NISSHOKU TECHNO FINE CHEMICAL CO., LTD., Jul.

19, 2023, 1/12

Issuing Date Dec.9, 2022

Revision Date Jul. 19, 2023

SAFETY DATA SHEET

1. Chemical Product and Company Identification

a. Product name: ZN-DA90SN

• Reference no.: NTF-03-0007-E
b. Information on manufacturer/supplier/distributor
• Company name: NISSHOKU TECHNO FINE CHEMICAL CO., LTD.
• Address: 9-1, Koya-shinmachi. City, Ichikawa-shi, Chiba, 272-0011, Japan
• Relevant dept.: RC Promotion Department
• Phone number: +81-47-328-1185
• Fax number: +81-47-328-1189
c. Recommended use: Rubber modifier

2. Hazards Identification

a. GHS Classification
• Physical and chemical hazards:
- Flammable solid Not classified
• Health hazards
- Acute toxicity (Oral) Category 4
- Acute toxicity (Dermal) Classification not possible
- Acute toxicity (Inhalation: gas) Not applicable
- Acute toxicity (Inhalation: vapor) Not applicable
- Acute toxicity (Inhalation: dust, mist) Classification not possible
- Skin corrosion/irritation Category 2
- Serious eye damage/irritation Category 1
- Respiratory sensitization Classification not possible
- Skin sensitization Classification not possible
- Germ cell mutagenicity Classification not possible
- Carcinogenicity Classification not possible
- Reproductive toxicity Classification not possible
- Specific target organ toxicity (Single exposure) Classification not possible
- Specific target organ toxicity (Repeated exposure) Classification not possible
- Aspiration hazard Classification not possible
• Environmental hazards
- Hazards to aquatic environment - acute hazard Category 3
- Hazards to aquatic environment - chronic hazard Classification not possible
b. Label elements
● Pictograms:
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● Signal words: Danger

● Hazard statements:
- H302 Harmful if swallowed
- H315 Causes skin irritation
- H318 Causes serious eye damage
- H402 Harmful to aquatic life
● Precautionary statements
[Prevention]
- P264 Wash hands and face thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P273 Avoid release to the environment.
- P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
- P310 Immediately call a POISON CENTER/doctor.
- P330 Rinse mouth.
- P362+P364 Take off contaminated clothing and wash it before reuse.
- IF SWALLOWED: P301+P312 Call a POISON CENTER/doctor if you feel unwell.
- IF ON SKIN: P302+P352 Wash with plenty of water.
- IF SKIN IRRITATION OCCURS: P332+P313 Get medical advice/attention.
- IF IN EYES: P305+P351+P338 Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
[Disposal]
- P501 Dispose of contents/container in accordance with local/regional/national/international
regulation.
[Other hazards]
- The dust can form an explosive mixture.
- The dust can be charged with static electricity.
- As a general harmfulness of powdered substances, it is known to cause pulmonary
disorders (symptoms of pneumoconiosis) by accumulating in the lungs when inhaling in
large quantities.

3. Composition/Information on Ingredients

Chemical substance/mixture Mixture

Chemical name or common name Zinc diacrylate
Zinc stearate

(Abbreviation) －
Content (wt.%) 90 (Zinc diacrylate), 10 (Zinc stearate)
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Chemical formula C6H6O4Zn (Zinc diacrylate), C36H70O4Zn (Zinc stearate)

CAS No. 14643-87-9 (Zinc diacrylate), 557-05-1 (Zinc stearate)
Serial no. of government gazette (1) 2-985 (Zinc diacrylate), 2-615 (Zinc stearate)
Serial no. of government gazette (2) -

(1) The Law concerning Examination and Regulation of Manufacture, etc. of Chemical Substances
(2) Industrial Safety and Health Law

4. First-aid Measures

a. Inhalation:
• Remove person to fresh air and keep comfortable for breathing.
• Immediately call a POISON CENTER/doctor.
b. Skin contact:
• Wash with plenty of soap and water.
• IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or
shower].
• Immediately call a POISON CENTER/doctor.
c. Eye contact:
• Wash the eyes with clean water for at least several minutes (desirably 15 minutes or longer),
(Remove the contact lenses if possible.) and get medical attention by an eye specialist
immediately. During washing, fully open the eyelid with fingers and wash in such a way as to let
water reach to every corner of the eyeball and eyelid.
d. Ingestion:
• Do not induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical attention immediately.

