WT1

(Batches: e-SANKALP-2325 S & T)
IIT – JEE, 2325 Paper Code

100769
(CLASS XI)
Time: 1 ½ Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.
B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Integer Questions, the answer to each question is a
non-negative integer. For each question, enter the correct integer corresponding to the answer and
each question carries +4 marks for correct answer. There is no negative marking.
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e-Sankalp2325 S & T-XI-PCM-(100769)-2
PART I : PHYSICS
SECTION – 1: (Only One Options Correct Type)
This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.
1. In figure shown block A starts moving with a

acceleration a. The magnitude of acceleration of P
of point P of string is B A
=0
a
(A) (B) a
2
3a
(C) (D) 2a
2
2. A uniform rope of mass ‘m’ is placed on a smooth fixed

h
sphere of radius ‘R’ as shown in the figure. Find the tension ‘m’
‘T’ in the rope when it is in a horizontal plane at a vertical
distance h = R/2 below the top of sphere. R
mg mg
(A) (B)
2 2
3mg 3mg
(C) (D)
 2
3. The three pulley arrangement shown in the figure are identical and S
four blocks are attached with the rope. The mass of rope is negligible.
At t = 0, all the blocks are released from rest. The tension in the string
‘S’ is
800 400
(A) N (B) N
3 3
1600
(C) N (D) 700 N
3
15 kg 12 kg
20 kg 10 kg
Space for Rough work
4. Two blocks of mass 3 kg and 7 kg are kept on a rough horizontal 1

3 kg
surface. A force F is applied on lower block of mass 7 kg. F
7 kg
Coefficient of friction between 3 kg and 7 kg is ‘1’ and between 7
kg and surface it is 2 = 0.2. Choose the correct option.
2 = 0.2
(A) If applied force is 15 N then slipping will occur between 3 kg and 7 kg.
(B) If 1 = 0 and applied force is 30 N then both block have same acceleration of magnitude
2
3 m/s .
(C) Slipping will start between 7 kg and surface for minimum value of F = 20 N and it is
independent of 1.
(D) For F = 10 N, slipping can be possible between 7 kg and 3 kg it will depend on 1.
5. A cylinder with radius R = (1/3) m spins around its axis with an angular speed . On its inner
surface, there lies a small block of mass 10 mg. The coefficient of friction between the block and
the inner surface of cylinder is  = (3/4). Find the minimum value of  for which the block does
not slip (stay still with respect to cylinder). The axis of cylinder is horizontal. (g = 10 m/s2)
Axis of cylinder
m
(A) 5 rad/s (B) 52 rad/s

(C) 4 rad/s (D) 42 rad/s
6. In the shown figure all surfaces are rough. A 3m

Block B is attached with a load of mass 6m
through an ideal string passing over an ideal B 2m
pulley. Coefficient of friction is  = 0.2 between C m
all the surfaces. The correct option is:
(A) friction force on C due to B is mg
(B) friction force on A is zero
55
(C) acceleration of block B is
11 6m
(D) Load remains at rest.
SECTION – 2: (Multi Correct Choice Type)
This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.
7. In the figure shown, when a horizontal force 

/3
F is applied to the larger block A, all the four m m
blocks move together. There is no slipping
between any two blocks. (Take m = 1 kg, M M M F
= 2 kg,  = 0.3 and g = 10 m/s2) B A
=0
(A) The maximum value of the applied horizontal force F is 3N
(B) In the above case, the friction force between the front blocks is 2N
(C) The maximum value of the applied horizontal force F is 2N
(D) In the above case, the friction force between the front blocks is 3N
8. The system is in equilibrium. The blocks A, B and C are of

equal masses, the incline face is frictionless, the thread is
S
light and inextensible and blocks B and C are connected to
axles of pulley by rigid links. When spring S is cut, then
choose correct acceleration immediately after it.
A
C
P
B

