Med-22-23-XII_C_C1_The Solid State Set-2 Assignment CS ad NEET SECTION -A Objective Type Questions (General Characteristics of Solld State, Crystal Lattice or Space Lattice, Unit Cell, Calculation of ‘number of atoms In a unit cell) 1. Which of the following crystal is represented by asdecandaspeye 907 (1) Ortromombic 2) Monociinie @) Trictnic (4) Tevagonal 2. Copper belongs to a crystal system represented, by the crystal dimensions as (1) a= B=¥=90,a=b=0 @ atpeyaz=b=c @) @ = B= 90% 7 # 90%, 4) a=pry= 90, a¢bee 3. A compound formed by element A and B ‘rystalizes in the cubic stucture, where A atoms ‘are at the comers of a cube and B atoms are at the centre of the body. The formula of the ‘compounds is (1) 48 @) AB, @ AB, (4) AB, 4. ‘Asolid with formula ABC, would probably have (1) A at body centre, B at face cones and C at ‘comers of the cube 2) A at comets of cube, B at body centre, C at face conve @) A at comers of hexagon, B at contres of the hexagon and C inside the hexagonal unit cat (4) A at comer, B at face contra, C at body contre Corporate Olice : Aakash Tower, bho A solid ABC has A, B and C arranged as below ‘The formula of solid is () Ase 2) ABC, @ Ase @) A8,0, ‘An alloy of copper, siver and gold is found to have ‘copper constituting the ccp lattice. if siver atoms. ‘occupy the edge centres and gold is present at body centre, the alloy has a formula (1) CuAg,Au @) Cupaay ©) Cura,ru () Cuagau Ina face centred cubic arrangement of A and 8 atoms, atoms of A are at the comer ofthe urst 2a) and atoms of B are at the face centres. One of the Aaatom is missing from one comer in unt cell The ‘simplest formula of compound is ) AB, @) AB, @) AB, (9) An8, A solid has a structure in which A atoms are located at the cube comers of the unit call, B ‘atoms are located at the cube edges of unit ce! and the C atoms at the body centre, Formula of the compound (1) cas, @) CAB, @) CAB ) CAB , Pusa Road, New Delhi-110005, Phone : 011-47623458 Scanned with CamScanner.—s Med-22-23-XII_C_C1_The Solid State Seow scorectieEmmsdewy ran sts w 8. When ape ot sok whee we ent meng (0 tee yt 2) Neto covet ok 0) Newari, (0) Mette eyes (close Packed Stuctres, Calclton of Pact Efficiency) a 10. In any one cyst Anas formed eal close backing and 8 stony are prsent at sve? teeanega vos any tarpe ot ey ana Nirameer cB tons ben narbe crass Satara on a’ @2N ) 2N 11. A binary soled A'S" has a stucture wit! Boas constiung the Inte and A* fons coctpying 25% terahedral les. Fomua of be sold is was @as 2) 8, A, 12. In a crystaline sold anions B are arranged in cubie close packing. Cation A are equally istnbuted bebween ectahedral and tetraesral ‘voids If al the octahedral voids are occupied. De formuta forthe sold 's as @) a8; OAs 8, 13. Ina cade cose packed structure of mixed exes, the latice is made up of exe ions, one eighth of tetrahedral vos are occupied by divalent (") fons, while one-hat of the octahedral words are ‘occupied by talent ions (Y™) thn te femal ot the onde (9) %%0, @) XN0, 0) X¥,0e 8) KY0 14. Teanum eqytazes a face centred cube ation Itrwacts wih carbon or hydrogen iterstaty by towing atoms of tse elements to occupy holes in the host latice, Hydrogen occupies tevahectal roles but earbon occupies octahedra! hoes the forma of tanium carbde and hyde are 0) TC, TH @) Te, TH, @) Tie. Te, () Te, TH ‘Corporate Oc : Aakash Tower, #, Pusa Road, New De 1 18 7 The ste lnbeied a8 2 i ee arrangement is x (0 Feu Serta © copewe cen ©) Carer ten (1 reeset dw} een Aunt cel is obtained by dosed packing layers ct atoms in ABAB. pater. The Wil murber et terarecr an ocho vs nw UNC respechey ma amas ass w 126 Incr sok, be oxteens ae aranged in ce Cations A occupy. © cr ne teranecral vids and catons 8 ccasy on thi fhe ctahestl vids She potabe formula of he compsund is ) a80, @ 18,0, ©) 80, ©) ABO, The numberof cctahedral stein a utc! cove pack aay of Nephees (Ne a2n aan won Fer a solid with the folowing structure, the Cmordnaton number othe pont B as os 10008 Phena : O11 4TERDESE Scanned with CamScannerMed-22-23-XII_C_C1_The Solid State 38° The Soli Site Board & yr et 20. The empty space between the shaded bats and hhotow bal’s as shown inthe ckagram Is ead (1) Hexagonal vod 2) Cctahesra! veld (2) Terahodral void (4) Double angular ois 21. An element erysalses in a bee’ lace, Nearest neighbours and next nearest neighbours of the ‘elements are respectvely 0 @ oes a 66 22. The total number of elements of symmety in a cubic crystal is wes an @ 0 wu (Calculation for Unit Cell Dimensions) 23. Ita! the length of unit cel, then which one is corect relationship? (1) For simple eubie lative, Radius of metal atom (@) For bec lattice, Radius of metal atom 2) For fc ‘tice, atom = 2. Radius of metal 7 (4) Avot hese 24. For face centered cubic structure edge length ‘a can bo related with ragius as () a=rxv2 @ @) a=2V2r Wane Corporate Otic : Aakash Tower, 8, Pusa Road, New Deii-110008. Phone 25, Polonlum adopt cubic structure with edge lengtn ‘of cube boing 0.336 nm The distanen betwen te polonium atoms which be a the comers along the ‘ody agonal is (1) 0.336 0m @) 0.291 9m @) 05820m @) 0481 am 25. leo eysaises in a hexagonal inten having the lume of unt eet a8 132» 10" em? densty is 