5. Fire Fighting Measures

a. Suitable extinguishing media:

• Small Fire: Chemical powder extinguisher, alcohol resistant foam fire extinguishing media,
carbon dioxide or water spray.
• Large Fire: Alcohol resistant foam fire extinguishing media, water spray or fog.
b. Unsuitable extinguishing media:
• Direct straight streams (may spread a fire)
c. Specific hazards of fire-fighting:
• Will be easily ignited by heat, sparks or flames.
• Containers may explode when heated. Fire will produce irritating, corrosive and/or toxic gases.
May polymerize explosively when heated or involved in a fire.
d. Specific extinguishing methods:
• Keep upwind of fire.
• Use of water spray at a large fire, when another fire extinguishing media may be inefficient.
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• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool
containers with flooding quantities of water until well after fire is out. For massive fire, use
unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire
burn.
e. Special protective actions for fire-fighters:
• During fire fighting work, wear proper protective equipment.
• Structural firefighters’ protective clothing will only provide limited protection.

6. Accidental Release Measures

a. Personal precautions, protective equipment and emergency measures:

• Promptly remove possible ignition sources from the vicinity.
• Use personal protection recommended in Section 8. Isolate the hazard area deny entry to
unnecessary and unprotected personnel.
b. Environmental precautions:
• Do not flush to sewer or allow to enter waterways.
• Prevent scattering and spread by covering with antistatic sheet and the like.
c. Methods and materials for containment and cleaning up:
• Carefully shovel or sweep up spilled material and place in suitable container. Avoid generating
dust.
• Eliminate all ignition sources. Use explosion-proof equipment. Dust can be a fire or explosion
hazard. Vacuum or sweep material and place in a disposal container.

7. Handling and Storage

a. Handling:
• Technical measures:
- Do not breathe dust.
- The dust can be charged with static electricity. Suppress generation and accumulation of
dust as much as possible. Take countermeasures for static electricity removal (grounding
others). Wear antistatic clothes and antistatic shoes to prevent human body electrification.
- Use explosion-proof [electrical/ventilating/lighting] equipment.
- Keep away from heat, hot surfaces, sparks, open flame and other ignition sources. No
smoking.
- Do not handle the containers harshly in such a way as to make them tumbled, dropped,
given a shock, or dragged.
• Local/total ventilation:
- Use the ventilation equipment described in Section 8.
• Precautions for safe handling:
- Not especially.
• Contact avoidance:
- Refer to the information in section 10 (Stability and reactivity).
• Hygiene measures:
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- During handling, be sure to wear proper protective equipment (refer to the section 8).
b. Storage:
• Conditions for safe storage:
- Store the containers in a well-ventilated dry cool dark place, keeping away from heat
sources like fire, boilers, and the like. Because this product has solidifying property and is
hygroscopic, avoid moistures like rain water.
• Safe packaging material:
- Store in tightly closed container.

8. Exposure Controls / Personal Protection

a. Controlled exposure level:

● Zinc diacrylate
- ACGIH TLV-TWA: Not established.
- ACGIH TLV-STEL: Not established.
- U.S.-OSHA PEL-TWA: Not established.
- U.S.-OSHA PEL-STEL: Not established.
• Zinc stearate
- ACGIH TLV-TWA: 3mg/m3 (Respirable particulate matter), 10mg/m3 (Inhalable particulate
matter)
- ACGIH TLV-STEL: Not established.
- U.S.-OSHA PEL-TWA: 5mg/m3 (Respirable fraction), 15mg/m3 (Total dust)
- U.S.-OSHA PEL-STEL: Not established.
b. Appropriate engineering controls:
● Install eye and body washing facilities near the handling place.
● Use closed equipment/machinery or use local ventilation equipment (Reference of permissible
concentration).
● ACGIH: As Particles (insoluble or poorly soluble) Not Otherwise Specified; Inhalable particles
TWA 10mg/m3, Respirable particles TWA 3mg/m3
● U.S.-OSHA: As Particulates Not Otherwise Regulated; Total dust TWA 15mg/m3, Respirable
fraction TWA 5mg/m3
c. Personal protective equipment:
● Respiratory protection: Dust mask
● Hand protection: Protective gloves (Antistatic ones are desirable.)
● Eye/face protection: Protective glasses, goggle, protective face shield
● Skin and body protection: Protective clothes, protective shoes (Antistatic ones are desirable.)

9. Physical and Chemical Properties

[Chemical product]
a. Physical state: Solid (powders)
b. Form: Powder (Average particle diameter 6.7μm)
c. Color: White
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d. Odor: Slight acid odor

e. Odor threshold: No data
f. Melting point/freezing point: No data
g. Boiling point or initial boiling point and boiling range: No data
h. Flammability: No data
i. Lower and upper explosion limit/flammability limit: No data.
j. Flashpoint: 218(℃) Seta Closed Cup
k. Auto-ignition temperature: No data
l. Decomposition temperature: No data
m. pH: No data
n. Kinematic Viscosity: No data
o. Solubility: Water: No data
p. Partition coefficient n-octanol/water (log value): No data
q. Vapor pressure: No data
r. Density and/or relative density: (True specific gravity)1.61
s. Relative vapor density: No data
t. Evaporation rate: No data
u. Particle characteristics: No data
v. Other data:
• Burning rate test (UN recommendations) Not continue to burn (Data of similar product)