(A) Acceleration of A is zero (B) Acceleration of A is g/2

(C) Acceleration of C is 2g (D) Acceleration of C is g
9. In the above question, when string is cut at point P and spring S is not cut, then choose correct
acceleration immediately after it.
(A) Acceleration of A is zero (B) Acceleration of A is g/2
(C) Acceleration of C is 2g (D) Acceleration of C is g
SECTION – 3: (Non-Negative Integer Value Correct Type)
This section contains three (03) questions. The answer to each question is a non-negative integer. For
each question, enter the correct integer corresponding to the answer.
10. A wedge is slides down a frictionless inclined plane that makes angle  = 30 with horizontal. A
small block is placed at the horizontal top side of wedge. During the slide, the block does not
move relative to wedge. The minimum possible coefficient of static friction S between the block
1
and the wedge is . Find the value of k.
2k 3
11. Over a smooth light pulley is passed a string supporting at one end a
weight of mass 4 kg. At the other end of the string is a pulley of mass 1 kg.
Two masses of 2 kg and 3 kg are suspended on either side of the 1kg
2
pulley as shown in figure. The acceleration (in m/s ) of the 4 kg mass is
1kg 4kg
2kg 3kg
12. A uniform chain of length L has one of its end attached to a

3L
vertical wall at point A, while of the length of the chain is A
4
lying on table as shown in figure. Tangent to the chain at A
makes an angle 37 with the wall. The minimum coefficient of 37
friction between table and chain so that chain remains in
equilibrium is
PART II : CHEMISTRY
1. 40 ml of 0.05 M solution of sodium sequicarbonate (Na2CO3.NaHCO3.2H2O) is titrated against

0.05 M HCl. When phenolphthalein is used as indicator, x ml HCl is used. In a separated titration
using methyl orange as indicator, y ml of HCl is used. The value of (y – x) is:
(A) 80 ml (B) 30 ml
(C) 120 ml (D) 180 ml
2. 0.01 mol of an acidic organic compound C2H2Ox was treated with 224 ml of O2 at STP. After
combustion the total volume of the gas was 560 ml at STP. On treatment with KOH solution the
volume decreases to 112 ml then value of x is:
(A) 4 (B) 2
(C) 3 (D) 6
3. A mixture of gas contains N2 and C2H2. 20 ml of this mixture is added to 70 ml of O2 and

combustion is allowed to take place over mercury. After cooling the volume of the gas is found to
be 68.5 ml. when the resultant gas mixture is passed through KOH solution. The volume of the
residual gas is 38.5 ml. The percentage composition of N2 in the mixture will be:
(A) 20 (B) 25
(C) 40 (D) 75
Space for rough work
4. A open ended mercury manometer is used to measure the pressure exerting by a trapped gas as
shown in the figure. Initially manometer shows no difference in mercury level in both column as
shown in diagram
P = 1 atm
NH3 gas
300 K
VL
Hg
After sparking ‘NH3’ dissociated according to following given reaction

1 3
NH3  g   N2  g  H2  g 
2 2
If pressures of NH3 decreases to 0.9 atm. Then difference in mercury level is (assume
temperature is constant during entire process.)
(A) 228 mm Hg (B) 38 mm Hg
(C) 76 mm Hg (D) 152 mm Hg
5. At critical temp. which of the following graph is correct

