WT8

(Batches: e-SANKALP-2325 S1, T1 & P1)
I I T – JEE, 2 3 2 5 Paper Code

100847
(CLASS XI)
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.
B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.
Enrolment No. :
Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
26513942
website: www.fiitjee.com.
eSANKALP2325S1, T1 & P1-PCM-Paper-(100847)-2
PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. A uniform thin, rod AB of length L and mass m is undergoing m, L

fixed axis rotation about end A, such that end A remains A P B
stationary as shown. The kinetic energy of section AP of rod is
equal to kinetic energy of section BP of rod at an instant. Then
AP
the ratio of length AP and length AB, that is,
AB
1 1
(A) (B) 1/3
2 2
1 1
(C) (D)
2 2 2
2. Let I be the moment of inertia of a uniform square plate about an axis AB that passes though its
centre and is parallel to two of its sides. CD is a line in the plane of the plate that passes through
the centre of the plate and makes an angle  with AB. The moment of inertia of the plate about
the axis CD is then equal to
(A) I (B) I cos2 
(C) I sin 
2 (D) I cos2(/2)
3. O is the centre of mass of a body of mass M as shown in the figure. A, B, C

are three different point on the body. OB = 8 cm, OC = 10 cm, BC = 6 cm A
O
and OA = 10 cm. Which of the following can be written by using parallel axis
theorem? I0 is the moment of inertia about the axis passing through point O
B C
and perpendicular to plane of object.
(A) IB = IC + M(BC)2 (B) IC = IB + M(BC)2
(C) IA = I0 + M(OB) 2 (D) None of these
Space for Rough work
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4. ABC is an isosceles triangular sheet of negligible thickness, made of A

isotropic material. Mass of the sheet is m. Its moment of inertia about 90
a a
axes perpendicular to its plane and passing through the points A and B
are I1 and I2 respectively. [AB = AC = a and BC = 2a]. Find I2/I1.
(A) 4 (B) 2 B 2a C
(C) 4/3 (D) 3/4
5. The Moment of inertia of the plate in fig(a)

about the about axis shown is I. The Moment of
inertia of the hexagonal plate of same material
shown in figure(b) about the axis given in
figure(b) is :
(A) 6I
(B) 12I
(C) 24I
(D) 30I
6. A particle is rotating about a vertical axis in the horizontal plane such R

that the angular velocity of the particle about the axis is constant and
is equal to 1 rad/s. Distance of the particle from axis is given by R0
R = R0- t where t stands for time. The speed of the particle as a O
function of time is
(A) 2  1 (B) (R 0   t)
(C) 2  (R 0  t) 2 (D) 
26513942
SECTION – 2 : (One or More Than One Options Correct Type)
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
7. Two identical semicircular discs of mass ‘m’ each and radius Z

‘R’ are placed in the XY (horizontal) plane and the YZ
(vertical) plane, respectively. They are so placed that they
have their common diameter along the Y-axis. Then, the
moment of inertia (In) of the system about the appropriate axis Y
is given by
(In refers to moment of inertia about axis n-where n is X, Y, Z)
1 O
(A) IX  mR2
2
X
1
(B) IY  mR2
2
3
(C) IZ  mR2
4
(D) IX  IY  IZ
8. A wire of mass M and length L is placed along x-axis with end A at Y

origin. The linear mass density  (of the rod) varies as  = 0x, where
x is distance from end A, 0 is a constant. X
2M A B
(A) The value of 0 is 2
L
1 2
(B) Moment of Inertia of the rod about an axis passing through A and parallel to y-axis is ML
2
(C) Moment of inertia of the rod about an axis passing through COM of the rod and parallel to y-
ML2
axis is .
18
1
(D) Moment of inertia of the rod about an axis passing through B and parallel to y-axis is ML2 .
6
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9. A ladder AB is supported by a smooth vertical wall and rough

