Chapter Chemical Bonding @iitjeehelps Intrinsic semiconductors are basically insulators, where the energy gap between adjacent bands is sufficiently small for thermal energy to be able to promote a small number of electrons from the full valence band to the empty conduction band, Both the promoted electron in the conduction band and the unpaired electron left in the valence band can conduct electricity. The conductivity of semiconductors increases with temperature, because the number of electrons promoted to the conduction band increases as the temperature increases. Both n-type and p-type semiconductors are produced by doping an insulator with a suitable impurity. The band from the impurity lies in between the valence and conduction bands in the insulator, and acts as a bridge, so that electrons may be excited from the insulator bands to the impurity bands, or vice versa (Figure 3.85). Encagy Energy Pasally K fed Conductor Conducts Energy Eneigy Energy Vecant Vacant Vocant ws ) sat ep | wee oe mop Piet Fite Piet Insulator seme Intinse semiconductor Figure 3.85 Conductors, insulators, impurity and intrinsic semiconductors. eRe S eae kaon 4. Ifall bond angles in AX, molecule are the same, then, Which of the following conclusions i corzect about AX? (AJAX, must be polar (B) AX, must be plana (C)AX, must have atleast 5 valence electrons. (D) X must connect from central atom with either single bond! or double bond, 2. Which ofthe following statements is correct for BrF? (A) Total number of lone pairs pretent in 15, (B) Total number of maximum number of atoms in fone plane = 5 (© Molecule is pola (D) Bromine has its maximum covalency in this molecule10. " 5 Which of the following orders is incorrect? (X=FICD, @iitjeehelps ‘What isthe shape ofthe cationic part of solid C1,0,? (A) Distorted octahedral (B) Square pyramidal (©) Square planar (D) None of these Which of the following orders of boiling point is incorrect? (A) CH, < CF, ()heBr 120" (B) <120° (12 (A) CHF, < CHF, < (FCF) (@) CHEE, < cH, 1, REX) (cnr, Fy HCH bond -§-0 (UD ‘The bond angle of Ph, is greater than PH, but the bond angle of NFis lever than NIL, 48, (01) The % stharacter in the etbita containing lone pair of 1,0 molecule is 30%. {HOH = 1045 and cost04.) = -025] 1. Which ofthe following statements isiare correct? (un (yu, jum (D) Ln Choose the correct order of boiling point (AH, CHCl (dipole moment) (B) IIF > 11,0 (extent of hydrogen bonding) (©) CHy> CF, oiling point) (D) KCI> NaCl (colubility in water) ‘Which of the following statements is correct for (A) Kcontains p, ~p, andp, ~ 4, (B) Iehas regular tetrahedeal geometry. ©0,>0, (D) Plane which contains maximum numberof tom In which of the following processes electron is not added to molecular orbital having gerade symmetry? (a) 0; > @) NON; ©) BB; @) C9 1 Hsa!’s rule and sp intermixingislare not consid- ‘red, then which of the following characteristics is ‘hanged in C,? (A) Number of electrons in gerade molecular orbital (B) Bond orde (©) Magnetic behaviour (©) Magnetic moment AA silicate mineral hae chemical formula Ca.Mg, $i0,(OB), and is known as temoit, Predict the value of x, ws 4 2 @m)s In which of the following N-N bond length is the WN, () Ny (ONO, (D)N,O, (unsymmetrical) Select the correct order of H- M—H bond angle, (A) PH,> PIL, (®) Pe PH, (QPH.>NH, — (D) PH, >NH, Compare bond angle x and y in the following ‘molecules | o¢Chapter Chemical Bonding 21 22. 23. 24. 25. 26. 27. 28. Byax (D) None of these Choose the cortect statement fom the following options. (A) All dg in H,CO, are identical (B) All dy, in SCL, axe identical, (C) HCI Gn HCO) B (NR), > BILNR, (D) BHNR, > BINR),> BH (NR), Note: R'= CH, inall the above cases,36. a7. 38. 39. a 43, 45, Calculate the percentage of p character in the orbital ‘occupied by the lone pair of electrons in water molecule, (Given HOH is 1045° and cos (104°) =-025] (ays0% Bwe (CMe —D)IS% Give the correct order of initials True (T) or False (F) {or the following statements (0) sp’ bybrid orbitals ace at 90° to one another. (AD) Adjacent sp'd! hybrid orbitals are at 90° to one another (am sp" hyo (QV) Bond order of itals are at 120° to one another =O bond in NOs AE (QTFIF @TTFF (FTTT W)FTET ‘Which among the following species is not perfectly planar? (CH, (8) CHE, (©):CF, (NO, Which of the following molecules has the maximum number of A-X bonds of identical length, where ‘A’ is the central atom and°X’ is the surrounding ators? (sr, (By, (re, (D) clog. Which of the following sequences shows the correct bbond angle order for isoelectronic species O,, NO and NOF (A) NO;>NOF>0, (B) 0,>NOz> NOF (€)0, $:CO, > BxCO,:po, oder when kept ized cmperatre na ted container (c)XeP,> Ket, Dipole moment order. (D)NGE, > NEE! Furie accepting tendency onder, Which of the following statements is correct for @iitjeehelps 48. 