(A) (B)
PV PV
P P
(C) (D)
PV PV
P P
6. A 6.85 g sample of the hydrate Sr(OH)2.xH2O is dried in an oven to give 3.13 g of anhydrous
Sr(OH)2. What is the value of ‘x’? (Atomic weights: Sr = 87.60, O = 16.0, H = 1.0)
(A) 8 (B) 12
(C) 10 (D) 6
7. A 10 mL mixture containing 0.2 g NaOH and 0.25 g Na2CO3 was treated with xN HCl required
15 mL of it with phenolphthalein indicator. After end point a 0.5 g NaHCO3 was added and it was
again titrated with y N HCl required 25.5 mL of HCl with methyl orange. Which of the following
is/are correct?
(A) x is almost 1.5 times of y
(B) If in above titration x N HCl is replaced with y N HCl then for first end point it will require
22.5 mL of HCl
(C) After first end point if instead of 0.5 g if 2.5 g NaHCO3 is added and titrated with x N HCl it will
require 64.1 mL
(D) Only (A) and (B) are correct
8. Two flasks A and B have equal volumes. Flask A containing H2 gas is maintained at 300 K while
B containing an equal mass of C2H6 gas is maintained at 900 K. Assuming ideal behaviour for
both the gases, identify the correct statement(s) :
(A) Molecules in flask A are moving 5 times as fast as the molecules in flask B.
(B) Kinetic energy per mole in the flask B is 3 times the kinetic energy per mole in flask A
(C) Total kinetic energy in flask A is 5 times total kinetic energy in flask B
(D) Compressibility factor of the gas in flask A is equal to that of the gas in flask B.
9. Find out the true statement among the following

(A) The gas with a larger value of the ratio of critical temperature to critical pressure (Tc/ Pc) will
have larger value of excluded volume (b)
(B) Molecules of different gases have the same kinetic energy at a given temperature.
(C) Inversion temperature of a gas is the temperature at which the distinction between a liquid
and a gas disappear
(D) According to kinetic theory of gas an ideal gas can not be liquefied at any temperature and
pressure?
10. 10 gram sample of FeS2 was roasted and SO2 thus produced required 10 ml of 0.15 M K2Cr2O7
solution in acidic medium. Hence the % of FeS2 in closest integer in the sample is………..
(Atomic mass = Fe = 56, S = 32)
11. 24 volume H2O2, means volume of O2 product at STP by heating 1 ml of aqueous solution of
H2O2
1
 H 2O     O 2  g 
H 2O 2  aq  
2
Above H2O2 solution is used to estimate KMnO4 quantitatively. If ‘v’ ml, xN H2O2 solution is used
with 0.1M, 200 ml, KMnO4 in acidic medium, find the value of x?
(Atomic mass: Mn = 55, K = 39, O = 16)

12. KMnO4  I  
H
 Mn 2  I 2
I  IO3 
 I2
I2  Na 2S2O3 
 NaI  Na 2S4 O6
0.15 mol KMnO4 and 0.25 moles of I has been used in above equation. Find the equivalents of
Na2S4O6 formed.
(Atomic mass: Mn = 55, K = 39, O = 16, I =127, S =32, Na = 23)
PART III : MATHEMATICS

1. If y = (sin x + cosec x)2 + (cos x + sec x)2 + (tan x + cot x)2

p 
where x  R – {x ; x = n, (2n + 1)/2  n  I} and minimum value of y = p then   is where [.]
3 
denotes the greatest function
(A) 4 (B) 6
(C) 7 (D) 8
2. Let k = 1, then 2 sin2k + 4 sin4k + 6 sin6k + … + 180 sin180k is equal to

(A) 90cosk (B) 90tan89
(C) 90 tank (D) 90cot89
3 
3. If tan9  (where 0 <  < ) then the value of (3 cosec 3 – 4 sec 3) is equal to
4 18
(A) 3 (B) 4
(C) 5 (D) 10
7
r
4. The value of  cos 15
r 1
is
1 1
(A) (B)
64 128
1 1
(C) (D)
32 4
5. Minimum value of sin x  cos x  tan x  cot x  sec x  cosec x is