[Ingredients]
Zinc diacrylate
a. Physical state: Solid (powders)
b. Form: Powder
c. Color: White
d. Odor: Slight acid odor
e. Melting point/freezing point: None (Polymerization at 210-240℃)
f. Boiling point or initial boiling point and boiling range: No data
g. Flammability: No data
h. Lower and upper explosion limit/flammability limit: Lower Limit: (Dust explosion)300(g/m3)
i. Flashpoint: 229(℃)
j. Auto-ignition temperature: No data
k. Decomposition temperature: No data
l. pH: 7.71
m. Kinematic Viscosity: No data
n. Solubility: No data
o. Partition coefficient n-octanol/water (log value): No data
p. Vapor pressure: No data
q. Density and/or relative density: (True specific gravity)1.68
r. Relative vapor density: No data
s. Particle characteristics: No data

Zinc stearate
a. Physical state: Solid
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b. Form: Soft (not gritty), white powder

c. Color: White
d. Odor: Slight, characteristic
e. Odor threshold: No data
f. Melting point/freezing point: 130(℃)
g. Boiling point or initial boiling point and boiling range: No data
h. Flammability: No data
i. Lower and upper explosion limit/flammability limit: Lower Limit: 20(g/m3)
j. Flashpoint: 277(℃) Open Cup
k. Auto-ignition temperature: 420(℃)
l. Decomposition temperature: No data
m. pH: No data
n. Viscosity: No data
o. Kinematic Viscosity: No data
p. Solubility: Water: 0.9(mg/L)(20℃) ethanol: Insoluble
q. Partition coefficient n-octanol/water (log value): 14.44
r. Vapor pressure: No data
s. Density and/or relative density: 1.1
t. Relative vapor density: No data
u. Evaporation rate: No data
v. Particle characteristics: No data

10. Stability and Reactivity

a. Reactivity:
● No data available.
b. Chemical stability:
• Heating, direct sunlight, peroxides, and iron rust can cause polymerization. It is hygroscopic.
c. Possibility of hazardous reactions:
● No data available.
d. Conditions to avoid:
● Because of its caking and hygroscopic properties, avoid contact with moisture like rain water.
e. Incompatible materials:
● No data available.
f. Hazardous decomposition products:
● During burning, it can decompose and form hazardous and irritating fume containing zinc oxide.

11. Toxicological Information

[Chemical product]
a. Acute toxicity:
● Oral: Category 4
- LD50:300-2000mg/kg[rat]
● Dermal : Classification not possible
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- No test data on the product

• Inhalation: Classification not possible (Gas), Classification not possible (Vapor), Classification
not possible(Dust/Mist)
- No test data on the product
b. Skin corrosion/irritation: Category 2
- Moderate[rabbit]
c. Serious eye damage/irritation: Category 1
- No test data on the product
d. Sensitization:
• Respiratory: Classification not possible
- No test data on the product
• Skin: Classification not possible
- No test data on the product
e. Germ cell mutagenicity: Classification not possible
- Ames Test: Negative
f. Carcinogenicity: Classification not possible
- No test data on the product
g. Reproductive toxicity: Classification not possible
- No test data on the product
h. Specific target organ toxicity (Single exposure): Classification not possible
- No test data on the product
i. Specific target organ toxicity (Repeated exposure): Classification not possible
- No test data on the product
j. Aspiration hazard: Classification not possible
- No test data on the product

[Ingredients]
Zinc diacrylate
a. Acute toxicity:
● Oral: Category 4
- LD50:300-2000mg/kg[rat] (Estimated)
● Dermal : Classification not possible
• Inhalation: Classification not possible (Gas), Classification not possible (Vapor), Classification
not possible(Dust/Mist)
b. Skin corrosion/irritation: Not classified
- Not irritating[rabbit]
c. Serious eye damage/irritation: Category 1
- Corrosive[rabbit]
d. Sensitization:
• Respiratory: Classification not possible
• Skin: Classification not possible
e. Germ cell mutagenicity: Classification not possible
- Ames Test: Negative
f. Carcinogenicity: Classification not possible
g. Reproductive toxicity: Classification not possible
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g. Specific target organ toxicity (Single exposure): Classification not possible

h. Specific target organ toxicity (Repeated exposure): Classification not possible
i. Aspiration hazard: Classification not possible