47. 49. 50. st. 52 53, 54. 55. Single Correct Choice Type Questions EEE} (A) AIL C-F bond lengths ate identical {B) Two CF bonds attacked to middle carbon atom ate longer as compazed to the other C-F bond at the terminal carbon, (©) Two C-F bonds attached to the middle carbon atom are shorter as compared to the other C-F bond at the terminal carbon (D) Nose ofthese. Which of the following statements ie not corr regarding NO, molecule? (A) Paramagnetic behaviour decreases when it undergoes in dimerization, (B) Mis coloured in its dimeric form, (©) The colour it duc to the presence of unpaired electron, (D) The free electron is present in one of the sp" hybrid orbital PCLF,, molecule will be polar and non-polar for what values of x respectively? Polar Non-polar Polar (A)2,3,Sand 0,41 (B)0,2,Sand (OA 3oand 20,4 D)21dand 7 Non-polar 31,4 3.0,5 Which of the following moleculesispecies has the sinimum number of lone paits? (AIC GBF (C)SnC,—(D) XeF, Find the pair of species having the same shape but illerent hybridization of the central atom, 0," (B) NO", ClO (A) S0,, C1 (C)BeCl, HCN (D) XeF,,SnC, Which of the following statements is incorrect regarding CLO molecule? (A) Tae molecule is planar. (B) The shape of the molecule is bent (C) The hybridization of the central atom is sp! (D) The molecule is non-planar, ‘Tae hybridization ofall carbon atoms in benzene it OE @)sp° (C)sp'andsp' ——(D) sph and ap The ratio of @ bond and bond in naphthalene WLS B21 (C195 W104 The strongest x bond is present in which of the ollowing species? (AQ He= cH (B) H-c=P os (0) H,c=cH, Which ofthe following pairs is iso-structural? (A)BOFanéSOy — (B) NO! and CO, (QHNCand Sac, (D) SnC; and $0, The d,, orbital i involved in which of the following hybridizations? (A) sp'd (square pyramidal) Ore (B) (D) None oftheseChapter Chemical Bonding 36. Which ofthe following species has incomplete octet? ASF, GN (CPB, D)B™ '57. Which of the following statements is correct for the two molecules, C,H, and B,NjH,? (A) C-H bond length is identical with N-H and B-H bond lengths. (B) The nature of double bond is perfectly identical in both, (©) Both the molecules are planar. (D) C,H is non-polar while B,NH, is polar. '58. Which ofthe following species has the same number of X-O-X linkages, where X= Sor P? MS.0." (5,0, aM) 5,0." av)P,0, (A) ev @)tein (jie Maw 59. In which of the following processes, the value of ‘magnetic moment does not change? (AN, 9 No (BN, > NO (0,205 Mo, 20, @iitjeehelps 0. Which ofthe following statements isnot correct? (A) +p) produces sp hybrid orbitals which are Tying the yz plane (B) (+p, produces sp hybrid orbitals which are Iving fh the vz plane (©) te = p.-=p) produces sp* hybrid orbitals which ae ying inthe nz plane (D) (+ p) produces sp hybrid orbitals which are Iving slong the y ax (61, Which isthe correct order ofthe bond angle? (A)NH.C1,0 ()PH,NGIH), (D) NH,>PH, '5. Which ofthe following moleculestions does not exist?” (A) KEE, (B) OF, (© Bere (D) SH, 6. In which of the following reactions, the magnitude fof change in bond angle with respect to underlined som is 220"? (A) Beh, +28 9 Be @) BR AF Br, (© NH, +H ONE ©) GAH, 56H, 7. Which ofthe following is correct onder for indicated bond length? (A) deci NAL > dag NE (B) devin NH, -Nii, > dg in, -NU, (©dncin SCH, > dy in SICH, W)dnrin cH dain CR, 8. Which ofthe following statements is/are not correct? (A) The bone angle SIOS: in (SiH.),0 is larger than that of C-0-C in (CH),0. (B) BF, has more Lewis acidic nature than BI, (©)pmdn bond electrons get delocalized between B fd N atoms in B,N\H, (©) CHNCS is linear, while SiLNCS is bent 9. Which of the following paits of molecules is/are not isostructural? (A) NMe, and N(SiMe,), (B) XeOF, and SOF, (OCR, and PR, (D) Si0, and CO,10. Which of the following statements islare correct for XeFOSOF? \Z 07 No (A) The number of sp" hybridized central atom ie3. (B) The number of identical $-O bond is 2 (C) Maximum number of atoms that may lie in one plane is 5 (D) All atom are lying in the same plane. Select the correct statement(s) about the following chemical species . 