JEE (Main + Advanced) 2021

GUIDED REVISION JEE (Main +ENTHUSIAST

Advanced) 2021
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ENTHUSE
ENTHUSIAST ALL
COURSE
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ORGANIC CHEMISTRY GR # 05 SCORE-1

SOT TYPE
This section contains 12 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 4(–1)

H
H Y
1. Newmann projection representation of CH3–CH2–CH–Et about C2 – C3 is
CH3 X H
Me

Then X & Y are respectively :

(A) Me, Et (B) H, Et (C) Et, H (D) Et, Me
2. Which of the following represent correct stability order of

(I) (II) (III) (IV)

(A) II > I > IV > III (B) II > III > IV > I (C) II > IV > III > I (D) II > IV > I > III
3. Which compound predominantly exist in its enol form -

O O O O O O O
(A) O (B) (C) (D)
O O O

4. Total number of possible cyclic isomer of molecular formula C5H10 is

(A) 7 (B) 6 (C) 5 (D) 4
5. 4 gm of (+)-2-chlorobutane is mixed with 6 gm of (–)2 chlorobutane . What will be the optical purity of
the obtained mixture.
(A) 10% (B) 20% (C) 30% (D) 40%
6. Identify compounds having ‘D’ configuration ?

O
O
H CH2OH C–H
H–C HO H
(A) (B) HO
HO
H (C) (D) All of these
H HOCH2 H
HOH2C OH
C–H OH
O

E-1/3 ORGANIC CHEMISTRY / GR # 05

 JEE (Main + Advanced) 2021
GUIDED REVISION ENTHUSIAST COURSE
ENTHUSE ALL

7. Identify meso compound -

Cl
Me Me
COOH
(A) HOOC (B)
Cl

CH3
Br
COOH
(C) HOOC (D)
Cl Br

8. Select the pair in which first member show geometrical isomerism but not second member-

(A) & (B) &

(II)
(I)

(C) (D) &

9. The resolvable compound among following

Cl
.. Me H H
(A) (B) H–N (C) (D) Cl Cl
Et
Cl Cl

10. Which of the following is most stable conformation of n-butane about (C2-C3) bond-

Me H Me Me
H Me H
H H H
(A) (B) (C) (D)
H Me H H
H H MeH
Me
H HH H
Me

11. Identify total number of possible ether for molecular formula C4H10O [Excluding Stereo Isomers].

(A) 4 (B) 3 (C) 5 (D) 6

12. How many stereoisomers are possible for the following molecule ?

(A) 1 (B) 2 (C) 3 (D) 4

E-2/3 ORGANIC CHEMISTRY / GR # 05

 JEE (Main + Advanced) 2021
GUIDED REVISION ENTHUSIAST COURSE
ENTHUSE ALL

INTEGER TYPE
This section contains 3 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 4(–1)
1. How many compounds from the following are optically active.

CHO
H H Cl Cl
H OH
(a) C=C=C (b) (c) (d) H OH
Me Me Cl Cl H OH
CH2–OH

H
F H F
(e) (f) (g) (h) Me
H Cl Me Cl
Me
2. How many structural isomers & stereo isomers are possible with given following molecular formula

(Total Aldehyde)
(i) C5H10O (ii) C4H8 (iii) C3H6O (Total Alcohol)
(Total Ketone)

Open chain
(iv) C4H 11N (v) C5H10 (vi) C5H8O2 (Total carboxylic acid)
Close chain
3. Number of geometrical isomers of X = b.
Number of structural isomers formed when same compound X undergo monochlorination = a
Find out a + b.

(X)

E-3/3 ORGANIC CHEMISTRY / GR # 05