducing GHG emissions without other nega- five bio-based plastics was applied, but we acknowledge that, in the
tive consequences10. future, their properties need to be improved and that their current
Several excellent global studies have modelled and quantified the life-cycle GHG emissions should serve as an upper bound to drive inno-
carbon footprint of the plastics life cycle, helping to visualize the con- vation. The current scenarios do not attempt to quantify or compare
sequences of implementing particular mitigation strategies. Notably, other negative environmental impacts, but it is worth emphasizing the
recent investigations led by Suh42, Bardow50 and Stegmann51 all show critical importance of continuing with such assessments42,80.
that isolated solutions cannot fix the plastics problem; it is only the The baseline scenario involves all plastics being both fully fossil
interplay of four interlinked targets that effectively reduces GHG emis- derived and disposed of in landfill or by incineration. Because no car-
sions towards net zero. Using these published models and datasets, bon is recirculated, future demand must be satisfied by manufacturing
we propose four different 2050 scenarios for the plastics economy, more virgin plastics from crude oil or gas. These upstream processes
at a time when the market is expected to grow to 1.1 Gt plastic per year result in an estimate of 4.0 GtCO2, that is, roughly 90% of all life-cycle
(Fig. 2): (1) baseline, (2) business-as-usual, (3) conservative commit- emissions. By comparison, the business-as-usual scenario linearly
ments and (4) bold system change. For each scenario, estimates of the tracks the range of EoL options relevant today to 2050, with rates of
consequences for GHG emissions and recirculated carbon content are incineration and recycling reaching up to 50% and 43%, respectively40.
provided, capturing the possible impacts and outcomes, rather than The climate cost of maintaining a business-as-usual scenario is massive:
any kind of absolute forecast. The scenarios apply the four mitiga- the carbon footprint remains >2.5-fold higher than the level of today
tion strategies: reducing plastic consumption, increasing recycling and surpasses 4.0 GtCO2 a year, not far from the projected baseline.
rates, replacing fossil carbon with renewable alternatives and power- This scenario reveals a key message: augmenting recycling of plastics
ing manufacturing and recycling processes with renewable electric- waste alone (approximately 40% of recirculated carbon) is simply not
ity (Supplementary information section 1)42,50,79. It should be noted enough to tackle the emissions crisis.
that, in these scenarios, there were many data gaps and, therefore, Breaking from the status quo is very challenging in complex
estimates had to be made, particularly given the diversity in global global economies and requires coordinated action and investment.
the bold-system-change scenario, implementation of smart design plastic products to reflect their social and environmental costs would
principles could help to greatly reduce GHG emissions (70–90%) com- also help to reduce demand by increasing the price of plastic per user.
pared with the business-as-usual scenario. In each sector, different A tax on plastic products may have the added benefit of generating
interventions will be necessary to curtail emissions, examples of which revenue to subsidize recycling and/or composting infrastructure,
include demand reduction for short-lived plastics, increased recycling helping to make recycled materials more competitive111. Such so-called
of recoverable plastics and ensuring complete biodegradability for hypothecated tax revenues do not typically appeal to finance minis-
irretrievable plastics (see Supplementary information section 2). To tries, but experience suggests that they make environmental taxes
implement smart design across all sectors, technical advances must be more politically palatable112, provided inequitable distributive conse-
guided by future sustainability criteria98,99 and supported by a robust quences are avoided or compensated for with an appropriate policy
legal framework and economic incentives, as discussed next for each mix86.
of the four key targets identified for a bold system change.
Switch to renewably sourced plastics
Reduce plastics demand So far, global climate targets are driving aspirational policy objectives
Restrictions on the production and consumption of unnecessary plas- for sustainable carbon cycles. However, any efforts to introduce renew-
tics incentivize smart design for application and thereby help to reduce able feedstocks must also carefully consider and minimize the other
overall plastic demand. These may take the form of national bans on environmental trade-offs, as mentioned previously. This is not an easy
single-use items, with early examples including the prohibition on task, as increasing use of biomass and CO2 use might result in trans-
certain plastic bags in Meghalaya (India)100, South Africa101, Eritrea102 fer of ecological burdens from climate change to other Earth-system
and Bangladesh103, and—more recently—the EU Single-Use Plastics processes1,10. On the other hand, the petrochemicals industry also has
(SUP) Directive104. It has also been suggested that the new international other negative environmental effects, including particulate pollution,
plastics treaty could, among other things, target both the phasing out/ ecosystem threat and release of volatile organic compounds, as well
reduction of primary plastics, of problematic and avoidable plastic as sulfur-containing and nitrogen-containing contaminant gasses.