(A) 6 (B) 10
(C) 2 (D) none of these
   
tan cot cot tan
  8   8   8   8
6. Let a1   tan  , a2   tan  , a3   cot  ,a 4   cot  , then which of the
 8  8  8  8
following statement(s) is/are true
(A) a4 > a3 > a2 > a1 (B) a3 > a4 > a2 > a1
(C) a3 > a4 > a1 > a2 (D) a3 > a1 > a2 > a4
7. The expression cos 3 + sin 3 + (2 sin2 – 3)(sin  – cos ) is positive for all  in
 3    
(A)  2n  , 2n   , n  I (B)  2n  , 2n   , n  I
 4 4  2 6
      3 
(C)  2n  , 2n   , n  I (D)  2n  , 2n  ,nI
 3 3  4 4 
cos  2  3r 1   cos  3  2r 1 

n n
8. Let S(n) = sin  3r  
r 1
,   18 and P(n) = 
r 1cos  2r  
,   36 , then
(A) S(2012) + P(2012) = 2010 (B) S(2012) + P(2012) = 2012

(C) P(2011) – S(2011) = 2009 (D) P(2011) – S(2011) = 2008
9. If sin 470  sin610  sin11 0  sin250   then

1 3 1
(A)   (B)  
2 2 2
5 1
(C)   (D)   cos1
4
cos 25º cos 70º cos85º

10. The value of   is equals to _____
sin70º sin85º sin25º sin85º sin25º sin70º
2
11. The value of tan 1º tan 2º + tan 2º tan 3º + ..... + tan 88º tan 89º is equal to cot 1  n, then the
value of n is ________
12. For three positive integers a, b and c and

 b 
4  8  32  768  a 2 cos   where b and c are co–prime to each other. Then the value
 c 
of (a + b + c) is equal to _____
(Batches: e-SANKALP2325 S & T)
IIT – JEE, 2325 Paper Code

(CLASS XI) 100769
ANSWERS
PHYSICS (PART-I)
1. A 2. D 3. C 4. C
5. B 6. A 7. A, B 8. A, C
9. B, D 10. 0.50 11. 1.80 12. 0.25
CHEMISTRY (PART-II)
1. A 2. A 3. B 4. C
5. A 6. A 7. A, B, C 8. B, C, D
9. A, B, D 10. 2.70 11. 23.36 12. 1.05
MATHEMATICS (PART-III)
1. A 2. B 3. D 4. B
5. D 6. C 7. A, B 8. A, D
9. A, B 10. 2 11. 89 12. 61
HINTS AND SOLUTION

CHEMISTRY (PART-II)
1
1. meq. of Na2CO3 = meq. of HCl
2
1
2 × 40 × 0.05 = x × 0.05
2
 x = 40 ml
With M.O.
Meq. of Na2CO3 + Meq. of NaHCO3 = Meq. of HCl
2 × 40 × 0.05 + 40 × 0.05 = y × 0.05
y = 120 ml
 (y – x) = 80 ml
3. 2C2H2  g  5O2  g   4CO2  g  H2 O   

Volume of CO2 = 68.5 – 38.5 = 30 ml
30
Volume of C2H2 =  15ml
2
Volume of N2 = 20 – 15 = 5 ml
5
% of N2 =  100  25%
20
1 3
NH3 
 N2  H2
2 2
4. 1 0 0
0.1 0.3
0.9
2 2
0.4
PT = 0.9 + = 0.9 + 0.2 = 1.1
2
P = 1.1 – 1
= 0.1 atm
= 76 mm Hg
5. At TC Z is 3/8 hence Z<1 so A only represents Z<1.
NaOH+HCl   NaCl  H2 O

 0.2
 40
7. Up to first end point 
Na2 CO3  HCl  NaHCO3  NaCl
 0.25

 106
NaHCO3 +HCl  NaCl  H2 O  CO2

Up to second end point  0.5 0.25
 
 84 106
The total equivalents of HCl till first end point
0.2 0.25
   7.36  103  15ml  xN
40 106
x = 0.5 N
0.5 0.25
The equivalents of HCl used up for second titration =   8.3  103
84 106
8.3 × 10 – 3 equi = 25.5 × 10 – 3 L × y N
y N = 0.325 N
x
 1.5
y
Hence, (A) is the correct answer.
As y is of weaker strength for the first titration instead of 15 ml of x, 1.5 times of 15 ml of y will be
used up so (B) is correct.
If 2.5 g of NaHCO3 is added
2.5 0.25
Total HCl equivalents required =   0.0322
84 106
0.0322 0.0322
So V =   0.064L
x 0.5
= 64.1 mL
Hence, (C) is also correct.
10. 4FeS2 +11O2 