0,0! NNO, Hy and Hy (A) Magnetic moment of NO is greater than that 2f 0, (B) The bond length of Q; is shorter than that of O, ue to removal of electron from x* (©) The ionization energy of Ny is greater than that of (D) H} is more stable than, the same bond order, Mhough both have 412, Which of the following orders isare incorrect, against the indicated properties? (A) AgP > AgCl> Agh: Covalent character (B) NaHCO, > KHCO, < RbHCO, : Solubility in water (O)Nak CaC,0, > BaC,O; Solubility in water 413, Select the correct statement(s) among the following (A) When lone pair of surrounding atom is involved in back bonding, the bond angle does not change anywhere, (B) When lone pair of central atom is involved in back bonding, the bond angle does not change. (C)In BAN, all B—N bond lengths are equal and these are shorter than the single B ~ N covalent ‘bonds due to delocalization of electrons (D) BF,, BCI, are gaseous, BBr, is quid and BI, is solid because when size increases, instantaneous Aipole-induced dipole interaction increases, Which of the following molecule have 3e~2e bond? (A) ALCL (B) AL(CH,), (©) [Be(OMe) J, ©) [Be(CH)., “Types of bonds in BT, (A)B-B Qc-20) (8) BBBGe-29, ()B-HGc-20) (D) BIB (Ge~2e) Be(OM), forms bridge bonding structure in their polymeric form of the compounds as given below. (© [Be,(OH),f* CD [Be,(OHD,) Which types of bonds are present in the above compounds? (A) 2e~2e bond (©) Sede bond 14 45, 16. (B) 3e—2¢ bond (D) All ofthese @iitjeehelps "7. 18. 1». 20. 21. 22. 23, 24, 25. 26. Mubtiple Correet Chioce Type Questions If polarizing power isin the order of M > Mz > M! and polarizability is in the order of X°>Y">Z" then select which of the following compounds have ‘more covalent character as compared to MSY"? Mex B) Mx" jour (>) Myz- Which of the following compounds ate thermally sore stale than compound C30, (A) Be0, (B)Ba0, (sro, @)Mz0, IE, TE, and TE, ofan atom X ate 170 keamole, 340 kcalimole and 1280 Kealimole, espectively. I this som X forms compounds with O, Cl and N, then hich offllowing compounds has th least chance ()X.0, @xa (xe, OXY, In which of following processes, do(es) the value of rmagnste moment change? (A)CO>CO"B) Ny NY (© Zn Za") 0, 905 Choose the conect statement(s) among the following for HPO," ions (A) All taree HPO angles re identical due to (B)All bond lengths ate identical due to resonance (©) The bond order of a1 P =O bond is 13, (D) None of these. London force works in (A) gaseous state (C) liquid state. (B) solid state (D) none of these, Which of the following d orbitals may participate in sp'd hybridization? Ad, Bd, Od, D) ds y Which of the following options represent incorzect hybridization of its central atom for the respective species? (A) SeCl, sp" (C) SIPC. sp! BBS spt (D) XeOfsap'dt Which of the following compounds have the same shape? (A) SF Oany (8) Xer, (Dy[sac Which of the following Lewis acid - base interac: tions ate associated with the further involvement of d-otbitals? (A) SbE, + HF 9 HY [SbR,- (B) NH, + BF, 9 H, N-BF, (© acl, + cr [atc] ©) sk, + F > [SR 7Chapter Chemical Bonding 27. 28. 20. n 32, 33. ‘Which of the following digrams indicate the forma tioa of xbond:? P B) oO @) BT - Which ofthe following ean be calculated from the Born-Haber eyele of formation of ALO,” (A) Latice energy of ALO, (B) Electzon afity of O atom (C) Hydration energy of AI (D) Ionization enctay of AL Which of the following set of molecules have the same shape but different hybridization? (A)H,O,SaCl, —(B) Xe0,, BrF, (QXe0,,SF—(D) BeCl, Which of the following types of bonds are present in NaNO,? (A) Tonic bond (B) Covalently bonded abond (© bond (D) Coordinate bond Which of the following compounds aze planar aswell asnon-polar? (Xe, (B) XeF, (©) Xe; (D) XeFy ‘Choose the correct statement. (A) 4, orbital les inthe x2 plane. (B) p, orbital cs along the + ais. (©) Lobes ofd._ orbital are at 90° with the 2 axis (D) Lobes of dy debital are at 90° with the z axis From octahedral electron geometry of the central atom, which of the following shapes of the molecule! species may be possible. @iitjeehelps 34, 35. 36. a7. 38. 