products and of chemicals and polymers of concern105. This raises Given the pressing need to reduce GHG emissions, the target to
further questions about the most appropriate criteria for definition scale up future renewable-feedstock technologies must be guided
and the need to clearly distinguish between substances and products. by careful environmental-sustainability analyses. Economic and legal
An international phasing out of substances of concern in relation to measures also help to drive this change, for example, in the EU, at least
plastics could draw inspiration from existing international restrictions 20% of the carbon used in chemical and plastic products should be
of persistent organic pollutants106 or of ozone-depleting substances107. from renewable sources by 2030 (ref. 113). Realizing these objectives
Furthermore, measures to reduce plastic demand could stipulate or requires investment in both the infrastructure and markets for such
prohibit plastic content, such as the US prohibition of microbeads in products. States can facilitate the transition through implementing
cosmetics108, the new EU ban on intentionally added microplastics109 or targets, for example, the Dutch Transition Agenda for Plastics plans to
the ban on oxo-degradable plastics in the EU104. In the packaging sector increase the percentage of recyclate and bio-based plastics to 41% and
alone, the elimination of unnecessary plastics combined with innova- 15%, by 2030, respectively114; the USA has a bold goal to, in 20 years,
tive product and packaging design is estimated to reduce by about “demonstrate and deploy cost-effective and sustainable routes to
38% packaging demand in Europe by 2050 (ref. 110). A tax or fee on convert bio-based feedstocks into recyclable-by-design polymers
• ‘Drop-in’ • ‘Drop-in’
• Reusable • Durable
• Recyclable • Recyclable
for example, recoverable for example, construction
packaging (rigids, bottles) (pipes, window frames)
Service
lifespan
Short Long
• Biodegradable • Biodegradable
• Compostable • Compostable
• Reusable • Durable
for example, complex packaging for example, agriculture
(flexibles, multimaterials) (mulching films)
Low
1.00 80
versus business as usual (%)
GHG emissions (GtCO2)
0.75 60
0.50 40
0.25 20
0 0
Recoverable Complex Construction Agriculture Recoverable Complex Construction Agriculture
packaging packaging packaging packaging
Fig. 3 | The impacts of smart design, service lifespan and recoverability in bold-system-change scenarios for four illustrative application sectors.
the carbon footprint of plastics. a, Taxonomy for plastic products based on c, Corresponding GHG savings attained by applying smart design principles
their inherent service lifespan and recoverability, with sector examples in in a system change.
each quadrant. b, Estimated GHG emissions for the business-as-usual and
that can displace more than 90% of today’s plastics”115,116; and the EU industries. Further developing such partnerships is therefore flagged
proposes to mandate the use of compostable packaging for certain as critical for achieving the US biotechnology and biomanufactur-
applications117. States can also facilitate these objectives indirectly ing goals, including through databases, joint funding opportunity
through exemptions, for example, the exemption for certain degra- projects116 and user facilities such as the Advanced Biofuels and Bio-
dable and soluble polymers from the restriction on intentionally products Process Development Unit (ABPDU), a scale-up facility that
added microplastics under EU chemicals law109. States can further has already helped companies raise more than US$2 billion in private
create demand for bio-based goods by implementing green public funding and transition 17 products to market. Similarly, the Circular
procurement criteria when exercising large-scale purchasing power Bio-based Europe Joint Undertaking (CBE JU) is a €2 billion public–
in contracts for goods, services and infrastructure development118. In private partnership that finances projects advancing competitive cir-
the EU, public authorities spend approximately €2 trillion each year cular bio-based industries. Conversely, phasing out fossil-fuel subsidies
on public contracts, equivalent to roughly 14% of its gross domestic could help to bridge the cost gap between fossil and renewably sourced
product (ref. 119). Such spending power serves as an effective tool for plastics121–123. Pressure to phase out inefficient fossil-fuel subsidies will
directing markets in a sustainable direction. probably intensify in line with SDG12 (ref. 92) and the Glasgow Climate
Scaling renewable plastics requires cost-competitiveness, a current Pact124, and the initiatives of some countries already signal a change in
key barrier. States can provide financial subsidies to allow manufac- this direction125. Further, a fossil-carbon-free system requires changing
turers to sell such plastics at lower cost, driving production at scale. the investment from petrochemical plants to technologies for biomass
Global growth of renewably sourced plastics could rapidly increase and CCU to chemicals. This could be stimulated by including CCU in
from about 4% to 10–20% if their adoption was subsidized and politi- emissions-trading schemes, such as under the recently amended EU
cally supported, similarly to contracts for difference used to grow Emissions Trading System (EU ETS), which already supported innova-
low-carbon (emissions) energy120. Public–private partnerships that tion in CCU and other low-carbon technologies through its Innova-
bring together the expertise and resources of several stakeholders can tion Fund, and where emissions allowances now no longer have to be
accelerate innovation and advance cost reduction for nascent bio-based surrendered for GHG that are captured and used where they become
Recycling targets
Eco-design regulations
Collaborative global approach to plastics
Deposit-return schemes
Tax ‘unnecessary’ plastics
R&D of renewable plastics
Ban ‘unnecessary’ plastics
Ban ‘harmful’ plastics
Producer voluntary commitments
Sustainable biomass production
5,000
Production
Carbon removal Business-as-usual emissions (CO2e)
Emissions (MtCO2e)
End of life
2,500
Bold-system-change emissions (CO2e)
0
2020 2025 2030 2035 2040 2045 2050
Year
Fig. 4 | Interventions roadmap for a bold-system-change scenario. Timeline economy. The interventions all support the four interlinked targets to reach
of interventions to prevent the projected GHG emissions of a business-as-usual the life-cycle emissions of the bold-system-change scenario outlined in Fig. 2.
pathway and their potential to curb the carbon footprint of the future plastics Further scaling efforts for carbon removal to attain net zero are also shown.
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