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About
1. Comdek Common Entrance Test
a. Introduction
b. Exam Dates
c. Exam Pattern
d. Syllabus
2. Preparation Study Material
3. Mock Tests
a. Mock Test 1
b. Mock Test 2
c. Mock Test 3
d. Mock Test 4
e. Mock Test 5
About
Welcome to the definitive resource for mastering the Consortium of Medical, Engineering, and
Dental Colleges of Karnataka (COMEDK) in 2024. Crafted with precision and expertise, this
ebook is your companion on the journey to success in one of Karnataka's most esteemed
entrance examinations.
COMEDK serves as the gateway to prestigious undergraduate programs in various disciplines
across the Karnataka state. As the landscape of education continually evolves, staying ahead
with thorough preparation and strategic insights becomes indispensable. This guide is
meticulously curated to equip aspiring candidates like you with the tools, knowledge, and
confidence needed to excel in COMEDK 2024.
● Introduction: Gain a thorough understanding of COMEDK, its significance, and its role
in shaping your academic journey.
● Exam Dates: Stay updated with crucial dates and deadlines to ensure you're on track
with your preparation schedule.
● Exam Pattern: Familiarize yourself with the structure, format, and marking scheme of
COMEDK 2024 to formulate an effective exam strategy.
● Syllabus: Delve into the detailed syllabus, ensuring you cover all the essential topics
and domains as prescribed for COMEDK 2024.
Warm regards,
Team Careers360
Comdek Common Entrance Test
Introduction
COMEDK, the Consortium of Medical, Engineering, and Dental Colleges of Karnataka, annually
conducts a computer-based entrance examination for admission to undergraduate courses in
engineering, medical, and dental colleges across Karnataka. The exam assesses candidates'
knowledge based on the syllabus of their 10+2 or equivalent examinations. Eligibility for the
COMEDK exam requires candidates to meet specified academic qualifications. Following
qualification, candidates attend mandatory counseling sessions where seats in colleges are
allotted based on merit and preferences. Final seat allotment is determined by both merit and
the choices made by candidates during counseling sessions.
Exam Dates
Exam Pattern
Syllabus
Physics
Chemistry
Physics
Q. 1 In a Young’s double slit experiment with light of wavelength the separation of slits is d and
distance of screen is D such that D > > d > > . If the Fringe width is , the distance from
point of maximum intensity to the point where intensity falls to half of maximum intensity
on either side is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Malus Law -
- wherein
Fringe Width -
- wherein
Distance of
Maxima
Distance of
maxima
Here
so
(i)
(ii)
Correct option is 2.
Q. 2 Using monochromatic light of wavelength , an experimentalist sets up the Young’s double
slit experiment in three ways as shown.
Option 1:
520 nm
Option 2:
540 nm
Option 3:
560 nm
Option 4:
580 nm
Correct Answer:
540 nm
Solution:
Given
Now
Correct option is 2.
Q. 3 A ray of light is incident from a denser to a rarer medium. The critical angle for total internal
reflection is and the Brewster’s angle of incidence is , such that
. The relative refractive index of the two media is :
Option 1:
0.2
Option 2:
0.4
Option 3:
0.8
Option 4:
0.9
Correct Answer:
0.8
Solution:
or
Q. 4 An object is at a distance of 10 cm from a mirror and the image of the object is at a distance
of 30 cm from the mirror on the same side as the object. Then nature of the mirror and its
focal length is:
Option 1:
Convex, 15cm
Option 2:
Concave, 1.5cm
Option 3:
Convex, 7.5cm
Option 4:
Concave, 7.5cm
Correct Answer:
Concave, 7.5cm
Solution:
As we learn
Sign Convention -
3) Distance measured in the direction opposite to that of incident rays are taken as negative.
4) Distance above the principal axis as positive and below the principal axis as negative.
u = -10 cm
f = -7.5 cm
Option 1:
300
Option 2:
450
Option 3:
750
Option 4:
600
Correct Answer:
600
Solution:
At point A:
from symmetry
Q. 6 A right angled prism of apex angle 40 and r. i. 1.5 is located in front of vertical plane mirror
as shown in fig.A horizontal ray of light is falling on the prism. Find the total deviation
produced in the light ray at it emerges second time from the prism:
Option 1:
80 cw
Option 2:
60 cw
Option 3:
1800 cw
Option 4:
1760 cw
Correct Answer:
1760 cw
Solution:
As we learn
Q. 7 The focal length of the objective and the eyepiece of compound microscope are 2cm and 3cm
respectively. The distance between the objective and eyepiece is 15 cm. The final image formed by
eyepiece is at infinity the distance (in cm) of the object and image produced by the objective,
measured from the objective lens are respectively.
Option 1:
2.4 and 12
Option 2:
2.4 and 15
Option 3:
2.3 and 3
Option 4:
2.3 and 12
Correct Answer:
2.4 and 12
Solution:
As we learnt
= 2 cm = 3cm
l = 15cm
Final image formed at infinity hence image formed by objective is at focal point of eyepiece
For objective:
or
or,
Q. 8 Planck's constant (h), speed of light in vacuum (c) and Newton's gravitational constant (G) are
three fundamental constants. Which of the following combinations of these has the
dimension of length?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Use the method of dimensional analysis between the quantities can be derived
Let Length
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
on comparing both sides we get
Q. 10 If the magnitude of sum of two vectors is equal to the magnitude of difference of the two
vectors, the angle between these vectors is:
Option 1:
0o
Option 2:
90o
Option 3:
45o
Option 4:
180o
Correct Answer:
90o
Solution:
As we learnt in
If two vector are represented by both magnitude and direction by two adjacent side of parallelogram taken from
same point then their resultant is also represented by both magnitude and direction taken from same point but by
diagonal of parallelogram.
- wherein
Represents law of parallelogram vector Addition
Q. 11 The horizontal range and the maximum height of a projectile are equal. The angle of
projection of the projectiles is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Horizontal Range -
Horizontal distance travelled by projectile from the point of projectile to the point on ground where its hits.
- wherein
R=H
Correct option is 2.
Option 1:
Velocity and acceleration both are perpendicular to .
Option 2:
Velocity and acceleration both are parallel to .
Option 3:
Velocity is perpendicular to and acceleration is directed towards the origin.
Option 4:
Velocity is perpendicular to and acceleration is directed away from the origin.
Correct Answer:
Velocity is perpendicular to and acceleration is directed towards the origin.
Solution:
As we learnt in
Vector or cross product of two vector & written as is a single vector whose magnitude is equal to
product of magnitude of & and the sine of smaller angle between them.
- wherein
and
So, velocity is to r and is directed towards the origin.
Correct option is 3.
Q. 13 A projectile is fired from the surface of the earth with a velocity of 5ms-1 and angle with
the horizontal. Another projectile fired from another planet with a velocity of 3 ms-1 at the
same angle follows a trajectory which is identical with the trajectory of the projectile fired
from the earth. The value of the acceleration due to gravity on the planet is (in ms-2) is:
(given g = 9.8 ms-2)
Option 1:
3.5
Option 2:
5.9
Option 3:
16.3
Option 4:
110.8
Correct Answer:
3.5
Solution:
As we learnt in
Horizontal Range -
Horizontal distance travelled by projectile from the point of projectile to the point on ground where its hits.
- wherein
(P plant, e earth)
Correct option is 1.
Option 1:
A charge moving at constant velocity
Option 2:
A stationary charge
Option 3:
A chargeless particle
Option 4:
An accelerating charge
Correct Answer:
An accelerating charge
Solution:
As we learnt in
q = Charge
= Acceleration of particle
- wherein
The accelerated charge particle produce EM wave. P is total radiant flux emitted by charge at any instant.
Q. 15 The transition from the state n = 3 to n = 1 in a hydrogen like atom results in ultraviolet
radiation. Infrared radiation will be obtained in the transition from:
Option 1:
3 2
Option 2:
4 2
Option 3:
4 3
Option 4:
2 1
Correct Answer:
4 3
Solution:
As we learnt in
Infrared Waves -
Frequency Range Hz to Hz
- wherein
Energy diffference for infrared radiation will be smaller than those ultraviolet region.
Q. 16 In an electromagnetic wave in free space the root mean square value of the electric field is
. The peak value of the magnetic field is:-
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Erms=6 V/m
peak value
Q. 17 From a sphere of mass M and radius R, a smaller sphere of radius is carved out such that
the cavity made in the original sphere is between its centre and the periphery. (See figure).
For the configuration in the figure where the distance between the centre of the original
sphere and the removed sphere is 3R, the gravitational force between the two spheres is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we discussed in
Gravitalional constant
Masses
- wherein
Vremoved =
Vremain =
Therefore the mass of removed sphere and remaining sphere are at respectively and
Q. 18 When 1019 electrons are removed from a neutral metal plate, the electric charge on it is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we Learned
Q. 19 When a body is earth connected, electrons from the earth flow into the body. This means the body is
Option 1:
Unchanged
Option 2:
Charged positively
Option 3:
Charged negatively
Option 4:
An insulator
Correct Answer:
Charged positively
Solution:
When a positively charged body is connected to the earth, electrons flow from earth to body and the body becomes
neutral.
Q. 20 Two copper balls, each weighing 10g are kept in air 10 cm apart. If one electron from every 106
atoms is transferred from one ball to the other, the coulomb force between them is (atomic weight of
copper is 63.5)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learned
Properties of Charge -
Transferable
- wherein
Q. 21 The electric field near a conducting surface having a uniform surface charge density is
given by
Option 1:
Option 2:
and is parallel to the surface
Option 3:
and is normal to the surface
Option 4:
and is normal to the surface
Correct Answer:
and is normal to the surface
Solution:
As we learned
- wherein
Electric field near the conductor surface is given by and it is perpendicular to surface.
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 23 A cylindrical piston of mass M slides smoothly inside a long cylinder closed at one end,
enclosing a certain mass of gas. The cylinder is kept with its axis horizontal. If the position is
disturbed from its equilibrium position, its oscillates simple harmonically. The period of the
oscillation will be
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Let the piston be displaced through distance towards left, then volume decreases, pressure increases.
If is increase in pressure and is decrease in volume, then considering the process to take place
gradually (i.e. isothermal)
This excess pressure is responsible for providing the restoring force to the piston of mass .
Hence
Comparing it with
Q. 24 A simple pendulum has a time period T in vacuum. Its time period when it is completely
immersed in a liquid of density one-eight of the density of the material of the bob is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
In vacuum,
Let be the volume and be the density of the mass of the bob.
= weight - upthrust
Q. 25 The charge flowing through a resistance R varies with time t as Q = at - bt2, where a and b
are positive constants. The total heat produced in R is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
5:1
Option 2:
5:4
Option 3:
3:4
Option 4:
3:2
Correct Answer:
3:2
Solution:
Given that,
Length l = 100 cm
The emf when the two cells are connected in series then the balance point is 50 cm.
....(I)
The emf when the two cells are connected in opposite direction then the balance point is 10 cm.
....(II)
Option 1:
cells
Option 2:
potential gradients
Option 3:
a condition of no current flow through the galvanometer
Option 4:
a combination of cells, galvanometer and resistances
Correct Answer:
a condition of no current flow through the galvanometer
Solution:
As we learnt in
Potentiometer -
It is a device used to measure e.m.f of a given cell and to compare e.m.f's of cells
- wherein
Because the method involves a condition of no current flow through the galvanometer the device can be
used to measure P.D internal resistance of a cell and compare emf's of two sources.
Q. 28 The resistance of a wire is 'R' ohm. If it is melted and stretched to 'n' times its original length,
its new resistance will be :
Option 1:
nR
Option 2:
Option 3:
n2 R
Option 4:
Correct Answer:
n2 R
Solution:
As we learnt in
Resistance formula -
- wherein
resistivity of material
Option 1:
-3 V
Option 2:
+3 V
Option 3:
+6 V
Option 4:
+9 V
Correct Answer:
+9 V
Solution:
As we learnt in
Potential difference -
The voltage accross the terminals of a cell when it is supplying current to external resistance is known as
Potential Difference .
- wherein
=2 2+3+1 2=9V
Q. 30 A filament bulb (500 W, 100 V) is to be used in a 230 V main supply. When a resistance R is
connected in series, it works perfectly and the bulb consumes 500 W. The value of R
Option 1:
230
Option 2:
46
Option 3:
26
Option 4:
13
Correct Answer:
26
Solution:
Q. 31 A cell having an emf and internal resistance r is connected across a variable external
resistance R. As the resistance R is increased, the plot of potential difference V across R is
given by:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
When,
Q. 32 If N0 is the original mass of the substance of halflife period =5 years, then the amount
of substance left after 15 years is
Option 1:
N0/8
Option 2:
N0/16
Option 3:
N0/2
Option 4:
N0/4
Correct Answer:
N0/8
Solution:
As we learnt in
or
Now,
No is the initial amount of substance and N is the amount left after decay.
So,
given that the repulsive potential energy between the two nuclei is
the temperature at which the gases must be heated to initiate the
reaction is nearly
[ Boltzmann's constant
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Nuclear fission -
e.g.
- wherein
In nuclear fission neutron trigger the reaction & in the process more than one neutron is released.
Correct option is 4.
Q. 34 The diagram shows the energy levels for an electron in a certain atom. Which transition
shown represents the emission of a photon with the most energy?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Correct option is 3.
Option 1:
Hydrogen atom
Option 2:
singly ionised helium atom
Option 3:
Deuteron atom
Option 4:
singly ionised neon atom
Correct Answer:
singly ionised neon atom
Solution:
Bohr's theory is applicable to hydrogen-like atoms (single electron system).
Q. 36 A nucleus disintegrates into two nuclear parts which have their velocities in the ratio 2:1 The
ratio of their nuclear sizes will be
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
m1 v1 = m 2 v2
Q. 37 Photoelectric emission occurs only when the incident light has more than a certain
minimum:
Option 1:
frequency
Option 2:
power
Option 3:
wavelength
Option 4:
intensity
Correct Answer:
frequency
Solution:
Q. 38 Electron used in an electron microscope are accelerated by a voltage of 25 kV. If the voltage
is increased to 100 kV then the de-Broglie wavelength associated with the electrons would
Option 1:
increase by 2 times
Option 2:
decrease by 2 times
Option 3:
increase by 4 times
Option 4:
increase by 4 times
Correct Answer:
decrease by 2 times
Solution:
As we learnt in
- wherein
Q. 39 Two Carnot engines A and B are operated in series. Engine A receives heat from a reservoir
at 600 K and rejects heat to a reservoir at temperature T. Engine B receives heat rejected by
engine A and in turn rejects it to a reservoir at 100 K. If the efficiencies of the two engines A
and B are represented by ηA and ηB, respectively,then what is the value of ? (Work
output is same for both)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt
are in kelvin
- wherein
Source temperature
Sink Temperature
from eqn1:
Q. 40 A gas is compressed is isothermally to half its initial volume. The same gas is compressed
separately through and adiabatic process until its volume is again reduced to half. Then:
Option 1:
Compressing the gas isothermally will require more work to be done.
Option 2:
Compressing the gas through adiabatic process will require more work to be done.
Option 3:
Compressing the gas isothermally or adiabatically will require the same amount of work.
Option 4:
Which of the case (wheather compression through isothermal or through adiabatic process) requires
more work will depend upon the atomicty of the gas.
Correct Answer:
Compressing the gas through adiabatic process will require more work to be done.
Solution:
As we learnt in
- wherein
ia Isothermal process
ib Adibatic process
Q. 41
Two hypothetical planets of masses m1 and m2 are at rest when they are infinite distance
apart. Because of the gravitational force they move towards each other along the line joining
their centres. What is their speed when their separation is ‘d’ ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Initial energy of the system = 0
Final energy =
Q. 42 ‘n’ moles of an ideal gas undergoes a process A→B as shown in the figure. The maximum
temperature of the gas during the process will be :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
At any point between A & B, we can write relation between P & V by using the equation of the straight line
From ideal gas equation
PV = nRT
Q. 43 The molar specific heats of an ideal gas at constant pressure and volume are denoted by Cp
and Cv, respectively. If
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Correct Answer: 80
Solution:
Specific Heat -
- wherein
C = specific heat
Change in temperature
m = Amount of mass
For (I)
now for (II)
Q. 45 Two identical beakers A and B contain equal volumes of two different liquids at each
and left to cool down. Liquid in A has density of and specific heat of
while liquid in B has density of and specific heat of
which of the following best describes their temperature versus time
graph schematically ?(assume the emissivity of both the beakers to be the same)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
- wherein
From given
and
at
and we know
Q. 46 A magnetic needle of magnetic moment 6.7×10−2 Am2 and moment of inertia 7.5×10−6 kg m2
is performing simple harmonic oscillations in a magnetic field of 0.01 T. Time taken ( in
seconds) for 10 complete oscillations is :
Correct Answer:
6.65
Solution:
As we learned in
Using
we get T = 0.665 s
Option 1:
IBR
Option 2:
Option 3:
Option 4:
Correct Answer:
IBR
Solution:
As we learned in
Option 1:
3 x 10-4 N toward right
Option 2:
6 x 10-4 N toward left
Option 3:
9 x 10-4 N toward left
Option 4:
Zero
Correct Answer:
3 x 10-4 N toward right
Solution:
towards left
Net force =
Q. 49 The V-I characteristic of a diode is shown in the figure. The ratio of forward to reverse bias
resistance is :
Option 1:
10
Option 2:
10−6
Option 3:
106
Option 4:
100
Correct Answer:
10−6
Solution:
.
Forward Resistance
Correct option is 2.
Q. 50 To get an output of 1 from the circuit shown in figure the input must be :
Option 1:
a = 0, b = 1, c = 0
Option 2:
a = 1, b = 0, c = 0
Option 3:
a = 1, b = 0, c = 1
Option 4:
a = 0, b = 0, c = 1
Correct Answer:
a = 1, b = 0, c = 1
Solution:
Option 1:
5 mA, 5 mA, 10 mA
Option 2:
15 mA, 7.5 mA, 7.5 mA
Option 3:
12.5 mA, 5 mA, 7.5 mA
Option 4:
12.5 mA, 7.5 mA, 5 mA
Correct Answer:
12.5 mA, 7.5 mA, 5 mA
Solution:
In the given figure
Voltage across RL= 2K is same as that across zener dioxide i.e 10V
Total applied potential = 60 V
Current through 4K =
Q. 52 A conducting circular loop is placed in a uniform magnetic field 0.04 T with its plane
perpendicular to the magnetic field. The radius of the loop starts shrinking at 2 mm/s. The
induced emf in the loop when the radius is 2 cm is:
Option 1:
4.8 V
Option 2:
0.8 V
Option 3:
1.6 V
Option 4:
3.2 V
Correct Answer:
3.2 V
Solution:
Induced emf in the loop is given by where A is the area of the loop.
So
Q. 53 A condenser of capacity C is charged to a potential difference of V1. The plates of the
condenser are then connected to an ideal inductor of inductance L. The current through the
inductor when the potential difference across the condenser reduces to V2 is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 54 In the given circuit the reading of voltmeter V1 and V2 are 300 volts each. The reading of the
voltmeter V3 and ammeter A are respectively
Option 1:
100 V, 2.0 A
Option 2:
150 V, 2.2 A
Option 3:
220 V, 2.2 A
Option 4:
220 V, 2.0 A
Correct Answer:
220 V, 2.2 A
Solution:
and are equal and out of phase with each other and thus get cancelled.
Thus and
Q. 55 A person trying to lose weight by burning fat lifts a mass of 10 kg upto a height of 1 m 1000
times. Assume that the potential energy lost each time he lowers the mass is dissipated.
How much fat will he use up considering the work done only when the weight is lifted up?
Fat supplies 3.8×107 J of energy per kg which is converted to mechanical energy with a 20%
efficiency rate. Take g = 9.8 ms−2 :
Option 1:
2.45×10−3 kg
Option 2:
6.45×10−3 kg
Option 3:
9.89×10−3 kg
Option 4:
12.89×10−3 kg
Correct Answer:
12.89×10−3 kg
Solution:
As we discussed in
If only conservative forces act on a system, total mechanical energy remains constant -
collide elastically at the origin. After the collision, they move along the indicated directions
with
Option 1:
6.5 m/s and 6.3 m/s
Option 2:
3.2 m/s and 6.3 m/s
Option 3:
6.5 m/s and 3.2 m/s
Option 4:
3.2 m/s and 12.6 m/s
Correct Answer:
6.5 m/s and 6.3 m/s
Solution:
................................(1)
............................................(2)
Q. 57 Two stones are thrown up simultaneously from the edge of a cliff 240 m high with initial
speed of 10 m/s and 40 m/s respectively. Which of the following graph best represents the
time variation of relative position of the second stone with respect to the first? (Assume
stones do not rebound after hitting the ground and neglect air resistance, take g=10 m/s2
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 58
Given in the figure are two blocks A and B of weight 20 N and 100 N, respectively. These are
being pressed against a wall by a force F as shown. If the coefficient of friction between the
blocks is 0.1 and between block B and the wall is 0.15, the frictional force (in N) applied by
the wall on block B is :
Correct Answer:
120
Solution:
Solution :
Q. 59 A uniform disc of radius R and mass M is free to rotate only about its axis. A string is
wrapped over its rim and a body of mass m is tied to the free end of the string as shown in
the figure. The body is released from rest. Then the acceleration of the body is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 60 From a solid sphere of mass M and radius R a cube of maximum possible volume is cut.
Moment of inertia of cube about an axis passing through its center and perpendicular to
one of its faces is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
M.O.I. of the cube about the given axis.
Chemistry
Q. 1 In a 0.2 molal aqueous solution of a weak acid HX, the degree of ionization is 0.3 .Taking
for water as 1.85 K molal-1 , the freezing point of the solution will be nearest to
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Case of dissociation
Option 1:
200 and 300
Option 2:
300 and 400
Option 3:
400 and 600
Option 4:
500 and 600
Correct Answer:
400 and 600
Solution:
(1)
(2)
Option 1:
Sodium chloride
Option 2:
Magnesium chloride
Option 3:
Sodium phosphate
Option 4:
Urea
Correct Answer:
Sodium phosphate
Solution:
Van't Hoff factor for dissociation of strong electrolyte
Na3PO4 gives the maximum ions and hence it shows the highest Van't Hoff factor.
Option 1:
5 x 10-4
Option 2:
5 x 10-3
Option 3:
5 x 103
Option 4:
5 x 102
Correct Answer:
5 x 10-4
Solution:
Specific conductance,
Resistivity,
Resistance, R=
molar conductivity,
Q. 5 The standard reduction potentials for Zn2+/Zn, Ni2+ / Ni and Fe2+ / Fe are –0.76, –0.23 and –
0.44 V respectively.
Option 1:
X = Ni, Y = Fe
Option 2:
X = Ni, Y = Zn
Option 3:
X = Fe, Y = Zn
Option 4:
X = Zn, Y = Ni
Correct Answer:
X = Zn, Y = Ni
Solution:
For a spontaneous reaction, Eo must be positive.
Alternatively, we can also solve this qualitatively. Elements with a low value of SRP are good reducing
agents and therefore, can be easily oxidized. Also, elements with a low negative value of SRP are good
oxidizing agents and can be reduced easily. Keeping the above in mind, we can clearly see that
and the reaction is:
Q. 6 Aluminium oxide may be electrolysed at 1000°C to furnish aluminium metal ( At. Mass = 27
amu,1 Faraday= 96,500 Coulombs ) The cathode reaction is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
0.1 M
Option 2:
0.02 M
Option 3:
0.01 M
Option 4:
0.001 M
Correct Answer:
0.01 M
Solution:
As we learnt in
Vol. = 100 ml
Molarity, M =
Option 1:
X2Cl
Option 2:
X2Cl2
Option 3:
XCl2
Option 4:
XCl4
Correct Answer:
XCl2
Solution:
Moles = Molarity X volume in litre.
No. of moles of AgNO3=M X V = 0.1 X 10 (In ml) = 0.1 X 10 X 10-3 (in L) = 10-3 mol
No. of moles the chloride= 0.05 X 10 X 10-3 (in L)= 0.5 x 10-3 mol.
Suppose the formula for the chloride is XCln then moles of chloride ion = n x 0.5 x 10-3
1 mol of Ag = 1 mol of Cl
Option 1:
Temperature is decreased
Option 2:
Solution concentration is increased
Option 3:
Number of solute molecules is increased
Option 4:
Volume is increased
Correct Answer:
Number of solute molecules is increased
Solution:
As we learned
Osmotic Pressure -
As soon as the solute molecules increases the osmotic pressure of solution increase.
Option 1:
The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is BaCl2 > KCl >
CH3COOH > sucrose.
Option 2:
The osmotic pressure of a solution is given by the equation where M is the molarity
of the solution.
Option 3:
Raoult's law states that the vapour pressure of a component over a solution is proportional to its
mole fraction.
Option 4:
Two sucrose solutions of same molality prepared in different solvents will have the same freezing
point depression.
Correct Answer:
Two sucrose solutions of same molality prepared in different solvents will have the same freezing
point depression.
Solution:
As we have learnt
Freezing -
Freezing occurs when liquid solvent is in equilibrium with solid solvent. As non volatile
solute decreases, the vapour pressure freezing point decreases.
The extent of depression in freezing point varies with the number of solute particles for a fixed solvent
only and it is a characteristics feature of the nature of solvent also. So for two different solvents the
extent of depression may vary even if number of solute particles be dissolved.
Therefore, option(4) is correct
Q. 11 The rise in the boiling point of a solution containing 1.8 gram of glucose in 100 g of a solvent
in 0.10C. The molal elevation constant of the liquid is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
Electrostatic attractions
Option 2:
van der Waals forces
Option 3:
Dipole - Dipole interactions
Option 4:
Hydrogen bonding
Correct Answer:
Hydrogen bonding
Solution:
As learnt in
Q. 13 The dipeptide, Gln-Gly, on treatment with CH3COCl followed by aqueous work up gives :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The structure of the dipeptide Gln-gly is given as
Now, acetylation occurs at the free hydroxy and amino groups. Amides do not undergo acetylation.
A is :
Option 1:
Glucose cyanohydrin
Option 2:
Glucose oxime
Option 3:
Glucosazone
Option 4:
Gluconic acid
Correct Answer:
Glucose cyanohydrin
Solution:
As we have learnt,
Glucose reacts with Hydrogen cyanide and undergoes nucleophilic addition reaction to form its
cyanohydrin.
Option 1:
Decomposition Reaction
Option 2:
Combination Reaction
Option 3:
Displacement Reaction
Option 4:
Disproportionate Reaction
Correct Answer:
Combination Reaction
Solution:
The different types of redox reactions are:
Decomposition Reaction
Combination Reaction
Displacement Reaction
Disproportionation Reactions
Decomposition Reaction
This is the reaction that involves the breakdown of a compound into different compounds. Some
examples of this type of reaction are:
This must be noted here that all decomposition reactions are not redox reactions. For example, the
decomposition of calcium carbonate is not a redox reaction.
Combination Reaction
These types of reactions are the opposite of decomposition reactions and hence involve the combination
of two compounds to form a single compound. Some examples include:
Displacement Reaction
Displacement reactions, also known as replacement reactions, involve compounds and the replacing of
elements. They occur as single and double replacement reactions. In other words, in these types of
reactions, an atom or an ion in a compound is substituted by another element. The general
representation of this reaction is as follows:
Disproportionation Reactions
Disproportionation reactions are those reactions in which a single element in one oxidation state is
simultaneously oxidized and reduced. Some examples include:
-
Therefore,option(2) is correct.
is , then what is x?
Option 1:
0.2
Option 2:
0.01
Option 3:
0.1
Option 4:
0.02
Correct Answer:
0.01
Solution:
As we have learned
M(s) is Solid -
[M] = 1
- wherein
Reaction is
as [Ag]= [Zn] =1
Q. 17 If the conductivity of the cell is ,then find the resistance of the cell. Cell constant
=
Option 1:
3.2
Option 2:
500
Option 3:
0.002
Option 4:
0.3125
Correct Answer:
500
Solution:
We know,
(i)
(ii)
(iii)
(iv)
Out of the following, select the set containing only paramagnetic complexes
Option 1:
(i), (ii)
Option 2:
(ii), (iii)
Option 3:
(i), (iii)
Option 4:
(i), (ii) and (iv)
Correct Answer:
(i), (iii)
Solution:
As we have learnt,
Cyanide ions are strong field ligands and cause pairing of electrons.
The electronic arrangement in the central metal ions in the given complexes with the Strong field ligand is
shown below:
Hence, only complexes (i) and (iii) are paramagnetic as they contain unpaired electrons
Q. 19 In any ferric salt, on adding potassium ferrocyanide, a Prussian blue colour is obtained,
which is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt,
Option 1:
Two types of ions
Option 2:
Only one type of ion
Option 3:
Four types of ions
Option 4:
Three types of ions
Correct Answer:
Three types of ions
Solution:
Potash alum is a mixed salt of and and upon dissolution in water, it gives all the
three ions from which it is made viz.
Correct Answer:
0.5
Solution:
Q. 22 A container at contains at pressure and an excess of
(neglect the volume of solid ). The volume of the containers is now decreased by
moving the movable piston fitted in the container. The maximum volume of the container,
when pressure of attains its maximum value, will be :
(Given that : )
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Before compression,
After Compression
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The equilibrium constant for the reverse reaction is the inverse of the equilibrium constant for the
reaction in the forward direction.