40. a (A) Square pyramidal (© Square planar (B) Linear (D) Bent Which of the following species has the maximum number of lone pais on the central toa? (a) Bir, ®) soy (Cor (D) XeF} ‘Which of folowing energy terms are associated with the Bora-Haber cycle of dissolution of BaCl, in water? (A) Hydra () Latice energy of BaCl, (©) Sublimation energy of Ba () Electron anity of Cr ‘The formal charges on different atoms in the Lewis structure of Ny are (1 (O20 (B)-1, 41,0 (D)0,44,-2 (Choose the correct angle order. (A) BPH in PH; = HCH in cH, (6) HINA in NH, < HPT in PH, (UNH in NU, < HPHin PHY (D) O86 in SO} < ONE in No; Select the correct statement(s) about O, molecule. (A) Correct structure of ozone is O=0=0, (B) Molecule is planar and polar. (©) Wis diamagnetic (D) Teas bent structure Choose the correct statements from the following, (A) The tatios of bond ta srbond in SO, and SO, are identical. (B) The hybridization of $ in SO, and SO, is identical (C)The § atom in SO, is more electronegative as compared to that in SO,, (D) SO, is planar while $O, is non-planar ‘Which ofthe following species are isoelectronic and also have the same number of atoms? (SFB) [BFS (CBF, () NF Conse the following four monoatomic ions M,N’, X and If lattice energy order is MX >NX and hydration ‘energy order is NY>NX, which of the following must be true? (A) Covalent character onder is MX > MY. (B) Thermal stability order is MY > NY. (C) Hiydration energy order is MX > NX. (D) Hydration energy order is MX-< NX@iitjeehelps Comprehension Type Questions (CoD Te ede ko chao Passage 1: For Questions 1-2 ‘According to Bent’ rule, more electronegative atom pro~ {ers to slay in that hybrid orbital which bas less s-char- acter and lone pair prefers to stayin that hybrid orbital which has more character Consider the molecules given below and answer the fol~ lowing questions. oS aa 41. Which of the following bond length order is correct? (A) d, H,-B-H, ®) WB, <1“ BoH, © mE BH, (D) None of these Passage 8: For Questions 15-17 ‘The binary boron-hydrogen compounds are called. boranes, Experimental and theorelical studies of the @iitjeehelps boranes have had a fundamental impact on all of chemis- ‘uy, organic aswell as inorganic. ‘There ate two series of boranes. @) BH, (called nidoboranes) (@) BUN, (called Arachno-boranes) 18. Select correct statements about BH, (diborane). () Is isoeleteonic with ethane (i) Tis isostructural with ethane {ltt Hybridization of each boron isp GV) AILB-T bonds are identical (V) Iisa nidoborane (A)LI0L j@y mv (OUI (D)LMLV 16. Find the maximum number of atoms present in one plane which i perpendicular to that plane which con- tains all 2c 2e bonds of BH, (A)Two (B) Four (six (D) Bight 17. In which of the following compounds at least one valance shell orbital of underlined atom remains uunhybridized? (BH, (8) BH: (Ba, (D) None of these Passage 9: For Questions 18-19 Dilletent kind of molecules ate available in chemistry, like molecules having single central atom, molecules hhaviog more than one centzal atom, molecules having odd ‘number of electrons and even if some molecules do not ‘exist with theoretical support 418. The reason for non-existence of which molecule is not the same with the molecules in other options? (A) Xett, (8) HFO, (SH, wm, 19. Which ofthe following statements is incorseet? (A) The free electron of C10, molecule is not present in the d-orbitl of Cl atom (B) The hybridization of central atom of CICO, isp" (©) The dein CH, is smaller than dey in CP, (D) The bybridization of N-atom(s) in NO, snd its dimer is diferent Passage 10: For Questions 20-22 Molecular orbital theory is completely based upon the wave mechasical approach, The MO diagram gives the energy comparison between different orbitals. 20. Choote the carect ionization energy order from the following options. (A)F.>F (B)B>B, (NB Which of the following orbital is having maximum umber of nodal planes? We, (B) Ais lobes interaction) © mo D) Fay 24.£22. In the process of Nz +N, , the electron is removed. from provided the x-axis is the bond formation axis (A), orbital ,. orbital (© %, orbital (D) 05, orbital Passage 11: For Questions 23-24 According to Molecular orbital theory, electrons in a mol- cule are present in molecular orbitals, Molecular orbital i defined as the region or space around two or more: nuclei where electron finding probability isthe maximum, 23. There is largest difference of energy between the molecular orbital of dioxygen in (a) 6, and, B) 4, ©) a, nde, id © o,,ando:, 24, B, molecule will be diamagnetic when (d) sp mixing is NOT operative, (Q)s_p_ mixing is operative and Hund's rule is violated, (11) «-p mixing is operative and Hund's rele is NOT violated (4). (an, B) @), am) (D) (D, (1) and com) Passage 12: For Questions 25-26 Dipole moment gives an idea of the polar character of a covalent molecule. Itis a vector quantity as it has a direc tioa ar well at magnitude. A molecule with y = 0 i non- polar and with #0 is pola, 25. Ifthe dipole moment of NF, is 0.80 x 10" Cm, then the dipole moment of NH, is (A) 080% 10 Cm (0) 4.90% 10° Cm (B) 12x10% cm (D) 07x10" Cm 26. Which of the following dipole moment order is correct? (A) XeF, do.» (OF,) (U The tes