0.82 9 em al a given tomperatre, then umber of 1,0 molecules per unt ct On @2 os ws 27, Libium meta has a body centred cubic stuck ts deny i 053 gem? and ts mor mass fs 8.94 g mot Caleulte the edge length ofa unt cel of Litium met () 1536 5m 2) 3518 pm @) 82749 (@) 2837 pm 28, What is the volime of a face centred cubic unit cel, when fs density is 20 9 en and the molar ‘mats ofthe substance i 60:23 9 mar"? () 4x 102% em?) 2« 10 emt 0) 444 10% em? — (4) 22 107 em? 29, The C-C and SHC interatomic distances are 154 pm () 77 pm 2) 94 pm @) 14pm @ tHpm {Imperfections of Defects in Solids, Applications of petype and nype Semiconductors) 30. Pyroslecticenstals produce febie electric curent (1) On deformation (2) On dissolving ina sohent (8) On heating (4) On sublimation 31. Zine oxide on heating changes to yellow. This is because (1) Zine oxide is a stoichiometric compound (2) Zinc oxide is covalent compound (@) Zine oxde shows metal excossive defect (4) Ht shows mati dafcieney defect 147623488 Scanned with CamScannerBoas & Exar (eve Med-22-23-XII_C_C1_The Solid State ‘The Said Sate 39 32. Feentes in an ionic erytae re (1) Latten stes containing electors 2) Intersil sites containing electrons (3) Lotion stes that are vacant (4) Intersil sts containing cations 33. Wen an element of group 14 is doped wah an lament of group 15, (1) type of sem-concuctors ae formed (2) type of som conductors ae formed (0) Zootes are formed (4) Bhectoiies ae formed 24. Ariteromagnetic property is oven 98 Orttr attest oryte mega 235, Substances which are magnetic but having lees ‘magnetic moment than theoretically exteulated ‘lua are cated (1) Femomagnete (2) Fernagnete (8) Aatioromagnetc (4) Oamagrete 36. Imantferomagnetism (1) Alignments of magnetic moments ed @) Alignments of magnetic moments in one ‘Arecton is compensated by algrments in 6 ‘opposte dvectons (9) Alignments of magnetic moments does not take place |) Algnments of magnetic moments varies with the natir ofthe mater! 37. Which is tue about Pezoelactic cysts? (1) They produce an electric curect on hestng @) They produce an electric current when a mechanical sress is apoiied (8) They ae isiators (4) They ae magnete in nate 38. When a crystal having rock sat ype geomety is heated in the presence of i's metal vapour ten fect int wil be (1) Soichiometne detect (2) Metal excess defect 8) Anion excess defect 1) Fronke! defect Corporate Ofice Aakash Tower, 8, Pusa Read, New Debi 110005, Phona 23 The percentage of Fe lon present in Fegas Oya 5% a 55% @) 100% 18% 111 moe of NaCl is ded wih 10° mole of Si, ‘Whats te numberof eatonie vacancies per moo nec? (109 mote (@) 802+ 10" mole" 0) 10% mote? (4) 602 « 10% mole? SECTION -B NCERT Based MCOs he INCERT Po. 6) (1) Molecular told @) Covalent sokd @) Amorphous sold (4) Metatie Sold ee c.ae fey 2 00" represents which of tho fotowng crystal eystom? INGER Pg. 10) (1) Rremboredm —@) Onherhembic @) Teragenat (8) Otic Tha lar hang AAA yp pator INCERT Pg, 14) (1) Soe cube (2) Facecented cubic 6G) Bodpeerted cubic (4) Endcenred ‘The formula of enstatine tod havieg atoms Bin cep arrangement, atoms ‘A occupying half of fectahedra and hat of etrahedra voids is (NCERT Pg 18) / AB Ae, OAS, AB, Number of moles of tetrahedral voids present in FCC type structure having 3 meles of atoms is INCERT Pg. 171 os ae oe 10 “The ecortnaton number in one mensional dose packed arangerert is INCERT Pg. 14) 2 as os ws lW ene of the atoms is removed from simple cubic Lunt cell, then the effective number of atoms remained aunt cel is [NCERT Pg. 12] m7 an oar Scanned with CamScanner | }40) Ime sats same 10. ” ‘The ruber of possible three mensional! aticws (Brava Lacon) = INCERT Pg. 11) or as au as ‘The fomusa of FeO generaty ranges tom Fey to Fe,0 due INCERT Pp 26), (1) Metal excess detect 2) Meta’ deficiency defect 18) Impurty cetect, (4) Frente! detect Zine ove, white colour at room temperate, ‘acquires yeBow colsu on heating du to INCERT Po. 26), (1) Zn being a transtion element @) Paramagnetic natu ofthe compout @) Trapping of electrons atthe site vacated by oxide 8 (4) Hgh coordination number Select the comectsttement(s) [NCERT Pg. 27] (1) The conductvty of meta's depends upon the umber of valence electrons avaiable pe stom @ The atomic orbitals of metal atoms form molecu efia’s whieh ae so cose in eersy {9 each other as to form a band {@) Sticon and germanium are called intrinsic semeonducors (8) Ab of these a Bona & Compnttin Exam (Lael 12 Whe of the ftiowing tone ofthe choratoristis ‘tporamagnetiesbstonen? (NCERT Pa 29) (1) Seong ateacted by a magna ld (2) Mognetzed in 9 magnetic field In he some ‘srecton {) Dot ose thoi magnetism in tba absarco of magnet td (4) Contains no unpaired alectrons 42. Which of the folowing compounds will show Sehotky defect? INCERT Pp. 25) as @) Ago @ os (8 aot 14, An elament forms cep latice with a cel edge length of 400 pm. The density ofthe element is 10 gem®. The alomc mass of tho lament vl be [Take N= 6.02% 108] (NCERT Pg. 22), assy @ 20 @) 9630 2050 18. Semiconductors have electrical conductive inthe range om INCERT Pg. 27) 104 t0 10% chart ar! (2) 10 to 107 oar ar (0) 10% to 10° chart art (8) 104 10° chert mt a Corporate Office : Aakash Tower, 8, Pusa