, - - - - - - - -- (1)
.......................(2)
- - - - - - - - - - (3)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Let us calculate the solability of each salt
1 0 0
1-s 2s s
s s
s s
s s
Option 1:
The molar solubilities of in water are indetical.
Option 2:
The molar solubility of in water is less than that of .
Option 3:
The salts and are more soluble in than in pure water.
Option 4:
The addition of the salt of to solution of will have no effect on their solubilities.
Correct Answer:
The molar solubility of in water is less than that of .
Solution:
Also
Q. 26 Apart from +3 oxidation state, other stable oxidation states shared by f-block elements
is/are:
Option 1:
+2 only
Option 2:
+2 and +4
Option 3:
+4 only
Option 4:
none of these
Correct Answer:
+2 and +4
Solution:
As we have learned
– They show variable valency.The +3 is the most important oxidation state.Few elements show +2 and
+4 oxidation states.
-
+2 and +4 oxidation state are also shown by f-block elements.
3) It is diamagnetic
Option 1:
1,2,3,4
Option 2:
1,2,3
Option 3:
2,3
Option 4:
1,2,4
Correct Answer:
1,2,4
Solution:
As we have learned
Transition elements have relatively low ionisation energies and have one or two electrons in their outer
most energy level (ns1 or ns2).As a result, metallic bonds are formed.The unpaired d- electron also result
in the formation of the metallic bond.
Since there are 6 H2O molecules attached as the ligand, thus its coordination number is 6 and its
geometry is octahedral but since it has 1 unpaired electron thus the complex is paramagnetic.
Option 1:
a, b only
Option 2:
a, b and d only
Option 3:
b only
Option 4:
a,b and c only
Correct Answer:
a,b and c only
Solution:
Dihalogen derivatives of hydrocarbons contain two halogen atoms apart from carbon and hydrogen
Here, in
In (c) Hydrogen is replaced from the alkane group, not from the Benzene group, so it is Dihalogen
derivatives of alkane.
Q. 29 Which one of the following orders is correct for the bond dissociation enthalpy of halogen
molecules?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Bond dissociation energies of the halogen family decrease down the group as the size of the atom
increases. The bond dissociation energy of fluorine, is, however, lower than those of chlorine and
bromine because of interelectronic repulsions present in the small atom of fluorine. Thus, bond energy
decreases in the order
Option 1:
Evapouration of water
Option 2:
Expansion of a gas at constant temperature
Option 3:
Sublimation of solid to gas
Option 4:
Correct Answer:
Solution:
Q. 31 U is equal to :
Option 1:
Adiabatic work
Option 2:
Isothermal work
Option 3:
Isochoric work
Option 4:
Isobaric work
Correct Answer:
Adiabatic work
Solution:
Adiabatic Process -
So,
Ans(1)
Option 2:
One bond
Option 3:
Four bonds
Option 4:
Three bonds
Correct Answer:
Four bonds
Solution:
One s and three p orbital undergo sp3 hybridization. Four sp3 hybrid orbitals form four σ bonds with
oxygen atoms. They are σ sp3 – p. Four pπ – dπ bonds are also formed with oxygen atoms by the
unpaired electrons.
Option 1:
BeCl2, XeF2
Option 2:
Tel2, XeF2
Option 3:
Option 4:
IF3, XeF2
Correct Answer:
Solution:
Option 1:
PH3
Option 2:
CIF3
Option 3:
NCl3
Option 4:
BCl3
Correct Answer:
BCl3
Solution:
Hybridisation -
When one s - and two p - orbitals of the same shell of an atom mix to form three new equivalent
orbitals.The hybridised orbital is called sp2 orbital.
- wherein
Option 1:
K
Option 2:
Ni
Option 3:
Al
Option 4:
Ca
Correct Answer:
K
Solution:
As we have learned
K has highest metallic character among the given elements as it has the highest size among the given
elements thus removing the electron from potassium is easiest.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt,
The reaction mechanism involves formation of free radicals and 1o carbon free radicals will react faster
due to lesser steric hinderance followed by 2o and then 3o.
Option 1:
Both ∆H and ∆S are negative.
Option 2:
Both ∆H and ∆S are positive.
Option 3:
∆H is positive while ∆S is negative.
Option 4:
∆H is negative while ∆S is positive.
Correct Answer:
Both ∆H and ∆S are positive.
Solution:
ΔG=ΔH−TΔS
At low temperature,
TΔS < ΔH
ΔG > 0 and the reaction is non-spontaneous.
At high temperature,
TΔS > ΔH
ΔG < 0 and the reaction is spontaneous.
Option 1:
RI >RBr >RCl
Option 2:
RCl>RBr>RI
Option 3:
RBr>RCl>RI
Option 4:
RBr>RI>RBr
Correct Answer:
RI >RBr >RCl
Solution:
The reactivity for nucleophile will be higher for those which can release H+ or R+ as easily as possible.
Thus, the correct order is:
Q. 39 The effect of lanthanoid contraction in the lanthanoid series of the element by and large
means?
Option 1:
Increase in both atomic and ionic radii.
Option 2:
Decrease in atomic radii and increase in ionic radii.
Option 3:
Decrease in both atomic and ionic radii.
Option 4:
Increase in atomic radii and decrease in ionic radii.
Correct Answer:
Decrease in both atomic and ionic radii.
Solution:
As we have learnt,
As a result of the Lanthanoid contraction, both the atomic radii and ionic radii decrease gradually in the
lanthanoid series.
Therefore,option(3) is correct
Option 1:
sp3d2
Option 2:
dsp2
Option 3:
d2sp3
Option 4:
dsp3d
Correct Answer:
d2sp3
Solution:
As we discussed in
Hybridisation -
d2sp3 - octahedral
sp3 - tetradedral
- wherein
dsp2 -
In the formation of this complex, the species which acts as the Lewis acid is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we discussed in
Central atom -
In coordination entity, the atom/ion to which a fixed no of ions/groups are bound in a definite
geometrical arrangement around it.
- wherein
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
is resonance stabilised while is stable due to hyperconjugation, Since resonance is
dominating over hyperconjugation,
Option(2): B is more stable than A as B has more alpha hydrogen(7 to 4) which implies more number of
hyperconjugation structures. This makes B more stable.
Option(3): B is more stable than A as a six-membered ring is more stable than a 3 membered ring due to
the lesser ring strain of the six-membered ring.
Option(4): A is more stable than B due to the possibility of resonance with each of the phenyl groups
attached to C.B doesn't show any resonance.
Therefore, option (4) is correct.
Q. 43 A first-order reaction is 50 % completed in 20 min at 27oC and in 5 min at 47oC. The energy
of activation (in kJ/mol) of reaction is:
Correct Answer:
55.14
Solution:
Given,
Now,
Arrhenius Equation -
= Rate constant
So,
(C) The half-life of the reaction depends on the initial concentration of the reactant.
Option 1:
Only A and B
Option 2:
Only B and C
Option 3:
A, B, and D
Option 4:
A, B, C, and D
Correct Answer:
A, B, and D
Solution:
A) The concentration of reactant which is following first-order kinetics always decreases exponentially
and becomes zero at infinity.
As the temperature increases, the rate constant increases and the half-life decreases since half-life is
inversely dependent on the rate constant.
K increase on increasing T.
C) The half-life of the reaction does not depend on the initial concentration of the reactant.
Option 3 is correct.
Q. 45 The half life of a first order reaction varies with temperature according to
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt for a first order reaction,
Now, ln(c) = b and Ea/R = a
So,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Reaction:
Given,
Question [B]=?
So, Net rate of formation of
Correct Option is 4.
Q. 47 The electron in the hydrogen atom undergoes a transition from higher orbitals to the
orbital of radius 211.6 pm. This transition is associated with :
Option 1:
Lyman series
Option 2:
Balmer series
Option 3:
Paschen series
Option 4:
Brackett series
Correct Answer:
Balmer series
Solution:
As we have learned,
Hence, the option number (2) is correct.
Q. 48 With respect to the conformers of ethane, which of the following statements is true?
Option 1:
Bond angle remains same but bond length changes
Option 2:
Bond angle changes but bond length remains same
Option 3:
Both bond angle and bond length change
Option 4:
Both bond angles and bond length remains same
Correct Answer:
Both bond angles and bond length remains same
Solution:
= Both bond angles ad bond length remains same
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
No. of electrons in
No. of electrons in
Q. 50 The most suitable method of separation of 1:1 mixture of ortho and para-nitrophenols is :
Option 1:
Sublimation
Option 2:
Chromatography
Option 3:
Crystallisation
Option 4:
Steam distillation
Correct Answer:
Steam distillation
Solution:
The 1:1 mixture of ortho and para nitrophenols is separated by steam distillation
is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
c>a>b
Option 2:
b > a> c
Option 3:
a>b>c
Option 4:
a>c>b
Correct Answer:
a>b>c
Solution:
All the given bases are aromatic amines having their lone pairs in conjugation with the Benzene ring.
Among the given bases, " a" is most basic because of methyl at the para position and "c" is least basic
because it shares lone pair with both phenyl rings.
Therefore, the correct order of basic strength of the given aromatic amines follow the order:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt,
Peptide bond is an amide linkage formed between two amino acids which is formed by condensation
reaction.
The bond formed between two amino acids by the elimination of a water molecules is called peptide
linkage or bond
Q. 54 6.02 x 1020 molecules of urea are present in 100 mL of its solution. The concentration of the
solution is:
Option 1:
0.01 M
Option 2:
0.001 M
Option 3:
0.1 M
Option 4:
0.02 M
Correct Answer:
0.01 M
Solution:
As we learnt in
Molarity is defined as the number of moles of the solute in 1 litre of the solution.
No. of moles
Volume of solution = 100 ml = 0.1 L
Therefore,
Q. 55 When 22.4 litres of H2(g) is mixed with 11.2 litres of Cl2(g), each at S.T.P, the moles of HCl(g)
formed is equal to:
Option 1:
1 mol of HCl (g)
Option 2:
2 mol of HCl (g)
Option 3:
0.5 mol of HCl (g)
Option 4:
1.5 mol of HCl (g)
Correct Answer:
1 mol of HCl (g)
Solution:
As we learnt in
The reactant which gets consumed and thus limits the amount of product formed is called the limiting
reagent.
Q. 56 1.0 g of magnesium is burnt with 0.56 g O2 in a closed vessel. Which reactant is left in excess
and how much?
Option 1:
Mg, 0.16 g
Option 2:
O2 , 0.16 g
Option 3:
Mg, 0.44 g
Option 4:
O2, 0.28 g
Correct Answer:
Mg, 0.16 g
Solution:
The reaction is as follows:
moles of
moles of
= 0.00667 X 24
= 0.16 g
Option 1:
0.177
Option 2:
1.770
Option 3:
0.0354
Option 4:
0.0177
Correct Answer:
0.0177
Solution:
As we learnt in
Given,
Option 1:
Amongst isoelectronic species, smaller the positive charge on the cation, smaller is the ionic radius.
Option 2:
Amongst isoelectronic species, greater the negative charge on the anion, larger is the ionic radius.
Option 3:
Atomic radius of the elements increases as one moves down the first group of the periodic table.
Option 4:
Atomic radius of the elements decreases as one moves across from left to right in the 2nd period of
the periodic table.
Correct Answer:
Amongst isoelectronic species, smaller the positive charge on the cation, smaller is the ionic radius.
Solution:
The Atomic radius of the elements decreases across a period from left to right due to an increase in
effective nuclear charge. On moving down a group, since, the number of shells increases, so atomic
radius increases. Amongst isoelectronic species, the ionic radius increases with increases in negative
charge or decrease in positive charge.
the compound D is
Option 1:
propanal
Option 2:
butanal
Option 3:
-butyl alcohol
Option 4:
-propyl alcohol.
Correct Answer:
-propyl alcohol.
Solution:
As we learnt in
Reagents used
- wherein
The reaction of Haloalkanes with Mg in the presence of ether - Grignard reagent is obtained
- wherein
Hence, the option number (4) is correct.
Q. 60 Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated
nitric acid, gives:
Option 1:
nitrobenzene
Option 2:
2, 4, 6-trinitrobenzene
Option 3:
2,4,6- trinitrophenol
Option 4:
p-nitrophenol
Correct Answer:
2,4,6- trinitrophenol
Solution:
Direct nitration of phenol is difficult as it gets oxidised by the nitrating mixture
. However, picric acid is formed as a minor product in the reaction.
To get a better yield of Picric acid, it is prepared by treating phenol first with concentrated sulphuric acid
which converts it to phenol-2,4-disulphonic acid, and then with concentrated nitric acid to get 2,4,6-
trinitrophenol.
Therefore, option (3) is correct.
Maths
Q. 1 Let be the number of all possible triangles formed by joining vertices of an n-sided
regular polygon. If then the value of n is
Option 1:
8
Option 2:
7
Option 3:
5
Option 4:
10
Correct Answer:
5
Solution:
As we have learnt,
If there are n points in the plane and out of which no three are collinear then, total no. of triangles that
can be formed using these n points = nC3
Now,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Limit is of 0/0 form. We can rationalize the irrational powers
Q. 3
The integral is equal to (where C is a
constant of integration)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learned in
-
Q. 4 If the equations have a common root,
then a : b : c is :
Option 1:
3:1:2
Option 2:
1:2:3
Option 3:
3:2:1
Option 4:
1:3:2
Correct Answer:
1:2:3
Solution:
For
Now case 1: If the first root is common between the equations, then p+iq is a root of second equation.
Now as coefficients of second equation are real, so its other root must be p-iq. So, both roots are
common in these 2 equations
Case 2: If the second root is common between the equations, then p-iq is a root of second equation. Now
as coefficients of second equation are real, so its other root must be p + iq. So, both roots are common in
these 2 equations in this case as well
Q. 5 If a point P has co-ordinates (0, -2) and Q is any point on the circle, x2 + y2 - 4x - 2y + 4 = 0,
then the maximum value of PQ is :
Option 1:
Option 2:
Option 3:
Option 4:
None of these
Correct Answer:
Solution:
As we learnt in
Now,
Centre C (2, 1)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Let
Put
So that,
Q. 7 The number of real values of λ for which the system of linear equations
2x+4y−λz=0
4x+λy+2z=0
λx+2y+2z=0
Solution:
As we learnt in
When and ,
- wherein
and
Option 2:
224 y2
Option 3:
225 y2
Option 4:
225 y
Correct Answer:
225 y
Solution:
As we learnt in
Differential Equations -
An equation involving independent variable (x), dependent variable (y) and derivative of
dependent variable with respect to independent variable
- wherein
So that
Q. 9
The integral equals :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
is:
Option 1:
increasing in R.
Option 2:
decreasing in R.
Option 3:
decreasing in (0, ∞) and increasing in (−∞, 0).
Option 4:
increasing in (0, ∞) and decreasing in (−∞, 0).
Correct Answer:
increasing in R.
Solution:
3. If f”(a) = a
If f’’’(a) ≠ 0, then f(x) has neither maximum nor minimum (inflection point) at x = a.
If f iv(a) < 0, then f(x) is maximum at x = a and if f iv(a) > 0 then f(x) is minimum at x = a and so on.
SUMMARY
-
So,
for
Correct option is 1.
where N is the set of natural numbers and denotes the greatest integer less than or
equal to , is :
Option 1:
one-one and onto.
Option 2:
one-one but not onto.
Option 3:
onto but not one-one.
Option 4:
neither one-one nor onto.
Correct Answer:
neither one-one nor onto.
Solution:
Taking x in an interval of five natural numbers, we have the following:
Therefore, here, x ∈N. hence, f(x) is neither a one-one function nor onto function.
Q. 12 If the arithmetic mean of two numbers a and b, a > b > 0, is five times their geometric mean,
then is equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learned in
and
In this Question,
If
We know,
Therefore:
Q. 13 An aeroplane flying at a constant speed, parallel to the horizontal ground, km above it, is
observed at an elevation of from a point on the ground. If, after five seconds, its
elevation from the same point, is , then the speed (in m/s) of the aeroplane, is :
Option 1:
Option 2:
400
Option 3:
Option 4:
Correct Answer:
400
Solution:
Angle of Elevation -
If an object is above the horizontal line from the eye, we have to raise our head to view the object.
- wherein
Q. 14 The area (in sq. units) of the parallelogram whose diagonals are along the vectors
Option 1:
26
Option 2:
65
Option 3:
20
Option 4:
52
Correct Answer:
65
Solution:
Area of Parallelogram
If and , are two non-zero, non-parallel vectors represented by AD and AB respectively and let Ө be
the angle between them.
NOTE:
As we learnt in
If and are two vectors and is the angle between them , then
- wherein
is unit vector perpendicular to both
and
- wherein
Area of parallelogram =
magnitude
Q. 15 The number of ways in which the examiner can assign 30 marks to 8 questions, giving not
less than 2 marks to any questions, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Hence,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
is given a polynomial function
becomes degree
becomes degree
Assume
we get
and
c=0
Similarly d=0
Hence
and
Option 2 is correct
Q. 17 The area (in sq. units) of the region common between the curves, x2 + y2 = 4 and y2 = 3x, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Finding point of intersection first
x2 + 3x - 4 = 0
x2 + 4x - x - 4 =0
x=1
and
Using symmetry,
Q. 18 The real number k for which the equation, has two distinct real roots in
[0,1].
Option 1:
does not exist.
Option 2:
lies between 1 and 2 .
Option 3:
lies between 2 and 3 .
Option 4:
lies between -1 and 0 .
Correct Answer:
does not exist.
Solution:
As we have learned
&
- wherein
Option 1:
an ellipse with eccentricity
Option 2:
an ellipse with the length of major axis 6
Option 3:
a hyperbola with eccentricity
Option 4:
a hyperbola with the length of conjugate axis 3
Correct Answer:
a hyperbola with the length of conjugate axis 3
Solution:
As we learnt in
Locus -
- wherein
Conjugate axis -
- wherein
On solving, from second equation
Here a=3, b=
Q. 20 if
Option 1:
7
Option 2:
8
Option 3:
Option 4:
Correct Answer:
7
Solution:
Q. 21 Let A be any 3×3 invertible matrix. Then which one of the following is not always true ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Inverse of a matrix -
Option 1:
Put n = 3
Option 3: and 4
so option 4 is not always true
Q. 22 The curve satisfying the differential equation, y dx − (x + 3y2) dy = 0 and passing through the
point (1, 1), also passes through the point:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
and
Q. 23
If and then the ordered
pair (A, B) is equal to : (where C is a constant of integration)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Rule of integration by Partial fraction -
Let
Find ...
By comparing and
meets x-axis at A and y-axis at B. If AP : BP=1 : 3 and (1)=1, then the curve also passes
through the point :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt in
Selection formula -
- wherein
A slope of a line -
- wherein
We have,
Now, Slope m=
Also, slope =
So,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Using
Then,
Correct Answer:
15
Solution:
As we learnt in
Sum of n terms of an AP -
or
In this Question,
(Negative value of n is rejected)
Q. 27
The expression can be written as:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 28 If the vector is written as the sum of a vector , parallel to , and
a vector perpendicular to
then is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
Collinear Vectors -
Two vectors are said to be collinear if and only if there exists a scalar m such as that
- wherein
m is a Scalar.
- wherein
Provided that
Vector Product of two vectors -
- wherein
So
Q. 29 On the sides AB,BC,CA, of 3,4,5 distibct points (excuding vertices A,B,C) are
respectively chosen. the number of trangles that can be constructed using these chosen
points as vertices are:
Option 1:
210
Option 2:
205
Option 3:
215
Option 4:
220
Correct Answer:
205
Solution:
Case 1:
Case 2:
Case 3:
Case 4:
Case 6:
Second Approach
Q. 30
equals:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Put
Q. 31
,then k is equal to:
Option 1:
1
Option 2:
2
Option 3:
3
Option 4:
4
Correct Answer:
1
Solution:
As learnt in concept
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
Since all variables must be converted into single variable ,
put t = x-1
Q. 32
If z is a complex number of unit modulus and argument ,then arg equals:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Arg (z)=
So,
Thus, arg
Q. 33 If two parallel chords of a circle, having diameter 4 units, lie on the opposite sides of the
centre and subtend angles at the center respectively, then the
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Circle -
A circle is the locus of a moving point such that its distance from a fixed point is constant.
- wherein
Q. 34
If for , the derivative of
is then equals :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
If
then,
Let,
................ ( 1 )
Now,
................... ( 2 )
From ( 1 ) and ( 2 )
On comparison,
Q. 35
If
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Now,
Now Put
similarly for
Q. 36 if and
then is equal to :
Correct Answer:
-24
Solution:
As we learnt in
Differential Equations -
An equation involving independent variable (x), dependent variable (y) and derivative of
dependent variable with respect to independent variable
- wherein
eg:
......................(i)
from (i)
Q. 37
Let
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Hence, and b = 0
Q. 38 The normal to the curve y(x−2)(x−3)=x+6 at the point where the curve intersects the y-axis
passes through the point :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Equation of Normal -
Equation of normal to the curve y = f(x) at the point P(x1, y1) on the curve having a slope MN is
-
equation of normal
Correct option is 1.
Q. 39
The function defined as , is
Option 1:
injective but not surjective
Option 2:
surjective but not injective
Option 3:
neither injective nor surjective
Option 4:
invertible
Correct Answer:
surjective but not injective
Solution:
So that
Correct option is 2
Q. 40 The number of ways in which 5 boys and 3 girls can be seated on a round table if a
particular boy B1 and a particular girl G1 never sit adjacent to each other, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
DISTINCT arrangement.
Number of ways
Correct option is 1.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
,
,
Thus
Q. 42
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
x and y are scalars.
and
- wherein
Also,
Also,
So,
Q. 43 The coordinates of the foot of the perpendicular from the point (1, −2, 1) on the plane
containing the lines
and
is
Option 1:
(2, −4, 2)
Option 2:
(−1, 2, −1)
Option 3:
(0, 0, 0)
Option 4:
(1, 1, 1)
Correct Answer:
(0, 0, 0)
Solution:
As we learnt in
Cartesian equation of plane passing through a given point and normal to a given vector -
- wherein
Putting in
We get
First, we find the equation of plane normal vector of plane containing and is
Unit vector
So plane is
Q. 44
The term independent of x in expansion of is :
Correct Answer:
210
Solution:
As we have learned
Q. 45
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 46 The objective function of a linear programming model is given as,
maximize,
Subject to constraint 1:
Constraint 2:
Option 1:
3
Option 2:
5
Option 3:
7
Option 4:
None of these
Correct Answer:
3
Solution:
As we learnt in
This method of solving an LPP graphically is based on the principle of extreme points theorem.
-
at
and
, is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
and
then the parallel vector of the line formed their intersection can be obtained by
and
say
putting z = 0
3x-y = 1 and x + 4y = 2
Q. 48
The sum of the rational terms in the binomial expansion of is
Option 1:
25
Option 2:
32
Option 3:
9
Option 4:
41
Correct Answer:
41
Solution:
There are only two rational terms - first term and last term.
Option 1:
Option 2:
Option 3:
(1,2)
Option 4:
Correct Answer:
Solution:
Q. 50 The mean age of 25 teachers in a school is 40 years. A teacher retires at the age of 60 years
and a new teacher is appointed in his place. If now the mean age of the teachers in this
school is 39 years, then the age (in years) of the newly appointed teacher is :
Option 1:
25
Option 2:
30
Option 3:
35
Option 4:
40
Correct Answer:
35
Solution:
No concept add
years
= sum of ages
now
Q. 51
The last integral value of of such that satisfies,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
satisfies
Q. 52 If the common tangents to the parabola, x2=4y and the circle, x2+y2=4 intersect at the point
P, then the distance of P from the origin, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Standard equation of parabola -
- wherein
Condition of tangency -
- wherein
Tangent to is
Also
If we put D=0
Hence Equation of Tangent is
Q. 53
The integral is equal to :
Correct Answer:
2
Solution:
As learnt in concept
When
- wherein
Also,
=2
Option 1:
3
Option 2:
5
Option 3:
4
Option 4:
6
Correct Answer:
3
Solution:
Q. 55
If be two complex numbers such that is a purely imaginary number ,
then is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 56 Consider an ellipse, whose centre is at the origin and its major axis is along the x-axis. If its
eccentricity is and the distance between its foci is 6, then the area (in sq. units) of the
quadrilateral inscribed in the ellipse, with the vertices as the end points of major and minor
axes of ellipse, is
Option 1:
8
Option 2:
32
Option 3:
80
Option 4:
40
Correct Answer:
40
Solution:
Given
and
Hence a = 5
= 40
is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in
Let be two curve then area bounded between the curves and the lines
x = a and x = b is
- wherein
Where
Point of intersection of
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given,
Now,
Q. 59 A square, of each side 2, lies above the x-axis and has one vertex at the origin. If one of the
sides passing through the origin makes an angle 300 with the positive direction of the x-axis,
then the sum of the x-coordinates of the vertices of the square
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Parametric form -
- wherein
Where is the inclination of the line and is the distance between and
x-coordinates of A is
Hence x - coordinate of B is
Hence Sum=
Q. 60 A line drawn through the point P(4, 7) cuts the circle x2+y2=9 at the points A and B. Then
PA⋅PB is equal to :
Option 1:
53
Option 2:
56
Option 3:
74
Option 4:
65
Correct Answer:
56
Solution:
As we learnt
Length of a tangent -
- wherein
Since we know,
Mock Test 2
Physics
Q. 1 In a Young's double slit experiment, the path difference , at a certain point on the screen
between two interfering waves is of the wavelength. The ratio of the intensity at this
point to that at the centre of a bright fringe is close to:
Option 1:
0.80
Option 2:
0.94
Option 3:
0.85
Option 4:
0.74
Correct Answer:
0.85
Solution:
Resultant Intensity of two wave -
- wherein
Phase difference
Putting
we get
At the centre
Q. 2 In young's double slit experiment, 16 fringes are observed in a certain segment of the
screen when light of wavelength 700 nm is used. If the wavelength of light is changed to 400
nm, the number of fringes observed in the same segment of the screen would be:
Option 1:
30
Option 2:
28
Option 3:
18
Option 4:
24
Correct Answer:
28
Solution:
Q. 3 An object is placed at a distance of 15cm from a concave mirror of the focal lenth 10cm. The
magnification of the image is:
Option 1:
2
Option 2:
-2
Option 3:
0.4
Option 4:
-0.4
Correct Answer:
-2
Solution:
As we learn
Mirror Formula -
- wherein
Option 1:
2
Option 2:
-2
Option 3:
0.4
Option 4:
-0.4
Correct Answer:
-2
Solution:
As we learned
Mirror Formula -
- wherein
Option 1:
0.25 I1
Option 2:
0.75 I1
Option 3:
I1
Option 4:
0.5 I1
Correct Answer:
0.75 I1
Solution:
As we learn
- wherein
Option 1:
there are two types of objets real object and vitrul object
Option 2:
it may be point object or an extended pbject
Option 3:
both (A) ,and (B)
Option 4:
none of these
Correct Answer:
both (A) ,and (B)
Solution:
as we lern
Object -
A source of light rays that are incident on an optical element. It may be a point object or an extended
object .They are of two kind real object & virtual object.
- wherein
There are two types of objects, rel object and virtual object
Q. 7 if keeping the incedence ray fixed ,the mirrior rotates by an angle the reflected light will
deviate from its original path by an angle
Option 1:
o
Option 2:
00
Option 3:
2 0
Option 4:
4 0
Correct Answer:
2 0
Solution:
as we learn
Rotation of Mirror -
Keeping the incidence ray fixed, When mirror is rotated by an angle , the reflected ray is rotated by an
angle .
- wherein
Q. 8 If the dimensions of a physical quantity are given by Ma Lb Tc, then the physical quantity will
be:
Option 1:
Velocity if a = 1, b = 0, c = -1
Option 2:
Acceleration if a = 1, b = 1, c = -2
Option 3:
Force if a = 0, b = - 1, c = - 2
Option 4:
Pressure if a = 1, b = - 1, c = - 2
Correct Answer:
Pressure if a = 1, b = - 1, c = - 2
Solution:
and
and
and
Option 1:
[L-1 T]
Option 2:
[L T-1]
Option 3:
[L1/2 T1/2]
Option 4:
[L1/2 T-1/2]
Correct Answer:
[L T-1]
Solution:
As we learnt in
- wherein
C=
Correct option is 2.
Q. 10 The x and y coordinates of the particle at any time are x = 5t - 2t2 and y = 10t respectively,
where x and y are in meters and t in seconds. The acceleration of the particle at t = 2s is
Option 1:
0
Option 2:
5m /s2
Option 3:
-4m /s2
Option 4:
-8m /s2
Correct Answer:
-4m /s2
Solution:
As we learnt in
Introduction to Differentiation -
- wherein
x = 5t - y = 10t
vx=5-4t vy=10
ax=-4 ay=0
Acceleration of particle at
Correct option is 3.