character in the orbital contsining lone pair of H,0 molecule is 30% where cos(1045°) m5] (1 HEH angle in CH, ~C=CHT is exactly equal 10 10928 (QV) The FNP in (NE isos than FEN NHL: (A) LILI @uwv (@ Lav @y.uL Passage 15: For Questions 33-36 IF, is a molecule in which T atom is in the maximum ‘oxidation state, and the hybridization for Tatom issp'd 33. ‘The number of FIF adjacent angles in IF, molecule is (ao 1s ©» i 34, The number of FHF angles less than 90° and equal to 90° are espectively (A) Sands (B) ands (©) Sand 10 (D) Wand 1s 35. The number of I~ F bonds having the longest and shortest lengths are respectively (A) Sand2 (B) 2ands (©) Sands (D)2and2 136, The number of planes of symmetry in IF, is ws wT 4 ws rcChapter Chemical Bonding Passage 16: For Questions 37-39 ‘One more electron oF atom can change the system a lot in several aspect, 37. Choose the correct bond angle order (wen, > én, sen, @)CH, cH, >éH, (CH, > CH, > CH, (D) CH,>CH, =CH, 38. Choose the correct bond angle order. . (a) CH, > CH, > CH, (8) CH, > cH, > én, (CH, >cH,> CH, (CH, > EH, > én, 39. Choose the correct onder for C-H bond length (A) CH; > CHT, > CH} (8) CH, = CH, > CH,” (CH=CH, =cH, (cH, > cH, > eH, Passage 17: For Questions 40-42 ‘The structures of P(CH,),F, and P(CH,)F, are shown below: : F weg? ae gh io | | \ (A) x 2120", y >120" (B) x 120", y < 120° For molecules P(CH,), F,,, when the value of n (©) dys (axial) decreases. a. 42 Passage 18: For Questions 43-44 London force depends upon molecular weight, the ‘number of polarizable electrons aad molecular size 43. Which type of interaction is involved in the solubility of noble gas in water? @iitjeehelps (A) Instantaneous dipote-induced dipole interaction. (B) Dipole-cipole interaction, (C) Dipole-induced dipole interaction. (D) Ton-dipote interaction, 44, Choose the correct order for boiling point, (A) Gel, > SiH, < CH, (B) Xe >Ne>He (Hest, () CH> cD, Passage 19: For Questions 4547 ‘No ionic compound is 100% ionic as well at no covalent compound i 100% covalent” 48. Correct solubility order is (A) CACIO,>BaCz0, (8) BECO, T, (C)D,>He (D)T,>D, Passage 20: for Questions 48-50 ‘Valence shell electron repulsion theory (VSEPR) can be used to predict the approximate shape of a molecule. Electrons in bonds and in lone pairs can be thought of as “charge cloud” that repel one another and stay as far apart possible, thus causing molecules to assume specific shapes, ‘The repulsive interactions of electron pairs decrease in the order: Lone pair-lone pair > Lone pait-bond pair > Bond pair— bond pair. ‘These repulsions result in deviations from idealized shapes snd alteration in bond angles in molecules 48. Molecular shape of XeFy, SFy and CF} are (A) the same with 2, 1 and 0 lone paits of electrons, respectively (B) different with 2, 1 and 0 lone pairs of electrons, respectively, (C) different with 0, 1 and 2 lone pairs of electrons, respectively (D) the same with 2,0 and 1 lone pairs of electrons, respectively, 49. Which of the following statements is correct with respect to bond angle? (A) The F-S-F angle in SF, is more than 109°. (B) The H-N-N angle in N.H, is approximately 180°. (©) The F-Kr-¥ angle in KrF, i 90, (D) The CLN-0 angle in NOCLis more than 120°.‘50. Which of the following statements is incorrect? (A) In CIF, the axial CLF bond length is larger than. equatorial CLE bond length, (8) In SP,, P-S-F equatorial bond angle is not 120° and 104° due to lone pair-bond pair repulsions. (€)In ICL; bond angles is 90°, (D) In OBr, the bond angle i less than OCI, Passage 21: For Questions 51-53 HEN and HINC molecules are formed by the same 51. Which of the following properties are identical for HEN and HNC molecules? (A) The number of obonds, (B) The number of bonds (©) Tae number of lone pairs. {D) All ofthese ‘The correct set of formal charges for HNC is. (A)0.0.0 (B01 (04-1 (D) +1,0,-1 Which of the following statements is incorrect regarding the HCN and HNC molecules? (A) The hybridization ofthe central alom is same for both, (B) They produce different ions in solution. (©) They produce the same ions in solution, (D) They produce the same number of ions in solution 52, 53, ASSERTION-REASONING TYPE QUESTIONS In the following set of questions, a Statement Tis given and a corresponding Statement Ile given below it. Mark, the correct answer as: (A)If both Statement I and Statement M1 are true and Statement II is the correct explanation of ‘Statement L. (B) If bots Statement I and Statement IE are true but Statement IT is not the correct explanation for Statement (© U Statement Tis