Road, New DeiN110005, Phone : 01147623459 Scanned with CamScannerMed-22-23-XII_C_C1_The Solid State Assi gnment (General Char Lattice or Space Lattice, Uni SECTION -A Objective Type Questions cteristics of Solid Sta number of atoms In a unit cell) 7 In crystaline sols, which of the following element ‘of symmetry is not present? (1) Axis of symmetry 2) Angle of symmetry (3) Centre of symmetry (4) Plane of symmetry Amorphous solids have (1) Orderly arrangement of atoms {@) Repeating unit of unit cei {@) Long range of meiting point (4) Anisotropy The type of crystal system shown is - (1) Cubic (2) Orthorhombic (2) Monectinic (4) Tetvragonal In a unit coll, atoms A, B, C and D are present at ‘comers, face-cenives, body-cenle and edge-centre: respectively in a cubic unit cell. The total number of aioms present per unit cell is M4 (2) 8 @) 15 (4) 27 Ina unit cai, atoms A, B, C and D are present at half of total comers, al faco-contres, body-centra ‘and one tied ofall edge-centres respectively. Then formula of unit eel is (1) 48,00, @) ABCD, (2) ABCD () ABCD, 6. Ina unit call, atonis A, 8, C and D are present at comers, face-centtos, body-centra and edgo- ccontes respectively. f atoms touching one of the plane pissing through two diagonally opposite ‘8dges are removed, thon formusa of compound is (1) aBeD, (2) ABD, @) ABD, (4) 48,0, 7. Number of atoms per unit cet, if atoms are present atthe comer of unit eal and 2 atoms at each body ‘agonal 3 @s @ 0 a4 48 Glass is'a” (1), Micté-crystalline solid =:(2) ‘Supereooled liquid @) Get (@) Polymeric mixture (1) Polymorphous (2) tsomer @) Isotope (4) tsomorphous {Close Packed Structures, Calculation of Packing Efficiency, Close Packing in lonic Compounds) 10, Ifradis of a metal atom (A) is S pm and radius of ‘an electronegative atom (B) is 20 pm, then in the unit coll (1) Ain octahedral voids, B in FCC unit @) Ain FCC unit, B in tetrahedral void @) Ain BCC unit, (4) A in totrahodral void, B in FCC unit 11, fn aunt cell containing X#*, Y%* and 2 where X** ‘occupies 1/8th of tetrahedral voids, Y°* occupies 1/2 of octahedral voids and 2?-forms ecp suucture. in cubic void Ther formula of compound is ar @ XV, 0) YZ ) XYZ, Scanned with CamScannerNET (Level) The Seid State 61 12. Ina cep type structure, if half of the face-centred ‘toms are removed, then percertage void in uit cel is approumateyy 0) 54% @) 46.25% @) 60% (6) 37% 13, Ina BCC unit col, hat of the atoms per uit cal ‘are removed, then percentage void is (1 68% @) 32% 44% ) 66% 14, Acrystaline sold AB adopts sodium chloride type structure wih edge length of the unt cei as 745, pm and formuta mass of 745 amu The densty (of the erystaline compound is (1) 216 gem? 2) 0.99 gem (8) 1.88 gem? (4) 1.197 ger? 15. W radius of an octahedral void is ¢ and atomic Indus of atoms assuming cubical close packing R. Thon the roiton between rand R is () r= 2k @ rasa R @) 04k te (8) e=04y wok 16. Which ofthe following statement is corde? (1) On increasing temperature the coordination ‘numberof sokd remains unchanged @) On increasing pressure the coordination umber of sobs increases (@) On increasing temperature the coordination ‘numberof gold increases (4) On increasing pressure the eoordination ‘numberof Soid decreases, (Calculation for Unit Cell Dimensions, Structure of Yonte Crystats) 17. InaCsClstracture, edge lengthisx then distance: boetwoen one Cs atom and one Ci atom i= ai a Wie Lire a 18. The comect statement about CCP stucture is (1) Packing traction = 26% (2) Coordinaton number = 6 (2) Unt cols face centred cubic (8) AB-AB type of packing 19. Ina NaCl structure, if postions of Na atoms and Ci toms are interchanged, then in the new unt cel (1) Na atom is present at body centre 2) Cl stom is present at face centre ) Na atom is present in tetrahedral voids (4) Cl.atom is present in octahedral voids 20. Ametal can be cxystalized in both BCC and FCC Unt cells whose edge lengths are 2 pm and 4 pm respectvely. Then rato of denstes of FCC and BCC tees wt aa oy J ¢ () 16 Oe “ 21. Number of unt cots in 199 Nact ise 28 ap oy Ada @ BEx0 5s, 88 108 ey ES > wy S80 22. Seecnd nearest reghbour in CACl sod os as o) «10 23. Ina caleium fluoride structure, the co-ordination number ef cation and anion is respectively 66 @ 84 44 4, 24 The packing efficiency of the 20 square unit cel ‘shown below is (1) 927% @) 802% @) 74.05% (4) 7054% 25 CC! crystalses in a cubic cel that has a Cr at leach comer and Cs" at the centre ofthe unit el. radius of Cs" is 169 A and 1,.