Q. 11 The speed of a swimmer in still water is 20 m/s . The speed of river water is 10 m/s and is
flowing due east . If he is standing on the south bank and wishes to cross he river along the
sortest path , the angle at which he should make his strokes w.r.t north is given by :
Option 1:
30 west
Option 2:
Option 3:
Option 4:
Correct Answer:
30 west
Solution:
Boat - River Problem -
width of river
u = speed of river
Q. 12 Preeti reached the metro station and found that the escalator was not working. She walked
up the stationary escalator in time t1. On other days, if she remains stationary on the
moving escalator, then the escalator takes her up in time t2. The time taken by her to walk
up on the moving escalator will be:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Velocity of Preeti
Velocity of escalator
distance
Q. 13 The displacement time graphs of two moving particles make angles of and with the
x-axis as shown in the figure. the ratios of their respective velocity are
Option 1:
1:1
Option 2:
1:2
Option 3:
Option 4:
Correct Answer:
Solution:
For the displacement-time graph,
Slope = velocity
Q. 14 Out of below four equations of Maxwell which shows monopole do not exists
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learned
i.e Total magnetic flux passing through a closed area is equal to zero.
And this Gauss Law for magnetism shows that monopole does not exist
Q. 15 The ratio of amplitude of magnetic field to the amplitude of electric field for an
electromagnetic wave propagating in vacuum is equal to:
Option 1:
reciprocal of speed of light in vacuum
Option 2:
the ratio of magnetic permeability to the electric susceptibility of vacuum
Option 3:
unity
Option 4:
the speed of light in vacuum
Correct Answer:
reciprocal of speed of light in vacuum
Solution:
As we learnt in
- wherein
Correct option is 1.
Q. 16 The energy of the em waves is of the order of 15 ke V. To which part of the spectrum does it
belong ?
Option 1:
Infra - red rays
Option 2:
Ultraviolet rays
Option 3:
- rays
Option 4:
X - rays
Correct Answer:
X - rays
Solution:
As we learnt in
X Rays -
Frequency Range Hz to Hz
- wherein
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
E=
Option 1:
Be doubled
Option 2:
Increase four times
Option 3:
Be reduced to half
Option 4:
Remain the same
Correct Answer:
Remain the same
Solution:
As we learnt in
Gauss's Law -
Formula:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Potential gradient.
If P lies inside -
We know
E= constant
E would be constant of
Q. 20 A parallel plate capacitor is made of two plates of length l, width w and separated by
distance d. A dielectric slab (dielectric constant K) that fits exactly between the plates is held
near the edge of the plates. It is pulled into the capacitor by a force where U is
the energy of the capacitor when dielectric is inside the capacitor up to distance x (See
figure). If the charge on the capacitor is Q then the force on the dielectric when it is near the
edge is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 21 The electric field in a region of space is given by, where E0=100 N/C. The
flux of this field through a circular surface of radius 0.02 m parallel to the Y-Z plane is nearly
:
Option 1:
0.125 Nm2/C
Option 2:
0.02 Nm2/C
Option 3:
0.005 Nm2/C
Option 4:
3.14 Nm2/C
Correct Answer:
0.125 Nm2/C
Solution:
New flux
Q. 22 A charged particle is suspended in equilibrium in a uniform vertical electric field of intensity 20000
V/m. If mass of the particle is , the charge on it and excess number of electrons on
the particle are respectively
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Electric field of intensity =20,000 V/m
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt
Q. 24
Intensity level of a sound of intensity I is 30 dB. The ratio is (where I0 is the threshold for
hearing)
Correct Answer:
1000
Solution:
Q. 25 The power dissipated in the circuit shown in the figure is 30 Watts. The value of R is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
In parallel Grouping -
Power
150R = 100(5+R) => 150R = 500+100R
Option 1:
0.001
Option 2:
0.01
Option 3:
1
Option 4:
0.05
Correct Answer:
0.001
Solution:
As we learnt in
Required shunt -
- wherein
The value of shunt required for converting it into ammeter of range 25 ampere is
Q. 27 In the circuit shown the cells A and B have negligible resistances. For VA = 12 V, R1 = 500
and R = 100 the galvanometer (G) shows no deflection. The value of VB is:
Option 1:
4V
Option 2:
2V
Option 3:
12 V
Option 4:
6V
Correct Answer:
2V
Solution:
Q. 28 If voltage across a bulb rated 220 volt - 100 watt drops by 2.5% of its rated value, the
percentage of the rated value by which the power would decrease is:
Option 1:
20%
Option 2:
2.5%
Option 3:
5%
Option 4:
10%
Correct Answer:
5%
Solution:
Q. 29 A ring is made of a wire having a resistance R0 = 12 . Find the points A and B as shown in
the figure, at which a current carrying conductor should be connected so that the resistance
R of the sub circuit between these points is equal to
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
In series Grouping -
- wherein
Equivalent Resistance
In parallel Grouping -
Upper Portion
Lower Portion
-------------------------(i)
-----------------------------------(ii)
or
Let
=>
Q. 30 A wire of resistance 4 is stretched to twice its original length. The resistance of stretched
wire would be:
Option 1:
16
Option 2:
2
Option 3:
4
Option 4:
8
Correct Answer:
16
Solution:
As we learnt in
Resistance formula -
- wherein
resistivity of material
New resistance
Q. 31 The internal resistance of a 2.1 V cell which gives a current of 0.2 A through a resistance of
10 is:
Option 1:
1.0
Option 2:
0.2
Option 3:
0.5
Option 4:
0.8
Correct Answer:
0.5
Solution:
given
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Bragg's law -
= wavelength
Q. 33 The half-life period of a radio-active element X is same as the mean life time of another
radio-active element Y . Initially they have the same number of atoms. Then
Option 1:
X and Y decay at same rate always
Option 2:
X will decay faster than Y
Option 3:
Y will decay faster than X
Option 4:
X and Y have same decay rate initially
Correct Answer:
X will decay faster than Y
Solution:
So
Wave property of electrons implies that they will show diffraction effects. Davisson and
Germer demonstrated this by diffracting electrons from crystals. The law governing the
diffraction from a crystal is obtained by requiring that electron waves reflected from the
planes of atoms in a crystal interfere constructively (see figure).
Option 1:
50
Option 2:
2000
Option 3:
100
Option 4:
500
Correct Answer:
50
Solution:
As we learnt in
Bragg’s formula -
- wherein
Condition of constructive interference is
Take n = 1
So
&
Q. 35 X- rays are -
Option 1:
Stream of neutral particles
Option 2:
Stream of negatively charged particles
Option 3:
Stream of protons
Option 4:
electromagnetic radiations of high frequency
Correct Answer:
electromagnetic radiations of high frequency
Solution:
As we learn
Characteristics x-ray -
=
- wherein
Characteristics x ray can be defined by knocking out of electron from inner orbit of an atom
Q. 36 Both the nucleus and the atom of some element are in their respective first excited
states. They get de-excited by emitting photons of wavelengths ,
respectively. The ratio is closest to :
Option 1:
Option 2:
10
Option 3:
Option 4:
Correct Answer:
Solution:
The nucleus emits radiation of order of 0.1 (like rays)
ratio
or
Q. 37 The momentum of a photon of energy h v will be
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Option 1:
1:4
Option 2:
1:2
Option 3:
1:1
Option 4:
1:5
Correct Answer:
1:2
Solution:
As we learnt in
Conservation of energy -
- wherein
Q. 39 A gas mixture consists of 2 moles of O2 and 4 moles of Ar at temperature T. Neglecting all
vibrational modes, the total internal energy of the system is
Option 1:
4 RT
Option 2:
15 RT
Option 3:
9 RT
Option 4:
11 RT
Correct Answer:
11 RT
Solution:
As we learnt in
- wherein
(Always)
is degree of freedom
Correct option is 4.
Column-1 Column-2
P. Process I a. Adiabatic
Q. Process II b. Isobaric
S. Process IV d. Isothermal
Option 1:
P a, Q c, R d, S b
Option 2:
P c, Q a, R d, S b
Option 3:
P c, Q d, R b, S a
Option 4:
P d, Q b, R a, S c
Correct Answer:
P c, Q a, R d, S b
Solution:
Q. 41
In a certain region of space, the gravitational field is given by Taking the
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As or
Option 1:
Option 2:
Option 3:
Cannot be predicted
Option 4:
Correct Answer:
Solution:
For an ideal gas
or
From figure,
or
or
Q. 43 In a vessel, the gas is at a pressure P. If the mass of all the molecules is halved and their
speed is doubled, then the resultant pressure will be:
Option 1:
4P
Option 2:
2P
Option 3:
P
Option 4:
Correct Answer:
2P
Solution:
Pressure of a gas -
- wherein
m = mass of a molecule
Pressure of a gas
Option 1:
100000000
Option 2:
1000
Option 3:
1000000
Option 4:
10000
Correct Answer:
1000000
Solution:
For string
for stone
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 46 Needles N1,N2,and N3 are made of a ferromagnetic, a paramagnetic and a diamagnetic
substance respectively. A magnet when brought close to them will
Option 1:
attract all three of them
Option 2:
attract N1 and N2 strongly but repel N3
Option 3:
attract N1 strongly, N2 weakly and repel N3 weakly
Option 4:
attract N1 strongly, but repel N2 and N3 weakly.
Correct Answer:
attract N1 strongly, N2 weakly and repel N3 weakly
Solution:
Ferromagnetic substance magnetizes strongly in the direction of magnetic field N1 is made up of
this material paramagnetic substance magnetizes weakly in the direction of magnetic field. N2 is made of
this material. Diamagnetic substance magnetizes weakly in the opposite direction of magnetic field. N3 is
made of this material.
Correct Answer:
12.87
Solution:
m=mass of particle
P=momentum of particle
here
Similarly
so
Q. 48 An arrangement of three parallel straight wires placed perpendicular to plane of paper
carrying same current 'I' along the same direction is shown in Fig. Magnitude of force per
unit length on the middle wire ' B' is given by :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
I1 and I2 current carrying two parallel wires
Q. 49 For CE transistor amplifier, the audio signal voltage across the collector resistance of is
4 V. If the current amplification factor of the transistor is 100 and the base resistance is
, then the input signal voltage is
Option 1:
10 mV
Option 2:
20 mV
Option 3:
30 mV
Option 4:
15 mV
Correct Answer:
20 mV
Solution:
As we learnt in
Transistor -
- wherein
Q. 50 The increase in the width of the depeltion region in a p-n junction diode is due to:
Option 1:
forward bias only
Option 2:
reverse bias only
Option 3:
both forward bias reverse bias
Option 4:
increase in forward current
Correct Answer:
reverse bias only
Solution:
In reverse biasing, the positive terminal of the battery is connected to the n-type whereas the negative
terminal is connected to the p-type junction. So the positive terminal tend to pull the electrons (near to
the depletion layer) in n-type towards itself whereas the negative terminal pulls the holes towards itself
which results in increase in the width of depletion layer.
Q. 51 The given circuit has two ideal diodes connected as shown in the figure below. The current
flowing through the resistance R1 will be
Option 1:
2.5 A
Option 2:
10.0 A
Option 3:
1.43 A
Option 4:
3.13 A
Correct Answer:
2.5 A
Solution:
As we learnt in
P -N junction as diode -
It is a one way device. It offers a low resistance when forward biased and high resistance when reverse
biased.
- wherein
R = 0, Forward
R Reverse
In the given figure is in Reverse biased mode. hence no current will flow through it while is in
forward biased mode hence will offer Zero resistance
Correct Option is 1.
Q. 52 A 220-volt input is supplied to a transformer. The output circuit draws a current of 2.0
ampere at 440 volts. If the efficiency of the transformer is 80%, the current drawn by the
primary windings of the transformer is
Option 1:
5.0 ampere
Option 2:
3.6 ampere
Option 3:
2.8 ampere
Option 4:
2.5 ampere
Correct Answer:
5.0 ampere
Solution:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
Option 2:
2.0 A
Option 3:
4.0 A
Option 4:
8.0 A
Correct Answer:
4.0 A
Solution:
Q. 55 A particle of mass m is dropped from a height h above the ground. At the same time
another particle of the same mass is thrown vertically upwards from the ground with a
speed of . If they collide head-on completely inelastically, the time taken for the
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
After t1 -
and
so time
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 57 Two blocks of masses 50 Kg and 30 Kg connected by a massless string pass over a tight
frictionless, pulley and rest on two smooth planes inclined at angles and respectively
with horizontal as shown in the figure. If the system is released from rest then find the time
taken by 30 Kg block to reach the ground
Option 1:
20 sec
Option 2:
30 sec
Option 3:
10 sec
Option 4:
50 sec
Correct Answer:
10 sec
Solution:
As we have learned
Now
Q. 58
A man weighs 80 kg. He stands on a weighing scale in a lift which is moving upwards with a
uniform acceleration of 5m/s2. What would be the reading on the scale. (g=10m/s2)
Correct Answer:
1200
Solution :
Reading of weighing scale = m(g+a) = 80(10 + 5) = 1200 N
Q. 59 A cylinder of mass Mc and sphere of mass Ms are placed at points A and B of two inclines,
respectively.
(See Figure). If they roll on the incline without slipping such that their accelerations are the
same, then
The ratio is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Acceleration along inclined plane
For sphere
For cylinder
Q. 60 A hollow hemisphere of mass m is placed on a hollow sphere of mass m. The center of mass
of given arrangement from point A is at the height
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Chemistry
Q. 1 A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of the pure
hydrocarbons at 20°C are 440 mm Hg for pentane and 120 mm Hg for hexane. The mole
fraction of pentane in the vapour phase would be:
Correct Answer:
0.478
Solution:
Q. 2 Benzene and toluene form nearly ideal solutions. At 20°C, the vapour pressure of benzene is
75 torr and that of toluene is 22 torr. The partial vapour pressure of benzene at 20°C for a
solution containing 78g of benzene and 46g of toluene in torr is:
Correct Answer:
50
Solution:
Option 1:
Option 2:
Benzene + Toluene
Option 3:
Option 4:
Correct Answer:
Solution:
Solution showing negative deviation from Raoult's law form maximum boiling azeotropes. The mixture of
and form non-ideal solution which shows negative deviation form Raoult's law.
Option 1:
Convert chemical energy to electrical energy
Option 2:
most batteries are chemical cells
Option 3:
i and ii
Option 4:
none
Correct Answer:
i and ii
Solution:
As we learnt
Chemical Cells -
The cells in which electrical energy is produced from the energy change accompanying chemical
reactions or a physical process are known as chemical cells.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
- wherein
Q. 6 Iodine reacts with concentrated to yield Y along with other products. The oxidation
state of iodine in Y, is :
Option 1:
5
Option 2:
3
Option 3:
1
Option 4:
7
Correct Answer:
5
Solution:
Oxidation state of oxygen family -
Oxygen shows -2,+2 and -1
The oxidation number of oxygen in most compounds is -2. There are two exceptions.
In peroxide (H2O2; Na2O2), the oxidation number is -1.
- wherein
Y here is HIO3 and the oxidation state of iodine in HIO3 is given below:
Option 1:
75
Option 2:
96
Option 3:
60
Option 4:
84
Correct Answer:
84
Solution:
As we learnt in
By the stoichiometry of the reaction above, we know that 1 mol of the gives 1 mol of MgO.
Moles of MgO that should have been obtained in a pure sample = 0.238
= 0.2
Option 1:
18 molecules of water
Option 2:
1.8 gram of water
Option 3:
18 gram of water
Option 4:
18 moles of water
Correct Answer:
18 moles of water
Solution:
Mole Concept -
Option 1:
Increase
Option 2:
Decrease
Option 3:
Remain Same
Option 4:
Either Increase or Decrease
Correct Answer:
Increase
Solution:
Henry's constant depends on temperature and nature of gas.
Option 2:
Increases
Option 3:
First Increases then decreases
Option 4:
None
Correct Answer:
Increases
Solution:
As we have learnt,
Solubility of Gases on Temperature and Pressure -
As
On increasing pressure, the collision of gas molecules on the liquid surface increases thus solubility of
the gas in liquid increases.
Q. 11 The value of & are 80, 145, 75, and 35 Kbar respectively, the least
soluble gas in water is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Gases having more values will have less solubility.
Among the given gases 'He' has the highest value.
Q. 12 Which of the following forces stabilize the tertiary structure of proteins i.e. further folding of
the secondary structure?
Option 1:
disulphide linkages
Option 2:
hydrogen bond
Option 3:
electrostatic forces of attraction
Option 4:
all of these
Correct Answer:
all of these
Solution:
As we have learnt,
Tertiary proteins are obtained when polypeptides undergo further folding and coiling of secondary
protein
Structure is stabilized by :
1. Ionic bond
2. Disulphide bond
3. bond
4. Vander waals forces
5. Electrostatic forces
Option 1:
Ligases
Option 2:
Hydrolases
Option 3:
Lyases
Option 4:
Oxidareductases
Correct Answer:
Ligases
Solution:
As we have learned
Ligase -
Enzymes are responsible for linking together of two molecules into one at the expense of energy.
- wherein
Eg. Synthetase
Ligases remove the elements of water from two fundamental groups to form a single bond.
a) Vitamin A
b) Vitamin B
c) Ascorbic acid
d ) Pyridoxine
e) Vitamin D
Option 1:
c,d
Option 2:
a,b,e
Option 3:
b,c
Option 4:
c,e
Correct Answer:
b,c
Solution:
As we have learned
Water-soluble vitamins -
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
We know that
And
from above
For Ag2+/Ag
Electron transfer :
and
After putting the value:
Therefore,option(4) is correct.
(Faraday's constant, )
Option 1:
-384
Option 2:
384
Option 3:
192
Option 4:
-192
Correct Answer:
-384
Solution:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Disproportionation reactions are those reactions where oxidation & reduction occur on the same species,
simultaneously
In MnO4- and I- reaction, Mn is going to +7 to +2 and I is going to -1 to zero, both reduction and oxidation
but with different atoms.
In NaBr and Cl2 reaction, both reduction and oxidation but with different atoms.
Q. 18 [Co2(CO)8] displays :
Option 1:
one Co−Co bond, six terminal CO and two bridging CO
Option 2:
one Co−Co bond, four terminal CO and four bridging CO
Option 3:
no Co−Co bond, six terminal CO and two bridging CO
Option 4:
no Co−Co bond, four terminal CO and four bridging CO
Correct Answer:
one Co−Co bond, six terminal CO and two bridging CO
Solution:
The structure of [Co2(CO)8]
In one Co-Co bond, six terminal bond and two bridge CO are present
Option 1:
Cu
Option 2:
Ag
Option 3:
Fe
Option 4:
Na
Correct Answer:
Ag
Solution:
The extraction of Silver is done using the McArthur Forest Cyanide method.
Option 1:
Optical
Option 2:
Co-ordination
Option 3:
Geometrical
Option 4:
Linkage
Correct Answer:
Linkage
Solution:
As we have learnt,
is an ambidentate ligand and can be attached from both the N site as well as the O site in the form
of and respectively.
Q. 21 The freezing point of a diluted milk sample is found to be , while it should have
been for pure milk. How much water has been added to pure milk to make the
diluted sample ?
Option 1:
2 cups of water to 3 cups of pure milk.
Option 2:
3 cups of water to 2 cups of pure milk.
Option 3:
1 cup of water to 3 cups of pure milk.
Option 4:
1 cup of water to 2 cups of pure milk.
Correct Answer:
3 cups of water to 2 cups of pure milk.
Solution:
Freezing point of milk
Q. 22 The percentage of pyridine (C5H5N) that forms pyridinium ion (C5H5N*H) in a 0.10 M
aqueous pyridine solution (Kb for C5H5N = 1.7 x 10-9) is:
Option 1:
0.0060%
Option 2:
0.013%
Option 3:
0.77%
Option 4:
1.6%
Correct Answer:
0.013%
Solution:
% pyridine that form pyridinium
Option 1:
Option 2:
Option 3:
Option 4:
zero
Correct Answer:
Solution:
Option 1:
BF3
Option 2:
PF3
Option 3:
CF4
Option 4:
SiF4
Correct Answer:
PF3
Solution:
A lewis base is a compound that can donate a lone pair of electrons while a lewis acid accepts a lone pair
of electrons.
behave like lewis's base because it has one pair of electrons, while can accept lone pair of an
electron in and in vacant orbitals and act as lewis acid.
has a value of at a particular temperature. What is the value of the equilibrium constant
for the following reaction at the same temperature?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The equilibrium constant for the reverse reaction is the inverse of the equilibrium constant for the
reaction in the forward direction.
is the equilibrium constant for the reverse direction.
for
Option 1:
Ferricyanide
Option 2:
Ferrous ferricyanide
Option 3:
Ferrous cyanide
Option 4:
Ferri ferrocyanide
Correct Answer:
Ferrous ferricyanide
Solution:
Turnbull's blue has the formula
Option 1:
Option 2:
Option 3:
Option 4:
Both a and b
Correct Answer:
Both a and b
Solution:
Borax bead -
Used for the detection of coloured basic radicals in borax bead test.
Q. 28 The major product of reaction of alcoholic silver nitrite with ethyl bromide is:
Option 1:
Ethane
Option 2:
Ethene
Option 3:
Ethylalcohol
Option 4:
Nitroethane
Correct Answer:
Nitroethane
Solution:
Alkyl halides when treated with AgNO2 in aqueous ethanol, Nitro alkane is obtained as a product.
- wherein
Therefore, Option(4) is correct
Q. 29 For the reaction, A(g) + B(g) → C(g) + D(g), H0 and S0 are, respectively, −29.8 kJ mol−1 and
−0.100 kJ K−1 mol−1 at 298 K. The equilibrium constant for the reaction at 298 K is :
Option 1:
1.0 × 10−10
Option 2:
1.0 × 1010
Option 3:
10
Option 4:
1
Correct Answer:
1
Solution:
Q. 30 The heats of combustion of carbon and carbon monoxide are −393.5 and −283.5 kJ mol−1,
respectively. The heat of formation (in kJ) of carbon monoxide per mole is:
Correct Answer:
-110
Solution:
Q. 31 The heat of atomization of methane and ethane are 360 kJ/mol and 620 kJ/mol, respectively.
The longest wavelength of light capable of breaking the C - C bond is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The heat of the atomization of methane is 360 kJ/mol.
This corresponds to the breaking of four C−H bonds.
This corresponds to the breaking of one C−C bond and six C−H bonds.
The heat corresponding to the breaking of on C-C bond will be 620−6(90)=80 kJ/mol
This corresponds to 1 mole. For one single bond, the required energy that can be obtained by dividing
with Avogadro's number is given by
Q. 32 Which one of the following pairs of species have the same bond order?
Option 1:
CO, NO
Option 2:
O2, NO+
Option 3:
CN-, CO
Option 4:
Correct Answer:
CN-, CO
Solution:
Bond Order -
Bond order is defined as one half the difference between the number of electrons present in the bonding
and the antibonding orbitals.
- wherein
Bond order
Option 1:
It is sp3d2 hybridised and octahedral
Option 2:
It is sp3d2 hybridised and tetrahedral
Option 3:
It is d2sp3 hybridised and octahedral
Option 4:
It is dsp2 hybridised and square planar
Correct Answer:
It is d2sp3 hybridised and octahedral
Solution:
Shape of molecules -
-
Q. 34 Consider the molecules CH4, NH3 and H2O. Which of the given statements is false?
Option 1:
The H - C - H bond angle in CH4, the H - N - H bond angle in NH3, and the H - O - H bond angle in H2O
are all greater than 90o.
Option 2:
The H - O - H bond angle in H2O is larger than the H - C - H bond angle in CH4.
Option 3:
The H - O - H bond angle in H2O is smaller than the H - N - H bond angle in NH3.
Option 4:
The H - C - H bond angle in CH4 is larger than the H - N - H bond angle in NH3.
Correct Answer:
The H - O - H bond angle in H2O is larger than the H - C - H bond angle in CH4.
Solution:
VSEPR Theory -
1. The shape of the molecule is determined by repulsions between all of the electron pair present in
valence shell.
2. Order of repulsion
3 Repulsion among the bond pair is directly proportional to the bond order and electronegativity
difference between the central atom and the other atom.
From the above fugure it is clear that H—O—H bond angle in is smaller than H—C—H bond angles
in .
Q. 35 Of the following outer electronic configurations of atoms, the highest oxidation state is
achieved by which one of them?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 36 The major product of the following reaction is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The given substrate undergoes dehydrohalogenation to form an alkene and the
subsequent polymerisation reaction occurs as:
It is to be mentioned that the chlorine attached to the Benzene ring will not undergo substitution with
KOH very easily due to partial double bond character between the benzene ring and the chloro group.
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Given that
Q. 38 Which of the following potential energy (PE) diagram represents the reaction?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt,
reaction occurs in two steps. The first step is the formation of the Carbocation while the second step
is the attack of the nucleophile to form the final product.
Since the formation of the Carbocation is the slow step in the reaction, the energy profile diagram will
have a higher peak for the formation of the carbocation. The second peak represents the activation
energy required for the nucleophile to bond with the Carbocation which will have a lower peak than the
slowest step.
Option 1:
3
Option 2:
4
Option 3:
5
Option 4:
6
Correct Answer:
6
Solution:
As we learnt in
Electronic Configuration -
Option 2:
Ac
Option 3:
Pa
Option 4:
U
Correct Answer:
Ac
Solution:
Electronic configuration - Actinoids follow the general configuration
Due to the electronic configuration of Actinium, it only shows a +3 oxidation state because,
after the loss of 3 electrons, actinium acquires noble gas electronic configuration.
Option 1:
On passing through acidified solution, a milky colour is observed.
Option 2:
is preferred over in volumetric analysis.
Option 3:
solution in acidic medium is orange.
Option 4:
solution becomes yellow on increasing pH beyond 7.
Correct Answer:
is preferred over in volumetric analysis.
Solution:
Due to hygroscopic nature of
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
LiAlH4 is a strong reducing agent, it reduces carboxylic group into primary alcoholic group without
affecting the double bond in the compound
where the time t is in hours. A dose of antibiotic, taken orally, needs 1 hour to reach the
wound.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
From t hour =>
at t = 1 hour ,
Now,
After 1 hour the graph will be from 1 hour to t hour and N' from eNo to N.
So, the curve will be a straight line and the slope will be positive.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt,
Q. 45 For a first order reaction, calculate the ratio between the time taken to complete 3/4 th of
the reaction and time taken to complete half of the reaction?
Option 1:
4/3
Option 2:
8/3
Option 3:
2
Option 4:
1
Correct Answer:
2
Solution:
Therefore, option(3) is correct
Q. 46 The half life of a first order reaction is 60 min. How long (in min.) will it take to consume 90%
of the reaction?
Correct Answer:
200
Solution:
For the first-order reaction,
Option 1:
de-Broglie's wavelength is given by , where m = mass of the particle, = group velocity of
the particle.
Option 2:
The uncertainty principle is
Option 3:
Half-filled and fully filled orbitals have greater stability due to greater exchange energy, greater
symmetry and more balanced arrangement.
Option 4:
The energy of 2s orbital is less than the energy of 2p orbital in case of Hydrogen like atoms.
Correct Answer:
The energy of 2s orbital is less than the energy of 2p orbital in case of Hydrogen like atoms.
Solution:
As we learned in
The principal quantum number determines the size and to large extent the energy of the orbital.
For a hydrogen-like atom, the energy of the 2s orbital is the same as the energy of the 2p orbital.
Option 1:
Option 2:
Option 3:
Option 4:
Q. 49 The ease of adsorption of the hydrated alkali metal ions on an ion- exchange resins follows
the order:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Ease of adsorption of the hydrated alkali metal ions on an ion-exchange resin decreases as the size of
alkali metal ion increases.
Since the order of the size of alkali metal ion follows the order-
is _______.
Option 1:
3-keto-2-methylhex-4-enal
Option 2:
5-formylhex-2-en-3-one
Option 3:
5-methyl-4-oxohex-2-en-5-al
Option 4:
3-keto-2-methylhex-5-enal
Correct Answer:
3-keto-2-methylhex-4-enal
Solution:
Q. 51 Reaction of benzene diazonium with A will give us benzene. A is
Option 1:
Fluroboric acid
Option 2:
Hypophosphorus acid
Option 3:
Potassium halide
Option 4:
water
Correct Answer:
Hypophosphorus acid
Solution:
As we have learned
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The reaction of tertiary arylamines with HNO2 -
Tertiary arylamines react with nitrous acid to form p - Nitroso aromatic compounds. Electrophilic
aromatic substitution occurs on the benzene ring in which a Nitroso group is substituted on the Benzene
ring.
Q. 53
The above process in which and form remain in equilibrium with acyclic form and a
change in optical rotation is observed which is called as -
Option 1:
Mutarotation
Option 2:
Epimerisation
Option 3:
Condensation
Option 4:
Inversion
Correct Answer:
Mutarotation
Solution:
When either of the two forms of glucose ( and ) is dissolved in
water , there is spontaneous change in specific rotation till the equilibrium value of
Option 1:
0.177
Option 2:
1.770
Option 3:
0.0354
Option 4:
0.0177
Correct Answer:
0.0177
Solution:
As we learned in
Q. 55 If Avogadro number NA, is changed from 6.022 x 1023 mol-1 to 6.022 x 1020 mol-1, this would
change :
Option 1:
the definition of mass in units of grams.
Option 2:
the mass of one mole of carbon.
Option 3:
the ratio of chemical species to each other in a balanced equation.
Option 4:
the ratio of elements to each other in a compund.
Correct Answer:
the mass of one mole of carbon.