true but Statement Is false. (D) If Statement Is false but Statement ITis true. 1. Statement I-The shape of the molecule depends upon hybridization ofthe central atom. Statement Ik: Hybridization can explain the shape of the molecule 2, Statement I: sp'd’ hybrid orbitals are at 90° to one another. Statement I: There are twelve 90° angles in regular ‘octahedral geometry, 3. Statement I: Hydrocarbons with cumulated double bonds are non-polar irrespective of the number of ouble bonds present in them, @iitjeehelps Assertion-Reasoning Type Questions Passage *22: For Questions 54-56 ‘The Lewis structure drawing i the first step to draw the structure of a compound, This method has a lot of limi tations which are overcome by the theory of bybridiza- tion to explain many properties af molecules! species. 54, Which of the following species have a bond as wel as coordinate c bondi thet Lewis sruere? (SIE, (B)CO, (©) SO, (D) NO; What are the diferent kinds of bonds and interac: tions preeat within CuSO, SHO? (@)ebond (II) wbond (IIT) Coordinate bond (QV) Electrostatic forces of traction (W)_ Hydrogen bond (ipo ~ dipole) (Wb Hydrogen bond (ion ~ dipole) (A) LIL only (3) 1,11, and TV only (©}HVLanéVronly —(D) Allsickinds of forces of wtrection ae present Which of the following statements isle incorrect regarding the real structure and Lewis structure of phosphate ion? {a) Thenamber of ehondsissame inboththestestnes (@)The number of lone partis same in both the 5. 56. structuses, (©) The number of = bonds is same in both the structures, (D)'The shape remains unchanged in both the structures “One of more than one correct answers. Statement IThe resultant bond vectors of two C-H bonds at two ends are lying in the tame line with opposite ditection. 4. Statement I: The dog in O.F, is almost same with that in O, molecule. Statement II: O,F, exists in the form of also, -FIF 5. Statement I: XeH, does not exist but Xe, exists. Statement UL F is more electronegative than Hand ‘causes lesser extent of d orbital contraction as com= ppared to that by H atom, 6. Statement I: The removal of an electron takes place rom #.gaq,OFbtal when N, converts to Ny. Statement I: The bond order decreases by 0.5 when Ny converts to, 7. Statement I: (AICI), i# not electron deficient but [AI(CH,) sis electron decent. Statement Mi: (AICI), possesses 3¢ - de bond while [AU(CH,)], possesses 3¢~ 2e bond. crChapter Chemical Bonding 8. Statement I: Allene molecule is non-polar. Statement Il: Allene molecule ie non-planar, 9, Statement I: On addition of two electrons to NOY, the N-O bond length increases by -9 pm while on adding only one electron to NO’, the N-O bond length increases by -9 pm. Statement I: In both the above processes, the bond order of N-O bond is decreased by 0. 10, Statement I: When BF, and BCI, are mixed together it produces BE,Cl and BFCI, through halogen exchange Statement II: Figure below isthe intermediate for the above process. WN Na? 41. Statement I The delocalization energy or BN i less as compared to CH, Statement It B NU, i polar while C,1T is non-polar. 412, Statement I: [AUBr,} exists while the existence of [Bris questionable Statement Il: Alis larger in size as compared to B atom. 413, Statement I: Sill, is highly reactive towards water while CH, is non-reactive Statement II: Polarity of SiH bonis just reverse of, that of C-H bond, 14, Statement I: HgF, is colourless while Hg, is coloured. Statement I ris more polarizable than F- F 15. Statement I:S,F, has the structure S=S{ but $,Cl, has no such analogous structure, F Statement IL F being more electronegative than CL causes better d orbital contraction as compared to Cl @iitjeehelps 16. Statement I In TH, the oxidation state of Tis + Statement IE: TH, is isomorphous with NILI, and Cel, 17. Statement I The deg in CH,CO,H ate different while that in CH,CO.Na are identical Statement I: Resonance lakes place in CH,CO,Na ‘but does not take place in CH,CO.H. 48. Statement I:The direction of back bonding in CCI, and:CCl, is the same Statement Ih In CCl, 2p-3d bonding and in CCl, 2p2- Sparbonding Lakes place. 19. Statement I dp is greater than dy it PFCl, Statement Il: The axial orbital has no s character ‘while equatorial orbital has 33.33% = character in ‘tigonal bipyramidal geometry. 20. Statement I: Be,Cl, molecule hasan incomplete octet Statement I: Tn Be,Cl, each Be atomisp* hybridized 21. Statement I The nodal planes of a bonds of 1.3 butadiene lie inthe same plane. Statement Il: rbonds are also lying inthe same plane in 13— butadiene. 