=1.81 A, what is the edge length of unt co"? (1) 350A @) 408A @) 2024 (4) 101A (Corporate Offce : Aakash Tower, 8, Pusa Road, New Deihi-110005. Phone : 011-47623456 Scanned with CamScanner SEL” weaMed-22-23-XII.C_C1_The Solid State 62. The Sold Stato 26. For telrahedral co-ordination, the radius ratio (lt) should be (1) 0416-0732 @) 0792-10 @) 0156-0225 (a) 0225-0414 27. The radius ofthe Nat is 95 pm and that of CI- fon {8 181 pm, The co-ordination number of Na* will be aa Q6 os (4) Unpredictable 28. A mineral having formula AB, crystallises in the cubic close packed lattice, with the A atoms ‘occupying the lattice points. Hence coordination number of A and B atoms are a) 4.8 Qa @) 88 a4 | ' 28. KF has NaCl type of structure. The edge length of its unt cet has been found to be 537.6 pm. The distance betwoen K* F-in KF is (1) 2688 pm (2) 268.8 pm,r3 (@) 2688 pm () Unpredictable, 30. Which of the following features is false regarding the structure of CsCl? (1) Ithas bec arrangements (@) For each ion coordination number is 8 {@) For each ion coordination number is 6, (4) The radius ratio (F,/r_) is 0.93) % 31. The mass of unit cell of Na,O { (1) Twice the formula mass of Nao |) {@) Four times the formula mass of Na,O (@) Six times the formula mass of Na,O (4) Thrice the formuia mass of Na,O 32. In normal spinel structure there is a closed packed array of OF ions. The trivalent cations are present in (1) 75% of octahedral voids (2) 50% of octahedral voids (2) 12.5% of tetrahedral voids (4) 25% of octahedral voids 33. What is the coordination number of Rb* in RbBr unit col ionic radi of Rb* and Br lons being 148 and 195 respectively? m6 a4 es (4) 12 Corporate Office : Aakash Tower, NEET (Levelt) 34, Acrystalino sobd AB has NaCl type structure with tadius of B- lon is 250 pm. Which of the following caalion can be made to slip into tetrahedtal site of crystals of A'B- 7 (1) (rads = 180 pr) (2) Q! = (radius = 56 pr) (radius = 200 pr) = 150 pm) Number of formula units in unit cell of MgO (rock ‘sak, ZnS (zinc blende) and Pt (fcc) respectively () 4,.3,2 43,4 84.44 @) 4.3.4 (imperfections or Defects in Solids, Applications of type and n-type Semiconductors) 36. On rising temperature and decreasing pressure in Cs solid (1) GN. of metal ion increases from 6 to 8 (2) Number of formula unit per unit cet (Z) changes from one to four |) Density of unit cell is increased 1 4). © (Cadi rat is increased 37. | Some of the molecular sods upon heating produces ‘small amount of electricity, hence solid is (1) Piezoelectric: (2) Pyroelectric 1,0) erietectic (4) Ferroelectric {8 Nac: becomes paramagnate at high tempesire due to (1) Formation of F-centre (2) Moten state (8) Chango in oxidation state (4) Conversion of Na* to Na 39. In which of the following defect density increases? (1) Schottky defect (2) Frenkel defect (2) Feconte (4) Impurity detect (Crystal Symmetry) 40 A crystal may have one or more planes of symmetry as well as one or more than one axis of symmetry but it has (1) Two centres of symmetry (2) Only one centre of symmetry (3) No contre of symmetry (4) Three centres of symmetry , Puan Road, Naw Dethi-110005. Phone : 011-47623456 Scanned with CamScannerMed-22-23-XII_C_C1_The Solid State NECTALove! Ih So Sime 63 41. Which of the folowing Is neorreet slatomant 6, A compound Is formed by cation © and bout the Braga's eqation mh = 2d th 7 nin A. the sein frm bawagonal com pac (1) 1 represents onde of relection (hep) Intica and the cations occupy 75% of 2) A, represents wavorength of UVrays used coda! vod, Th format oft compcna (0) 0. roprosents ange of Incdonca ieer201m, (4) 4, represents distance betwaen two parallal () CA, (2) CA, planes 0 cA, CA, 42. The ratio of number of rectangular plane and 7: ton exhibits ben structure at roam terparatrn, diagonal plana ina cic uit co Is ‘Above 900°C, It tansforms to fer stncturn The ae aan aloof donsty of ton at rece trngaratia to that 151 900°C (assuming molae mass and aoc act 2:3 ()o:4 of kon remains constant with torporature) is SECTION - B (WeEr-2019) Previous Years Questions ” Res @ ai 4. Right option for the number of tetrahedral and ve we ‘octahedra voids in hexagonal primitive unit col are: 1 wi oF © 2B (NEET-202 2 a nazis 0.4) rng 8 Which th ncoroct statement? (EET2OT7] @ 612 24 | | Feogphesoon stoma ml ery 2. The correct option forthe number of body centred! “ Ti cols ina typos of Brave Inte unt, @), ensky decreases in case of erysta's wih cols is INEET-2024] | Sehothy’s defect “3 a7 {@) NaCKs) i insulator, sticon is semiconeveter, oe we mihi | silver Is conductor, quartz is piezo elect Fs enya 3. Anelement has a body centered cubie'(bec) | Groce witha col edge of 288 pm, The atomic) (@) Frenkel defect is favoured in those ionic ane compounds in which sizes of eation and ‘anions are almost equal (y 2288 pm In calcium fuoride, having the forte structure, he a coordination numbers for calcium ion (Ca) and 4 B foride on F-) aro—=«(NEET-Phase-2.2016) a) x288pm 4) 93.288 pm OR aly siete (1) 4and2 (2) Gans 4. Which one of the following compounds shows (3) and 4 () donde bah raw Sheets? 4a hum has a oe ssi ts Sent DiGET.2020 (Phase 530 kg m- and its atomic mass is 6 94 g mot (2s @) Acer Calulato the edge length of a ust co of Lithium Ad (4) Nac motal (N,= 602% 10% mol!) [NEET-2016) 5. Formula of nickel oxide with metal deficiency (1) 264 pm (2) 154 pm dofect in its crystal is Nip yO Tho crystal (3) 352 pm (4) 527 pen contains N?