Solution:
As we learnt in
One mole is the amount of a substance that contains as many particles or entities as there are atoms in
exactly 12 g (or 0.012 kg) of the 12C isotope.
1 mole of substance = 6.0221367 X 1023 units of that substance (such as atoms, molecules, or ions). The
number 6.0221367 X 1023 is known as Avogadro's number or Avogadro's constant.
Q. 56 10 g of hydrogen and 64 g of oxygen were filled in a steel vessel and exploded. Amount of
water produced in this reaction will be -
Option 1:
1 mol
Option 2:
2 mol
Option 3:
3 mol
Option 4:
4 mol
Correct Answer:
4 mol
Solution:
The reaction will be-
Two moles of H2 and one mole of O2 will produce two moles of water.
5 Moles of H2 can produce 5 moles of water while 2 moles of O2 can produce 4 moles of water.
Option 1:
0.477 M and 0.477 M
Option 2:
0.955 M and 1.910 M
Option 3:
1.910 M and 0.955 M
Option 4:
1.90 M and 1.910 M
Correct Answer:
1.910 M and 0.955 M
Solution:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Smaller the value of z/e, the larger the size of that species. Smaller z means the effective nuclear charge
is small hence size is large.
Cations lose electrons and are smaller in size than the parent atom, whereas anions add electrons and
are larger in size than the parent atom. Hence the order is
For isoelectronic species, the ionic radii decrease with an increase in atomic number, i.e., nuclear charge.
Hence the correct orders are as given below:
Therefore, the correct option is (3).
Q. 59 The increasing order of the acidity of the following carboxylic acids is:
Option 1:
I < III < II < IV
Option 2:
IV < II < III < I
Option 3:
II < IV < III < I
Option 4:
III < II < IV < I
Correct Answer:
III < II < IV < I
Solution:
As we learnt in
-NO2 and -Cl are electron withdrawing groups while -OH is electron donating group.
Ring deactivating groups increases the acidic character whereas ring activating groups decreases the
acidic strength.
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Between OH and OMe, OH is more attacking species due to the formation of phenoxide ion by OH group.
Hence, the option number (1) is correct.
Maths
Q. 1 5- digit numbers are to be formed using 2,3,5,7,9 without repeating the digits.If p be the
number of such numbers that exceed 20000 and q be the number of those that lie between
30000 and 90000 then p:q is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Number greater than 20000 or p
1st place can be placed with 5 possibilities and second with 4 possibilities and so on
So
And
1st place can be placed with 3 possibilities(3,5,7) and second with 4 possibilities and so on
So
Q. 2 Twenty meters of wire is available for fencing off a flower-bed in the form of a circular
sector. Then the maximum area (in sq. m) of the flower-bed, is :
Correct Answer:
25
Solution:
As we have learned
- wherein
So,
So ,
Hence
Q. 3
If
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
Since all variables must be converted into single variable ,
Q. 4
Let ,where z is any non-zero complex number.
Option 1:
(-1,1)
Option 2:
[-1,1]
Option 3:
[0,1)
Option 4:
(-1,0]
Correct Answer:
(-1,1)
Solution:
Now,
Q. 5 The eccentricity of an ellipse having centre at the origin, axes along the co-ordinate axes
and passing through the points (4, −1) and (−2, 2) is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Eccentricity -
- wherein
and
Q. 6
If , then 'a' is equal to :
Option 1:
2
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
It is form.
Q. 7 For two 3 × 3 matrices A and B, let A + B = 2B' and 3A + 2B = I3, where B' is the transpose of B
and I3 is 3 × 3 identity matrix. Then :
Option 1:
5A + 10B = 2I3
Option 2:
10A + 5B = 3I3
Option 3:
B + 2A = I3
Option 4:
3A + 6B = 2I3
Correct Answer:
10A + 5B = 3I3
Solution:
Given A + B = 2B' .............(1)
(A + B)' = (2B')'
Now from these 4 equations we need to get a relation in A and B by eliminating A' and B'
And 2 x (2):
2A' + 2B' = 4B
2A' + A + B = 4B
2A' + A - 3B = 0 .....(6)
Q. 8 If
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
put
- wherein
Equation with convert to
Now put
Q. 9
If
is equal to :
Option 1:
log4
Option 2:
Option 3:
log2
Option 4:
Correct Answer:
log2
Solution:
As learnt in concept
Integration By PARTS -
- wherein
is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Where
1+b=0 b=-1
Q. 11
For, let and
Correct Answer:
1.67
Solution:
Put n = 0
Put n = 1
Put n = 2
( same as fo(x))
So at n = 0, 3, 6, ...............96,99;
at n = 1, 4, 7, ...................97,100,103;
and n = 2, 5, 8,............98,101,104 ;
Q. 12 Let Sn =
Correct Answer:
199
Solution:
Its term is
.....
Now
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
We have given
Q. 14 In a triangle ABC, right angled at the vertex A, if the position vectors of A, B and C are
respectively
Option 1:
parallel to x-axis.
Option 2:
parallel to y-axis.
Option 3:
making an acute angle with the positive direction of x-axis.
Option 4:
making an obtuse angle with the positive direction of x-axis
Correct Answer:
making an acute angle with the positive direction of x-axis.
Solution:
As we learnt in
- wherein
3x-2y+13=0
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Case 1
Case 2
Case 3
Case 4
Hence
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept @ZWYX and use of maxima/minima
Q. 17 The area (in sq. units) of the region described by A = {(x, y)|y ≥ x2 − 5x + 4, x + y ≥ 1, y ≤ 0} is
:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Let be two curve then area bounded between the curves and the lines
x = a and x = b is
- wherein
Where
Point of intersection of
at x=1, y=0;
x=3, y= -2
Req Area
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 19 If y = mx + c is the normal at a point (in first quadrant) on the parabola y2 = 8x whose focal
distance is 8 units, then |c| is equal to
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Here
We know that for ,
Thus 8 = 2 + at2
2t2 = 6
Now
Put value
Comparing with y = mx + c
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
L - Hospital Rule -
- wherein
If
Put, x=1, y=1
Put,
such that the point (a, b, c) lies on the plane then equals :
Correct Answer: 1
Solution:
As we learnt in
Cramer's rule for solving system of linear equations -
When and ,
- wherein
and
and given
so that
Q. 22 The order and the degree of the differential equation of all ellipses with centre at the origin,
major axis along x-axis and
eccentricity \frac{\sqrt{3}}{2} are, respectively :
Option 1:
2, 2
Option 2:
1, 1
Option 3:
2, 1
Option 4:
1, 2
Correct Answer:
1, 1
Solution:
As we learned in
The order of a differential equation is the order of highest order occurring in a differential equation
- wherein
order of
is 2.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 24 If m and M are the minimum and the maximum values of
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Let,
So that
m=4
and
Correct option is 4.
Q. 25
If and then S:
Option 1:
is an empty set
Option 2:
contains exactly one element
Option 3:
contains exactly two elements
Option 4:
contains more than two elements
Correct Answer:
contains exactly two elements
Solution:
(i)
(ii)
Multiplying (i) by 2
and
Correct option is 3.
Option 2:
a, b and c are in A.P.
Option 3:
a, b and c are in G.P.
Option 4:
b, c and a are in G.P.
Correct Answer:
b, c and a are in A.P.
Solution:
225a2+9b2+25c2+225a2+9b2+25c2-2(15a)(3b)-2(3b)(5c)-2(5c)(15a) = 0
So that
Now
a, b,c are not in A.P.
Now
And a + b = 2k/5
So b, c, a are in A.P.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given equation is
So, the number of solutions is 3.
Q. 28 If and are unit vectors satisfying , then the angle between the
vectors and is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 29 The sum of the digits in the unit’s place of all the 4-digit numbers formed by using the
numbers 3, 4, 5 and 6, without repetition, is :
Option 1:
432
Option 2:
108
Option 3:
36
Option 4:
18
Correct Answer:
108
Solution:
No. of 4 digits number formed = 4 !
So sum = 3! (3+4+5+6)
= 6 x 18
= 108
Q. 30
Option 1:
−2
Option 2:
Option 3:
Option 4:
2
Correct Answer:
−2
Solution:
Now use series expansion
Option 1:
6
Option 2:
3
Option 3:
7
Option 4:
Correct Answer:
3
Solution:
Using Property
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Hence, the required quadratic equation is
Q. 33 The two adjacent sides of a cyclic quadrilateral are 2 and 5 and the angle between them is
600. If the area of the
quadrilateral is then the perimeter of the quadrilateral is :
Option 1:
12.5
Option 2:
13.2
Option 3:
12
Option 4:
13
Correct Answer:
12
Solution:
As we have Learnt
Using concept ABDC, Cyclic quadrilateral (opp. angles are supplementary), and concept of properties
of triangle
Area of
Area of
now,
and
Also
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given function is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we leant in
Multiplication of matrices -
-
- wherein
so that
Q. 36 The solution of the differential equation
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given differential equation is
Q. 37 For if is a differentiable function such that
then y(x)
equals : (where C is a constant.)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Again differentiate
Solve the differential equation
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 39 For then
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
COMPOSITION OF FUNCTIONS -
-
Correct option is 2.
is equal to :
Correct Answer:
330
Solution:
As we learnt in
and
Now,
f(x) = ax2 + bx + c
a+b+c=3
Then
f(1) = a + b + c =3
f(1) =3
put x = 1, y = 1
f(2) = f(1) + f(1) + 1 1
=2f(1)+1
=2 3+1=7
put x=1, y = 2
f(3)= f(1)+f(2)+2 1
=3+7+2
=12
Let An2+Bn+C
At n =2: 7 = 4A+2B+C
At n =3: 12 = 9A+3B+C
1= 2A
B+C =
2B+C
=7-2 = 5
C=0
So
put n =10
= 330
Option 1:
Statement 1 is true ; Statement 2 is true ; Statement 2 is a correct explanation for Statement 1
Option 2:
Statement 1 is true; Statement 2 is true; Statement 2 is not a correct explanation for Statement 1
Option 3:
Statement 1 is false; Statement 2 is true.
Option 4:
Statement 1 is true ; Statement 2 is false.
Correct Answer:
Statement 1 is true; Statement 2 is true; Statement 2 is not a correct explanation for Statement 1
Solution:
Hence, there are two common solutions, there each of the statement- 1 and 2 are true but statement- 2
is not a correct explanation for statement-1.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
and
- wherein
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt
Intercept form -
- wherein
- wherein
is given by
where,
So,
Q. 44 If for positive integers , , the coefficients of the and powers of x
in the expansion of are equal,then n is equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 45 A bird is sitting on the top of a vertical pole 20 m high and its elevation from a point O on
the ground is 450. It flies off horizontally straight away from the point O.After one second,
the elevation of the bird from O is reduced to 300. Then the speed (in m/s) of the bird is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
The height or length of an object or the distance between two distant objects can be determined with the
help of trigonometric ratios.
-
Q. 46 Following is an infeassible solution for the linear programming model given below:
Maximize,
Subject to constraint
Constraint 2
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
This method of solving a LPP graphically is based on the principle of extreme points theorem.
-
At (1,3), it is maximum
2x−4y+3z=2,
then the shortest distance between this line and the line
is
Option 1:
2
Option 2:
1
Option 3:
0
Option 4:
3
Correct Answer:
0
Solution:
As we have learned
- wherein
So,
Where
So distance = 0
Q. 48
If the 7th term in the binomial expansion of , , is equal to 729,
then x can be :
Option 1:
Option 2:
e
Option 3:
Option 4:
Correct Answer:
e
Solution:
Given expansion is
Correct Answer:
3
Solution:
As we learnt in
Trigonometric Equations -
The equations involving trigonometric function of unknown angles are known as trigonometric
equations.
- wherein
e.g.
Q. 50 Three people P, Q and R independently try to hit a target. If the probabilities of their hitting
the target are respectively, then the probability that the target is hit by P or Q
but not by R is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Addition Theorem of Probability -
in general:
Independent events -
Two or more events are said to be independent if occurrence or non-occurrence of any of them does not
affect the probability of occurrence of or non - occurrence of other events.
P (P or Q not R) =
Option 1:
Statement I is true;Statement II is true;Statement II is a correct explanation for statement I.
Option 2:
Statement I is false; Statement II is true .
Option 3:
Statement I is true;Statement II is false.
Option 4:
Statement I is true;Statement II is true;Statement II is not a correct explanation for statement I.
Correct Answer:
Statement I is false; Statement II is true .
Solution:
Q. 52 Let k be an integer such that the triangle with vertices (k, −3k), (5, k) and (−k, 2) has area 28
sq. units. Then the value of k is
Option 1:
3
Option 2:
1
Option 3:
2
Option 4:
None of these
Correct Answer:
2
Solution:
Area = 28 sq units
or
Q. 53
The integral is equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
Since all variables must be converted into single variable ,
Differentiating,
Q. 54
if is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given equation is
Q. 56 The radius of a circle, having minimum area, which touches the curve y=4−x2
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
and concept
- wherein
This figure shows the circle with least area satisfying the conditions.
On rationalising,
Q. 57
is equal to
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt
Walli's Method -
where
- wherein
Q. 58 Two ships A and B are sailing straight away from a fixed point O along routes such that
AOB is always 1200. At a certain instance, OA = 8 km, OB = 6 km and the ship A is sailing at
the rate of 20 km/hr while the ship B sailing at the rate of 30 km/hr. Then the distance
between A and B is changing at the rate (in km/hr) :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
The height or length of an object or the distance between two distant objects can be determined with the
help of trigonometric ratios.
.......................... (2)
Q. 59 The eccentricity of an ellipse whose centre is at the origin is . If one of its directrices is x = −
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
We have
Directrix: x = - 4
So a = 2
Now,
Q. 60 A hyperbola passes through the point and has foci at (±2, 0).
Then the tangent to this hyperbola at P also passes through the point
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As foci lie on x-axis and mid-point of foci is th eorigin, so the equation of hyperbola can be assumed to
be
Focus is
Also we know,
Equation of hyperbola is
Physics
Q. 1
Focal length of a convex lens water is 40cm. Find its focal length in air. Given that
and
Option 1:
80 cm
Option 2:
5 cm
Option 3:
10 cm
Option 4:
40 cm
Correct Answer:
10 cm
Solution:
As we learn
Lensmaker's Formula -
- wherein
Option 1:
32 cm
Option 2:
2 cm
Option 3:
30 cm
Option 4:
4 cm
Correct Answer:
4 cm
Solution:
As we learn
- wherein
so
36
Q. 3 An object is placed between two plane morriors inclined at an angle of 600 the number of
image formed are
Option 1:
2
Option 2:
3
Option 3:
4
Option 4:
5
Correct Answer:
3
Solution:
as we learn
a) If even number
Number of image =
b) If odd number
Number of image =
b) If odd number
Number of image =
number of images=
Option 1:
real
Option 2:
virtual
Option 3:
real or virtual depending upon the distance of object from mirror
Option 4:
none of these
Correct Answer:
virtual
Solution:
as we learn
Image -
Point of convergence or apparent point of divergence of rays. Image can be real or virtual.
- wherein
The image formed will be virtual
Q. 5 An object of length 9 Cm is placed on the principal axis of a concave mirror of focal length 'F
' at a distance 4F the length of image will be
Option 1:
2 Cm.
Option 2:
3Cm
Option 3:
4Cm
Option 4:
5Cm
Correct Answer:
3Cm
Solution:
as we learn
Longitudinal magnification -
- wherein
Longitudinal magnification is used when object is placed along principal axis.
u = object distance
v = image distance
Q. 6
In the given digram the mirror and object is moving with speed 2 m/s
Option 1:
0 m/s
Option 2:
5 m/s
Option 3:
2 m/s
Option 4:
4 m/s
Correct Answer:
0 m/s
Solution:
AS we learn
Relation between object and image velocity if object is moving along principal axis -
= -
= -
- wherein
= velocity of light
= velocity of image
= velocity of mirror
Q. 7 If the speed of light in vacum 10 m/s then the velocity of light in a medium of refrective
index 1.3 is
Option 1:
Option 2:
Option 3:
C
Option 4:
Correct Answer:
Solution:
As we learn
Refractive index -
- wherein
Q. 8 If the dimensions of a physical quantity quantity are given by MaLbTc, then the physical
quantity will be:
Option 1:
Velocity if a=1, b=0,c=-1
Option 2:
Acceleration if a=1,b=1,c=-2
Option 3:
Force if a=0,b=-1,c=-2
Option 4:
Pressure if a=1,b=-1,c=-2
Correct Answer:
Pressure if a=1,b=-1,c=-2
Solution:
As we learnt in
Time period of a simple pendulum -
- wherein
Q. 9 In an experiment four quantities a, b, c and d are measured with percentage error 1%, 2%,
3% and 4% respectively. Quantity P is calculated as follows: % error in P is:
Option 1:
10%
Option 2:
7%
Option 3:
4%
Option 4:
14%
Correct Answer:
14%
Solution:
As we learnt in
Relative error /Fractional error -
- wherein
% error In P = 14%
Correct option is 2.
Option 1:
Option 2:
Option 3:
5 Units
Option 4:
9 Units
Correct Answer:
Solution:
Q. 11 The velocity of a projectile at the initial point A is m/s. Its velocity (in m/s) at point
B is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Equation of path -
it is equation of parabola
initial velocity
Angle of projection
- wherein
From Fig, x component remains unchanged, while the y component is Reverse, so velocity at point B will
be
Correct option is 4.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
20 m, 2s
Option 2:
40m, 3s
Option 3:
40m,5s
Option 4:
45m,5s
Correct Answer:
45m,5s
Solution:
Initially, the ball is thrown upward from the top of the building(point A)
For journey B to C:
After reaching the maximum point at B from A. the ball will reach eventually to point C
Q. 14 Displacement current is continuous
Option 1:
When electric field is changing in circuit
Option 2:
When magnetic field is changing
Option 3:
In both types
Option 4:
Through resistance and wires only
Correct Answer:
When electric field is changing in circuit
Solution:
As we learned
The total current (displacement conduction) going into the volume is equal to the total current coming
out of it.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learned,
- wherein
Q. 16 The decreasing order of wavelength of infrared, microwave, ultraviolate and gamma rays is
Option 1:
Microwave, infrared, ultraviolet, gamma rays
Option 2:
Gamma rays, ultraviolet, infrared, microwaves
Option 3:
microwaves, gamma rays, infrared, ultraviolet
Option 4:
infrared, microwave, ultraviolet, gamma rays
Correct Answer:
Microwave, infrared, ultraviolet, gamma rays
Solution:
As we learnt in
Micro Wave -
Frequency Range Hz to Hz
- wherein
Infrared Waves -
Frequency Range Hz to Hz
- wherein
Ultra-Violet Radiation -
Frequency Range Hz to Hz
- wherein
Frequency Range Hz to Hz
- wherein
Q. 17 Infinity number of the masses, each 1 kg , are placed along the X-axis at
. The magnitude of the resultant
gravitational potential in terms of gravitational constant G at the origin is . Then 'n'
will be :
Option 1:
4
Option 2:
2
Option 3:
8
Option 4:
0.5
Correct Answer:
4
Solution:
As we know
So, V= 4G
Hence n = 4.
Q. 18 A charge of Q coulomb is placed on a solid piece of metal of irregular shape. The charge will distribute
itself
Option 1:
Uniformly in the metal object
Option 2:
Uniformly on the surface of the object
Option 3:
Such that the potential energy of the system is minimised
Option 4:
Such that the total heat loss is minimised
Correct Answer:
Such that the potential energy of the system is minimised
Solution:
As we learned
Charge on a conductor -
Potential energy depends upon the charge at peaks of irregularities. Since every event in the universe leads to the
minimisation of energy
Q. 19 The acceleration of an electron in an electric field of magnitude 50 V/cm, if e/m value of the
electron is C/kg, is
Option 1:
Option 2:
Option 3:
Option 4:
Zero
Correct Answer:
Solution:
Option 1:
1.8 X 104 V
Option 2:
0
Option 3:
1.8 V
Option 4:
1.4 X 108 V
Correct Answer:
1.8 X 104 V
Solution:
The electric potential due to charged ring at its axial position is given by
Q. 21 Three charges are placed at the vertices of an equilateral triangle of side ‘a’ as shown in the following
figure. The force experienced by the charge placed at the vertex A in a direction normal to BC is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learned
- wherein
Hence force experienced by the charge at A in the direction normal to BC is zero.
Q. 22 Figure shows a solid hemisphere with a charge of 5 nC distributed uniformly throughout its
volume. The hemisphere lies on a plane and point P is located on the plane, along a radial
line from the centre of curvature at distance 15 cm. The electric potential (in Volt) at point P
due to the hemisphere, is :
Option 1:
150
Option 2:
300
Option 3:
450
Option 4:
600
Correct Answer:
300
Solution:
- wherein
By argument of symmetry, it will be half of the potential produced by the full sphere
Q Charge on hemisphere = Q,
so charge on sphere = 2Q
Q. 23 Two cars are moving in 2 perpendicular roads towards a crossing with speeds of 72 km/hr
and 36 km/hr. If first car blows horn of 280 Hz then frequency (in Hz) of horn heard by driver
of second car when line joining the car makes with roads, will be
Correct Answer:
298
Solution:
As we learnt in
- wherein
Option 1:
(30, 40, 40) cm
Option 2:
(20, 80, 10) cm
Option 3:
(60,30, 20) cm
Option 4:
(10, 60, 40) cm
Correct Answer:
(60,30, 20) cm
Solution:
As we learnt in
Sonometer -
It is a device used to measure the velocity of the transverse mechanical wave in a stretched wire.
- wherein
,
Q. 25 Two cities are 150km apart. Electric power is sent from one city to another city through
copper wires. The fall of potential per km is 8 volt and the average resistance per km is 0.5
. The power loss in the wires is:
Option 1:
19.2W
Option 2:
19.2kW
Option 3:
19.2J
Option 4:
12.2kW
Correct Answer:
19.2kW
Solution:
As we learnt in
Power loss=
Power loss=
Q. 26 The resistance in the two arms of the meter bridge are 5 and R , respectivilty. When the
resistance R is shunted with an equal resistance, the new balance point is at . The
resistance 'R' is:
Option 1:
10
Option 2:
15
Option 3:
20
Option 4:
25
Correct Answer:
15
Solution:
As we learnt in
Meter bridge -
To find the resistance of a given wire using a meter bridge and hence determine the specific resistance of
its materials
- wherein
Divide and
Or,
From equation
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we discussed in
Resistance of ammeter RA is
Q. 29 A potentiometer wire has length 4 m and resistance 8 ohm. The resistance that must be
connected in series with the wire and an accumulator of e.m.f. 2V, so as to get a potential
gradient 1 mV per cm on the wire is:
Option 1:
44 ohm
Option 2:
48 ohm
Option 3:
32 ohm
Option 4:
40 ohm
Correct Answer:
32 ohm
Solution:
As we learnt in
Potential gradient -
- wherein
internal resistance
So for 400 cm
Q. 30 A potentiometer wire of length L and a resistance r are connected in series with a battery of
e.m.f. E0 and a resistance r1. An unknown e.m.f. E is balanced at a length I of the
potentiometer wire. The e.m.f. E will be given by:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Current in the circuit having
since the balanced point is obtained at length I of the potentiometer wire, the emf of the cell E has to
match the voltage dropped in length I of the wire.
Q. 31 A galvanometer having a coil resistance of 60 shows full scale deflection when a current of
1.0 amp passes through it. It can be converted into an ammeter to read currents upto 5.0
amp by:
Option 1:
putting in series a resistance of 15
Option 2:
putting in series a resistance of 240
Option 3:
putting in parallel a resistance of 15
Option 4:
putting in parallel a resistance of 240
Correct Answer:
putting in parallel a resistance of 15
Solution:
Galvanometer is a very sensitive instrument therefore it cannot measure heavy currents. In order to
convert a Galvanometer into an Ammeter, a very low shunt resistance is connected in parallel to
Galvanometer. The value of shunt is so adjusted that most of the current pass through the shunt.
If the resistance of the galvanometer is and it gives full-scale deflection when current is passed
through it.
Then,
Let a shunt of resistance ( ) is connected in parallel to the galvanometer.
So option C is correct
(A) Radius of the muonic orbit is 200 times smaller than that of the electron.
(B) The speed of the in the orbit is times that of the electron in the orbit.
(C) The ionization energy of muonic atom is 200 times more than that of an hydrogen atom.
(D) The momentum of the muon in the orbit is 200 times more than that of the electron.
Option 1:
(A), (B), (D)
Option 2:
(A), (C), (D)
Option 3:
(B), (D)
Option 4:
(C), (D)
Correct Answer:
(A), (C), (D)
Solution:
As we learnt
and
- wherein
Option 2:
0.5 A0
Option 3:
0.75 A0
Option 4:
1.25 A0
Correct Answer:
0.5 A0
Solution:
As we learn
Continuous x-ray -
- wherein
Also called cutoff wavelength . All other wavelength are greater than this.
Q. 34 In x-ray diffraction first maxima occur at =300 then the wavelength of X-ray are
( ):
Option 1:
1
Option 2:
2
Option 3:
3
Option 4:
0.5
Correct Answer:
1
Solution:
Bragg's law -
= wavelength
Q. 35 If the Rydbarg's constant is R then the wave number in second brackett series is -
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learn
Brackett Series -
- wherein
Q. 36 In the Bohr's model of hydrogen - like atom the force between the nucleus and the electrons
is modified as,
Where is a constant . For the atom, the radius of the nth orbit in the terms of the Bohr
radius
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
So,
Q. 37 In the Davisson and Germer experiment, the velocity of electrons emitted from the electron
gun can be increased by
Option 1:
increasing the potential difference between the anode and filament
Option 2:
increasing the filament current
Option 3:
decreasing the filament current
Option 4:
decreasing the potential difference between the anode and filament
Correct Answer:
increasing the potential difference between the anode and filament
Solution:
As we learnt in
- wherein
Electron is accelerated by applying potential difference between anode & cathode hence velocity of
electron emitted from the electron gun can be increased by increasing potential difference between the
anode and the filament.
Q. 38 In photoelectric emission process from a metal of work function 1.8 eV, the kinetic energy of
most energetic electrons is 0.5 eV. The corresponding stopping potential is
Option 1:
1.8 V
Option 2:
1.2 V
Option 3:
0.5 V
Option 4:
2.3 V
Correct Answer:
0.5 V
Solution:
As we learnt in
It is defined as the potential necessary to stop any electron from reaching the other side.
Q. 39
A Carnot engine having an efficiency of as heat engine, is used as a refrigerator. If the
work done on the system is 10 J, the amount of energy absorbed from the reservoir at lower
temperature is :
Option 1:
1J
Option 2:
90 J
Option 3:
99 J
Option 4:
100 J
Correct Answer:
90 J
Solution:
As we learnt in
- wherein
are in kelvin
- wherein
Source temperature
Sink Temperature
= Coefficient of performance
Option 1:
1.5
Option 2:
2.5
Option 3:
2
Option 4:
1
Correct Answer:
1
Solution:
From eqn(1),
For monoatomic gas,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Potential at point A
Potential at point B
Potential difference
Q. 42 The mean free path of molecules of a gas, (radius 'r') is inversely proportional to:
Option 1:
r3
Option 2:
r2
Option 3:
r
Option 4:
Correct Answer:
r2
Solution:
As we learnt in
temperature
Boltzmann's Constant
Q. 43
The ratio of the specific heats in terms of degrees of freedom (n) is given by:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
f = degree of freedom
- wherein
f = degree of freedom
n= degree of freedom
is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As
Buoyant force-
V= Volume of the solid body immersed in the liquid or Volume of the fluid displaced
So
Q. 45 The total radiant energy per unit area, normal to the direction of incidence, received at a
distance R from the centre of a star of radius r, whose outer surface radiates as a black body
at a temperature T K is given by
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have leaqrned
Power of radiation
Option 1:
4.55
Option 2:
2.3
Option 3:
1.15
Option 4:
9.1
Correct Answer:
9.1
Solution:
As we learnt in
, ,
Q. 47 A long wire carrying a steady current is bent into a circular loop of one turn. The magnetic
field at the centre of the loop is B. It is then bent into a circular coil of n turns. The magnetic
field at the centre of this coil of n turns will be
Option 1:
nB
Option 2:
n2B
Option 3:
2nB
Option 4:
2n2B
Correct Answer:
n2B
Solution:
As we learnt in
- wherein
Option 1:
1 GHz
Option 2:
100 MHz
Option 3:
62.8 MHz
Option 4:
6.28 MHz
Correct Answer:
1 GHz
Solution:
As we learnt in
-
Frequency =
Q. 49 In a common emitter transistor amplifier the audio signal voltage across the collector is 3 V.
The resistance of collector is 3 . If current gain is 100 and the base resistance is 2 ,
the voltage and power gain of the amplifier is :
Option 1:
200 and 1000
Option 2:
15 and 200
Option 3:
150 and 15000
Option 4:
20 and 2000
Correct Answer:
150 and 15000
Solution:
As we learnt in
Amplifier -
- wherein
Voltage gain =
Power gain=
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
P -N junction as diode -
It is a one way device. It offers a low resistance when forward biased and high resistance when reverse
biased.
- wherein
R = 0, Forward
R Reverse
For forward biased P type should be at higher potential from the figure only 1 is in forward biased mode.