22, Statement I dyy-g in MnO; it less than that in MnO; Statement IL: The higher oxidation state of an ele- ‘ment causes higher extent of d orbital contraction and forms more effective bond with O atoms. 23. Statement Mercurous ion is always diamagnetic, Statement I: The 79th electron of each Hg atom gets paired up to form a bond between two Hg atoms sce Wim de he ao ‘The answer to each of the following questions isa non- negative integer 4. Find the number of compounds of Xe which islare associated with 180° bond angles XeF,, ICH, 1, XeF, Xe0,4,Xe0, Xe TEC, 2. Find the total number of d-onbitas used for bonding in XeO.F, '3. Among the following, find the umber of processes in Which ion-dipole interaction is not observed, TF in I, KClin water, CO, in water, Xe in ice CHCL in water 4. Find the total aumber species) among the following, containing 3e-2e bond. Be Hy (BeHl),,Be,Cl, Al (CH), ALC, 1.0 BH BALCH), 5. Find the total number of chemical species in which mentioned bond length decreases due to back bonding BF, (BF) B(OMs), (40) PF, (PF) H,SINCO_(N-Si), BINH, (BN) Ne (N-0) 0, (0-0) 46, Find the total number of compounds whose bond ‘order is unaffected whether the s-p mixing s consid ered oF not, B, C.N,.O, 7. Caleulate the value of win 22,4, (Si,0,.) 24,0, 8. Find the maximum number of hydrogen atoms that ‘may le in one plane in BH,(CH,), molecules,9. Find the number of chemical species which are iso~ electronic and have the same bond order a8 of CO. CN", NO", CF.08 10, Find the number of chemical species which are planar and d,, orbital of central atom participates in the hybridization Xek,XeF, XeF,, Xek, SF, ICT, 11, Find the tolal number of compound(s), which ialare repelled by magnetic field .0, KO, O, (Ft) NOTBE] KOS 30, 412, In the compound PCI, F,., possible values of k ate 0 to 5.Then sum of all possible value of k for the com- pounds having zero dipole moment is, 413. Find the number of 90° angles in XeFS molecules 14, The sum of oxidation states of N atom in the follow- ing compounds of nitrogen is ‘NH, NIH, NH,OH,N,N,0,NO,N,0,,.NO,.N,O, 415, The maximum number of atoms lying in the same plane in B Fis, 16. In a molecule of CH,CI, the number of planes con- sisting of maximum aumber of atoms where at least two atoms are same i 417. The number of planes of symmetry in TeCl, is 18. The number of planes whieh divide TeCl, molecule {into two equal halves is. 419. The umber of planes of symmetry in SbF, ie 20. The number of planes of symmetry in SII, is 21. The maximum number of atoms lying in the same plane in (AICL and the number of such planes are respectively and @iitjeehelps Matrix-Match Type Questions 22. In Me,C molecule, the maximum number of atoms that may ie in the ame plane and the number of such planes are respectively and 23. The maximum number of atoms that may lie in the same plane of eclipsed form of C,H, and the number ‘of such planes are respectively and 24. The maximum number of atoms that may lie ia the same plane in P(CH,), (CE,), is and the ‘number of such planes is. 25. The maximum number of equal angles in CHF, is 26. The sumber of lone pairs in BEY is, 27. The maximum number of atoms that may lie in the same plane in (CH),C = SF,(CH,),is, 28. The maximum number of atoms that may lie in the same plane in N(SiIL,), and the number of atoms are ‘out of that plane are respectively and 29. The number of nodal planes when two d,, orbitals from two atoms produce antibonding 8 bonds is 30. The maximum number of atoms that may lie in the same plane of staggered form of CH, and the number of sueh planes are respectively and 31. The sum of the number of «orbitals whose lobes are available along the axis and are involved in the hybridization of central atom of Xe and XeF is 132. The number of triatomic molecules, which are non- planaris SaCl, BE, BeF, OC, 33. The sum of oxidation states of all P atoms in the fol- lowing compound of phosphorus is P., PH, IPO, P,0,,H,PO,H,PO, MATRIX-MATCH TYPE QUESTIONS In each of the following questions statements are given in| to columns, which have to be matched, The statements in Column I are labelled as (A), (B), (C) and (D), while those in Column II are labelled as (P), (Q), (R), (8) and (1). Any given statement in Column T can have correct satching with one or more statements in Columa IL 1. Mateh the molecules withthe type of overlap in their bridge bonds Column Column (A) Bei, ©) ap -s—ap @) BE, (Q) spt-s-5 © AL(CH), (8) sp -sp'- () Be(CH,). (S) sp'~sp'- sp" 2, Match the molecules with their properties. Gaumnt (A) Na (rans) (P) Thas only two lone pairs (B) NAL (gauche) (Q) Ie