horizontal floor as shown. A boy starts moving from A to B slowly.
The ladder remains at rest, then pick up the correct statement(s) :
(A) Magnitude of normal reaction by wall on ladder at point B will
increase.
(B) Magnitude of normal reaction by wall on ladder at point B will
decrease.
(C) Magnitude of normal reaction by floor on ladder at point A will
remain unchanged.
(D) Magnitude of friction force by floor on ladder at point A will
increase.
SECTION – 3: (Numerical Answer Type)
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
10. A semi circular uniform ring of mass m and radius R is pivoted at end A
and another end B is attached with a string such that line AB is horizontal A B
as shown in the figure. All the contact surfaces are smooth. What is the
net hinge reaction (approximately in Newton) applied by the hinge at A on
the ring just after the burning of the string. (mass of the ring m = 1 kg and
take g = 10 m/s2)
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11. The two identical rectangular steel frames with the dimensions shown are fabricated from a bar of
the same material and are hinged. Rectangular at the midpoints A and B of their sides(3m  1m).
If the frame is resting in the position shown on a horizontal surface with negligible friction,
determine the velocity v (in m/s) with which each of the upper ends of the frame hits the
horizontal surface if the cord D is cut. (Take the value of dimensions shown in figure c = 1 m, b =
 3  4
3/2 m and  = 74 i.e., sin  and cos  & g = 10 m/s2)
2 5 2 5
c side view
b c
 
b
A B
b
b
D
b
Smooth horizontal
surface
12. Moment of inertia of a cubical body of side ‘a’ P

4a
about its body diagonal is I. The moment of inertia
of the given cubical body of side ‘4a’ about the
line PQ in which a cubical part of side ‘2a’ is cut 2a
from the cube is nI, as shown in the figure. Find
the value of n. (density of both the cube is same) 4a
2a
2a
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PART II : CHEMISTRY
SECTION – 1 : (Only One Option Correct Type)
out of which ONLY ONE option is correct.
1. The following equilibria is maintained in a closed vessel:

N2 (g)+ 3H2 (g)‡ˆ ˆˆ †ˆˆ 2NH3 (g)
Moles at equilibrium 1 3 2
Equilibrium is now disturbed by removing x moles of H2 and simultaneously doubling the volume
of vessel. At new equilibrium, 17 gms of NH3 is obtained. Find x.
(A) 1 (B) 1.3
(C) 1.9 (D) 2.5
2. K 2Cr2O7 is one of the most widely used oxidizing reagent. The following equilibriums are
established in aqueous solution of Cr(VI)
HCrO-4 +H2O ‡ˆ ˆ †ˆ CrO-2
4 + H3 O
+
K a1 = 3.16×10 -7
2HCrO-4 ‡ˆ ˆˆ †ˆ Cr2 O7-2 +H2O K a2 = 22.0

All other equilibria with involving of chromium should be ignored.
Evaluate the equilibrium constant for Cr2O7-2 + 2OH- ƒ 2CrO-2 4 +H2O
(A) 1.38 × 10 20 (B) 2.323 × 1016
(C) 4.54 × 1013 (D) 0.436
3. The ionic product for pure formic acid K  HCOOH2  HCOO   has been estimated as 10-6 at
room temperature. The density of formic acid is 1.15 g/cm3. What percent of formic acid
molecules is converted to formate anion:
(A) 0.001% (B) 0.002%
(C) 0.003% (D) 0.004%
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4. Consider the following exothermic heterogenous equilibrium,

ˆˆ 2MNO3(aq) + H2O( l ) with Kc = 3 at 300 K. Select the incorrect option.
M2O(S) + 2HNO3(aq) ‡ˆ ˆˆ †
(A) Addition of small amount of H2O( l ) to above equilibrium has no effect on equilibrium
composition (%) of HNO3 and MNO3.
(B) On dilution, concentration of both HN03 and MN03 decreases.
(C) At 310 K, Kc < 3, if H is – ve.
(D) Kc is dependent on equilibrium concentration of HNO3.
5. 10 moles of pure PCl5 gas is put into a closed container of volume 'V' and temperature 'T' and
allowed to reach equilibrium, at an equilibrium pressure 20 atm. The pure PCl5 is found to be 50%
dissociated at equilibrium. PCl5(g) ‡ˆ ˆˆ †
ˆˆ PCl3(g) + Cl2(g)
If 20 moles of PCl5(g) is added to original equilibrium mixture keeping total pressure constant to 20
atm at same temperature 'T’, then ratio of new equilibrium volume to the initial volume V will be:
(A) 1.5 (B) 2.0
(C) 1.8 (D) 3.0
6. Which of the following solution will have pH close to 1.0?