Correct option is 1.
Option 1:
AND gate
Option 2:
OR gate
Option 3:
NOR gate
Option 4:
NOT gate
Correct Answer:
NOR gate
Solution:
As we learnt in
NOR Gate -
NOT + OR Gate
- wherein
Y is out put
= =
Option 1:
a
Option 2:
b
Option 3:
c
Option 4:
d
Correct Answer:
a
Solution:
induced emf
During 0 to = constant
So, e =-ve
For to , =0
i.e., e=0
For to , = constant
i.e., e =+ve
Option 1:
10 mA
Option 2:
100mA
Option 3:
200mA
Option 4:
20mA
Correct Answer:
20mA
Solution:
As we learnt in
R.M.S. Value=
average value=
- wherein
Q. 54 A coil has resistance 30 ohm and inductive reactance 20 ohm at 50Hz frequency. If an ac
source, of 200volt, 100Hz, is connected across the coil, the current in the coil will be
Option 1:
4.0A
Option 2:
8.0A
Option 3:
Option 4:
2.0A
Correct Answer:
4.0A
Solution:
As we learnt in
Inductive reactance (XL) -
- wherein
Inductive reactance =
Then at 100Hz,
Q. 55 A 60 HP electric motor lifts an elevator having a maximum total load capacity of 2000 kg. If
the frictional force on the elevator is 4000N , then the speed of the elevator at full load is
close to: (1 HP=746 W, g=10 ms-2).
Correct Answer:
Solution:
Power -
Instantaneous power-
Where,
Fnet=(2000 x 10+4000)=24000 N
Q. 56 After perfectly elastic oblique collision of two bodies of equal masses (if the second body is
at rest), the scattering angle would be
Correct Answer: 90
Solution:
Along x-axis-
….. (1)
Along y-axis-
…..(2)
….(3)
And In Perfectly Elastic Oblique Collision
Value of e=1
We apply e=1
Special condition
We get,
i.e; after perfectly elastic oblique collision of two bodies of equal masses (if the second body
is at rest), the scattering angle would be .
So, answer is -
Q. 57 In case (i) plane is smooth and in case (ii) plane is rough. If the time taken by the block in
case (ii) to come down is 3 times to the time to come down in case (i) then the coefficient of
friction of plane in case (ii) is?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Length covered in both cases is same so for smooth wedge
Now
Solving
Q. 58 Calculate the acceleration of block of the following diagram. Assume all surfaces are
frictionless . Here m1 = 100kg and m2 = 50kg
Option 1:
0.33m/s2
Option 2:
0.66m/s2
Option 3:
1m/s2
Option 4:
1.32m/s2
Correct Answer:
1.32m/s2
Solution:
(i)
(ii)
Q. 59 Moment of inertia of a body about a given axis is . Initially the body is ate rest. In
order to produce a rotational kinetic energy of , the angular acceleration of
must be applied about the axis for a duration of :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given
Q. 60 A circular disc of radius b has a hole of radius a at its centre (see figure). If the mass per unit
area of the disc varies as , then the radius of gyration of the disc about its axis passing
through the centre is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Chemistry
Q. 1 A mixture of 100 m mol of and 2 g of sodium sulphate was dissolved in water
and the volume was made up to 100 mL .The mass of calcium sulphate formed and the
concentration of in resulting solution , respectively , are : (Molar mass of
, are 74, 143 and 136 g , respectively ;
)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
We know that
Q. 3 Solution of two components containing n1 moles of 1st component and n2 moles of 2nd
component is prepared, M1 and M2 are molecular weight of component 1 and 2
respectively. If d is the density of the solution in g mL-1, C2 is the molarity and x2 is the mole
fraction of 2nd component, C2 can be expressed as:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 4 The equivalent conductances of Ba2+ and Cl- are 63.5 ohm-1 cm2 eq-1 and 76 ohm-1 cm2 eq-
1,respectively, at infinite dilution. The equivalent conductance (in ohm-1 cm2) of BaCl at
2
infinite dilution will be:
Option 1:
101
Option 2:
239.5
Option 3:
203
Option 4:
139.5
Correct Answer:
139.5
Solution:
From Kohlrausch's Law :
Q. 5 The resistance of a 0.1 N solution of acetic acid is 250 when measured in a cell of cell
constant 1.15 cm-1. The equivalent conductance (in ohm-1 cm2 eq-1) of 0.1 N acetic acid is:
Option 1:
9.2
Option 2:
24.6
Option 3:
36.8
Option 4:
46
Correct Answer:
46
Solution:
Option 1:
0.295
Option 2:
-0.295
Option 3:
-0.59
Option 4:
0.59
Correct Answer:
-0.295
Solution:
Therefore,option(2) is correct
Q. 7 The number of atoms in 0.1 mol of a triatomic gas is (NA = 6.02 x1023 mol-1)
Option 1:
6.026 x 1022
Option 2:
1.806 x 1023
Option 3:
3.600 x 1023
Option 4:
1.800 x 1022
Correct Answer:
1.806 x 1023
Solution:
Option 1:
8 g H2
Option 2:
64 g SO2
Option 3:
44 g CO2
Option 4:
48 g O3
Correct Answer:
8 g H2
Solution:
No. of moles of H2
Q. 9 A mixture has 18 g water and 414 g of ethamol. The mole fraction of water in mixture is :
Option 1:
0.1
Option 2:
0.4
Option 3:
0.7
Option 4:
0.9
Correct Answer:
0.1
Solution:
As we learn
Mole Fraction -
Option 1:
0.1 M Nacl solution
Option 2:
0.1 M sugar solution
Option 3:
0.1 M BaCl2 solution
Option 4:
0.1 M Fecl3 solution
Correct Answer:
0.1 M sugar solution
Solution:
As we learn
Lesser the number of particles in solution, lesser the depression in freezing point, hence higher freezing
point.
Option 1:
0.1 M glucose
Option 2:
0.1 M Kcl
Option 3:
0.6% glucose soln
Option 4:
0.6 KCl solution
Correct Answer:
0.1 M glucose
Solution:
As we learn
Isotonic solutions -
- wherein
at constant Temp.
Q. 12 A certain compound gives a negative test with ninhydrin and positive test with Benedict's
solution. The compound is:
Option 1:
Protein
Option 2:
Monosaccharide
Option 3:
Lipid
Option 4:
An amino acid
Correct Answer:
Monosaccharide
Solution:
A compound which gives a negative test with ninhydrin, it cannot be a protein or an amino acid. As it
gives a positive test with Benedict's solution. So, it must be a monosaccharide but not a lipid.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Vitamin - Night blindness , Xerophthalmia
Vitamin (Thiamine) - Beriberi
Osteomalacia ( in adults )
Option 1:
6 molecules of ATP
Option 2:
18 molecules of ATP
Option 3:
10 molecules of ATP
Option 4:
8 molecules of ATP
Correct Answer:
18 molecules of ATP
Solution:
As we have learned in
Option 1:
2895 C
Option 2:
5040 C
Option 3:
1680 C
Option 4:
8467.2 C
Correct Answer:
2895 C
Solution:
Therefore,option(1) is correct
Assertion: Zn metal can displace Ag metal from a solution containing the complex ion [Ag(CN)2].
Option 1:
If both assertion and reason are true and reason is the correct explanation of assertion
Option 2:
If both assertion and reason are true but reason is not the correct explanation of assertion
Option 3:
If assertion is true but reason is false
Option 4:
If both assertion and reason are false
Correct Answer:
If assertion is true but reason is false
Solution:
As we learn
Electrochemical series -
The standard reduction potential of a large number of electrodes has been measured using standard
hydrogen electrode as the reference electrode. These various electrodes can be arranged in increasing
electrode potential.
Zn is more reactive metal than Ag. So it displaces less reactive. Ag metal from its salt solution.
Reduction potential of Ag+ is greater than that of Zn+2, hence Ag+ has higher tendency to get reduced to
Ag. Therefore reason is the false statement while Assertion is true.
Assertion : Conductivity always decreases with decrease in concentration for strong electrolyte.
Reason : The number of ions per unit volume that carry the current in a solution decreses on dilution.
Option 1:
If both assertion and reason are true and reason is the correct explanation of assertion
Option 2:
If both assertion and reason are true but reason is not the correct explanation of assertion
Option 3:
If assertion is true but reason is false
Option 4:
If both assertion and reason are false
Correct Answer:
If both assertion and reason are true and reason is the correct explanation of assertion
Solution:
As we learn
Conductivity -
- wherein
SI unit of Conductivity =
On increasing dilution (decreasing the concentration) the number of ions per unit volume that carry the
current in the solution decreases. Therefore conductivity always decreases with decrease in
concentration both for weak and strong electrolytes. Hence reason is the correct explanation for the
given assertion.
Option 1:
+3
Option 2:
+6
Option 3:
+5
Option 4:
+2
Correct Answer:
+3
Solution:
Option 1:
Same as primary valency
Option 2:
Sum of primary and secondary valencies
Option 3:
Same as secondary valency
Option 4:
None of these
Correct Answer:
Same as secondary valency
Solution:
According to Werner's theory, primary valency of complex compound is its oxidation number while
secondary valency is the co-ordination number.
Hence, the co-ordination number of any metal is the same as its secondary valency
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
is hybridised and thus has a square planar structure
Option 1:
Molality
Option 2:
Molarity
Option 3:
Mole fraction
Option 4:
Weight percentage
Correct Answer:
Molarity
Solution:
As we learned in
Option 2 is correct.
Q. 22 Given the reaction between 2 gases represented by and to give the compound
.
If the reaction takes place in a sealed vessel at , then the value of Kc will be:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Law of Chemical equilibrium -
At a given temperature, the product of the concentration of the reaction products raised to the
respective stoichiometric coefficient in the balanced chemical equation divided by the product of the
concentration of the reactants raised to their individual stoichiometric coefficients has a constant value.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 24 Equimolar solutions of the following substances were prepared separately. Which one of
these will record the highest pH value?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Value of pH -
For all the species except BaCl2, pH will be lower than 7 because they are salt of a weak base and strong
acid.
is a salt of a strong base and strong acid so, its pH will be 7, the highest.
Option 1:
These give unionized acid or base on reaction with added acid or alkali.
Option 2:
Acids and alkalies in this solution are shielded from attack by other ions.
Option 3:
They have large excess of ions.
Option 4:
They have a fixed value of pH.
Correct Answer:
These give unionized acid or base on reaction with added acid or alkali.
Solution:
Buffer Solutions - The solutions which resist change in pH on dilution or with the addition of small
amounts of acid or alkali are called buffer solutions.
Buffer solutions resist a change in pH because they react with any added acid or base to give a salt.
Option 1:
On passing through acidified solution, a milky colour is observed
Option 2:
is preferred over in volumetric analysis
Option 3:
solution in acidic medium is orange
Option 4:
solution becomes yellow on increasing the pH beyond 7
Correct Answer:
is preferred over in volumetric analysis
Solution:
A hygroscopic substance is one that readily attracts water from its surroundings, through either
absorption or adsorption.
Option 1:
They have higher melting points than pure metal.
Option 2:
They retain metallic conductivity.
Option 3:
They are chemically reactive.
Option 4:
They are much harder than the pure metal.
Correct Answer:
They are chemically reactive.
Solution:
Formation of Interstitial Compounds -
Interstitial compounds are those which are formed when small atoms like H, C, or N are trapped inside
the crystal lattices of metals. They are usually nonstoichiometric and are neither typically ionic nor
covalent, for example, TiC, Mn4N, Fe3H, VH0.56, and TiH1.7, etc. The formulas quoted do not, of course,
correspond to any normal oxidation state of the metal. Because of the nature of their composition, these
compounds are referred to as interstitial compounds. The principal physical and chemical characteristics
of these compounds are as follows:
(i) They have high melting points, higher than those of pure metals.
(ii) They are very hard, some borides approach diamonds in hardness.
(iii) They retain metallic conductivity.
(iv) They are chemically inert.
Interstitial compounds are chemically unreactive, much harder than pure metal, they have a higher
melting point than pure metal, and retain metallic conductivity.
Q. 28 The products obtained when chlorine gas reacts with cold and dilute aqueous NaOH are :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
(Cold)
Correct Answer:
-1366.95
Solution:
Q. 30 The standard enthalpy of formation of NH3 is -46.0 kJ/mol. If the enthalpy of formation of H2
from its atoms is -436 kJ/mol and that of N2 is -712 kJ/mol, the average bond enthalpy (in
kJ/mol) of N-H bond in NH3 is :
Correct Answer:
352
Solution:
Correct Answer:
-23.03
Solution:
Entropy for isobaric process -
Q. 32 Which one of the following orders is correct for the bond dissociation enthalpy of halogen
molecules
Option 1:
I2 > Br2 > Cl2 > F2
Option 2:
Cl2 > Br2 > F2 > I2
Option 3:
Br2 > I2 > F2 > Cl2
Option 4:
F2 > Cl2 > Br2 > I2
Correct Answer:
Cl2 > Br2 > F2 > I2
Solution:
Bond strength -
The energy required to break one mole of bonds of particular type in gaseous state is called bond energy
or bond strength.
- wherein
The same amount of energy is released in formation of one mol of particular bond.
Bond dissociation enthalpies of halogen family decreases down the group as the size of atom increases.
The bond dissociation enthalpy of fluorine, is however, lower than those of chlorine and bromine
because of inter electronic repulsion present in small atoms of flourine.
Option 1:
lone pair - lone pair > lone pair - bond pair > bond pair - bond pair
Option 2:
lone pair - lone pair > bond pair - bond pair > lone pair - bond pair
Option 3:
bond pair - bond pair > lone pair - bond pair > lone pair - lone pair
Option 4:
lone pair - bond pair > bond pair - bond pair > lone pair - lone pair
Correct Answer:
lone pair - lone pair > lone pair - bond pair > bond pair - bond pair
Solution:
VSEPR Theory -
1. The shape of the molecule is determined by repulsions between all of the electron pair present in
valence shell.
2. Order of repulsion
3 Repulsion among the bond pair is directly proportional to the bond order and electronegativity
difference between the central atom and the other atom.
-
According to VSERPR theory the repulsive forces between lone pair are greater than between lone pair
and bond pair which are further greather than bond pair and bond pair.
Q. 34 Match the compounds given in column I with the hybridization and shape given in column
II and mark the correct option.
Column I Column II
Code:
Option 1:
(i) (iii) (iv) (ii)
Option 2:
(i) (ii) (iv) (iii)
Option 3:
(iv) (iii) (i) (ii)
Option 4:
(iv) (i) (ii) (iii)
Correct Answer:
(i) (iii) (iv) (ii)
Solution:
VSEPR Theory -
1. The shape of the molecule is determined by repulsions between all of the electron pair present in
valence shell.
2. Order of repulsion
3 Repulsion among the bond pair is directly proportional to the bond order and electronegativity
difference between the central atom and the other atom.
distorted octahedron
pyramidal
square pyramidal
square planar
Option 1:
Yb2+
Option 2:
Ce2+
Option 3:
Sm2+
Option 4:
Eu2+
Correct Answer:
Yb2+
Solution:
The electron configuration of Yb is [Xe] 4f14,6s 2 and due to no unpaired electrons in Yb2+ it is
diamagnetic.
Option 1:
CH2=CHCH2CH=CHCH3
Option 2:
CH2=CHCH=CHCH2CH3
Option 3:
CH3CH=C=CHCH2CH3
Option 4:
CH3CH=CH−CH=CHCH3
Correct Answer:
CH3CH=CH−CH=CHCH3
Solution:
Conjugated alkene in which double bonds are more substituted is the major product. When
dibromoalkane is heated with CH3OH/KOH, it undergoes dehydrohalogentation. Two molecules
of HBr are eliminated to form alkadiene.
Q. 37 The entropy (So) in (JK-1mol-1) of the following substances are :
Correct Answer:
-312.7
Solution:
Given reaction
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt ,
- wherein
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Correct option Co2
Option 4 is correct.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
both Sc and Zn do not exhibit variable oxidation states
Option 2:
both and ions are colourless and form white compounds
Option 3:
in case of orbitals are partially filled but in Zn these are completely filled
Option 4:
last electron is assumed to be added to 4s level in case of Zn
Correct Answer:
in case of orbitals are partially filled but in Zn these are completely filled
Solution:
Transition Elements -
The elements in which second last shell is incompletely filled called Transition elements.
- wherein
Transition elements are those in which second last shell is incompletely filled.
In , the config is
wheareas in config is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
– When HX is in excess
- wherein
Q. 43 Raising the concentration of a particular reactant by a factor of 5 increases the reaction rate
25 times. What is the kinetic order of this reactant?
Option 1:
2
Option 2:
0
Option 3:
1
Option 4:
3
Correct Answer:
2
Solution:
Let the reaction rate -
Raising the concentration of a particular reactant by a factor of 5 increases the reaction rate 25 times.
Q. 44 If k1 and k2 are the rate constants at temperature T1 and T2 then which of the following
relation holds good?
Option 1:
Option 2:
Option 3:
Option 4:
None of above
Correct Answer:
Solution:
We have the rate constant K1 at temperature T1 and rate constant K2 at temperature T2.
Option 1:
180
Option 2:
900
Option 3:
300
Option 4:
120
Correct Answer:
900
Solution:
We know this for first-order reactions-
So, half-lives
Then,
t = 900 sec
Q. 46 If 50% of a reaction occurs in 100 second and 75% of the reaction occurs in 200 second, the
order of this reaction is :
Correct Answer:
1
Solution:
If 50% of a reaction occurs in 100 second and 75% of the reaction occurs in 200 second -
Ans = 1
Q. 47 If the shortest wavelength in Lyman series of hydrogen atom is A, then the longest
wavelength in Paschen series of He+ is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
we know that,
Q. 48 Which one of the following is the wrong statement?
Option 1:
The uncertainty principle is:
Option 2:
Half filled and fully filled orbitals have greater stability due to greater exchange energy, greater
symmetry and more balanced arrangement.
Option 3:
The energy of 2s orbital is less than the energy of 2p orbital in case of Hydrogen-like atoms.
Option 4:
de-Broglie's wavelength is given by
where m=mass of the particle , v=group velocity of the particle
Correct Answer:
The energy of 2s orbital is less than the energy of 2p orbital in case of Hydrogen-like atoms.
Solution:
As we learnt in
Option 1:
H+
Option 2:
Li+
Option 3:
Na+
Option 4:
Mg2+
Correct Answer:
Li+
Solution:
Isoelectronic species are those which have an equal number of electrons present in them.
Q. 50 The most suitable method of separation of 1:1 mixture of ortho and para-nitrophenols is:
Option 1:
Chromatography
Option 2:
Crystallisation
Option 3:
Steam distillation
Option 4:
Sublimation
Correct Answer:
Steam distillation
Solution:
Steam Distillation -
This method is used to separate substances which are steam volatile and are immiscible with water.
- wherein
Steam distillation is the most suitable method of separation of 1: 1 mixture of ortho and para
nitrophenols as there are intramolecular H-bonds in ortho nitrophenol.
Option 1:
a,c
Option 2:
a,d
Option 3:
b,c
Option 4:
b,d
Correct Answer:
b,c
Solution:
As we have learned
In a neutral medium, it converts into hydroxylamine {Reagent Zn + NH4Cl } and in the basic medium, it
converts to azobenzene { Reagent Zn + NaOH }
- wherein
In the neutral medium, it converts to hydroxylamine and in basic medium, it converts to azobenzene.
Option 1:
Reduction of group to
Option 2:
yellow precipitate
Option 3:
Fehling's test
Option 4:
White precipitate
Correct Answer:
Reduction of group to
Solution:
As we have learned
The ethanolic solution of nitrobenzene is treated with zinc dust and solution. The mixture is
heated and filtered in a test tube containing Tollen's reagent. A grey or black precipitate ( Ag mirror ) is
formed.
In the test is reduced to group. Hydroxylamine group then reduces the fehlings
reagent and gets oxidised to nitroso compound
Option 1:
ribose sugar and thymine
Option 2:
ribose sugar and uracil
Option 3:
deoxyribose sugar and thymine
Option 4:
deoxyribose sugar, and uracil.
Correct Answer:
ribose sugar and uracil
Solution:
As we learned, Ribonucleic acid (RNA) -
It is made up of nucleotides consisting of pentose sugar which is ribose, Phosphoric acid and
bases (Adenine , Guanine , cytosine and uracil)
Option 1:
1.7700
Option 2:
0.1770
Option 3:
0.0177
Option 4:
0.0344
Correct Answer:
0.0177
Solution:
1.00 molal solution means 1 mole of solute in 1 kg (or 1000 g) of water.
Option 1:
0.1770
Option 2:
0.0177
Option 3:
0.0344
Option 4:
1.7700
Correct Answer:
0.0177
Solution:
As we learnt in
Given,
Q. 56 A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H2SO4. The evolved
gaseous mixture is passed through KOH pellets. Weight (in g) of the remaining product at
STP will be
Option 1:
2.8
Option 2:
3.0
Option 3:
1.4
Option 4:
4.4
Correct Answer:
2.8
Solution:
As we learnt in
Option 1:
0.00224 L of water vapours at 1 atm and 273 K
Option 2:
0.18 g of water
Option 3:
18 mL of water
Option 4:
10-3 mol of water
Correct Answer:
18 mL of water
Solution:
We know that,
If the mass of water is maximum then the mole will be maximum hence number of molecules of water
will be maximum.
Now,
B) 0.18 g of water
So 18 g = 18 ml
Q. 58 Which of the following arrangements represents the correct order of least negative to most
negative electron gain enthalpy for C, Ca, Al, F, O?
Option 1:
Ca < Al < C < O < F
Option 2:
Al < Ca < O < C < F
Option 3:
Al < O < C < Ca < F
Option 4:
C < F < O < Al < Ca
Correct Answer:
Ca < Al < C < O < F
Solution:
As we learnt
Electron gain enthalpy increases along the period as the attraction between incoming electron and the
nucleus increases or Zeff Increases.
Q. 59 Which one of the following will give 2 different types of alcohol upon reduction ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt ,
- wherein
Q. 60 When phenyl magnesium bromide reacts with tert. butanol , which of the following is
formed?
Option 1:
Tert. butyl methyl ether
Option 2:
Benzene
Option 3:
Tert. butyl benzene
Option 4:
Phenol
Correct Answer:
Benzene
Solution:
As we learnt,
Zerewitinoff Method -
- wherein
Maths
Q. 1 An eight digit number divisible by 9 is to be formed using digits from 0 to 9 without
repeating the digits. The number of ways in which this can be done is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Here, 0+1+2+......+9= 45, which is divisible by 9
Now we have to select 8 digits to form an 8-digit number, which means we have to reject 2 no.s while
keeping the sum divisible by 9
2) If other 4 sets are rejected, we can form numbers in 7 (7!) (0 can't be at first place)
Q. 2 If
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
x = a and x = b is
- wherein
Where
and
Area
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 5 If the tangent at a point P, with parameter t, on the curve x = 4t2 + 3, y = 8t3 − 1, t R, meets
the curve again at a point Q, then the coordinates of Q are :
Option 1:
( t2 + 3, −t3 −1 )
Option 2:
( 4t2 + 3, −8t3 −1 )
Option 3:
( t2 + 3, t3 − 1 )
Option 4:
( 16t2 + 3, −64t3 −1 )
Correct Answer:
( t2 + 3, t3 − 1 )
Solution:
As learnt in concept @MNOP
and
at P;
Tangent at P is
We get
Hence
Hence, Q = ( t2 + 3, t3 −1 )
Q. 6
Let then log p
is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
It is form
Q. 7 If S is the set of distinct values of ‘b’ for which the following system of linear equations
x+y+z=1
x+ay+z=1
ax+by+z=0
Option 1:
an infinite set
Option 2:
a finite set containing two or more elements
Option 3:
a singleton
Option 4:
an empty set
Correct Answer:
an empty set
Solution:
As we leant in
When and ,
- wherein
and
=a - b - 1 + a + b - a2 = 0
=> 2a - 1 -a2 =0
=> a2- 2a +1 =0
=> (a - 1)2 = 0
=> a = 1
It is independent of b
Q. 8 If a curve passes through the point and satisfies the differential
equation, then
is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Q. 9
The integral
is equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
Let
Thus I=
Q. 10 A wire of length 2 units is cut into two parts which are bent respectively to form a square of
side=x units and a circle of radius=r units. If the sum of the areas of the square and the
circle so formed is minimum, then :
Option 1:
2x = (π+4) r
Option 2:
(4−π) x = πr
Option 3:
x = 2r
Option 4:
2x = r
Correct Answer:
x = 2r
Solution:
As we learnt in
Circle -
A circle is the locus of a moving point such that its distance from a fixed point is constant.
- wherein
and
r is radius of circle
sum of Areas
of
Hence
Q. 11 In a certain town, 25% of the families own a phone and 15% own a car ; 65% families own
neither a phone nor a car and 2,000 families own both a car and a phone. Consider the
following three statements :
Then,
Option 1:
Only (a) and (b) are correct.
Option 2:
Only (a) and (c) are correct.
Option 3:
Only (b) and (c) are correct
Option 4:
All (a), (b) and (c) are correct.
Correct Answer:
All (a), (b) and (c) are correct.
Solution:
Let P denote families owning a phone, C denote families owning a car
100 - n(P ∪ C) = 65
35 = 25 + 15 - n(P ∩ C)
n(P ∩ C) = 5%
So, 5% of x = 2,000
5x/100 = 2,000
x = 40,000
So, total 40000 families live in this town (statement (c) is correct)
Option 1:
270
Option 2:
258
Option 3:
342
Option 4:
216
Correct Answer:
216
Solution:
As we have learned
Now,
But given
Q. 13 if then is equal to :
Correct Answer:
2
Solution:
As we have learnt,
Now,
Q. 14 Let be three vectors such that
.
is equal to
Correct Answer:
3
Solution:
Q. 15 8 - digit numbers are formed using the digits 1, 1, 2, 2, 2, 3, 4, 4. The number of such
numbers in which the odd digits do not occupy odd places, is :
Option 1:
160
Option 2:
120
Option 3:
60
Option 4:
48
Correct Answer:
120
Solution:
Odd nos - 1,1,3
1,1,3 can come at any of the 4 even places (2nd, 4th, 6th and 8th)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Q. 17
For x>0,let
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
Q. 18
If z is a complex number such that then the minimum value of
Option 1:
is strictly greater than
Option 2:
is strictly greater than but less than
Option 3:
is equal to
Option 4:
lies in the interval (1, 2)
Correct Answer:
lies in the interval (1, 2)
Solution:
As we have learned
Hence,
meets the coordinate axes at A and B, (A ≠ B), then the locus of the midpoint of AB is :
Option 1:
6xy = 7(x + y)
Option 2:
4( x + y )2 − 28( x + y ) + 49=0
Option 3:
7xy = 6( x + y )
Option 4:
14( x + y )2 − 97( x + y ) + 168 = 0
Correct Answer:
7xy = 6( x + y )
Solution:
As we have learned
Section formula -
- wherein
- wherein
Family of lines
Now for x = 0
This (h,k ) satisfies
at is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
is the distance from the line .
- wherein
slope
at
Slope of normal =
equation of normal
= 2 units
Q. 21
If and
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
Transpose of a Matrix -
The matrix obtained from any given matrix , by interchanging its rows and columns.
- wherein
Multiplication of matrices -
2015 times
Now , if
so , .
Option 1:
0
Option 2:
1
Option 3:
-1
Option 4:
2
Correct Answer:
0
Solution:
=8 - 8 - 13 log | 2 | + 13 log 2 = 0
Hence, y(-4) = 0.
Q. 23 The area (in square units) of the region bounded by the curves y + 2x2 = 0 and y + 3x2 = 1 , is
equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Let be two curve then area bounded between the curves and the lines
x = a and x = b is
- wherein
Where
y+2x2=0; y+3x2=1
y= -2x2; y=1-3x2
-2x2= 1-3x2
=> x2=1
=> x= 1
=>
=>
Correct Answer:
-1
Solution:
Rolle's Theorems
3. f(a) = f(b)
Now,
It is continuous and differentiable in any interval as it is a polynomial, hence it is continuous in [-1,1] and
differentiable in (-1,1)
Also
b = 1/2
So,
Q. 25 Let A = {x1,x2,x3......,x7} and B = { y1 ,y2 ,y3 } be two sets containing seven and three distinct
elements respectively. Then the total number of functions : A B that are onto, if there
exist exactly three elements x in A such that (x) = y2, is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Since if there exist exactly three elements x in A. which give single image y2. If means four elements of A
will give image of y1 and y3. So that (24 - 2) of .
Correct option is 4.
Q. 26 Let a1, a2, a3, ......, an, ..... be in A.P. If a3 + a7 + a11 + a15 = 72, then the sum of its first 17
terms is equal to :
Option 1:
306
Option 2:
153
Option 3:
612
Option 4:
204
Correct Answer:
306
Solution:
Given that
Q. 27 The angle of elevation of the top of a vertical tower from a point P on the horizontal ground
was observed to be . After moving a distance 2 metres from P towards the foot of the
tower, the angle of elevation changes to . Then the height of the tower (in metres) is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Now, PQ=2
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
..............(i)
Also here,
Put in (i)
Q. 29 The number of ways of selecting 15 teams from 15 men and 15 women, such that each team
consists of a man and a woman, is
Option 1:
1120
Option 2:
15!