shows geometrical isomerism. © No, (R) Was shortest NAN distance. () NH (8) lis non-planar. (1) Ithas ze10 value of dipole ‘moment Celumn llChapter Chemical Bonding 3. Match the compounds with their properties ern Column ll (A) Xe, (®) Pyramidal geometry. (B) XeOF, (Q) Non-planar molecule (© XeOF, (R) One lone pairs present ‘on Xe. (8) d, orbital is involved in hybridization of central atom. 4, Match the compounds with their properties. Columnl Column (A) BH, (P) Allatomss are central atom. (B) Sik, (0) Tt has no lone pair. (© BN, (R) Ithas only bond. () sic (8) Itis non-planar. '5. Match the compounds with their Lewis structures, Columnt Column tt (@) so () The central atom does not have lone pai (@) INC (Q) All atoms ofthe species have lone pair(s) © sir, (8) Ithas cowedinate bond. ©) Noy (S) thas o- bond and sx-bond as well as coordinate bond. (1) Species having only bond. 6, Match the type of hybridization with the orbital involved. Eolumnt Column (A) sp'd (TBP) ®p, (B) sp" (orbitals tyingin xz plane) (Q)p, Ome ®d., ds @iitjeehelps 8, Match the molecules/species with their properties, Column (a, (P) The axial bond length is larger than the equatorial ‘bond length, (Q)'The axial bond length is shorter than the equatorial bond length, (8) 4, orbitals are involved in bonding. (6) Alipossible bond angles are ‘ot identical (D)Allpossble bond angles are tical ‘Column ll (B) [SIF (©) Be, ©) Pu" ‘9. Match the moleculesispecies with their properties. Gelumn| __Column J (a) BR, (P) thas atleast one angle less than 90" (8) 10, (0) The central atom issp'd hybridized © 10" (8) Itis non-planar. (8) The central atom is having only one lone pair. 10. Match the molecules with their properties. Golurwn Column (0, (®) srbond is present in the molecule (8) XeF, (Q) bonds are only present (©) BeH, (B) Its byperootet. ©) co (6) lis bypovalent. (Wis linea 11. Match the moleculesispecies with eorrect statement related to their property 7. Match the moleculesfspecies with their properties Golumnt Column tt (A) ABs, (P) Teas zero dipole moment B) CR, (O)Itis planar, (Ia (R) The central atom of the molecule is sp"d hybridize, ©) PCLF, (8) Itisnon-planar. (1) Maximum four atoms are lying in the same plane Column | Column ©) [BRI (®) Allatoms are p-block elements (8) [BF () The central atom is as-block clement. © sic (B) The centtal atoms) is(are) sp" hybridized, ©) BEY (8) All atoms are s-block elements (1) The central atom is p-block element but the surrounding atoms axe block elements. Single Correct Choice Type Questions +) 6.) n.© 20 20 12.0) 3. ©) 8.0) 2© 4© 9. @) 14.6 5.0 10.8) 13.) 16.18) 21.0) 26.(B) 17.) 22.(D) 27.0) 18.4) 23.0) 28.0) 19.0) 24.0) 29.) 20.(A) 25.0) 30.0)34.(A) 32.(A) 33.8) 34. 0) 35. B) 6.0) 37. ©) 38. (B) 39. (A) 40. (B) 41.0) 42, (A) BRRBRE ) B) B) B) ) © ‘Multiple Correct Choice Type Questions |. (A). (©). (D) (A).@) (A). (C).(D)_ 10. (B).(©) 1 (A).C).D) 14. (B),(©),(D) BO.) (A).(@) (A).B).(D) 14. (B),() 8. B).(.D) 9. (A),B).@) 12. (A),) 13. (©) Comprehension Type Questions ©) ®) @) @) (B) B) ©) B) 9. (D) 10. (0) 11.) 12.6) 13.) 14. (A) 15.) 16. @) 7.0) 18. @) 19.) 20. (D) 45. 16. 7. 18. 19. 20. 2. 2 22. 23. 24, 2s. 26. 27. 28. 29. 30. Assertion-Reasoning Type Questions 1.) © 2.0) 6. @) 3. (A) 7. (a) 4. (A) 2. @) Integer Answer Type Questions 14 7.2 23 a4 34 9.5 4s 10.1 5.5 4 64 12.8 9. 10. 1" 2 13. 1", 45. 16. ”. 18, (0.0) “© (),6) HO ),6) (A), ©) W© oO “ ) “ o @) B) B) oO ) “ “ © “w @iitjeehelps 49, 51. 52, 53, 8) 22, 23, (C). D) 25. 26. 27. 28. 31. 32, 33. ) @) cy © Cy (A).8), (0) (A), (D) AO (A). A.D) (A).(8),(D) a) o 8) © 35. (D) 37. 38, a) B) © 39.(A) 40. 13. 14. 45. 16. 19. 20. 21, 22, 23. ) a) “ “ @) 3,10 612 46 or 55. 56. 57. 58 59. 60. a 42. 43. 47. 43. 49. 50. "7. 18. 19. 20. 25. 26. 27. 28. 29. © ©) © cy) ©) B - (A) (D) (A), 8). (©, ©) (A). B).) (0) A.) (A),@) ©) © © - B) 45. 46. “w ) @) @) © ©) © ©) ©) @ 2 16 4,6 “1 62. 51 52 53. 54, 5. 56. a1. 22, 23. Answers @) @) - (A), (B) = (A), (©). D) ©.) - (8). (C).(D) - (A), (B.C) BO.) A.) @) © () )(©,@) @) B).(0,) © “™ “ 31.4 32.0 33. 6 155Chapter Chemical Bonding Matrix-Match Type Questions 14.) @Q 4. (A) (0), (R) ) >) B®.) © >) (> (0) ©) 3) D) >), OB), (8) 2. (AVP), B).C) 5. (A) ©). (8). B) > @),(8) B) > ®).®).(8) © (> @). ©) >) ©) >). 3.4) 3 @).(0).(B) (A) >), (0.18) B) >(Q).(8) (B) > ().(Q) © >).®.8) © >O),().®).(9) @iitjeehelps 7. (A) >®), (Q).D) 8) (0), ®).) (>®), Q ©) ®.), 8 (A) 4 ().(R),(S) B) > ®.S) > @), 8) O90 9. (A) >), BS) B)>@). (Q) (> BW.) 10. (A) >) B) > Q).®).) (©) Q).(S).0) ©) >@), 0 1.7 RO B)>O.® (>®), ®) Oh), ®&