WT7

(Batches: e-SANKALP-2325 S1, T1 & P1)
IIT – JEE, 2325 Paper Code

100844
(CLASS XI)
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.
B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.
Enrolment No. :
Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
e-Sankalp2325 S1, T1 & P1-XI-PCM-(100844)-2
PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. The friction coefficient between the horizontal surface and 1.0 m/s
each of the block shown in the figure is 0.2. The collision
between the blocks is perfectly elastic. Then the separation 2 kg 4 kg
2
between them when they come to rest is (g = 10m/s ).
(A) 5 cm (B) 6 cm 16 cm
(C) 8 cm (D) 10 cm
2. Two identical particles A and B of mass m each are connected together by a light and
inextensible string of length . The particle are held at rest in air in same horizontal level at a
separation . Both particles are released simultaneously and one of them (say A) is given speed
v0 vertically upward. Choose the correct options(s). Ignore air resistance.
v02
(A) The maximum height attained by the centre of mass of the system of A and B is
8g
(B) The kinetic energy of the system of A and B when the centre of mass is at its highest point, is
mv 20
.
2
v2
(C) The maximum height attained by the centre of mass of the system of A and B is 0
4g
(D) The kinetic energy of the system of A and B when the centre of mass is at its highest point, is
mv 20
.
8
3. A block of mass m1 = 3 kg is connected with ideal u = 4 m/s

spring of spring constant k = 30000 N/m and kept at k
horizontal frictionless surface as shown in the figure. m2 m1
The block m 2 = 1 kg is moving with velocity u = 4 m/s
towards block m 1. v1 and v 2 are the final speed of the
block m1 and m2 respectively.
Choose the correct statement(s)
(A) v1 = v2 = 1m/s
(B) The maximum compression in the spring is 2 cm
(C) The maximum compression in the spring is 4 cm
(D) None
Space for Rough work
4. A semi-cylindrical wedge A of mass M and radius R is B

placed on a horizontal smooth surface. A solid cylinder of
mass m and radius r is placed at the top of the wedge as O
m
shown in the figure, and released with a gentle rightward r
push. There is no friction between the curved surface of
semi cylinder and solid cylinder. Find the velocity of the
wedge when the line CO makes an angle of 60 with the
vertical. (given R = 3r and M = 3m) M
4gr gr R
(A) (B) Wedge-A
15 5
2gr gr C
(C) (D)
15 15
5. An undeformed spring of spring constant k is connected to a bead of

mass m as shown in figure. Bead can move along long rigid rod without
k
friction. A particle of mass m moving with velocity ‘v’ in the vertical plane
containing spring and rod strikes bead at an angle 45 with horizontal
and sticks to bead. Choose correct alternative representing maximum m
elongation of spring is, all particles are in same horizontal plane. 
v
 m 1 m  m
(A)   v (B)  v
 k  2  k 
 m 1 m 
(C) 2   v (D)  v
 k  4  k 
6. Three blocks A, B and C whose masses are m, km and 4m m km 4m

respectively kept at rest on the horizontal smooth surface, as shown A B C
in the figure. The ball A is given velocity v0, rightward and it collides
with the ball B elastically. Then ball B collides elastically third ball C.
The value of k, for which third ball C receive the maximum speed is
(A) 1 (B) 2
(C) 3 (D) 4
SECTION – 2 : (One or More Than One Options Correct Type)
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
7. Two balls A and B of masses m and 2m respectively

are lying on a smooth surface as shown in the figure.
Ball A hits the ball B (which is at rest) with a velocity 5m
v = 16 m/s. Such that B just reaches the highest point A v B
of inclined plane. (g = 10 m/s2)
(A) e = 3/4 (B) e = 7/8
(C) vA = 4 m/s (D) vA = 8 m/s
where e is the coefficient of restitution and v A is velocity of the ball A after collision.
 