* and Ni ons. The fraction of nickel 44. The ionic rad of A° and B* ins are 0.98 «10-"> exiting 08 Nos in tho crystal is mand 1.81 x10" m. The coordnaton numberof {NEET-2019 (Odisha)] jach lon in AB is (NEET2016) «) 031 2) 096 2 as ©) 004 (060 4 we Corporate Office : Aakash Tower, , Pusa Road, New Dethl+110008, Phone : 011-4762345 Scanned with CamScannerMed-22-23-XII_C_C1_The Solid State GA The Solid State 42, The vacant space in bec lattice unit ea Is [Re AIPMT:2015) (ny 23% (2) 92% @) 26% (4) 48% 43. The correct statement regarding defects in crystatine solids i [Re-AIPMT-2015] (1) Frenke! defect isa distocation defect @) Frenkel defect is found in halides of alkaline metals @) Schottky defects have no effect on the density of exystaline solids (4) Frenkel detects de crystalline solids 14. Agiven metal cystalizes out with a cubic structure having edge length of 361 pm. If there are four ‘metal atoms in one unit cel, what isthe radius of se the density of cone atom? TAIPMT-2015] (1) 108 pm (2) 40pm () 127m (4) 80pm 415. las the length of the side of a cube, the distance between the body centered atom and ene comer ‘atom in the cube will be [AIPM 2014) oo Fa 4. @ fa 46. Ametalhasa{cclatice. The edge length ofthe unit, cell is 404 pm. The density of the metal is 2.72g em? The molar mass of the metal is (N, is Avogadro's constant = 6 02*10" mol) INeET-2013] (1) 209ml" 2) 27 gmot* (@) 209mol* (4) 40.9mot* 17. The numberof carbon atoms per unt cello damond unt calis (NEET-2013] we as aot a4 18. Ametalcrystalizes with aface-centered cubic lattice. “The edge of the unit coll is 408 pm The diameter of the metal atorn is [AIPMT (Prolims)-2012] () 44pm (2) 204 pm @) 288m (4) 408 pm. 19 a 23 24 25. EET Lovett) “The number of octahedral vids) par atom presant ina cubio close-packed structuro is [APC (Pretims}-2012), m2 4 ot 3 Structure of a mixed oxide is cubic cose packed {cep). The cubic unit cel of mixed oxide is composed ‘of oxide ions. One fourth of the tetrahedral voids are ‘occupiedby divalent metal Aand the octahedra! voids fare occupied by a monovalent metal B. The formula ofthe oxide is TAIPMT (Mains}2012} () ABO, @ Aso, @ ABO, @) ABQ, ‘sold compound XY has NaCI structure. the radius ‘ofthe cation is 100 pm, the radius ofthe anion (¥") willbe [AIPM (Mains)-2011] (1) 241.5pm (2) 165.7 pm @) 275A pm (4) 3225pm ‘AB crystallizes in a body centred cubic latice with edge length ‘a’ equal to 387 pm. The distance between two oppositively charged ions in the latices [AIPMT (Prelims)-2010} (1) 35pm (2) 250pm @) 200pm (4) 300pm ‘ ‘Among the folowing which one has the highest cation to anion size ratio? TAPMT (Mains)-2010) (1) cst 2) csF @) UF (4) NaF Lithium metal erystalises in a body centred cubic crystal Ifthe length of the side of the unit col of lithium is 351 pm, the atomic radius of the lithium willnearly bo {AIPMT (Prolims)-2008] (1) 152 pm. @) 75pm (@) 300pm (4) 240 pm. Copper crystallses in a face-cenired cubic lattice ‘with a unit col ength of 361 pm. What is the radius ‘of copper atom inpm? — [AIPMT (Prolims}-2008) (1) 187 @) 181 @) 108 (@) 128 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 Scanned with CamScannerNEET (Levelt) 26, 'a'stands forthe edge length ofthe cubic systoms ‘simple cubic, body centred cubic and faca centrad atic, then the rato of radi of the spheres in those systems wilbe respectively TPMT (Proiims)-2008] 27. Percentage of free space in a body centred cubic unit cell is [AIPMT (Prelims)-2008] (1) 26% 2) 30% @) 32% (8) 34% 28, With which one of the following elements silicon should be doped so as to give p-type of semiconductor ? [AIPMT (Pretims)-2008] (1) Boron (2) Germanium (3) Arsenic (4) Selenium pw 28. Which of the following statements is not correct ? TAIPMT (Prelims) (1) Thenumber of ravaislaticesinwhichatystal_ | can be categorized is 14 wit (2) The fraction ofthe total volume occupied by the atoms in a primitive eal is 0.52 (8) Molecular solids are generally volatile (4) The number of carbon atoms in 8 uit ell of diamond is 4 } 30, The fraction of total volume occupied by the atoms present ina simple cube is ’ IAIPMT (Prelims)-2007) oF Qe x ® 9 3a 48 31. If NaCl is doped with 10+ mol % SrCi,, the concentration of cation vacancies will be (N,=6.02« 10? mol") [AIPMT (Prellms)-2007] (1) 6.02 10% mor (2) 6.02 « 10" mot" @) 6.02 10% mot? (4) 6.02 « 10°" mot* 32. CsBr crystalises in a body centred cubic latica. ‘The und cet length is 436 6 pm. Given that the atomic mass of Cs = 133 and that of Br = 80 amu and ‘Avagadro number being 6 02 « 10” mot, thadensity of CsBris, TAIPMT (Prelims)-2006] (1) 425 glem* @) 0.425 glem (2) 8.25 glem’ (4) 4.25 gfe iQ) 4x10 37, An element (atomic mass = 100 gm/moi) having “The Solid State 65 33. The appearance of colour in sold alka matalhaides is gonorally due to (1) Fecentres (2) Schottky defect, (@) Frenkel dofect (4) Interstitial positions [AIPMT (Prolims}-2006) 34. Ina face.centerad cubic lattice, a unit call is shared equally by how many unit cells ? [AIPMT (Prelims)-2005], () 8 aa @ 2 (4) 6 Questions asked Prior to Medical Ent, Exams, 2005 35. Ionic solids, with Schottky defects, contain in their structure (1) ‘Cation vacancies only (2) Cation vacancies and interstitial cations (3) Equal number of cation and anion vacancies. (4) Anion vacancies and interstitial anions }.36. The number of atoms in 100 g of an FCC crystal with density d = 10 gfem? and cell edge equal to 100 pm, is equal to () 2 108 @) 1 «10% (4) 3 1025 BCC structure has unit cell edge 400 pm. The density of element is ||) 7.289 gem ) | @) 2.144 gavem? @) 10.376 grvcm? (4) 5.188 govem? 