 2Fe2O3 + 8SO2

H
SO 2  K 2Cr2O7  Cr 3   SO 4  9
9
m. moles  4.5
2
moles of FeS2 = 2.25  10–3
moles = 120  2.25  10–3 = 0.27 g
0.27
% FeS2   100  2.70%
10
11. % of H2O2
22400 ml O2 is produced by = 68 g H2O2
68
1 ml O2 is produced by = g H2O2
22400
68  24
24 ml O2 is produced by = g H 2 O 2  0.0728 or 7.28%
22400
7.28 1000
Normality of H2O2 solution   4.28
100 17
Volume of H2O2, V  4.28 = 0.1  5  200
v = 23.36
0.75 0.75
12. Total moles of I2 produced =   0.525
2 5
Equivalents of I2 used with Na2S2O3 = 0.525  2 = 1.05
Equivalents of Na2S4O6 formed = 1.05
MATHEMATICS (PART-III)
1. A
y = sin2x + cosec2 x + 2 + cos2 x + sec2 x + 2 + tan2 x + cot2 x + 2
= 1 + 6 + 1 + tan2 x + 1 + cot2 x + tan2 x + cot2 x
= 9 + 2(tan2 x + cot2 x)
2
= 9 + 2 [(tan x – cot x) + 2]
2
= 13 + 2 (tan x – cot x)
ymin = 13 = p
p
 3   4
2. B
Let y = 2 sin2 + 4 sin4 + … + 178 sin178
 y = 178 sin178 + 176 sin176 + … + 2 sin2
 2y = 180(sin2 + sin4 + … + sin178)
3. D
3
tan9 
4
sin9 cos 9
 
3 4
3 4 
10  cos3  sin3
3 4  3 cos 3  4 sin3   5 5 
Now  2 =
sin3 cos 3 2sin3 cos 3 sin6
 sin9 cos3  cos9 sin3  sin  9  3 
= 10    10 = 10
 sin6  sin6
4. B
 2 4 7 1
cos cos cos cos 
15 15 15 15 16
3 6 1
cos cos 
15 15 4
5 1
cos 
15 2
1
 required value is
128
5. D
2 2  sin x  cos x 
y  sin x  cos x  
sin 2x sin2x
2 1  sin x  cos x 
y   sin x  cos x  
 sin x  cos x 2  1
2
y t
t 1
2
y  1   t  1 
 t  1
Hence none of these
6. C
   
As 0    cot  1  tan
8 4 8 8
 a3 > a4
 
Again, cot  1  tan  0
8 8
 a1 < a3
Hence a2 < a1 < a4 < a3.
7. A, B
2 2  
4(cos  – sin )(cos  + sin  cos  + sin  – sin  cos ) = 4 2 sin      0
 4
 
sin     is negative
 4

(2n – 1) <  – < 2n.
4
8. A, D
2 + 3 = 90
2 = 90 – 3
2 . 3r – 1  = 90 . 3r – 1 – 3r 
cos(2 . 3r – 1 ) =  sin(3r )
cos  2  3r 1  1, r is odd
 
sin  3  
r
 1, r is even
 cos  3  2r 1  , r  1
r
Similarly, cos(2 ) =  .
cos  3  2   , r  2
r 1
9. A, B
sin 470  sin610  sin110  sin250
 2sin540 cos70  2sin180 cos70
 2cos70 sin540  sin180 
 5  1   5  1  
 2cos70      
 4   4  
 cos70
   cos70
Clearly,   cos70  cos150
Also,   cos360 and   cos1 (as 1 is in radian)
10. 2
cos 25º sin25º  cos 70º sin70º  cos85º sin85º
Given expression =
sin 25º sin70º sin85º
sin50º  sin140º  sin170º
=
2 sin 25º sin70º sin85º
4
= (Using sin 2A + sin 2B + sin 2C = 4 sin A sin B sin C where A + B + C = 180º)
2
=2
11. 89
sinrº sin r  1 º cos1º cos1º  sin (r  1)º r 