(A) 100 mL of M/10 HCl + 100 mL of M/10 NaOH
(B) 55 mL of M/10 HCl + 45 mL of M/10 NaOH
(C) 10 mL of M/10 HCl + 90 mL of M/10 NaOH
(D) 90 mL of M/10 HCl + 10 mL of M/10 NaOH
26513942
SECTION – 2 : (One or More Than One Options Correct Type)
and (D) out of which ONE or MORE THAN ONE are correct.
7. Find out which of the following statements are true :

(A) Both pH and POH decreases with rise in temperature for pure H 2O.
(B) pH decreases while POH increases with rise in temperature for pure H2O.
(C) The pH scale shortens with increase in temperature.
(D) Kw increases with rise in temperature as dissociation of water is exothermic.
8. The shown snapshots represents three molecular level scenes of a gaseous mixture as it reaches
equilibrium (starting with ‘A’) over a time in a vessel of volume 1 litre.
Which of the following is/are correct for the Reaction : X2(g) + Y2(g) ‡ˆ ˆˆ †
ˆˆ 2XY(g)
(A) If each particle represents 0.2 moles then the value of reaction quotient (Q) for scene B is 4?
(B) In snapshot 'A-C' if each particle represents 0.1 mole then on introducing another 0.4 mole
each of X2 and Y2 in scene A, the equilibrium stage can be represented by the snap shot
(C) ‘C’ part of the 'film strip' represents the equilibrium irrespective of the value of each particle
in terms of moles.
(D) Only (B) and (C) are correct options.
9. In aqueous solution the ionization constants for carbonic acid are:
K1 = 4.2 x 10–7 and K2 = 4.8 x 10–11
Select the incorrect statement(s) for a saturated 0.034 M solution of the carbonic acid.
(A) The concentration of CO23  is 0.034 M
(B) The concentration of CO23  is greater than that of HCO3
(C) The concentration of H+ and HCO3 are approximately equal
(D) The concentration of H+ is double that of CO32
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10. 10 mL of a strong acid solution of pH = 2.000 are mixed with 990 mL of another strong acid solution of
pH = 4.000. The pH of the resulting solution will be....? (Given: log1.99 = 0.3)
11. Three solutions of strong electrolytes 25 mL of 0.1 M HX, 25 mL of 0.1 M H 2 Y and 50 mL of 0.1 N
Z(OH)2 are mixed. What is the pOH of the solution? [Given log 5 = 0.7]
12. The dissociation constant of acetic acid at a given temperature is 2.0 10–5. The degree of dissociation
of 0.1 M acetic acid in presence of 0.001 M HCl is equal to....?
26513942
PART III : MATHEMATICS

SECTION – 1: (Only One Options Correct Type)
and (D) out of which ONE is correct.
1. Let M =  x, y  | y  x  and N   x,y  | x

2 2

  y  a   1 . What is a necessary and sufficient
2
condition for M  N = N?
5 5
(A) a  (B) a 
4 4
(C) a  1 (D) 0 < a < 1
2. Let a line with the inclination angle of 60º be drawn through the focus F of the parabola
y2 = 8(x + 2). If the two intersection points of the line and the parabola are A and B, and the
perpendicular bisector of the chord AB intersects the x-axis at the point P, then the length of the
segment PF is ( ).
16 8
(A) (B)
3 3
16 3
(C) (D) 8 3
3
3. Given A(0, 2) and two points B and C on the parabola y2 = x + 4 such that AB  BC, determine
the range for the y-coordinate of point C.
(A) y  (–, 0]  [4, ) (B) y  (–, –4]  [0, )
(C) y  (–, –2]  [4, ) (D) y  (–, 0]  [2, )
4. From a fixed point A, three normals are drawn to the parabola y2 = 4ax at the points P, Q and R.
Two circles C1 and C2 be drawn on AP and AQ as diameter. If slope of the common chord of the
circles C1 and C2 be m1 and the slope of the tangent to the parabola at the point R be m2, then
m1  m2 is equal to
1
(A) (B) 2
2
1
(C) – (D) – 2
2
Space for rough work
26513942
5. A(1, 2) and B(4, – 4) are two points on the parabola y2 = 4x. Circles passing through A, B
intersect the parabola again at C and D. The locus of intersection of tangents to the parabola at C
and D is
(A) x – 1 = 0 (B) x + 2 = 0
(C) x + 3 = 0 (D) none of these
6. Let x  y + 7 = 0 is any chord of parabola x2 = 28y meeting it at A and B and the tangents drawn
to the parabola at A, B meet at C. The locus of circumcentre of ABC is
(A) x2 = 14 (y  7) (B) x2 = 14y  7
(C) x2 = 14y + 7 (D) none of these
SECTION – 2: (Multi Correct Choice Type)
out of which ONE OR MORE may be correct.
7. A tangent is drawn at any point (l, m), l, m  0 on the parabola y2 = 4ax and the tangents are
drawn from any point on this tangent to the circle x2 + y2 = a2 (where a > 0) such that all chords of
contact pass through a fixed point (, ), then
(A) l > 0, m > 0 (B) l < 0, m > 0
2 2 2
 l  m  l  m
(C) 2       8 (D) 4       0
       