38, Ifwe mix a pentavalent impurity in a crystal lattice ‘of germanium, what type of semiconductor formation will occur? (1) n-type semiconductor (2) ptype semiconductor @) Both (1) & 2) (4) None of these 39. The intermetallic compound LiAg crystallizes in cubic lattice in which both lithium and siver have Coordination number of eight. The crystal class i (1) Face-centred cube 2) Simple cube (8) Body-contred cube (4) None of these Corporate Office ; Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 Scanned with CamScanner6 40. a 42. 43, Med-22-23-XII_C_C1_The Solid State ‘The Sol State Schottky defect in crystals is observed when (1) Density of the crystal is increased (2) Unequa’ number of cations and anions are missing from the lattice @) Anion teaves its norma’ site and occupies an interstitial site (8) Equal number of cations and anions are missing from the lattice The edge length of rock salt type unit cell is 508 pm. If the radius of the cation is 110 pm, the radius of the anion assuming NaCI type structure is (1) 144 pm (2) 398 pm (8) 288 pm (4) 618 pm. ‘The second order Bragg diffraction of X-rays with 2.= 1.00 A from a set of parallel planes in a metal ‘occurs al an angle 60°, The distance between the (1) 200A @) 1,00. (3) 0575.4 (A) 116A In crystals of which one of the following on'c compounds would you expect maximum distance between centres of cations and anions? (1) est @) CsF @ UF @ ut a a NEET (Levelt) 44. In cube of any crystal A-atom placed at every ‘comers and 8-atom placed at every centre of face, “The formula of compound (1) AB (2) AB, @) AB: (4) ABs 45. Coordination number in ABAB .. type arrangement is 6 as @ 2 4 46. The pyknometric density of sodium chloride crystal is 2.165 « 10? kg mv while its X-ray density 2.178 « 10? gr". The fraction of unoccupied site in sodium chloride crystal is (1) 596 @) 5.96% 102 @) 596% 104 (4) 598% 107 47. A compound formed by elements X and Y ‘ceystalzes in a cubic structure in which the X atoms are atthe comers of a cube and the Y atoms ara at the face-centres. The formula of the compound is (1) XY @) XY ox 4) XY, a usa Road, New Delhi-110005. Phone : 011-47625456 Scanned with CamScanner8 The Sots state Solutions of Assignment (Set2) (Level!) Solutions (Set-2) SECTION - A 1 Answer (3) a2 +c. 0282.90" is the parameter for crystal triclinic 2 Answer (1) (Cu beiongs to cubic erystal which has dimensions a = b= cand a=fi==90" 3 Answer (1) A-+ comers of cube = Total 8 atcms at comer, which have contrbution at comer 2 a So tubers meer tis tA pertent B — centre of body ~+ at centre of body one atom contributed completely Sostxt=4 10.,A,8, = AB 4 Answer (2) ABC, 1 ‘Atcomers number of atom = 8%1=1 feontbuton atcomer) FA Atbody centre = 1 a8 6x 1+ 23 Atface centre = rentwny 2 ac (comedinnne) aac, 5. Answer (1) ‘A- present at body contre in given figure So, its number = 1 x 1= 1 (contributed compietely) 4A B-sprosentatcomers= 8 x Lat a8 (cosbaten) 222% a “4 + Present a + crow 2st) . ac (© -+ Present at two opposite face i pene eodenl So, formula ABC 6. Answer (3) Present at comers = 8x 224 | Cu -seep : } Total 4 cu Present at centres of each face = 6 x $3) Agratedgecenre+ 12, x 1 33 tainraven A ‘Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 Scanned with CamScannerMed-22-23 -XII_C_C1_The Solid State_Ans and Sol Ihe Said Suto Suions of Assignment (Sot.2) Level ‘hus at body contr -» contnbuted complately = 11.994 CupasAn, 7 Answer (3) Ao box dot craton 8 onan) B-stococente-» 6 x + 93 rent 2a ‘Now, one atom s missing from ane comer => 8-1 "7 1 z sarx to at 7 t i A (comma cont) ABs > AB 8 Anewer(t) Arcos txdet Ay f 1 \ Boedges= 12xt=9 48, C-sbody centre 2 1x 1= 1.9, mae pos 8. Answer (2) p ‘ ‘Nebwort covalent solids have highest meting point due to network stricture in wich bonds are ight held tke SO, | | | yt ! I je 10. Answer (2) sae vents oom [befor 2 mannan dans 2=4e8 ‘given B => 8 =9N. So, numberof atoms is all the umber of (8) alam, io, S-> 4 of Qs 11 Answer (3) AB» Rock salttype -»f.c.c. -r numberof aloms = 4 [Tetrahedral void = 2xna. of atoms B+ constiuting the tatica -»/0., => 4 = 2xda8 Corporate Otic : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 ao on Scanned with CamScannero Med-22-23-XII_C_C1_The Solid State_Ans and Sol = | 10" The sous ste sontors oh cot2) Ly & oo Be? = z S 3 | pfocsedta = no.of some «N= 4 Ee ‘Teranedral => doube f na of aloms(2N) = 8) dial void ae occupied (oczoding to octahod}) AB. AS 13, Answer (1) 2 age 0? sep aafexdeoxd | a cool oxg eo 4] 4 ssf ammo t So, fort XV; 14, Answer (2) Tepatee 4 givens carbon at 0,740,971 =, ¢ rans hyrogen>tterahedral hols = double of poner of ams pore \ Tits oT, \ 15, Answer (2) ‘ t rr recenepnitiche ean) peer set aus a abate eS nas camer mt (07 -scop => 4 (n0. of atoms) { 1 8 1 4 j Eremadean"t 99 Beton § corporate Oe: hash Tower, 8, Puta Road, Now Deh 11005. Prone MTATS2SSMed-22-23-XII.C_C1_The Solid State_Ans and Sol Scanned with CamScanner Corporate Otice Ankash Tower, 8, Puss Read. New Debi110005. Prone : On1-47620486Schon of Asigart(Se.2) (ve) Jia= ¥x0:336 om 1205819 nm 0.582 nm Myo =18 98 = volume of unt call = 132 = 102% em? = volume of unt col = V Z=4-fortee t= 188-77-9 111 pm toon Corporate Ofc: Aakash Tower, 8, Pusa Road, New Dalh-110008. Phone: O41-47823488 Scanned with CamScannerMed-22-23-XII_C_C1_The