8. Velocity of a particle of mass 2 kg changes from v1  2iˆ  2ˆj m / s to v 2  (iˆ  ˆj)m / s after
colliding with a plane surface
 1
(A) The angle made by the plane surface with the positive x–axis is 90º + tan–1  
3
 1 
(B) The angle made by the plane surface with the positive x–axis is tan1  
3
1
 
(C) The direction of change in momentum makes an angle tan1   with the +ve x–axis
3
 1
(D) The direction of change in momentum makes an angle 90  tan1   with the plane surface
3
9. Consider one dimensional collision between two identical particles A and B. B is stationary and A

has momentum P before impact. During impact, B gives impulse J to A. Choose the correct
alternative(s)
(A) the total momentum of the (A + B) system is P before and after the impact and (P  J) during
the impact.

(B) During the impact, A give impulse J to B.
2J
(C) The coefficient of restitution is 1
P
J
(D) The coefficient of restitution is  1
P
SECTION – 3: (Numerical Answer Type)
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
10. A bob of mass m , suspended by a string of length l1 is given a minimum velocity required to
complete a full circle in the vertical plane. At the highest point, it collides elastically with another
bob of mass m suspended by a string of length l2, which is initially at rest. Both the strings are
mass-less and inextensible. If the second bob, after collision acquires the minimum speed
required to complete a full circle in the vertical plane, the ratio l1/l2 is
11. A small ball of mass 100 g is attached to a light and 30 cm

inextensible string of length 50 cm. The string is tied to a O A
support O and the mass m released from point A which is at a
horizontal distance of 30 cm from the support. Find the speed Particle
of the ball at its lowest point of the trajectory.
12. A small sphere and a big sphere are released from rest with a very small
gap from height h as shown in the figure. The mass of bigger sphere is
very large as compared to mass of smaller sphere. The height from the
point of collision of smaller sphere with the bigger sphere to which the h
smaller sphere will rise if all the collisions are elastic is 10kh . Find the
value of k.
PART II : CHEMISTRY
SECTION – 1 : (Only One Option Correct Type)
out of which ONLY ONE option is correct.
1. I2 + I– I 3–
–
This reaction is set up in aqueous medium. We start with 1 mol of I2 and 0.5 mol of I in 1L flask.
After equilibrium is reached, excess of AgNO3 gave 0.25 mol of yellow ppt. Equilibrium constant
is
(A) 1.33 (B) 2.66
(C) 2.00 (D) 3.00

OH
2. In a dilute aqueous solution, the reaction OCl +I   OI +Cl take place in the following steps.
(i) K1
O C l + H 2 O H O C l + O H (fast)
K2
(ii) I +HOCl 

3 K
HOI+ Cl (slow)
(iii) OH + HOI
K1



 
 H 2 O + O I (fast)
K2
Rate of consumption of I for the given equation would be
K 3K1 [OCl- ][I- ] K1K 2 [OCl- ][I- ]

(A) (B)
K2 [OH- ]2 K3 [OH- ]
K1K3 [OCl- ][I- ] K 2K 3 [OCl- ][I- ]

(C) (D)
K2 [OH- ] K1 [OH- ]
3. Biacetyl, the flavouring that makes margarine taste “just like butter,” is extremely stable at room
temeperature, but at 200oC it undergoes a first order break down with a half-life of 12.0 min. An
industrial flavor enhancing process requires that a biacetyl flavoured food be heated briefly at
200oC. How long can the food be heated and retain 85% of its butter flavor? (log 1.176 = 0.0706)
(A) 2.81 sec (B) 169 sec
(C) 2 mins (D) 16.9 mins
4. In a vessel of capacity 1 litre at 27oC (containing some inert gas also) for the first order
decomposition of
C2H5Br (g) → C2H4(g) + HBr (g) ,
the initial pressure of 200 mm of Hg changes to 390 mm of Hg after infinite time, where all the
reactant is consumed. If at 10 min, 0.2 g of NaOH was required to react completely with reaction
mixture, then find out the half life of reaction?
(A) 8 min (B) 10 min
(C) 15 min (D) Data insufficient
5. A closed rigid container contains a gas ‘A’(g) at 16 atm and decomposes as :
Assume the temperature remains constant.