Tr   1 1 = 1 =   1
cos rº cos 1  r  º cosrº cos(r  1)º sin1º  cosrº cos(r  1)º 
= cot1º tan  r  1 º  tanrº  1  T1  T2  .....T88  cot1º (tan89º  tan1º )  88 = cot 2 (1º )  89
12. 61
Let 768  32cos 
16 3  32cos 
3 
cos    
2 6
   11
So 4  8  32  32cos = 4  8  8 cos = 4  4 sin = 4  4 cos
6 12 24 24
 11  2 11 11
= 4  1  cos  = 4  2cos = 2 2 cos
 24  48 48
So a = 2, b = 11, c = 48
(a + b + c) = 61

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(Batches: e-SANKALP-2325 S & T)

IIT – JEE, 2325 Paper Code

B. Question Paper Format

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

1. In figure shown block A starts moving with a

2. A uniform rope of mass ‘m’ is placed on a smooth fixed

Space for Rough work

4. Two blocks of mass 3 kg and 7 kg are kept on a rough horizontal 1

(A) 5 rad/s (B) 52 rad/s

6. In the shown figure all surfaces are rough. A 3m

Space for Rough work

SECTION – 2: (Multi Correct Choice Type)

7. In the figure shown, when a horizontal force 

8. The system is in equilibrium. The blocks A, B and C are of

(A) Acceleration of A is zero (B) Acceleration of A is g/2

Space for Rough work

SECTION – 3: (Non-Negative Integer Value Correct Type)

12. A uniform chain of length L has one of its end attached to a

Space for Rough work

1. 40 ml of 0.05 M solution of sodium sequicarbonate (Na2CO3.NaHCO3.2H2O) is titrated against

3. A mixture of gas contains N2 and C2H2. 20 ml of this mixture is added to 70 ml of O2 and

Space for rough work

After sparking ‘NH3’ dissociated according to following given reaction

5. At critical temp. which of the following graph is correct

Space for rough work

SECTION – 2: (Multi Correct Choice Type)

9. Find out the true statement among the following

Space for rough work

SECTION – 3: (Non-Negative Integer Value Correct Type)

Space for rough work

PART III : MATHEMATICS

1. If y = (sin x + cosec x)2 + (cos x + sec x)2 + (tan x + cot x)2

2. Let k = 1, then 2 sin2k + 4 sin4k + 6 sin6k + … + 180 sin180k is equal to

5. Minimum value of sin x  cos x  tan x  cot x  sec x  cosec x is

Space for rough work

SECTION – 2: (Multi Correct Choice Type)

cos  2  3r 1   cos  3  2r 1 

(A) S(2012) + P(2012) = 2010 (B) S(2012) + P(2012) = 2012

9. If sin 470  sin610  sin11 0  sin250   then

Space for rough work

SECTION – 3: (Non-Negative Integer Value Correct Type)

cos 25º cos 70º cos85º

12. For three positive integers a, b and c and

Space for rough work

(Batches: e-SANKALP2325 S & T)

IIT – JEE, 2325 Paper Code

9. B, D 10. 0.50 11. 1.80 12. 0.25

9. A, B, D 10. 2.70 11. 23.36 12. 1.05

HINTS AND SOLUTION

3. 2C2H2  g  5O2  g   4CO2  g  H2 O   

5. At TC Z is 3/8 hence Z<1 so A only represents Z<1.

10. 4FeS2 +11O2 

sinrº sin r  1 º cos1º cos1º  sin (r  1)º r 

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