Solid State_Ans and Sol i See Stn 49) 3. Answer (3) Pyrostecileenta rode fenbie lactic cent on hentng 31. Answer (3) 20—*By" +40, tacos of 2h nc cag mec (a) 9 ara ts eu In some defect, nepaiv ions may be missing frm tek lace sites leaving hols in which lactrons remain trapped to rattan electric! rev, The Pols wth envapped elacrons ae caled Fecenves. They impart coro cys ate eg Peting esta of Matin vapor cl i 33. Answer (2) CGroup-t4 element eg.» Si+ valence electors. ++ ee tte poor Toyte mone eared naps ay 0 elt ah tra es cat tecer on toeran aa tO tt how inet dona sige pnt! an spl cone nun it. results in some net magnetic moment Ferimagnetic | t | 1 | Joie ‘magnetic moment than eet ated be mow) nastoramaptas| | | [>not errt. opt near maer=0 3 pa acoact eyti oca letcrnen 2 mehr sts pte 3 tro) toa rs elect -sReed ne pss ls el wp ig LNA Na om tomer Corporate Ofice: Aakash Tower, 8, usa Road, Now Dshi-110005, Phone: O11-47623450 Scanned with CamScanner‘ Med-22-23-XII_C_C1_The Solid State_Ans and Sol { ry | 1 mol of SIC -sereates one moe cation vacancy Given 10° moe of Sci, + eeates 10°» N ruber of vacancy, 26.024 10 mot! | SECTION -B 1 Answer) 2 Answer (1) 3 Aaswer (1) 4. Answer (3) Ina unt eet, toms of B = 4,atems ot A= fea + 2x86, «. Fomua =A, 2 6 Corporate Otce: Aakash Tower, 8, Puta Road, New Dei: 110005. Phone: O11-47620456 Scanned with CamScanner} f @ © w ky Med- Chapter 1 The Solid State 1 Answer (2) 22-23-XII_C_C1_The Solid State_Ans and So EME - ff - | Solutions SECTION -A not erdoredaffangement nol repeating ints | Jong range of melting pont fsotopy Talal atoms ina cube = 8 +6+1+12=27 1 As oxder 3 4 “aca conte B= 1x6 Face conto B= La6=3 Corporate Oc :Askash Tower, 8, Pura Road, New DetN-110008. Phone: O11-47623488 Scanned with CamScanner+29. = Bare TERETE Ob [OS pue suyareis pllos AYL~LO-O“IIX-EZ-ZZ-PAaW BE ey SS mr OS Tae Scanned with CamScanner Ife |Med-22-23-XII_C_C1_The Solid State_Ans and Sol Soon ot Ashe ev Sagem sitwtmmet et) nats me gp eta etahea voit =| "eet lls cam xt Lot tvebenet wd 1 vet otove tea pov. Lane So, fornia 22X;7¥3? 5 x¥,2, 12, Answer (1) Ine, + 74% space is occupied by 4 slams (ton al comer and face can slams av located) ‘Given Half of face centred atoms are removed. So, total face centred atoms = 6 half removed it becomes = 3 Foe som 7% (pn cei) 1-2 3 if tor $ tom» "x5 + 4625% 10, % vot» 100 Loni pce = 100-4828 « 4 13. Answer (4) In BCC. -» 68% space is occupied by 2 stoms. It half of atoms per unit cll is removed then it beccrves =2-154. $0.2 tan ~ 6 1 wton + 290% cid ac) Non. vod 100 =p sae = 00-34 60% ‘14. Answer (4) forNacl-+ tee, Z=4) > 4745 > §02B x10 (745 x10 M=745 amu 31.197 glem? 45 pm = 745 10cm 15. Answer (3) For octahedra void 204uR New Deth-t10008. Phone: 011-47623488 Corporate Oftce : Aakash Tower, 8, Pusa R Scanned with CamScanner | | || Med-22-23-XII_C_C1_The Solid State_Ans and Sol . 4 4 he fd tne nm $$$ nett ot pergrners vt 16 Anewoe 2) (On incronsing pressure tha GN. of weil irons ‘coser to wach of femporatre « f decreases) [EN closeness of stom 40, ecorthation number} [Cateuiaton for unt ent amenslone, 17. Anwwoe (1) ‘tructurm of lnk exysta 18. Anewee (3) aching fraction = 74% enna Unit en tee ABCA 19, Anewor 4) InNaci seucture ‘Nat prasent at edge centios(octahvral voids) and as we! a8 body cote, CC: prosent al comers and conto ofeach face Given atom are interchanged then 'Na* comes at comers and conto of each face, CC coms at ode cents (octahedral vids) and at body cant, 20, Answer (1) 2M Pe (04.4 = conta) | | Ei Pree. . Zee Mee A ay Pak a ea ne lover, gee = 20m: Bycc, * 4 pm) 21. Angwor (1) In NaCl. 4 atoms per unit col tte 4. 4 atoms in one unit eo Ihaci=23+355= 583] (mote = °°. ert atomin Stn copa :Ath Tea Pt Rend Ne ab 808 Pom HATERS ee Scanned with CamScannera Te Med-22-23-XII_C_C1_The Solid State_Ans and Sol a a he Sie 00 49 agen ot unpre geveyy th i toma (8 ma) ESN unt cat ‘oN atoms» (1 ot) + YN 10 henge t® AS, mates LANs yg wt om = as ANN eg wnt em 22 Aner) Im cal et nearest nelybous (8) ht ur atoms bow at comers a fut aor bio a conn 23. Answer (2) CaF, +B, ype-¥ EN = 8:4 Retiapeyaraspnenbes A nts Yi waa! focezp atoms = 4 Tetrahedra hoes = 8 24 Anower(t) 6 etcsoney = 22,2100 = 70.54% a 25. Arower (2) he Les gs + Bones bene anemia tay oes 25. newer (8) j Fer wvahera vid bo ras rao ©0225-0414 21 Answer (2) £25 «0.52 van proton beta al ange 4, CN oman 6) every tha CH, of AG 6 when ©0414-0792 ‘Comorst Otte; Aakash Towa, 8, Puse Rend, New Delis 110008, Phone O11A7623458 Scanned with CamScanner 1 1 {Med-22-23-XII_C_C1_The Solid State_Ans and Sol 20° Tha Sa Sate Sous of herent es 20. Annwer it) AB, > CaF, pe of expt whch has CN = BA Anew (2) For NaCt le) and KF 4 28° Le Jovan ann on) Tewntetaied | 1) 3s Ov. socataved ; peor) 8 ‘This rai (0.75) s mor than 0.7320, ils cubic stature which has C= 8 4 hase (2) For NaCl type Ssoare-a7s2 oan reo. 1035 “Tis is radius of void to, the caton which has aqua! te hs radus or smart this rads can easy ito 1 ate option (2) Q = 66pm which Is smaller than radu of void tats why 8 can ft no 250 Scanned with CamScanner2 u Med-22-23-XII_C_C1_The Solid State_Ans and Sol | ‘Sektons ot ov 1m 6 se 24 35 Room (9) Myo = 4 Prec) =4 36. Anewer (2) Inaot som (2-4) cue WFC. {40 to spl cubic ‘On hreasing emperaure and decreasing presse closanass of alos In CC! esa decreases bacon enon. a, ut [EEN nS) Set ts cree |densty of unt cal dacieasas 37. Answer (2) Pyroelectic aro tho molecular sods whch produces smal amaurt of eleccy upon heating 38 Answer (1) r 'Naci becomes paramagnete a hightemperature nthe presence of Na vapcut due to marten of Con {he surface fom lien by which vacancy is produced known a F-centre in which @” is rapped trem outer Na Wome, some fee cto comes lien sy Bees pera 38. Anower (4) { 2 Sn impure erty ersten ere froutes wl deo Gate wc nereees ase ‘So, deny increases. j O00 O tan O00 000) MF ATO" Noma erat rae nomi ey hott . 