The total pressure inside container after 10 min is:
(A) 16 atm (B) 20 atm
(C) 24 atm (D) 30 atm
1 3
6. At 25o C Go for 

N2  H2  o
 NH3 ; is 16.5kJ / mol; what is G for
2 2


N2  3H2  o
 2NH3 ; at 25 C ?
(Given antilog 0.8917 = 7.7941, and log6.07 = 0.7832)
(A) 3.3 kJ / mol (B) 33 kJ / mol
(C) 330 J / mol (D) 33 J / mol
SECTION – 2 : (One or More Than One Options Correct Type)
and (D) out of which ONE or MORE THAN ONE are correct.
7. 2X(g) + Y(g) + 3Z(g)  Products

The rate equation of above reaction is given by
1 0 2
Rate = K [X] [Y] [Z]
Choose the correct statement(s)
(A) If 75% of X undergoes reaction in 20 sec, 50% of X will react in 10 sec if [Z] > > [X]
(B) Rate of reaction decreases by reducing the concentration of y to half of the original value
(C) The half life of Z increases by increasing its concentration if [X] > > [Z]
(D) On doubling the concentration of X, Y and Z, rate of reaction becomes 8 times
8. For the reaction A + B  P; experimental observations are given as follows:

[A] M [B] M Initial rate (M sec–1)
at 300 K at 400 K
2.5 × 10–4 3.0 × 10–5 5.0 × 10–4 2.0 × 10–3
5.0 × 10–4 6.0 × 10–5 4.0 × 10–3
–3 –5
1.0 × 10 6.0 × 10 1.6 × 10–2
Which of the following is/are correct statement(s)?
(A) The value of rate constant at 300 K is 2.667 × 108 M–2 sec–1 :
(B) Overall order of reaction is 3
(C) Order of consumption is B is 2
(D) The energy of activation for reaction is 3.36 kcal/mol
9. For the overall reaction between A and B to yield C and D, two mechanisms are proposed:
I. A + B  AB*  C + D k1 = 1 × 10–5 M–1s–1
II. A  A*  E k1 = 1 × 10–4 M–1s–1
E + B  C + D k2 = 1 × 1010 M–1s–1
Species with * are short lived. Which of the following is/are correct?
(A) Rate according to mechanism I when concentration of each reactant is 0.1 M will be 1 × 10–7
M s–1
(B) Rate according to mechanism II when concentration of each reactant is 1 M will be 1 × 10–4 M
s–1.
(C) At concentration of B = 10 M, rates of reaction by both the mechanism are equal
(D) All the above are correct
10. A compound ‘A’ in aqueous phase dissociates to form unknown number of moles of gaseous
products. Find the number of moles of gaseous products formed per mole of ‘A’ reacted if Kpc of
2
the reaction is 8 and Kc = 2 at temperature of Kelvin (where R = gas constant).
R
11. For a radioactive decay reaction : 

X  Y + q  (where q is the number of stoichiometric coefficient)
Following graph was observed:
Y
Concn
X
t1 t2
Time
If the ratio of the volume of emitted helium gas at different time t1 and t2 be ½. Find the value of q.
12. The decomposition of ethane into ethene and hydrogen involves 5 different steps, having rate
constants K1, K2, K3, K4 and K5. The rate law is given by:
1
d  C2H6   K K K 2
  1 3 4   C2H6 
dt  K5 
if Ea1 (9 kJ/mol), Ea3 (6 kJ/mol), Ea4 (5 kJ/mol) and Ea5 (0) are the energies of activation associated
with 1st , 3rd, 4th and 5th steps respectively, find the overall energy of activation (kJ/mol) for ethane
decomposition.
PART III : MATHEMATICS