Option 3:
1880
Option 4:
None of these
Correct Answer:
15!
Solution:
Let us fix men (M1, M2, ......,M15), and pair them with women
......
Q. 30 Let the tangents drawn to the circle, x2+y2=16 from the point P(0, h) meet the x-axis at points
A and B. If the area of is minimum, then h is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Maxima Minima -
A functions graph follow up and down along x-axis then upper part is known as maxima and lower part is
known as minima.
Q. 31
If where C is a constant, then g(2) is equal
to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
Put
So,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
- wherein
- wherein
Also
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Parametric form -
- wherein
Where is the inclination of the line and is the distance between and
- wherein
slope
- wherein
So,
Line Required
Correct Answer:
3
Solution:
As we learnt in
equation, in the
interval is
Correct Answer: 2
Solution:
As we leant in
When and ,
- wherein
and
C1 C1+C2+C3
Q. 36 The solution of the differential equation if
is equal to :
Correct Answer:
3
Solution:
As we learnt in
- wherein
Put & Q = 2y
Its solution is
2+1=x
x=3
Correct Answer:
100
Solution:
As learnt in concept
- wherein
Hence
Q. 38 The equation of a normal to the curve,
at x = 0, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Use the concept of
Equation of Normal -
Equation of normal to the curve y = f(x) at the point P(x1, y1) on the curve having a slope MN is
Put x = 0
Q. 39 Let A and B be two sets containing four and two elements respectively. Then the number of
subsets of the set A x B, each having at least three elements is :
Correct Answer:
219
Solution:
As we learnt in
SUBSETS -
- wherein
{ae},{af},{be},.......{df}
Similarly
{af,be},{af,bf}..........= 6 elements
28 + 8+1 = 37
Correct option is 1.
Q. 40 If the 2nd, 5th and 9th terms of a non-constant A.P. are in G.P., then the common ratio of this
G.P. is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
A, B, C are in G.P where A, B, C are 2nd, 5th and 9th terms of an A.P
For AP, let first term is a and common difference is d, and for GP first term is G and common ratio be r
then
A = a+d = G
B = a+4d = Gr
C= a+8d = Gr2
Now,
Q. 41 Statement I : The equation has a solution for all
Option 1:
Both statements I and II are true.
Option 2:
Both statements I and II are false.
Option 3:
Statement I is true and statement II is false.
Option 4:
Statement I is false and statement II is true.
Correct Answer:
Statement I is false and statement II is true.
Solution:
As we learnt in
When
However, this is an insufficient condition as sin-1 x is between which will impose additional
constraints.
Not true
Statement 2: (true)
Hence,
Q. 42 Let be three non-zero vectors such that no two of them are collinear and
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
- wherein
Thus
Q. 43 The distance of the point (1, 3, −7) from the plane passing through the point (1, −1, −1),
having normal perpendicular
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
is given by
5-7-3=C=-5
So plane is 5x+7y+3y+5=0
distance from (1,3,-7) is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
r = 10
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Also,
Maximize ,
Subject to constraint
Constraint
Option 1:
4
Option 2:
5
Option 3:
7
Option 4:
None
Correct Answer:
5
Solution:
As we learnt in
Objective Function -
Linear function Z = ax + by, where a, b are constants which has to be maximized or minimized.
- wherein
Ex. Z = 2x + 5y
Z= 3+2 1=3+2=5
Q. 47 The plane which bisects the line joining the points and at right angles
also passes through the point :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
Now,
coeff of
coeff of
and
and
a = 16
b = 272/3
Q. 49
if then is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Number of throws = 8
Let 'getting at least one head' be represented by A, and 'getting at least one tail' be represented by B
= P (A ∩ B)
= 1 - P ((A ∩ B)')
Now A' means getting no Head (all tails) and B' means getting no Tails (all heads)
Q. 51 Let be a complex number. Then the set of all complex numbers z satisfying
the equation for some real number k, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
- wherein
- wherein
Now,
And
Q. 52 A circle passes through (−2, 4) and touches the y - axis at (0, 2). Which one of the following
equations can represent a diameter of this circle ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Since circle touches x=0 at the point (0, 2), so let the equation of circle be
It passes through
Thus,
Equation of circle is
Out of the given options, the line in option (B) satisfies this point, hence it is a diameter if the given circle
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
Q. 54
If is the arithmetic mean of
and , then
is equal to :
Correct Answer:
1.4
Solution:
As we learnt in
where-in
Therefore,
dividing (2) by (1), we get
Thus,
Q. 55 If equations
, and
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
&
- wherein
- wherein
&
So , non real roots which means both roots are common (as complex roots occurs in conjugate )
Option 1:
7
Option 2:
-7
Option 3:
5
Option 4:
-5
Correct Answer:
-7
Solution:
As we learnt in
Equation of directrices -
- wherein
or
for Hyperbola
Also
Also,
Q. 57
The integral
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
=>
If
Q. 58 Let 10 vertical poles standing at equal distances on a straight line, subtend the same angle
of elevation at a point O on this line and all the poles are on the same side of O. If the
height of the longest pole is ‘h’ and the distance of the foot of the smallest pole from O is ‘a’,
then the distance between two consecutive poles is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
For all poles to subtend the same angle, the longest pole must be farthest, smallest pole must be nearest,
while all other poles are arranged in ascending order of height. Let distance between 2 cosecutive poles
be x. Then,
In,
..............( 1 )
Q. 59 A ray of light is incident along a line which meets another line, 7x − y + 1 = 0, at the point (0,
1). The ray is then reflected from this point along the line, y + 2x = 1. Then the equation of
the line of incidence of the ray of light is :
Option 1:
41x − 38y + 38 = 0
Option 2:
41x + 25y − 25 = 0
Option 3:
41x + 38y − 38 = 0
Option 4:
41x − 25y + 25 = 0
Correct Answer:
41x − 38y + 38 = 0
Solution:
Option 1:
2:3
Option 2:
1:2
Option 3:
4:1
Option 4:
3:4
Correct Answer:
4:1
Solution:
Given equation of the lien are
4x + 3y = 10
and 8x + 6y + 5 = 0
Physics
Q. 1 Two coherent sources of light can be obtained by
Option 1:
Two different light source
Option 2:
Two different light source but of same power
Option 3:
Two different light source of same colour
Option 4:
None of the above
Correct Answer:
None of the above
Solution:
As we learn
Coherent Source -
- wherein
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learn
- wherein
Phase difference
Path Difference
Wavelength
Q. 3 When a biconvex lens of glass having refractive index 1.47 is dipped in a liquid, it acts as a
plane sheet of glass. This implies that the liquid must have refractive index:
Option 1:
equal to that of glass
Option 2:
less than one
Option 3:
greater than that of glass
Option 4:
less than that of glass
Correct Answer:
equal to that of glass
Solution:
As we learnt in
Lensmaker's Formula -
- wherein
This can happen only when the refractive index of liquid is equal to refractive index of lens.
Q. 4 A ray of light is incident at an angle of incidence i, on one face of prism of angle A (assumed
to be small) and emerges normally from the opposite face. If the refractive index of the
prism is , the angle of incidence i is nearly equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 5 A concave mirror of focal length 'f1' is placed at a distance of 'd' from a convex lens of focal
length 'f2'. A beam of light coming from infinity and falling on this convex lens - concave
mirror combination returns to infinity. The distance 'd' must equal:
Option 1:
f1+f2
Option 2:
-f1+f2
Option 3:
2f1+f2
Option 4:
-2f1+f2
Correct Answer:
2f1+f2
Solution:
As we learnt in
Mirror Formula -
- wherein
- wherein
For final image to return to infinity, the first image must be centre of curvature of mirror. Hence distance
of image I from the mirror must be equal to
Correct option 3.
Q. 6 The magnifying power of a telescope is 9. When it is adjusted for parallel rays the distance
between the objective and eyepiece is 20 cm. The focal length of lenses are:
Option 1:
10 cm, 10 cm
Option 2:
15 cm, 5 cm
Option 3:
18 cm, 2 cm
Option 4:
11 cm, 9 cm
Correct Answer:
18 cm, 2 cm
Solution:
As we learnt in
Astronomical Telescope -
- wherein
magnifying power =
Also
Q. 7 In Young's double slit experiment, the slits are 2 mm apart and are illuminated by photons
of two wavelengths 1 = 12000 and 2 = 10000 . At what minimum distance from the
common central bright fringe on the screen 2 m from the slit will a bright fringe from one
interference pattern coincide with a bright fringe from the other?
Option 1:
3 mm
Option 2:
8 mm
Option 3:
6 mm
Option 4:
4 mm
Correct Answer:
6 mm
Solution:
As we learnt in
Fringe Width -
- wherein
Distance of
Maxima
Distance of
maxima
let mth bright fringe of first will concide with nth bright fringe of other
Maxima
Q. 8 The density of material in CGS system of units is 4g/cm3. In a system of units in which unit of
length is 10 cm and unit of mass is 100g, the value of density of material will be
Option 1:
0.4
Option 2:
40
Option 3:
400
Option 4:
0.04
Correct Answer:
40
Solution:
As we learnt in
Option 1:
Young's modulus and energy
Option 2:
Impulse and surface tension
Option 3:
angular momentum and work
Option 4:
work and torque
Correct Answer:
work and torque
Solution:
As we learnt in
Dimension -
The power to which fundamental quantities must be raised in order to express the given physical
quantities.
Option 1:
0
Option 2:
1
Option 3:
A
Option 4:
1+A
Correct Answer:
0
Solution:
As we have learned
-
We know 1+A=1 always, hence the output of OR gate would be always 1, irrespective of any value of A
1 A OR
1 0 1
1 1 1
Similarly
We know that output of AND gate is zero, if atleast one input to AND gate is zero.
A 0 AND
1 0 0
0 0 0
Hence X=0
Q. 11 A bus is moving with a speed of 10ms-1 on a straigth road. A scooterist wishes to overtake
the bus in 100s. If the bus is at a distance of 1km from the scooterist, with what speed
should the scooterist chase the bus?
Option 1:
40ms-1
Option 2:
25ms-1
Option 3:
10ms-1
Option 4:
20ms-1
Correct Answer:
20ms-1
Solution:
As we learnt in
Case of Relative velocity. -
When A and B are moving along a straight line in the same direction.
= Velocity of object A.
= Velocity of object B.
Relative velocity of A wr to B is
- wherein
a)
= (20 - 5) ms-1
= 15 ms-1
b)
= (5 - 20) ms-1
= - 15 ms-1
Q. 12 A student measures the distance traversed in free fall of a body, initially at rest in a given time. He
uses this data to estimate g, the acceleration due to gravity. If the maximum percentage errors in
the measurement of the distance and the time are e1 and e2 respectively, the percentage error in
the estimation of g is
Option 1:
e 2 - e1
Option 2:
e1 + 2e2
Option 3:
e 1 + e2
Option 4:
e1 - 2e2
Correct Answer:
e1 + 2e2
Solution:
Q. 13 The speed of a projectile at its maximum height is half of its initial speed. The angle of
projection is
Option 1:
60°
Option 2:
15°
Option 3:
30°
Option 4:
45°
Correct Answer:
60°
Solution:
Q. 14 An eletromagnetic wave of frequency v=3.0 MHz passes from vacuum into a dielectric
medium with relative permittivity . Then
Option 1:
wavelength is doubled and frequency is unchanged
Option 2:
wavelength is doubled and frequency becomes half
Option 3:
wavelength is halved and frequency remains unchanged
Option 4:
wavelength and frequency both remain unchanged
Correct Answer:
wavelength is halved and frequency remains unchanged
Solution:
As we learnt in
Wavelength of EM Wave -
- wherein
= Wavelength in vacuum
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Momentum of EM wave -
- wherein
u = Energy of EM wave
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Momentum of EM wave -
- wherein
u = Energy of EM wave
For a photon E = pC
momentum transferred
Q. 17 The height at which the weight of a body becomes 1/16th, its weight on the surface of Earth
(radius R), is:
Option 1:
5R
Option 2:
15R
Option 3:
3R
Option 4:
4R
Correct Answer:
3R
Solution:
As we learnt in
Positive vector
- wherein
So,
Weight at surface of earth is =
Weight at height
According to question
or Re + h = 4 Re or h = 3 Re
Q. 18 A non-conducting solid sphere of radius R is uniformly charged. The magnitude of the electric field
due to the sphere at a distance r from its centre
Option 1:
Increases as r increases for r<R
Option 2:
Decreases as r increases for
Option 3:
Decreases as r increases for
Option 4:
both a and c
Correct Answer:
both a and c
Solution:
As we learned
Suppose charge Q is uniformly distributed in the volume of a non conducting sphere of Radius R.
- wherein
For non-conducting solid sphere
and
Option 1:
for charged non-conducting sphere
Option 2:
for charged non-conducting sphere
Option 3:
for charged non-conducting sphere
Option 4:
for charged non-conducting sphere
Correct Answer:
for charged non-conducting sphere
Solution:
As we learned
Potential - If P lies at centre of uniformly charged non-conducting sphere -
i.e
Q. 20 The electric potential V at any point x, y, z (all in metres) in space is given by The
electric field at the point (1m, 0, 2m) in volt/metre is
Option 1:
8 along negative X-axis
Option 2:
8 along positive X-axis
Option 3:
16 along negative X-axis
Option 4:
16 along positive Z-axis
Correct Answer:
8 along negative X-axis
Solution:
As we learned
- wherein
Potential gradient.
By using Hence at point (1m, 0, 2m). volt/mi.e. 8
along – ve x-axis.
Option 1:
– 20 V/m
Option 2:
6 V/m
Option 3:
11 V/m
Option 4:
– 23 V/m
Correct Answer:
– 20 V/m
Solution:
As we learned
- wherein
Potential gradient.
By using
x = 1m
Q. 22 If the potential function is given by then the magnitude of electric field intensity at
the point (2, 1) will be
Option 1:
11
Option 2:
5
Option 3:
7
Option 4:
1
Correct Answer:
5
Solution:
As we learned
In space -
, ,
By using i.e.,
Q. 23 A sound wave of frequency 245 Hz travels with the speed of 300 ms -1 along the positive x-
axis. Each point of the wave moves to and fro through a total distance of 6 cm. What will be
the mathematical expression of this travelling wave ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 24 Two cars moving in opposite directions approach each other with speed of 22 m/s and 16.5
m/s respectively. The driver of the first car blows a horn having a frequency 400 Hz. The
frequency heard by the driver of the second car is [velocity of sound 340 m/s]:
Option 1:
350 Hz
Option 2:
361 Hz
Option 3:
411 Hz
Option 4:
448 Hz
Correct Answer:
448 Hz
Solution:
As we learnt in
Frequency of sound when source and observer are moving towards each other -
- wherein
Speed of sound
Speed of observer
speed of source
Original frequency
apparent frequency
Q. 25 A circuit contains an ammeter, a battery of 30 V and a resistance 40.8 ohm all connected in
series. If the ammeter has a coil of resistance 480 ohm and a shunt of 20 ohm, the reading
in the ammeter will be:
Option 1:
0.25 A
Option 2:
2A
Option 3:
1A
Option 4:
0.5 A
Correct Answer:
0.5 A
Solution:
As we learnt in
Ammeter -
- wherein
Resistance of ammeter is
R=40.8Ω Ω+19.2Ω
Q. 26 A wire of resistance 12 ohms per meter is bent to form a complete circle of radius 10 cm.
The resistance between its two diametrically opposite points, A and B as shown in the
Figure, is:
Option 1:
3
Option 2:
6
Option 3:
6
Option 4:
0.6
Correct Answer:
0.6
Solution:
Q. 27 A student measures the terminal potential difference (V) of a cell (of emf and internal
resistance r) as a function of the current (I) flowing through it. The slope, and intercept, of
the graph between V and I, then, respectively, equal:
Option 1:
- r and
Option 2:
r and -
Option 3:
- and r
Option 4:
and - r
Correct Answer:
- r and
Solution:
The terminal potential difference (V) of a cell is given as
V= - Ir ----------(1)
Q. 28 The thermo e.m.f. E in volts of a certain thermo-couple is found to vary with temperature
difference in °C between the two junctions according to the relation
Option 1:
450°C
Option 2:
400°C
Option 3:
225°C
Option 4:
30°C
Correct Answer:
225°C
Solution:
Option 1:
Both A and B are wrong
Option 2:
A is correct and B is wrong
Option 3:
A is wrong and B is correct
Option 4:
Both A and B correct
Correct Answer:
Both A and B correct
Solution:
As we learnt in
In a circuit at any junction the sum of the currents entering the junction must equal the sum of the
currents leaving the junction .
- wherein
and,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 31 In the circuit shown in the figure, if the potential at point A is taken to be zero, the potential
at point B is
Option 1:
-2V
Option 2:
+1V
Option 3:
-1 V
Option 4:
+2 V
Correct Answer:
+1V
Solution:
Applying Kirchhoff voltage law in the circuit as shown in the figure below.
Q. 32 When electron jumps from higher orbital to n = 3, energy level then this is belongs to
spectral series:
Option 1:
Lymen
Option 2:
Pfund
Option 3:
Paschen
Option 4:
Balmer
Correct Answer:
Paschen
Solution:
As we learn
Paschen Series -
- wherein
When electron jump from higher orbital to n=3 energy level
Q. 33 If the energy of hydrogen atom in the ground state is 13.6 ev then the energy of He+ ion in
the first excited state will be -
Option 1:
-6.8 ev
Option 2:
-54.4 ev
Option 3:
-27.2 ev
Option 4:
-13.6 ev
Correct Answer:
-13.6 ev
Solution:
As we learn
- wherein
Q. 34 In a radioactive decay chain , the initial nucleus is . At the end there are 6 -
particles and 4 - particles which are emitted. . If the end nucleus is , A and Z are given
by :
Option 1:
A = 208 ; Z = 80
Option 2:
A = 200 ; Z = 81
Option 3:
A = 202 ; Z = 80
Option 4:
A = 208 ; Z = 82
Correct Answer:
A = 208 ; Z = 82
Solution:
α -decay -
- wherein
β minus decay -
- wherein
Initially
Let finally
So let reaction
Balance Z -
Balance A -
So A =208 and Z = 82
Q. 35
A particle of mass m moves in a circular orbit in a central potential field U(r) = . If
Bohr's quantization conditions are applied, radii of possible orbitals and energy levels vary
with quantum number n as :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 36 For a radioactive material T is half life, then the fraction that would remain after a time T/2 is
:
Option 1:
Option 2:
Option 3:
2
Option 4:
0.5
Correct Answer:
Solution:
As we learn
- wherein
Option 1:
2V
Option 2:
3V
Option 3:
5V
Option 4:
1V
Correct Answer:
2V
Solution:
As we learnt in
Conservation of energy -
- wherein
&
It is defined as the potential necessary to stop any electron from reaching the other side.
Option 1:
Option 2:
Option 3:
Option 4:
12.2 nm
Correct Answer:
Solution:
- wherein
SO v=10000
SO
Q. 39 An ideal gas goes from state A to state B via three different processes as indicated in the P -
V diagram:
If Q1, Q2, Q3 indicate the heat absorbed by the gas along the three processes and U1,
U2, U3 indicate the change in internal energy along the three processes respectively, then:
Option 1:
Q3 > Q2 > Q1 and U1 = U2 = U3
Option 2:
Q1 = Q2 = Q3 and U1 > U2 > U3
Option 3:
Q3 > Q2 > Q1 and U1 > U2 > U3
Option 4:
Q1 > Q2 > Q3 and U1 = U2 = U3
Correct Answer:
Q1 > Q2 > Q3 and U1 = U2 = U3
Solution:
As we learnt in
- wherein
work done is
Since
Correct option is 4.
Q. 40 During an adiabatic process, the pressure of a gas is found to be proportional to the cube of
its temperature. The ratio of
Option 1:
Option 2:
Option 3:
2
Option 4:
Correct Answer:
Solution:
As we learnt in
Equation of state -
- wherein
On solving
or = constant ......(1)
.....(2)
Q. 41 A spherical planet has a mass MP and diameter DP. A particle of mass m falling freely near
the surface of this planet will experience an acceleration due to gravity, equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 42 Two vessels separately contain two ideal gases A and B at the same temperature; the
pressure of A being twice that of B. Under such conditions, the density of A is found to be
1.5 times the density of B. The ratio of molecular weight of A and B is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
OR
where
Given
Q. 43 4.0 g of a gas occupies 22.4 litres at NTP. The specific heat capacity of the gas at constant
volume is 5.0 JK-1 mol-1. If the speed of sound in this gas at NTP is 952 ms-1, then the heat
capacity at constant pressure is
Option 1:
7.5 JK-1 mol-1
Option 2:
7.0 JK-1 mol-1
Option 3:
8.5 JK-1 mol-1
Option 4:
8.0 JK-1 mol-1
Correct Answer:
8.0 JK-1 mol-1
Solution:
As we learnt in
- wherein
given M = 4gm
Velocity of sound
Q. 44 A body cools in 7 minutes from to . The temperature of the surrounding is
. The temperature of the body after the next 7 minutes
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Method-1
Using exact law of cooling
Case-I:
Case-II: or
Or
Methode-2
Using newton’s average law of cooling
Case-I:- .......(i)
Case-II:- ........(ii)
Q. 45 The pressure (in pa) that has to be applied to the ends of a steel wire of length 10 cm to
keep its length constant when its temperature is raised by 1000C is :
(For steel Young’s modulus is 2 x 1011 N m-2 and coefficient of thermal expansion is 1.1 x
10-5 K-1)
Solution:
As we have learned
Thermal Strain -
- wherein
Thermal strain
Option 1:
3J
Option 2:
Option 3:
Option 4:
Correct Answer:
3J
Solution:
--------------------- (i)
in magnitude
-----------------(ii)
from equation (i) and (ii)
Q. 47 A proton carrying 1 MeV kinetic energy is moving in a circular path of radius R in uniform
magnetic field. What should be the energy of an - particle to describe a circle of same
radius in the same field?
Option 1:
1 MeV
Option 2:
0.5 MeV
Option 3:
4 MeV
Option 4:
2 MeV
Correct Answer:
1 MeV
Solution:
E = Kinetic energy
Rproton = R -particle
and
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 49 The input resistance of a silicon transistor is 100 . Base current is changed by which
results in a change in collector current by 2 mA. This transistor is used as a common emitter
amplifier with a load resistance of . The voltage gain of the amplifier is:
Option 1:
3000
Option 2:
4000
Option 3:
1000
Option 4:
2000
Correct Answer:
2000
Solution:
As we learnt in
Transistor -
NPN or PNP
- wherein
Voltage gain
Q. 50
Logic 1 = > 5 V
Logic 0 = < 1 V
Option 1:
AND Gate
Option 2:
OR Gate
Option 3:
XOR Gate
Option 4:
NOR Gate
Correct Answer:
AND Gate
Solution:
As we have learned
AND Gate -
- wherein
Hence A B output
1 1 1
1 0 0
0 1 0
0 0 0
Q. 51 Consider the junction diode as ideal. The value of current flowing through AB is:
Option 1:
0A
Option 2:
10-2 A
Option 3:
10-1 A
Option 4:
10-3 A
Correct Answer:
10-2 A
Solution:
P -N junction as diode -
It is a one way device. It offers a low resistance when forward biased and high resistance when reverse
biased.
- wherein
R = 0, Forward
R Reverse
since diode is ideal and it is in forward biased mode it will not offer resistance
Option 1:
2V
Option 2:
0.2 V
Option 3:
0.0002 V
Option 4:
0.02 V
Correct Answer:
0.02 V
Solution:
- wherein
change in flux
N = 800
So
So
Q. 53 A series of LCR circuit is connected to an ac voltage source. When L is removed from the
circuit, the phase difference between current and voltage is If instead C is removed from
the circuit, the phase difference is again between current and voltage. The power factor
of the circuit is:
Option 1:
zero
Option 2:
0.5
Option 3:
1.0
Option 4:
-1.0
Correct Answer:
1.0
Solution:
Q. 54 An inductor of inductance L, a capacitor of capacitance C and a resistor of resistance 'R' are
connected in series to an ac source of potential difference 'V' volts as shown in figure.
Potential difference across, C and R is 40 V, 10V and 40V, respectively. The amplitude of
current flowing through LCR series circuit is . The impedance of the circuit is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 55 If W1, W2 and W3 represent the work done in moving a particle from A to B along three
different paths 1, 2 and 3 respectively (as shown) in the gravitational field of a point mass m,
find the correct relation
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
1. Conservative field-
In the conservative field, work done by the force depends only upon the initial and final position.
In the conservative field, work done by the force does not depend on the path.
In the conservative field, work done by the force along a closed path is zero.
2. Conservative force-
So,
As gravitational field is conservative in nature. So work done in moving a particle from A to B does not
depends upon the path followed by the body. It always remains the same.
Q. 56 A 10 kg satellite completes one revolution around the earth at a height of 100 km in 108
minutes. The work done by the gravitational force of earth will be
Option 1:
108 x 100 x 10 J
Option 2:
Option 3:
Option 4:
Zero
Correct Answer:
Zero
Solution:
3. Zero work
Means
E.g-When a body moves in a circle the work done by the centripetal force is always zero.
So,
Q. 57 Two blocks A and B of masses 3m and m respectively are connected by a massless and
inextensible string. The whole system is suspended by a massless spring as shown in figure.
The magnitudes of acceleration of A and B immediately after the string is cut, are
respectively:
Option 1:
Option 2:
Option 3:
g, g
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Option 1:
41%
Option 2:
200%
Option 3:
100%
Option 4:
68%
Correct Answer:
41%
Solution:
change
Q. 59
A rod ' ' has non-uniform linear mass density given by where a and b
are constants and The value of x for the centre of mass of the rod is at :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 60 Which of the following statements are correct?
(a) Centre of mass of a body always coincides with the centre of gravity of the body.
(b) Centre of mass of a body is the point at which the total gravitational torque on the body
is zero.
(c) A couple on a body produce both translational and rotational motion in a body.
(d) Mechanical advantage greater than one means that small effort can be used to lift a
large load.
Option 1:
(b) and (d)
Option 2:
(a) and (b)
Option 3:
(b) and (c)
Option 4:
(c) and (d)
Correct Answer:
(b) and (d)
Solution:
As we learnt in concept
Centre of gravity -
Centre of gravity of a body is a point, through which the resultant of all the forces experienced by various
particles of the body due to attraction of earth, passes irrespective of the orientation of the body.
1) Centre of mass of a body always coincides with the centre of gravity of body is wrong
2) M.A=load / effort
Chemistry
Q. 1 A solution is prepared by mixing 8.5 g of CH2Cl2 and 11.95 g of CHCl3. If vapour pressure of
CH2Cl2 and CHCl3 at 298 K are 415 and 200 mmHg respectively, the mole fraction of CHCl3 in
vapour form is : (Molar mass of Cl=35.5 g mol−1)
Option 1:
0.162
Option 2:
0.675
Option 3:
0.325
Option 4:
0.486
Correct Answer:
0.325
Solution:
Q. 2 Excess of NaOH(aq) was added to 100 mL of FeCl3(aq) resulting into 2.14 g of Fe(OH)3. The
molarity of FeCl3(aq) is :
(Given molar mass of Fe=56 g mol−1 and molar mass of Cl=35.5 g mol−1)
Option 1:
0.2 M
Option 2:
0.3 M
Option 3:
0.6 M
Option 4:
1.8 M
Correct Answer:
0.2 M
Solution:
The chemical equation for the reaction is as follows:
Q. 3 Which of the following statements about the composition of the vapour over an ideal 1: 1
molar mixture of benzene and toluene is correct? Assume that the temperature is constant
at 25°C. (Given, Vapour Pressure Data at 25°C, benzene = 12.8 kPa, toluene = 3.85 kPa)
Option 1:
The vapour will contain a higher percentage of benzene.
Option 2:
The vapour will contain a higher percentage of toluene.
Option 3:
The vapour will contain equal amounts of benzene and toluene.
Option 4:
Not enough information is given to make a prediction.
Correct Answer:
The vapour will contain a higher percentage of benzene.
Solution:
As we learned in
More volatile liquids are those when intermolecular forces are weak.
When we look at vapour pressure data of benzene (12.8 kPa) and toluene (3.85 kPa) we find that benzene
is more volatile than toluene and hence will exert greater pressure and will have a higher percentage in
the vapour phase.
Option 1 is correct.
Option 1:
If both assertion and reason are true and reason is the correct explanation of assertion
Option 2:
If both assertion and reason are true but reason is not the correct explanation of assertion
Option 3:
If assertion is true but reason is false
Option 4:
If both assertion and reason are false
Correct Answer:
If both assertion and reason are true and reason is the correct explanation of assertion
Solution:
As we learn
Corrosions -
Slow formation of undesirable compounds such as oxides, sulfides or carbonates at the surface of metals
by reaction with moisture and other atmospheric gases is known as corrosion.
Zn is used for covering the iron to protect it from rusting. This process is called galvanization. Zn is more
reactive metal than iron.
Zn has more negative electrode potential (standard reduction potential) than that of Fe. Therefore Zn
loses electrons in preference to iron. When the layer of zinc comes in contact with moisture, oxygen and
co2 a protective thin layer of Znco3. Zn(oH)2 is formed. Hence reason is the correct explanation of the
assertion.