Zinc stearate
a. Acute toxicity:
● Oral: Not classified
- LD50: >5000mg/kg[rat]
- LD50: >10g/kg[rat]
● Dermal : Not classified
- LD50: >2000mg/kg[rabbit]
• Inhalation: Not classified (Gas), Not classified (Vapor), Not classified(Dust/Mist)
- LC50: >50mg/L/4h[rat]
b. Skin corrosion/irritation: Not classified
c. Serious eye damage/irritation: Not classified
d. Sensitization:
• Respiratory: Classification not possible
• Skin: Classification not possible
e. Germ cell mutagenicity: Classification not possible
f. Carcinogenicity: Classification not possible
- EPA: D
- ACGIH: A4
g. Reproductive toxicity: Classification not possible
j. Specific target organ toxicity (Single exposure): Classification not possible
k. Specific target organ toxicity (Repeated exposure): Classification not possible
l. Aspiration hazard: Classification not possible

12. Ecological Information

[Chemical product]
a. Ecotoxicity:
• Acute hazard: Category 3
- Fish: LC50(96hr): 10-100mg/L [Oryzias latipes]
- Crustacea: No test data on the product
- Algae or other aquatic plants: No test data on the product
• Chronic hazard: Classification not possible
b. Persistence and degradability: No test data on the product
c. Bioaccumulative potential: No test data on the product
d. Mobility in soil: No test data on the product
e. Hazardous to the ozone layer: Classification not possible
- No test data on the product

[Ingredients]
Zinc diacrylate
a. Ecotoxicity:
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• Acute hazard: Category 3

- Fish: LC50(96h): 10-100mg/L [Oryzias latipes]
• Chronic hazard: Classification not possible
b. Hazardous to the ozone layer: Classification not possible

Zinc stearate
a. Ecotoxicity:
• Acute hazard: Not classified
- Fish: No data
- Crustacea: No data
- Algae or other aquatic plants: No data
• Chronic hazard: Not classified
- Fish: No data
- Crustacea: No data
- Algae or other aquatic plants: No data
b. Persistence and degradability: Not rapidly biodegradable
c. Bioaccumulative potential: Low bioaccumulation
d. Hazardous to the ozone layer: Classification not possible

13. Disposal Considerations

Disposal methods:
● When waste material and waste water are to be treated, incinerate them or collect them into
specified containers and entrust the disposal to a licensed industrial waste disposal company.
● Do not use the used containers for other purposes like filling other substances. After treating
the content according to the above description, the empty containers should be reused,
recycled, or disposed through suitably qualified or licensed contractor, in accordance with
national/local regulations.

14. Transport Information

a. ICAO/IATA:
● UN classification: Not regulated as a dangerous good
● UN number: Not regulated as a dangerous good
● Proper shipping name: Not regulated as a dangerous good
● Packing group: Not regulated as a dangerous good
b. IMDG:
● UN classification: Not regulated as a dangerous good
● UN number: Not regulated as a dangerous good
● Proper shipping name: Not regulated as a dangerous good
● Packing group: Not regulated as a dangerous good
c. Marine pollutant: Not applicable
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d. Transport regulations: Transport this product in accordance with local/regional/national/international

regulations.
e. Special precautions:
• Load the containers in such a way as not to fall down, tumble, or being damaged.
• Cover the loaded cargo to prevent direct sunlight.

15. Regulatory Information

a. EU-REACH (1907/2006): Not listed in Annex XIV, XVII and candidate list of SVHC for authorization.
b. U.S.-CERCLA/SARA: Not applicable
c. U.S.-OSHA: Not applicable to the specifically regulated chemicals codified at 29CFR PART1910
Subpart Z (1910.1001 to 1910.1096)
d. U.S.-TSCA (Toxic Substances Control Act): Not applicable to the restricted substances codified at
40CFR PART (747,749,761,763) and PART721(SNUR)
e. Inventories:
• Japan (ENCS): Listed
• Korea (KECL): Listed
• Australia (AICS): Listed
• Canada (DSL): Listed
• China (IECSC): Listed
• EU (EINECS): Listed
• New Zealand (NZIoC): Not Listed
• USA (TSCA): Listed
• Philippines (PICCS): Listed
• Taiwan (TCSI): Listed
f. Restriction:
• at export (Japan): Not applicable

16. Other Information

a. Disclaimer
• The described information is based on the latest material, information and other data available
at the time of preparation; however, it does not intend to guarantee anything like contents,
physical/chemical properties, and danger/hazards. Also, the precautions mentioned above are
for ordinary handling; therefore, for special handling, it is the obligation of each user of the
product to take proper measures suitable for each handling condition. Take enough care for
such matters.
• This SDS is based on JIS Z7252:2019 and JIS Z7253:2019. If “Not classified” is provided in the
GHS classification in Section 2, it means that sufficient information is available to classify the
product and sufficient evidence is found to determine that it is not applicable to any hazard
categories defined by JIS Z7252. And another case is that it based on comprehensive
judgement by experts.
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• Regulatory information with regard to this substance in your country or region should be
examined by your own responsibility.