SECTION – 1: (Only One Options Correct Type)
and (D) out of which ONE is correct.
1. The coordinates of the point on the parabola y = x 2 + 7x +2, which is nearest to the straight
line y = 3x – 3 are
(A) (–2, –8) (B) (1, 10)
(C) (2, 20) (D) (–1, –4)
2. The number of point(s) (x, y) (where x and y both are perfect squares of integers) on the parabola
2
y = px, p being a prime number, is
(A) one (B) zero
(C) two (D) infinite
3. If the parabola y = (a – b) x2 + (b – c)x + (c –a) touches the x-axis in the intervals [0, 1] then
the line ax + by +c = 0
(A) always passes through a fixed point
(B) represents the family of parallel lines
(C) data insufficient
(D) none of these
4. The length of the chord of the parabola x 2 = 4y passing through the vertex and having slope
cot is
(A) 4 cos . cosec2 (B) 4 tan sec
(C) 4 sin. sec2 (D) none of these
Space for rough work
5. If the focus of a parabola is (1, 2) and feet of perpendicular on any two tangents to the parabola
from focus are (3, 4) and (4, 6), then vertex of the parabola is
8 9 7 9
(A)  , (B)  ,
5 5  5 5 
9 8 9 7
(C)  , (D)  ,
5 5  5 5 
6. If the line y - 3 x + 3 = 0 cuts the parabola y2 = x + 2 at A and B, then PA. PB is equal to (where
P  ( 3 , 0))
(A)

4 32  (B)

42 3 
3 3
(C)
4 3
(D)

2 3 2 
2 3
SECTION – 2: (Multi Correct Choice Type)
out of which ONE OR MORE may be correct.
7. If two distinct chords of a parabola y2 = 4ax, passing through (a, 2a) are bisected on the line
x + y =1, then length of the latus-rectum can be
(A) 2 (B) 1
(C) 4 (D) 5
8. A circle of radius r, r  0 touches the parabola y2 + 12x = 0 at the vertex of the parabola. The
centre of the circle lies to the left of the vertex and the circle lies entirely within the parabola. Then
the interval(s) in which r lies can be
(A) (1, 7) (B) (0, 6)
 13 
(C)  1,  (D) (2, 8)
 2 
9. The directrix of a parabola is 2x  y  1 . The focus lies on y -axis. The locus of one end of the
latus rectum is
(A) 7x  y  1  0 (B) 2x  y  1  0
(C) 2x  y  1  0 (D) 3x  y  1  0
2
10. Consider the parabola y = 4x. Let P and Q be two points (4, – 4) and (9, 6) on the parabola. Let
R be a moving point on the arc of the parabola between P and Q. If the maximum area of triangle
RPQ is S then (4S)1/3 equals _____________
2 4
11. If parabola with focus  ,  touches x and y axis at A and B respectively, then area of OAB
5 5
is, where O is origin ____________
12. A parabola which have directrix x + y + 2 = 0 and touches a line 2x + y – 5 = 0 at (2, 1). If m is the
m
latus rectum of the parabola, then the value of is ____________
2

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(Batches: e-SANKALP-2325 S1, T1 & P1)

IIT – JEE, 2325 Paper Code

B. Question Paper Format

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

3. A block of mass m1 = 3 kg is connected with ideal u = 4 m/s

Space for Rough work

4. A semi-cylindrical wedge A of mass M and radius R is B

5. An undeformed spring of spring constant k is connected to a bead of

6. Three blocks A, B and C whose masses are m, km and 4m m km 4m

Space for Rough work

SECTION – 2 : (One or More Than One Options Correct Type)

7. Two balls A and B of masses m and 2m respectively

Space for Rough work

SECTION – 3: (Numerical Answer Type)

11. A small ball of mass 100 g is attached to a light and 30 cm

Space for Rough work

(ii) I +HOCl 

Rate of consumption of I for the given equation would be

K 3K1 [OCl- ][I- ] K1K 2 [OCl- ][I- ]

K1K3 [OCl- ][I- ] K 2K 3 [OCl- ][I- ]

Space for Rough work

5. A closed rigid container contains a gas ‘A’(g) at 16 atm and decomposes as :

Assume the temperature remains constant.

Space for Rough work

SECTION – 2 : (One or More Than One Options Correct Type)

7. 2X(g) + Y(g) + 3Z(g)  Products

8. For the reaction A + B  P; experimental observations are given as follows:

Space for Rough work

SECTION – 3: (Numerical Answer Type)

11. For a radioactive decay reaction : 

Space for Rough work

PART III : MATHEMATICS

Space for rough work

SECTION – 2: (Multi Correct Choice Type)

Space for rough work

SECTION – 3: (Numerical Answer Type)

Space for rough work

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