8. For the parabola y2 = 4x, let P be the point of concurrency of three normals and S be the focus. If
1 be the sum of the angles made by three normals from the positive direction of x-axis and 2 be
  2
the angle made by PS with the positive direction of x– axis then 1 can be equal to

(A) 1 (B) 2
1 3
(C) (D)
2 2
26513942
9. A tangent is drawn at any point (x1, y1) other than vertex on the parabola y2 = 4ax. If tangent are
drawn from any point on this tangent to the circle x2 + y2 = a2 such that all the chords of contact
pass through a fixed point (x2, y2), then
y1
(A) x1, a, x2 are in G.P. (B) , a, y 2 are in G.P.
2
y x
(C) 4, 1 , 1 are in G.P. (D) x1 x2 + y1 y2 = a2
y2 x2
 
10. Point A and B are on the parabola y2 = 4x, satisfying OA  OB  4 and point F is the focus of the
parabola. Then S OFA  S OFB = _______
11. Let the focus and directrix of parabola y2 = 2px(p > 0) be F and L respectively. A and B are

moving points on the parabola satisfying AFB  . Let the projection of M the midpoint of
3
MN
segment AB on l be N. Then the maximum value of is ___
AB
12. Two equal parabolas with vertical axis of symmetry p1 and p2 have their vertices at (0, 4) and
(6, 0) respectively. If they touch each other at a point, the sum of abscissa and ordinate of point of
contact is __________
26513942

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(Batches: e-SANKALP-2325 S1, T1 & P1)

I I T – JEE, 2 3 2 5 Paper Code

B. Question Paper Format

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

1. A uniform thin, rod AB of length L and mass m is undergoing m, L

3. O is the centre of mass of a body of mass M as shown in the figure. A, B, C

Space for Rough work

4. ABC is an isosceles triangular sheet of negligible thickness, made of A

5. The Moment of inertia of the plate in fig(a)

6. A particle is rotating about a vertical axis in the horizontal plane such R

(C) 2  (R 0  t) 2 (D) 

Space for Rough work

SECTION – 2 : (One or More Than One Options Correct Type)

7. Two identical semicircular discs of mass ‘m’ each and radius Z

8. A wire of mass M and length L is placed along x-axis with end A at Y

Space for Rough work

9. A ladder AB is supported by a smooth vertical wall and rough

SECTION – 3: (Numerical Answer Type)

Space for Rough work

12. Moment of inertia of a cubical body of side ‘a’ P

Space for Rough work

1. The following equilibria is maintained in a closed vessel:

2HCrO-4 ‡ˆ ˆˆ †ˆ Cr2 O7-2 +H2O K a2 = 22.0

Space for Rough work

4. Consider the following exothermic heterogenous equilibrium,

6. Which of the following solution will have pH close to 1.0?

Space for Rough work

SECTION – 2 : (One or More Than One Options Correct Type)

7. Find out which of the following statements are true :

9. In aqueous solution the ionization constants for carbonic acid are:

K1 = 4.2 x 10–7 and K2 = 4.8 x 10–11

Space for Rough work

SECTION – 3: (Numerical Answer Type)

Space for Rough work

PART III : MATHEMATICS

1. Let M =  x, y  | y  x  and N   x,y  | x

Space for rough work

SECTION – 2: (Multi Correct Choice Type)

Space for rough work

SECTION – 3: (Numerical Answer Type)

Space for rough work

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