40. Asner @) ¢ ‘Nea my ie mor ha plow of ome an se ray ber of smelt ny ae 4. Annee 2) é Aepresets wavelength cf Xays used 42. Answer () ‘ “otal numberof etangut plane = 3 ‘Number ef agonal plane = 6 ratio= 9:6 1:2 SECTION -B 1. Answer (1) ‘+ Number of octahedra 2h respecvely 1 Each hexagonal unt el contain 6 alome terete, number fterahotal and octahedral voids are 12 and respective 2 Answer (1) in 14 ypes of Brava latices, body cenved nt ce Is present in cub, téragonal and othomembie ranedral volds formed by N closed packed atoms are N ana ne 1+ Hance, body ented possi variation i present in thee cyt! systems ‘Corporate Ofc: Aakash Tower, Pus Rodd; New OXNL110005. Phone: O11-47623456, Scanned with CamScannerMed-22-23-XII.C_C1_The Solid State_Ans and Sol Ny O #47 2 one at Net charge = 0 x2] 40:98-»)«a1+[-201=-0 xr ost Fracton of ike existing 95 no OS f Ne = O55 = 0959-098 } 6 Asm 3) XG ‘Arions{A) ate in hep, so cumbor of anit (A) = 8 Catens(C) aren 75% OV, 2 pumber of eaiens (©) a sor} 2 ‘So formato compound wil be Cake Coa CAs OM 7 Answer) =. 4 “ For Bcc ianica :2 #2, 8° For FCC atic :2= 4,0 Er (ar Sees. ANA Ieee © dove iF Bo ce ¢Ef-08 x corporate Often: Aska Tower, 8, Puts Read, New D4-110005, Phone OHF-47eZ3456 Scanned with CamScanner2 & 2 wie 1” J 5 15 6 . Med-22-23-XII_C. saueors " rome (84) Free detect crs nota on copcinds n wich te caton and no's ey rr Noveoihonar fort onde Fey yop ands de amet efency dlc sooner) Inca, Cahn ec argent a on ae preset rahe ods © Comraton rrr Ca” an om a8 a doom) 052 gion? 22854910 Cn sing. 3829 poswet 2) fy, gana" iy tenia Le. lone std has cabedal groney, tus eer umber teach on AB rower) Pacing traci na ber aes 6% The vacant space in esate = 32% dower) Fact poswer() Forte arangement = aaswer(t) ia=e 00) Aaower(2) aN za z a ° wonenae 1 2rBabnt uous? = 404 «10% on = 269 = 27 gal Zed atertec Answer(t) Number ot Ser Sed ana of evahedra vis (= 4) and S*° ras fee rangement ‘carton atom perunt cots 8x4 « ox 4 Cconporte Often: Aakash _C1_The Solid State_Ans and Sol carbon atoms per unt ee of mond unt eels 8. thas ZnS zine bende) tk sect in when ‘ower 8, Puss Road, New Debi- 110008. Phone: OAATE2SS Scanned with CamScannerQe a law Med-22-23-XII_C_C1_The Solid State_Ans and Sol Aner) Naber ef OV eau rub tome 4 atoms i nt cal + 4 OV. ‘So, ft atom + 10V Avowerit) Gven ove ert exp = 4+ dear eats be atta (oatov.=4 “xy has NaCl ruete © = 0.414 -0.732 wo agate gr aL nz som r ane poset acc.s-2 (oor 28 E387 359m poset 2) ne oF ‘See of Ce maximum and sce Fie minimum sora pest Answer) #351 pm a Rand, New Dov 110005, Phone O1LATE2DEG YM el Be AB) Scanned with CamScannerote a8 Ormat ame oa w te [eemte ee seen ee cS tee aioe hin sm ene mane tere w tem pte neh Toews etal ar Rom te ES ain ee om 8 me yma (4) 8 em me a a wt ted 8 8 Macatee = aoceeons erpaencey~ One moe 8% sams om me ate my S00 moe SC, wt came 2 nce cutee wee ere ecg «at octet ate Domeai Ofie hekath Trt Pint Rea Mew aN Pane SPAMERIASS Lit Scanned with CamScanner \ \ | i | iMed-22-23-XII_C_C1_The Solid State_Ans and Sol 26) Me Sou sate 32. Anewera) i ae as6eom (C88 133,6¢2 89m Tot mass = 193 + 80.2213 Zeterewrsec) 33. Answer) DuetoFcenves 34. Anawer(t) 35 Answer) "| pay | Ze4brtec.a | DAN xa? _ 10x65 Moar mass «2 | Schoty defect equal ruber featon and anon vacances are present @c@e se wow e “O-Q © Osean ary 1024100510") soba 00x10 7 6159 Number of aloms = moles «Ny = corporate Otice : Aakash Tower, 8, Pusa Road, New Deli 110008, Phone O1T47623458 [ee ee ee es ria | } 1 2 100 108 #10? = 100 = 10° om, w= 1009, wy, «12 x6xt0" ano = 26x10 a at0 Nena $ 1 \ Scanned with CamScannerMed-22-23-XII_C_C1_The Solid State_Ans and Sol Eskew strand geet tna i 8 222-400) 2x100 ney 4008102 “presente 1400» 10° 400 em “Re + 8008+ 1 eszoem | 38 pemwett Ge 4 group slot +4 velco 10810 a An tote | : | So Bae OT me f |e | 29 Answer (2) (i Spep) But ond Ag hve simp eae args Equal numberof cations and equal numberof aions misng trom tin. 41, Ansar) wor norrs F#254— 110° 144 pm 42 Answer) = 26nd Bate? diosa" ‘Cs largest cation and I largest anion among thor group. So, distance between them lo vr Nigh CComorte Oe: Aakash Tower 8, Puss Rood, New Debe110005. Phone: O1-47620486 es = sngor | ants \ 8 ome | Scanned with CamScannerMed-22-23-XII_C_C1_The Solid State_Ans and Sol 220° re sons see newer} Nace) oer Hitce) => 45 Anowor() 46, Anmwer(t) Uncccipieg tes = Kay density ~pytnomein: density #2178 108-2965 11080), Ccoporate Oe: Aakash Tower, 8,Puse Read, New Debi 110005. Phone: 0147620486 | 1 Scanned with CamScanner