Assertion : In electrolysis, the quantity of electricity needed for depositiong 1 mole of Ag is different
from that required for 1 mole copper.
Option 1:
If both assertion and reason are true and reason is the correct explanation of assertion
Option 2:
If both assertion and reason are true but reason is not the correct explanation of assertion
Option 3:
If assertion is true but reason is false
Option 4:
If both assertion and reason are false
Correct Answer:
If both assertion and reason are true but reason is not the correct explanation of assertion
Solution:
As we learn
The mass of any substance deposited or dissolved at any electrode during electrolysis is directly
propotional to the quantity of electricity passed through the solution.
- wherein
W=ZIt
Ag+ + e- Ag
Cu+2 + 2e- cu
Option 1:
6 x 1023
Option 2:
6 x 1020
Option 3:
3.75 x 1020
Option 4:
7.48 x 1023
Correct Answer:
3.75 x 1020
Solution:
As we learnt in
So,
Since
Option 1:
10
Option 2:
20
Option 3:
30
Option 4:
40
Correct Answer:
30
Solution:
The reaction is :
Option 1:
1g of Li(s) [Atomic mass of Li = 7 ]
Option 2:
1g of Ag(s) [ Atomic mass of Ag = 108 ]
Option 3:
1g of Mg(s) [ Atomic mass of Mg = 24 ]
Option 4:
1g of O2(g) [ Atomic mass of O = 16 ]
Correct Answer:
1g of Li(s) [Atomic mass of Li = 7 ]
Solution:
For Li:
Number of atoms in 1 g
For Ag:
Number of atoms in 1 g
For Mg:
Number of atoms in 1 g
For O2:
Number of atoms in 1 g
Q. 9 The freezing point of benzene decreases by 0.450C when 0.2 g of acetic acid is added to 20 g
of benzene. If acetic acid associates to form a dimer in benzene, percentage association of
acetic acid in benzene will be :
Option 1:
74.6%
Option 2:
94.6%
Option 3:
64.6%
Option 4:
80.4%
Correct Answer:
94.6%
Solution:
In benzene ,
t=0 1 -
t=t 1-
Given:
w = 0.2g W = 20 g T = 0.45 K
As we know ,
, observed M = 113.78 (acetic acid)
Q. 10 At 100°C the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732mm. If Kb
= 0.52, the boiling point of this solution will be:
Option 1:
101°C
Option 2:
100°C
Option 3:
102°C
Option 4:
103°C
Correct Answer:
101°C
Solution:
As we learned in
Mathematical Expression -
Where -
Now,
Let's find the molar mass of the solute first By Roalt's law of partial pressure,
Option 1 is correct.
Q. 11 The van't Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium
hydroxide is:
Option 1:
0
Option 2:
1
Option 3:
2
Option 4:
3
Correct Answer:
3
Solution:
As we learned in the concept
Option 4 is correct.
Option 1:
D-fructose
Option 2:
D-ribose
Option 3:
D-glucose
Option 4:
L-glucose.
Correct Answer:
D-glucose
Solution:
As we learnt in
Cellulose -
- wherein
Linkage : linkage
Cellulose is a straight chain polymer of D-glucose, which upon hydrolysis gives its monomer (D-glucose)
Option 1:
Uracil
Option 2:
Cytosine
Option 3:
Guanine
Option 4:
Thymine
Correct Answer:
Uracil
Solution:
As we learnt in
Made up of nucleotides consisting of pentose sugar which is ribose, Phosphoric acid and bases
(Adenine , Guanine , cytosine and uracil)
Option 1:
(A)-(R), (B)-(S), (C)-(P), (D)-(Q)
Option 2:
(A)-(S), (B)-(R), (C)-(P), (D)-(Q)
Option 3:
(A)-(S), (B)-(R), (C)-(Q), (D)-(P)
Option 4:
(A)-(R), (B)-(S), (C)-(Q), (D)-(P)
Correct Answer:
(A)-(R), (B)-(S), (C)-(P), (D)-(Q)
Solution:
As we learnt in
Made up of nucleotides consisting of pentose sugar which is ribose, Phosphoric acid and bases
(Adenine , Guanine , cytosine and uracil)
Q. 15 Zinc can be coated on iron to produce galvanized iron but the reverse is not possible. It is
because
Option 1:
zinc is lighter than iron
Option 2:
zinc has lower melting point than iron
Option 3:
zinc has lower negative electrode potential than iron
Option 4:
zinc has higher negative electrode potential than iron
Correct Answer:
zinc has higher negative electrode potential than iron
Solution:
Zinc can be coated on iron to produce galvanized iron but the reverse is not possible.
Iron gets oxidized in presence of moisture which is known as rusting. To protect the iron, it is coated with
zinc because zinc has a higher negative reduction potential than iron, so zinc gets oxidized before iron, so
it protects the iron from getting oxidized.
Zn has higher negative SRP (Standard reduction potential) so it works as anode and protects iron to make
iron as the cathode. So, iron will reduce and zinc will oxidize.
The reverse is not possible because even if the zinc is coated with iron means iron will be in contact with
moisture, zinc will get oxidized first due to high negative reduction potential.
Option 4 is correct.
The potential difference needed for the electrolytic reduction of aluminium oxide (Al2O3) at
500oC is at least:
Option 1:
3.0 V
Option 2:
2.5 V
Option 3:
5.0 V
Option 4:
4.5 V
Correct Answer:
2.5 V
Solution:
The given reaction is -
Now,
Q. 17 Molar conductivities at infinite dilution of NaCl, HCl and CH3COONa are 126.4, 425.9
and 91.0 respectively.
Option 1:
180.5 S cm2 mol-1
Option 2:
290.8 S cm2 mol -1
Option 3:
390.5 S cm2 mol-1
Option 4:
425.5 S cm2 mol-1
Correct Answer:
390.5 S cm2 mol-1
Solution:
As we learnt in
Option 1:
It states there should be maximum overlapping of atomic orbitals
Option 2:
Greater is overlapping, higher is the strength of chemical bond.
Option 3:
It explains magnetic properties
Option 4:
None of the above
Correct Answer:
It explains magnetic properties
Solution:
Valence bond theory does not explain the magnetic properties of the molecules.
Q. 19 The magnetic moment of an octahedral homoleptic Mn (II) complex is 5.9 BM. The suitable
ligand for this complex is :
Option 1:
CO
Option 2:
ethylenediamine
Option 3:
NCS-
Option 4:
CN-
Correct Answer:
NCS-
Solution:
As we have learnt in magnetic moment,
Now, has a configuration and presence of 5 unpaired electrons will only be possible for weak
field ligands like
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt,
Now, as Pt belongs to the 5d series, weaker ligands are also able to cause pairing because of greater
splitting due to larger size of the orbiratal.
Electronic configuration of
With a weak field ligand like Chloride ion, it shows hybridisation
Electronic configuration of
With a weak field ligand like Chloride ion, it shows hybridisation and tetrahedral geometry.
Electronic configuration of
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
For an ideal solution, intermolecular forces between the components are identical to that present in pure
components.
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Lewis acids and bases - Lewis defined an acid as a species that accepts electron pairs and bases which
donate an electron pair.
In lewis acid, many acids do not have protons but have vacant orbitals to accept lone pair of electrons.
has no lone pair of electrons but can accept lone pair of electrons acting as a lewis acid.
Option 1:
Na2S > ZnS > CuS
Option 2:
CuS > ZnS > Na2S
Option 3:
ZnS > Na2S > CuS
Option 4:
Na2S > CuS > ZnS
Correct Answer:
Na2S > ZnS > CuS
Solution:
Ionic character of the compound decrease as the size of the cation increases and solubility decrease as
ionic character decreases.
Solubility order is
Option 1:
6.13
Option 2:
7.00
Option 3:
7.87
Option 4:
5.13
Correct Answer:
6.13
Solution:
Pure water is always neutral, at different temperatures the pH scale can change but water is always
neutral.
On an increase of temperature range of the pH scale decreases.
At
At
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The solubility of sulfides is directly proportional to the ionic character.
The more the covalent character, the lower the solubility of the salt.
Due to the poor shielding effect of d orbitals in d block elements, hence CuS and ZnS are more covalent
in comparison to Na2S.
in the case of Cu2+ and Zn2+, Cu2+ has a smaller size hence, more charge-to-size ratio, more polarizing
power, more covalent character, and lower solubility.
Option 1:
FeCl3, SnCl2
Option 2:
HgCl2, SnCl2
Option 3:
FeCl2, SnCl2
Option 4:
FeCl3, KI
Correct Answer:
FeCl2, SnCl2
Solution:
The pair of compounds that can exist together is FeCl2, and SnCl2.
FeCl2and SnCl2(both are reducing agents and have lower oxidation no.)
Hence neither can reduce the other.
The correct answer is option 3.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The reaction of aqueous with in acidic conditions gives:
The oxidation number of Mn in MnSO4is +2. Hence, the correct answer is option 2.
is :
Option 1:
(2R, 3S)
Option 2:
(2S, 3R)
Option 3:
(2S, 3S)
Option 4:
(2R, 3R)
Correct Answer:
(2S, 3R)
Solution:
As we learnt ,
Chiral Carbon -
- wherein
For C2
This rotation suggests R but the least prior group is at horizontal position so the configuration is R.
For C3
This rotation suggests S but the least prior group is at horizontal position so the configuration is S.
Q. 29 The standard enthalpy of formation ( fHo298) for methane, CH4 is -74.9 kJ mol-1. In order to
calculate the average energy given out in the formation of a C - H bond from this it is
necessary to know which one of the following?
Option 1:
the dissociation energy of the hydrogen molecule, H2.
Option 2:
the first four ionisation energies of carbon.
Option 3:
the dissociation energy of H2 and enthalpy of sublimation of carbon (graphite).
Option 4:
the first four ionisation energies of carbon and electron affinity of hydrogen.
Correct Answer:
the dissociation energy of H2 and enthalpy of sublimation of carbon (graphite).
Solution:
Enthalpy of Sublimation -
Amount of enthalpy change to sublimise 1 mole solid into 1-mole vapour at a temperature below its
melting point
It is the average of enthalpy required to dissociate the said bond present in the different gaseous
compounds into free atoms in the gaseous state.
Now,
Step 1 :
Step 2 :
Q. 30 A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a
constant temperature of 370 C. As it does so ,it absorbs 208 J of heat. The values of q and w
for the process will be :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The process is isothermal reversible expansion
Hence dT = 0
U=0
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The change in entropy for an ideal gas in terms of C(p) -
Where,
Molar heat capacity at constant pressure
Now,
and
Option 1:
octahedral, sp3d2
Option 2:
trigonal bipyramidal, sp3d
Option 3:
planar triangle, sp3d3
Option 4:
square planar, sp3d2
Correct Answer:
octahedral, sp3d2
Solution:
-
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Resonance -
For molecules and ions showing resonance it is not possible to draw a single Lewis structure.All the
properties can only be explained by two or more Lewis structures.
- wherein
Because of double bond character in the carbon-carbon bridge this compound will have an atom planar.
Q. 34 Which one of the following compounds shows the presence of intramolecular hydrogen
bond?
Option 1:
H 2 O2
Option 2:
HCN
Option 3:
Cellulose
Option 4:
Concentrated acetic acid
Correct Answer:
Cellulose
Solution:
Hydrogen Bonding -
Attractive force which binds hydrogen atom of one molecule with the electronegative ( F, O, N ) atom of
another molecule.
- wherein
It is of two type
1. Intermolecular and
2. Intramolecular
H2O2 , HCN and concentrated CH3 COOH (acetic acid) form inter-molecular hydrogen bonding while
cellulose has intramolecular hydrogen bonding.
Option 1:
Negligible screening effect of 'f' orbitals
Option 2:
Increasing Nuclear charge
Option 3:
Decreasing nuclear charge
Option 4:
Decreasing screening effect
Correct Answer:
Negligible screening effect of 'f' orbitals
Solution:
The lanthanoid contraction results from the poor shielding effect of the 4f orbitals due to which outer 6s
electrons are more strongly attracted by the nucleus thus resulting in a decrease in size of the atoms
subsequent to lanthanoids i.e from hafnium.
Option 1:
acetone
Option 2:
acetamide
Option 3:
2-methyl-2-propanol
Option 4:
acetyl iodide.
Correct Answer:
2-methyl-2-propanol
Solution:
As we learnt in
Alkane is obtained.
- wherein
Q. 37 At 320 K, a gas is 20% dissociated to A(g). The standard free energy change at 320 K and
1 atm in is approximately : (R=8.314 ; ln 2=0.693; ln 3=1.098)
Option 1:
4763
Option 2:
2068
Option 3:
1844
Option 4:
4281
Correct Answer:
4281
Solution:
As we learnt in
- wherein
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Dehydration of alcohols -
Ease of dehydration
- wherein
The more stable carbocation generated, more easily it will dehydrated. The order of stability of
carbocations
Correct option is 3.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Calculation of spin only magnetic moment -
- wherein
magnetic moment,
=> x(x + 2) = 8
=> x = 2
Electronic confiq of
Option 1:
Hydrolysis
Option 2:
Oxidation
Option 3:
Cracking
Option 4:
Distillation under reduced pressure
Correct Answer:
Cracking
Q. 41 The number of d-electrons in Fe2+(Z = 26) is not equal to the number of electrons in which
one of the following ?
Option 1:
d - electrons in Fe (Z = 26)
Option 2:
p - electrons in Ne (Z = 10)
Option 3:
s - electrons in Mg (Z = 12)
Option 4:
p - electrons in CI (Z =17)
Correct Answer:
p - electrons in CI (Z =17)
Solution:
Fe(26) = 1s2 2s2 2p6 3s2 3p6 4s2 3d6
So the number of d electrons in Fe2+ is not the same as the number of p electrons in Cl.
Option 1:
30 % alcohol and 70 % petrol
Option 2:
45 % alcohol and 55 % petrol
Option 3:
20 % alcohol and 80 % petrol
Option 4:
10 % alcohol and 90 % petrol
Correct Answer:
20 % alcohol and 80 % petrol
Solution:
As we learnt,
Power alcohol -
Mixture of alcohol and petrol in 20 : 80 ratio is called power alcohol . It is used in automobiles as they
generate energy from it for their operation.
Q. 43
For a first-order reaction, , (half-life) is 10 days. The time required for
conversion of A (in days) is :
Correct Answer:
4.1
Solution:
Fro the first-order reaction: -
Q. 44 decomposes to and and follows first order kinetics. After 50 minutes, the
pressure inside the vessel increases from 50 mmHg to 87.5 mmHg.
The pressure (in mmHg ) of the gaseous mixture after 100 minute at constant temperature
will be :
Correct Answer:
106.25
Solution:
t=0 50 0 0
t=50min
=25
t=100min
12.5
+ +
=50+56.25
=106.25mm of Hg
Q. 45 for a reaction
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Rate of reaction -
The rate of the reaction during the courses of a reaction in any instant of time is the change in
concentration of reacting species. Rate is a positive quantity.
Option 4 is correct.
Q. 46 For a reaction .
Which graph is correct for the rate of disappearance of A?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Rate of disappearance of R
This can be seen that conc. of A decreases with time as the reaction proceeds.
Option 1:
Principle quantum number
Option 2:
Magnetic quantum number
Option 3:
Azimutual quantum number
Option 4:
Spin quantum number
Correct Answer:
Spin quantum number
Solution:
As we learned in
For the two electrons occupying the same orbital value of n, l and m are the same but is different.
Q. 48 The product formed by the reaction of an aldehyde with a primary amine is:
Option 1:
Schiff base
Option 2:
Ketone
Option 3:
Carboxylic acid
Option 4:
Aromatic acid
Correct Answer:
Schiff base
Solution:
The reaction
Option 1:
H+
Option 2:
Li+
Option 3:
Na+
Option 4:
Mg2+
Correct Answer:
Li+
Solution:
Electronic config of
Electronic config of
Option 1:
5-formylhex-2-en-3-one
Option 2:
5-methyl-4-oxohex-2-en-5-al
Option 3:
3-keto-2-methylhex-5-enal
Option 4:
3-keto-2-methylhex-4-enal
Correct Answer:
3-keto-2-methylhex-4-enal
Solution:
The IUPAC name of the compound will be "3-keto-2-methylhex-4-enal"
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The reaction occurs as
Q. 52
Option 1:
III > I > II
Option 2:
II>I> III
Option 3:
I > II > III
Option 4:
I > III>II
Correct Answer:
III > I > II
Solution:
Reaction:
The basicity order will depend on the groups attached with 'N' other than the benzene ring.
Option 1:
Maltose and lactose has 1, 4-glycosidic linkage.
Option 2:
Sucrose and amylose has 1, 2-glycosidic linkage.
Option 3:
Cellulose and amylose has 1, 4-glycosidic linkage.
Option 4:
Lactose contains β-D-galactose and β-D-glucose.
Correct Answer:
Sucrose and amylose has 1, 2-glycosidic linkage.
Solution:
As we learnt in
Starch -
- wherein
Q. 54 An organic compound contains 78% (by wt.) carbon and remaining percentage of hydrogen.
The right option for the empirical formula of this compound is :[ Atomic wt.C is 12, H is 1]
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Mass ratio of Carbon : Hydrogen = 78 : 22
Thus, on the basis of the given data, the most probable answer is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Give reaction
From above,
But is so,
Q. 56 One mole of carbon atom weighs 12 g, the number of atoms in it is equal to, ( Mass of
carbon - 12 is )
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The number of atoms present in 12 g of carbon is equal to Avogadro's number ( )
Hence, the correct answer is option 3.
Q. 57 The right option for the mass of produced by 20 g of 20% pure limestone is (Atomic
mass of Ca =40)
Option 1:
1.12g
Option 2:
1.76g
Option 3:
2.64g
Option 4:
1,32g
Correct Answer:
1.76g
Solution:
Q. 58 The species Ar, K+ and Ca2+ contain the same number of electrons. In which order do their
radii increase ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learned in
In the case of isoelectronic species, radius decreases with an increase in nuclear charge.
Option 1:
NaOH
Option 2:
NaOH/CaO,
Option 3:
,
Option 4:
Correct Answer:
,
Solution:
As we learned
Oxidation of Phenol -
Product form is conjugated diketone known as benzoquinone.
- wherein
Option 1:
Acetal
Option 2:
Hemiacetal
Option 3:
Ketone
Option 4:
Ketal
Correct Answer:
Ketal
Solution:
As we learnt ,
Produces an unstable hemiketal intermediate and further stable compound called ketal.
- wherein
Ketal
Maths
Q. 1 If in a regular polygon the number of diagonals is 54, then the number of sides of this
polygon is :
Option 1:
10
Option 2:
12
Option 3:
9
Option 4:
6
Correct Answer:
12
Solution:
As we have learned
no. of diagonals =
Q. 2 Let k and K be the minimum and the maximum values of the function
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Use the concept of
Maxima Minima -
A functions graph follow up and down along x-axis then upper part is known as maxima and lower part is
known as minima.
Put x=0
Q. 3 The integral
is equal to:
Option 1:
2
Option 2:
4
Option 3:
1
Option 4:
6
Correct Answer:
1
Solution:
....(i)
Also,
.....(ii)
Q. 4
if are the root of equation ,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
- wherein
are root of quadratic equation
- wherein
We have ,
Now ,
Q. 5 A hyperbola whose transverse axis is along the major axis of the conic
and has vertices at the foci of this conic. If the eccentricity of the
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Correct Answer:
2
Solution:
Statement - I :
Option 1:
Statement-I is true, but Statement-II is false.
Option 2:
Statement-I is false, but Statement-II is true.
Option 3:
Both the statements are true.
Option 4:
Both the statements are false.
Correct Answer:
Both the statements are true.
Solution:
Given that
Option 1:
e
Option 2:
0
Option 3:
2
Option 4:
2e
Correct Answer:
2
Solution:
As we learnt in
- wherein
I.F.
Put x=1
0=c-2 = c=2
at x=e
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Let be two curve then area bounded between the curves and the lines
x = a and x = b is
- wherein
Where
Ponits of intersection of
Q. 10 If the function.
Option 1:
2
Option 2:
Option 3:
Option 4:
4
Correct Answer:
2
Solution:
As we have learned
Continuity at a point -
1. f(a) is defined : at x = a.
-
Condition for differentiability -
FOr continuity at x= 3 ,
m = 2/5
and k = 8/5
therfore m+k = 2
Q. 11 If is the set of
natural numbers,then
is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Let us 1st simplify set X
And
Solution:
Q. 13 If the angles of elevation of the top of a tower from three collinear points A, B and C, on a
line leading to the foot of the
tower, are 300, 450 and 600 respectively,then the ratio, AB : BC, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
The height or length of an object or the distance between two distant objects can be determined with the
help of trigonometric ratios.
In
...................... ( 1 )
In
.................... ( 2 )
In
..................... ( 3 )
Now,
Q. 14 If equals:
Option 1:
17
Option 2:
7
Option 3:
5
Option 4:
1
Correct Answer:
5
Solution:
As we learnt in
- wherein
Thus
Q. 15 The number of integers greater than 6,000 that can be formed, using the digits 3, 5, 6, 7 and
8, without repetition, is :
Option 1:
216
Option 2:
192
Option 3:
120
Option 4:
72
Correct Answer:
192
Solution:
Such numbers can be 4-digit or 5 digit
3 options (6,7,8) for first place as number has to be greater than 6,000
2. Five-digit numbers
5 x 4 x 3 x 2 x 1 = 120
Total = 192
if
then is equal to :
Correct Answer:
0
Solution:
As we learnt in
- wherein
c=2
Now
So that
b=-2
c=2
So
=8-16+8=0
Q. 17
The integral is equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
- wherein
where
Q. 18
If z1, z2 and z3, z4 are 2 pairs of complex conjugate numbers, then
equals:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given
and
So,
Q. 19 Two sides of a rhombus are along the lines, x−y+1=0 and 7x−y−5=0. If its diagonals intersect
at (−1, −2), then which one of the following is a vertex of this rhombus ?
Option 1:
(−3, −9)
Option 2:
(−3, −8)
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
slope
Let C be
and
Slope of
Hence, slope of
equation of
Point satisfies the line BD
Q. 20
is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
1
Correct Answer:
Solution:
As we learnt in
-
Q. 21
if ,then the determinant of the matrix (A2016−2A2015−A2014) is :
Option 1:
2014
Option 2:
−175
Option 3:
2016
Option 4:
−25
Correct Answer:
−25
Solution:
. If equals:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
put
- wherein
equals:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
If the function is continuous in (a, b ) then integration of a function a to b will be same as the sum of
integrals of the same function from a to c and c to b.
- wherein
Q. 24
If g is the inverse of a function and is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Here, we have,
And,
hence, we have
And,
Hence,
therefore, for solution to happen LHS should also be same.
Q. 26 Let the sum of the first three terms of an A.P. be 39 and the sum of its last four terms be
178. If the first term of this A.P. is 10, then the number of terms of the A.P. is :
Correct Answer:
14
Solution:
Let the AP is
given
Now
Q. 27
Let where
Then a value of is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Formulae of Inverse Trigonometric Functions
when
Q. 28 if then a value of
Option 1:
Option 2:
12
Option 3:
24
Option 4:
Correct Answer:
Solution:
As we learnt in
Collinear Vectors -
Two vectors are said to be collinear if and only if there exists a scalar m such as that
- wherein
m is a Scalar.
Q. 29 Let R= {(3,3), (5,5), (9,9), (12,12), (5,12), (3,9), (3,12), (3,5)} be a relation on the set A=
{3,5,9,12}. Then R is :
Option 1:
reflexive , symmetric but not transitive
Option 2:
symmetric, transitive but not reflexive
Option 3:
an equivalence relation.
Option 4:
reflexive, transitive but not symmetric
Correct Answer:
reflexive, transitive but not symmetric
Solution:
Let R= {(3,3), (5,5), (9,9), (12,12), (5,12), (3,9), (3,12), (3,5)} be a relation on the set
A= {3,5,9,12}
Also, R is transitive relation because it satisfies the property that if aRb and bRc then aRc.
Q. 30 If and g are differentiable functions in [0, 1] satisfying (0) = 2 = g (1), g (0) = 0 and (1)=6,
then for some c [0, 1] :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
cauchy's Theorem -
for some
- wherein
We have
For some
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
aS LEARNT IN CONCEPT
Let be two curve, then area bounded by the curves and the lines
y = a and y = b is
- wherein
Q. 32 If and are roots of the equation, for some k
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
- wherein
- wherein
and
Now ,
k= 2 acceptable for ln k to be definite
Q. 33 The centres of those circles which touch the circle, x2+y2−8x−8y−4=0, externally and also
touch the x-axis, lie on :
Option 1:
a circle.
Option 2:
an ellipse which is not a circle.
Option 3:
a hyperbola.
Option 4:
a parabola.
Correct Answer:
a parabola.
Solution:
As we learnt in
When two circles touch each other externally, there are three common tangents, two of them are direct.
- wherein
- wherein
- wherein
Circle:
externally
compared to
Represent a parabola
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Maxima Minima -
A functions graph follow up and down along x-axis then upper part is known as maxima and lower part is
known as minima.
-
So solve
and
Q. 35
Correct Answer:
5
Solution:
Hence,
And
Given that these two matrices are equal, so by comparing the elements of these 2 matrices
Q. 36
if is equal to :
Option 1:
Option 2:
Option 3:
1
Option 4:
Correct Answer:
Solution:
As we learnt in
Differential Equations -
An equation involving independent variable (x), dependent variable (y) and derivative of
dependent variable with respect to independent variable
- wherein
eg:
Then
Now,
.............(i)
...........(ii)
So that,
Q. 37
is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
-
and
Q. 38
if is continuous and , then is equal to :
Option 1:
Option 2:
Option 3:
0
Option 4:
Correct Answer:
Solution:
As we learnt in
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt in
- wherein
Q. 40
The value of is equal to
Option 1:
7785
Option 2:
8155
Option 3:
7775
Option 4:
8100
Correct Answer:
8155
Solution:
Now
So that
So
Q. 41 The number of for which
is
Option 1:
2
Option 2:
4
Option 3:
6
Option 4:
8
Correct Answer:
4
Solution:
As we know that
Now,
he number of is 4.
Q. 42 If are three unit vectors in three-dimensional space, then the minimum value of
is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
Unit vector -
- wherein
It is denoted by .
- wherein
Dot product is commutative for , where is the angle between the vectors
Minimum value 3
and
Option 1:
[0, 1)
Option 2:
[1, 2)
Option 3:
(2, 3]
Option 4:
(3, 4]
Correct Answer:
(2, 3]
Solution:
As we learnt in
and is given by
Where
So shortest distance =
Correct Answer:
202
Solution:
As we have learned
Now,
Q. 45 Let
be
two sets. Then :
Option 1:
P ⊂ Q and Q−P ≠ φ
Option 2:
Q⊄P
Option 3:
P⊄Q
Option 4:
P=Q
Correct Answer:
P=Q
Solution:
Let P
Let Q
Maximize
Subject to ,
all variables
Option 1:
(50,40)
Option 2:
(30,50)
Option 3:
(60,30)
Option 4:
(90,20)
Correct Answer:
(60,30)
Solution:
As we learnt in
Decision Variables -
-
x = 60
y = 30 is feasible.
Q. 47 The distance of the point (1, −2, 4) from the plane passing through the point (1, 2, 2) and
perpendicular to the planes x − y + 2z = 3 and 2x −2y + z + 12=0, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
So equation of plane is
3+6=C
Distance
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
Now,
So sum =
Now coefficient of
Q. 49 The angle of elevation of the top of a vertical tower from a point A, due east of it is 450. The
angle of elevation of the top of the same tower from a point B, due south of A is 300. If the
distance between A and B is m , then the height of the tower (in metres), is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
The height or length of an object or the distance between two distant objects can be determined with the
help of trigonometric ratios.
-
Q. 50 From a group of 10 men and 5 women, four member committees are to be formed each of
which must contain at least one woman. Then the probability for these committees to have
more women than men is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Let A be the event that at least one woman is selected in the committee
Let B be the event that there are more women than men in the committee
P (B) =
So,
(Note that here B is a subset of A, so their intersection equals B itself)
Q. 51
Lets be any complex number such that is a purely imaginary number. Then
is:
Option 1:
0
Option 2:
Any non-zero real number
Option 3:
A purely imaginary number
Option 4:
None of these
Correct Answer:
Any non-zero real number
Solution:
Let (As it is purely imaginary)
So,
Q. 52 If one of the diameters of the circle, given by the equation, x2 + y2 − 4x + 6y − 12=0, is a chord
of a circle S, whose centre is at (−3, 2), then the radius of S is :
Option 1:
Option 2:
Option 3:
5
Option 4:
10
Correct Answer:
Solution:
As we learnt in
- wherein
centre =
radius =
Q. 53
The integral equals :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in concept
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
--------------------------------- (1)
Substituting
------------------------------------ (2)
Correct Answer:
7
Solution:
General Solution of Trigonometric Ratios
Now,
Thus,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
- wherein
is the equation
Case (1)
Acceptable value =
case (2)
x < 3/2
Acceptable value
sum of roots =
Q. 56 Let P be the point on the parabola, y2=8x which is at a minimum distance from the centre C
of the circle, x2 + (y+6)2=1. Then the equation of the circle, passing through C and having its
centre at P is :
Option 1:
x2 + y2 − 4x + 8y + 12 = 0
Option 2:
x2+y2−x+4y−12=0
Option 3:
Option 4:
x2 + y2 − 4x + 9y + 18 = 0
Correct Answer:
x2 + y2 − 4x + 8y + 12 = 0
Solution:
As we learnt in
Parametric coordinates of parabola -
- wherein
Equation of a circle -
- wherein
Equation of normal of in
parametric form
Put a=2
we get t= -1
Hence equation is
Q. 57
The integral is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Integration By PARTS -
- wherein
Q. 58 A man is walking towards a vertical pillar in a straight path, at a uniform speed. At a certain
point A on the path, he observes that the angle of elevation of the top of the pillar is 300.
After walking for 10 minutes from A in the same direction, at a point B, he observes that the
angle of elevation of the top of the pillar is 600. Then the time taken (in minutes) by him,
from B to reach the pillar, is :
Correct Answer:
5
Solution:
As we learnt in
The height or length of an object or the distance between two distant objects can be determined with the
help of trigonometric ratios.
-
Let PQ represent pillar. Say height = h
In ,
In
Now, the person is walking at a uniform speed, hence time taken will be proportional to distance
travelled.
Thus,
Q. 59 The eccentricity of the hyperbola whose length of conjugate axis is equal to half of the
distance between its foci, is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As per the question
(Using )
Q. 60
The points
Option 1:
Form an obtuse angled triangle.
Option 2:
Form an acute angled triangle.
Option 3:
Form a right angled triangle.
Option 4:
Lie on a straight line.
Correct Answer:
Lie on a straight line.
Solution:
As we learnt in
Area of triangle
where vertices of ∆ ABC are A(x1,y1) , B(x2,y2), C(x3,y3)
If area of triangle is zero, then the three points must be lying on the same line (collinear)
Area of
Physics
Q. 1 A plano convex lens fits exactly into a plano concave lens. Their plane surfaces are parallel to
each other. If lenses are made of different materials of refractive indices and and R is
the radius of curvature of the curved surface of the lenses, then the focal length of the
combination is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
or
Q. 2 A parallel beam of fast moving electrons is incident normally on a narrow slit. A fluorescent
screen is placed at a large distance from the slit. If the speed of the electrons is increased,
which of the following statements is correct ?
Option 1:
The angular width of the central maximum will be unaffected.
Option 2:
Diffraction pattern is not observed on the screen in the case of electrons.
Option 3:
The angular width of the central maximum of the diffraction pattern will increase.
Option 4:
The angular width of the central maximum will decrease.
Correct Answer:
The angular width of the central maximum will decrease.
Solution:
As we learnt in
- wherein
slit width
Q. 3 For a normal eye, the cornea of eye provides a converging power of 40 D and the least
converging power of the eye lens behind the cornea is 20 D. Using this information, the
distance between the retina and the cornea - eye lens can be estimated be:
Option 1:
1.5 cm
Option 2:
5 cm
Option 3:
2.5 cm
Option 4:
1.67 cm
Correct Answer:
1.67 cm
Solution:
As we learnt in
Optical power of a mirror -
- wherein
Given,
and,
We have
Q. 4 In the Young's double-slit experiment, the intensity of light at a point on the screen where
the path difference is is K, ( being the wave length of light used). The intensity at a point
where the path difference is , will be:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Resultant Intensity of two wave -
- wherein
Intencity of wave 1
Intencity of wave 2
Phase difference
phase difference =
Q. 5 For a parallel beam of monochromatic light of wavelength ' ' diffraction is produced by a
single slit whose width 'a' is of the order of the wavelength of the light. If 'D' is the distance
of the screen from the slit, the width of the central maxima will be:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
For the condition of maxima
Q. 6 In a double slit experiment, the two slits are 1 mm apart and the screen is placed 1 m away.
A monochromatic light of wavelength 500 nm is used. What will be the width of each slit for
obtaining ten maxima of double slit within the central maxima of single slit pattern ?
Option 1:
0.5 mm
Option 2:
0.02 mm
Option 3:
0.2 mm
Option 4:
0.1 mm
Correct Answer:
0.2 mm
Solution:
As we learnt in
Fringe Width -
- wherein
Distance of
Maxima
Distance of
maxima
We need to obtain 10 maxima of double slit with in central maxima of single slit
or or ----------------------(1)
According to question
Q. 7 A beam of light consisting of red, green and blue colours is incident on a right angled prism.
The refractive index of the material of the prism for the above red, green and blue
wavelengths are 1.39, 1.44 and 1.47, respectively.
Option 1:
separate all the three colours from one another
Option 2:
not separate the three colours at all
Option 3:
separate the red colour part from the green and blue colours
Option 4:
separate the blue colour part from the red and green colours
Correct Answer:
separate the red colour part from the green and blue colours
Solution:
As we learnt in
Critical angle -
- wherein
When angle of incidence of a travelling from a dence medium to rarer medium is greater than critical
angle, no refraction occurs.
For green
For blue
Since refractive index of green and blue is greater than and hence their critical angles are less than
So green and blue will be completely reflected while red will emerge out of prism. Hence red will be
separated from green and blue.
Option 1:
Instrumental errors
Option 2:
Personal errors
Option 3:
Least count errors
Option 4:
Random errors
Correct Answer:
Random errors
Solution:
Cause is not known so, It is Random error.
Q. 9 If energy (E), velocity (V) and time (T) are chosen as the fundamental quantities, the
dimensional formula of surface tension will be:
Option 1:
Option 2:
[E V-2 T-2]
Option 3:
Option 4:
Correct Answer:
[E V-2 T-2]
Solution:
P=power
Surface Tension =
Surface Tension
Correct option is 1.
Option 1:
(Velocity)2/3
Option 2:
(Velocity)3/2
Option 3:
(Distance)2
Option 4:
(Distance)-2
Correct Answer:
(Velocity)3/2
Solution:
Q. 11 A particle has initial velocity and has acceleration . Its speed after
10 s is
Option 1:
10 units
Option 2:
7 units
Option 3:
7 units
Option 4:
8.5 units
Correct Answer:
7 units
Solution:
Q. 12 A particle moves a distance x in time t according to equation x=(t+5)-1. The acceleration of
particle is proportional to:
Option 1:
Option 2:
(distance)2
Option 3:
(distance)-2
Option 4:
Correct Answer:
Solution:
So
Similarly
Option 1:
9.9m
Option 2:
10.1m
Option 3:
10m
Option 4:
20m
Correct Answer:
10.1m
Solution:
As we learnt in
Tips of distance -
It is always positive.
Dimension
- wherein
Semi circle
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learned
- wherein
= Permittivity of vacuum
Energy density =
Q. 15 Which of the following statement is false for the properties of electromagnetic waves?
Option 1:
Both electric and magnetic field vectors attain the maxima and minima at the same place and same
time
Option 2:
The energy in electromagnetic wave is divided equally between electric and magnetic vectors
Option 3:
Both electric and magnetic field vectors are parallel to each and perpendicular to the direction to
propagation of wave
Option 4:
These waves do not require any material medium for propagation
Correct Answer:
Both electric and magnetic field vectors are parallel to each and perpendicular to the direction to
propagation of wave
Solution:
As we learnt in
Electromagnetic Wave -
EM wave have both electric and magnetic field mutually perpendicular and both perpendicular to
direction of propagation.
Option 1:
5
Option 2:
4
Option 3:
3
Option 4:
6
Correct Answer:
5
Solution:
As we learned
- wherein
= Permittivity of vacuum
Q. 17 A body of mass 'm' is taken from the earth's surface to the height equal to twice the radius
(R) of the earth. The change in potential energy of body will be:
Option 1:
Option 2:
mg 2R
Option 3:
Option 4:
3 mgR
Correct Answer:
Solution:
Mass = m, height = 2R
At height the acceleration due to gravity decreases , hence the value of acceleration due to gravity
becomes
Q. 18 A charged particle of mass m and charge q is released from rest in a uniform electric field E
. Neglecting the effect of gravity, the kinetic energy of the charged particle after ‘t’ second is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Force on particle=
Kinetic energy
Q. 19 A positively charged particle moving along x-axis with a certain velocity enters a uniform electric field
directed along positive y-axis. Its
Option 1:
Vertical velocity changes but horizontal velocity remains constant
Option 2:
Horizontal velocity changes but vertical velocity remains constant
Option 3:
Both vertical and horizontal velocities change
Option 4:
Neither vertical nor horizontal velocity changes
Correct Answer:
Vertical velocity changes but horizontal velocity remains constant
Solution:
As we have learned
- wherein
Vertical velocity changes due to electric field, but no change in horizontal velocity.
Q. 20
The potential energy of particle in a force field is, ,
where A and B are positive constants and r is the distance of particle from the centre of the
field. For stable equilibrium, the distance of the particle is:
Option 1:
B / 2A
Option 2:
2A / B
Option 3:
A/B
Option 4:
B/A
Correct Answer:
2A / B
Solution:
For equilibrium
For stable equilibrium
Q. 21 Four point charges -Q, -q, 2q and 2Q are placed, one at each corner of the square. The
relation between Q and q for which the potential at the centre of the square is zero is:
Option 1:
Q = -q
Option 2:
Option 3:
Q=q
Option 4:
Correct Answer:
Q = -q
Solution:
As we learnt in
- wherein
Potential at the centre O due to given charge configuration is
-Q-q+2q+2Q=0 Q+q=0 or Q= - q
Q. 22 ABC is an equilateral triangle with O as its centre , and represents three forces
acting along the sides AB, BC and AC respectively. If the total torque about O is zero the
magnitude of is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Q. 23 The two nearest harmonics of a tube closed at one end and open at other end are 220 Hz
and 260 Hz. What is the fundamental frequency of the system?
Option 1:
10 Hz
Option 2:
20 Hz
Option 3:
30 Hz
Option 4:
40 Hz
Correct Answer:
20 Hz
Solution:
As we learnt in
- wherein
length of pipe
number of overtones
Nearest harmonics of an organ pipe closed at one and differ by twice of its fundamental frequency
Q. 24 Three sound waves of equal amplitudes have frequencies (n - 1), n, (n + 1). They
superimpose to give beats. The number of beats produced per second will be
Option 1:
1
Option 2:
4
Option 3:
3
Option 4:
2
Correct Answer:
2
Solution:
As we learnt in
Beat -
A phenomena resuits when two sound wave having equal amplitude and travelling in a medium in the
same direction but having slightly different frequency.
Beat Frequency -
- wherein
Q. 25 The rate of increase of thermo-e.m.f. with the temperature at the neutral temperature of a
thermocouple:
Option 1:
Is negative
Option 2:
Is positive
Option 3:
Is zero
Option 4:
Depends upon the choice of the two materials of the thermocouple
Correct Answer:
Is zero
Solution:
The slope of thermo-e.m.f. with temperature at neutral point is zero.
Option 1:
20
Option 2:
11
Option 3:
10
Option 4:
9
Correct Answer:
10
Solution:
As we have learned
- wherein
External resistance
internal resistance
In series Grouping -
- wherein
Equivalent Resistance
In parallel Grouping -
Case I Case II
And
identical cells (having internal resistance 'r' each) which are connected in series. The terminals of
the battery are short-circuited and the current I is measured. Which of the graphs shows the
correct relationship between I and n ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learnt
Series Grouping -
- wherein
Q. 28 Six similar bulbs are connected as shown in the figure with a DC source of emf E, and zero
internal resistance.
The ratio of power consumption by the bulbs when 1) all are glowing and 2 ) in the situation
when two from section A and one from section B are glowing will be :
Option 1:
4: 9
Option 2:
9:4
Option 3:
1:2
Option 4:
2:1
Correct Answer:
9:4
Solution:
Option 2:
inductor
Option 3:
switch
Option 4:
fuse
Correct Answer:
fuse
Solution:
- wherein
Answer is fuse as it will work as open circuit.So current passing will be zero.
Q. 30 Which of the following represents the variation of the resistivity with temperature (T) for
copper?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The variation of resistivity of copper with temperature is parabolic in nature.
Q. 31 A charged particle having drift velocity of in an electric field of
has mobility in of:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 32 The half life period of radium is 1600 years. Its average life time will be-
Option 1:
4215 yrs
Option 2:
3250 yrs
Option 3:
2319 yrs
Option 4:
5000 yrs
Correct Answer:
2319 yrs
Solution:
Average life -
Average life -
Q. 33 A mixture consists of two radioactive materials A1 andA2 with half lives of 20 s and 10 s
respectively. Initially the mixture has 40 g of A1 and 160 g of A2. The amount of the two in
the mixture will become equal after:
Option 1:
60 s
Option 2:
80 s
Option 3:
20 s
Option 4:
40 s
Correct Answer:
40 s
Solution:
As we learnt in
or
- wherein
or
Q. 34 If the nuclear radius of 27Al is 3.6 fermi, the approximate nuclear radius of 64Cu in fermi is:
Option 1:
2.4
Option 2:
1.2
Option 3:
4.8
Option 4:
3.6
Correct Answer:
4.8
Solution:
Q. 35 A certain mass of Hydrogen is changed to Helium by the process of fusion. The Mass defect
in fusion reaction is 0.02866 u. The energy liberated per u is:
Option 1:
13.35 MeV
Option 2:
2.67 MeV
Option 3:
26.7 MeV
Option 4:
6.675 MeV
Correct Answer:
6.675 MeV
Solution:
Energy associated with 1u =931 MeV
As
=6.675 MeV
Q. 36 A radio isotope 'X' with a half life 1.4 x 109 years decays to 'Y' which is stable. A sample of the
rock from a cave was found to contain 'X' and 'Y' in the ratio 1:7. The age of the rock is :
Option 1:
1.96 x 109 years
Option 2:
3.92 x 109 years
Option 3:
4.20 x 109 years
Option 4:
8.40 x 109 years
Correct Answer:
4.20 x 109 years
Solution:
As we learnt in
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Work Function negligible
Q. 38 The graph which shows the variation of the De Broglie wavelength (A) of a particle and its
associated momentum (p) is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The Broglie wavelength of a particle is
momentum of particle
Q. 39 A gas is taken through the cycle A B C A, as shown. What is the net work done by the
gas?
Option 1:
-2000 J
Option 2:
2000 J
Option 3:
1000 J
Option 4:
Zero
Correct Answer:
1000 J
Solution:
As we learnt in
- wherein
Work is positive if cycle is clock wise. Work is negative if cycle is anti clock wise.
(for P - V diagram)
The given diagram is a P-V indicator diagram. Work done for P-V indicator diagram is area of the cycle.
Area of cycle
Correct option is 3.
Q. 40 A monoatomic gas at a pressure P, having a volume V expands isothermally to a volume 2 V,
and then adiabatically to a volume 16 V. The final pressure of the gas is:
Option 1:
64 P
Option 2:
32 P
Option 3:
Option 4:
16 P
Correct Answer:
Solution:
As learnt in
Equation of state -
- wherein
On solving
Option 1:
Option 2:
3 mgR
Option 3:
Option 4:
mg2R
Correct Answer:
Solution:
As we learnt in
mass of body
Mass of earth
- wherein
change in potential energy
Q. 42 Two vessels separately contain two ideal gases A and B at the same temperature, the
pressure of A being twice that of B. Under such conditions, the density of A is found to be
1.5 times the density of B. The ratio of molecular weight of A and B is:
Option 1:
Option 2:
2
Option 3:
Option 4:
Correct Answer:
Solution:
Ideal gas equation PV=nRT
OR
where
Q. 43 If cp and cv denote the specific heats (per unit mass) of an ideal gas of molecular weight M,
then (where R is the molar gas constant)
Option 1:
cp-cv=R/M2
Option 2:
cp-cv=R
Option 3:
cp-cv=R/M
Option 4:
cp-cv=MR
Correct Answer:
cp-cv=R/M
Solution:
Q. 44 There is a circular tube in a vertical plane. Two liquids which do not mix and of densities d1
and d2 are filled in the tube. Each liquid subtends 900 angles at the centre. The radius joining
their interface makes an angle with vertical. Ratio is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Pressure at interface A must be the same from both sides in equilibrium.
So
Q. 45 Three rods of Copper, Brass and Steel are welded together to form a Y - shaped structure.
Area of cross - section of each rod = 4 cm2. End of copper rod is maintained at 1000C
where as ends of brass and steel are kept at 00C. Lengths of the copper, brass and steel rods
are 46, 13 and 12 cms respectively. The rods are thermally insulated from surroundings
except at ends. Thermal conductivities of copper, brass and steel are 0.92, 0.26 and 0.12
CGS units respectively. Rate of heat flow through copper rod is :
Option 1:
1.2 cal/s
Option 2:
2.4 cal/s
Option 3:
4.8 cal/s
Option 4:
6.0 cal/s
Correct Answer:
4.8 cal/s
Solution:
The arrangement of rods is shown in the above figure.
So using
So
Option 1:
will become rigid showing no movement
Option 2:
will stay in any position
Option 3:
will stay in north-south direction only
Option 4:
will stay in east-west direction only
Correct Answer:
will stay in any position
Solution:
As we learnt in
Total intensity can be resolved into horizontal component (BH) and vertical component (Bv)
A compass needle which is allowed to move a horizontal plane is taken to a geomagnetic pole. It will
Stay in any Position as the horizontal. Component of earth is naganetic field become Zero at
the geomagnetic pole.
Q. 47 An -particle moves in a circular path of radius 0.83cm in the presence of a magnetic field
of . The wavelength associated with the particle will be:
Option 1:
1
Option 2:
0.1
Option 3:
10
Option 4:
0.01
Correct Answer:
0.01
Solution:
As we learnt in
-
Q. 48 A bar magnet of length 'l' and magnetic dipole moment 'M' is bent in the form of an arc as
shown in figure. The new magnetic dipole moment will be:
Option 1:
Option 2:
M
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
Q. 49 The output (X) of the logic circuit shown in figure will be:
Option 1:
Option 2:
Option 3:
Option 4:
X = A.B
Correct Answer:
X = A.B
Solution:
As we learnt in
AND Gate -
- wherein
Y is out put
Option 1:
Holes are majority carriers and trivalent atoms are dopants.
Option 2:
Electrons are majority carriers and trivalent atoms are dopants.
Option 3:
Electron are minority carriers and pentavalent atoms are dopants.
Option 4:
Holes are minority carriers and pentavalent atoms are dopants.
Correct Answer:
Holes are minority carriers and pentavalent atoms are dopants.
Solution:
The n-type semiconductor can be produced by doping impurity atoms of valence 5 i.e. pentavalent
atoms, i.e., phosphorous.
Q. 51 Two ideal diodes are connected to a battery as shown in the circuit. The current supplied by
the battery is:
Option 1:
0.75 A
Option 2:
zero
Option 3:
0.25 A
Option 4:
0.5 A
Correct Answer:
0.5 A
Solution:
As we learned in
P -N junction as diode -
It is a one way device. It offers a low resistance when forward biased and high resistance when reverse
biased.
- wherein
R = 0, Forward
R Reverse
Since D2 is in Reverse biased mode, hence no current will flow through it.
Correct Answer:
1584
Solution:
Ans: (1584)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 54 A light bulb and an inductor coil are connected to an ac source through a key as shown in
the figure below. The key is closed and after sometime an iron rod is inserted into the
interior of the inductor. The glow of the light bulb
Option 1:
remain unchanged
Option 2:
will fluctuate
Option 3:
increases
Option 4:
decreases
Correct Answer:
decreases
Solution:
As L increases, emf induced across the inductor will increase leaving less voltage across the bulb.
Therefore, the glow of the light bulb decreases.
Q. 55 A body of mass makes an elastic collision with a second body at rest and continues to
move in the original direction but with one fourth of its original speed.What is the mass (in
kg) of the second body ?
Solution:
- wherein
mass of body =
mass of body
A B
rest
(from e=1)
momentum balance
If and , the is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
- wherein
before collision:
after collision:
&
Q. 57 A car of mass 1000 kg negotiates a banked curve of radius 90 m on a frictionless road. If the
banking angle is 45°, the speed of the car is:
Option 1:
20 ms-1
Option 2:
30 ms-1
Option 3:
5 ms-1
Option 4:
10 ms-1
Correct Answer:
30 ms-1
Solution:
As we learnt in
Bending a Cyclist -
From figure.
(i)
(ii)
r = radius of track
- wherein
Correct option is 2.
Q. 58 A car is negotiating a curved road of radius R. The road is banked at an angle . The
coefficient of friction between the types of the car and the road is s. The maximum safe
velocity on this road is:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
angle of banking
coefficient of friction
V = velocity
- wherein
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Resolving power
- wherein
i.e.
Q. 60 A rope is wound around a hollow cylinder of mass 3 kg and radius 40 cm. What is the
angluar acceleration of the cylinder if the rope is pulled with a force of 30 N?
Option 1:
Option 2:
Option 3:
Option 4:
25
Correct Answer:
Solution:
As we learnt in
Torque -
- wherein
- wherein
Chemistry
Q. 1 The solubility of N2 in water at 300 K and 500 torr partial pressure is 0.01 g L−1. The solubility
(in g L−1) at 750 torr partial pressure is :
Option 1:
0.0075
Option 2:
0.015
Option 3:
0.02
Option 4:
0.005
Correct Answer:
0.015
Solution:
Q. 2 Vapour pressure of chloroform (CHCl3) and dichloromethane (CH2CI2) at 25oC are 200
mmHg and 415 mmHg respectively. Vapour pressure of the solution obtained by mixing 25.5
g of CHCI3 and 40 g of CH2CI2 at the same temperature will be :
Option 1:
615.0 mmHg
Option 2:
347.9 mmHg
Option 3:
285.5 mmHg
Option 4:
173.9 mmHg
Correct Answer:
347.9 mmHg
Solution:
As we learnt in
Rault's Law -
The total vapour pressure of a binary mixture of miscible liquids be having ideally is given by
Where and are mole fraction of A and B in liquid phase.
Moles of
Moles of
Option 2 is correct.
Q. 3 PA and PB are the vapour pressure of pure liquid components, A and B, respectively of an
ideal binary solution. If XA represents the mole fraction of component A, the total pressure
of the solution will be.
Option 1:
PA + XA ( PB - PA)
Option 2:
PA + XA (PA - PB)
Option 3:
PB + XA (PB - PA)
Option 4:
PB + XA (PA - PB)
Correct Answer:
PB + XA (PA - PB)
Solution:
As we learnt in
Raoult's law -
The total vapour pressure of a binary mixture of miscible liquids be having ideally is given by
Where and are mole fractions of A and B in the liquid phase
Given,
So,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
More positive the value of reduction potential, the stronger will be the oxidising agent thus is the
strongest oxidising agent.
Reduction Potentials are -
More Negative value or low value of reduction potential shows good reducing properties thus strongest
oxidising agent is .
Now, see below the value of oxidation potential has the highest value among others, It will be a better
reducing agent.
Q. 5 Four successive members of the first series of the transition metals are listed below. For
which one of the standard potential value has a positive sign?
Option 1:
Ni (Z = 28)
Option 2:
Cu (Z = 29)
Option 3:
Fe (Z = 26)
Option 4:
Co (Z = 27)
Correct Answer:
Cu (Z = 29)
Solution:
We know the standard electrode potential values-
The standard potential value of Cu has a positive sign.
Option 2 is correct.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
The more negative the value of the reduction potential, the stronger will be reducing agent, thus I- is the
strongest reducing agent. The more positive value of reduction potential shows good oxidizing
properties. Thus strongest oxidizing agent is F2.
Option 2:
C, D and E only
Option 3:
A and E only
Option 4:
B, C and E only
Correct Answer:
B, C and E only
Solution:
Statement (A) and (D) are incorrect.
Because → Atoms of all element are composed of there fundamental particles (e, p, n)
(D) 'Protons' & 'Neutrons' are collectively known as nucleons.
Q. 8 Which of the following reaction will NOT given primary amine as the product?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 9 Which condition is not satisfied by an ideal solution?
Option 1:
Option 2:
Option 3:
Option 4:
Obeyance to Raoult's Law
Correct Answer:
Solution:
Ideal Solutions-
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Ionization constant of weak acids -
Degree of dissociation
Option 1:
KCl
Option 2:
C6H12O6
Option 3:
Al2(SO4)3
Option 4:
K2SO4
Correct Answer:
Al2(SO4)3
Solution:
As we learned in
Where,
So,
Now,
Option 3 is correct.
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Nucleoside -
1. Pentose sugar
2. Nitrogenous base
Q. 13
Option 1:
Glucose and manmose
Option 2:
mannose and galactose
Option 3:
Glucose and fructose
Option 4:
fructose and galactose
Correct Answer:
Glucose and fructose
Solution:
As we have learned
Sucrose is boiled with dilute or in alcoholic solution , glucose (dextorotatory) and fructose
(laevorotatory) are obtained in equal amount .
- wherein
Glucose and fructose are obtained when sucrose is boiled with dilute acid
Q. 14
What is A ?
Option 1:
Fructose
Option 2:
Glucose
Option 3:
mannose
Option 4:
Galactose
Correct Answer:
Glucose
Solution:
As we have learned
Preparation of glucose from starch -
- wherein
Starch can be hydralysed to glucose by boiling with dilute acid or by actiion of enzymes like amylase
Q. 15 Four successive members of the first series of the tranisiton metals are listed below. For
which one of them the standard potential value has a positive sign?
Option 1:
Co (Z=27)
Option 2:
Ni (Z=28)
Option 3:
Cu (Z=29)
Option 4:
Fe (Z=26)
Correct Answer:
Cu (Z=29)
Solution:
Standard electrode potential -
The thermochemical parameters related to the transformation of the solid metal atoms to M2+ ions in
solution and their standard electrode potential Eo shown in fig.
-
Among the transition metals given, only has a positive standad potential
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learned in
Option 1:
40.800%
Option 2:
2.080%
Option 3:
20.800%
Option 4:
4.008%
Correct Answer:
4.008%
Solution:
Application of Kohlrausch's law -
Option 4 is correct.
Q. 18 Consider the complex ions -
Option 1:
Both (A) and (B) cannot be optically active.
Option 2:
Both (A) and (B) can be optically active.
Option 3:
(A) cannot be optically active, but (B) can be optically active.
Option 4:
(A) can be optically active, but (B) cannot be optically active.
Correct Answer:
(A) cannot be optically active, but (B) can be optically active.
Solution:
Trans - [Co(en)2Cl2]+ has plane of symmetry. So it is not optically active.
Cis - [Co(en)2Cl2]+ does not have any plane of symmetry, so it can be optically active.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Ru belongs to the 4d series of elements and ethylene diamine(en) is a chelating ligand which causes a
larger splitting in the 4d orbitals. This leads to a pairing of electrons in the orbital due to which the
electronic configuration is
is a weak field ligand which is unable to cause pairing in and hence the configuration is
accomodated as
Option 1:
-0.8 + 2P
Option 2:
-0.4
Option 3:
- 0.8
Option 4:
-0.4 +P
Correct Answer:
-0.4
Solution:
Means all ligands behaves as weak field ligands
So,
Q. 21 The boiling point of 0.2 mol kg-1 solution of X in water is greater than equimolal solution of Y
in water. Which one of the following statements is true in this case ?
Option 1:
Molecular mass of X is less than the molecular mass of Y.
Option 2:
Y is undergoing dissociation in water while X undergoes no change.
Option 3:
X is undergoing dissociation in water.
Option 4:
Molecular mass of X is greater than the molecular mass of Y.
Correct Answer:
X is undergoing dissociation in water.
Solution:
As we learned in
Where
degree of dissociation
Now,
The only factor among all the options that could make a difference is that "X" undergo dissociation
thereby making (i > 1) and therefore, having a higher boiling temperature. If Y is undergoing dissociation
in the water while X undergoes unchanged then Y will have more boiling than X.
It is equimolal, so there is no point to discuss or compare the molecular mass of X and the molecular
mass of Y.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
x x
y y
Now
Putting this we get
and
Option 1:
1:10
Option 2:
4:5
Option 3:
10:1
Option 4:
5:4
Correct Answer:
10:1
Solution:
As we learnt in
Value of Ka -
At a given temperature T, Ka is a measure of the strength of the acid HX. Ka is a dimensionless quantity.
The Correct answer is option 3.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
NaCl and KCl are salts of strong acids and strong bases and hence are neutral.
CuSO4 is salt of a weak base and strong acid hence, acidic in nature.
Among all the species given, is a salt of a weak acid and strong base which upon hydrolysis will
give a solution with the highest pH.
The of in water at
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Relation between Gibbs energy and reaction Quotient -
At equilibrium,
hence,
Q. 26 Because of lanthanoid contraction, which of the following pairs of elements have nearly the
same atomic radii? (Numbers in the parenthesis are atomic numbers).
Option 1:
Zr (40) and Hf (72)
Option 2:
Zr (40) and Ta (73)
Option 3:
Ti (22) and Zr (40)
Option 4:
Zr (40) and Nb (41)
Correct Answer:
Zr (40) and Hf (72)
Solution:
Due to lanthanoid contraction, the atomic radii of Zr and Hf are nearly the same.
Hf has atomic number 72 and has an electronic configuration of , due to the presence
of electrons in poorly shielded f-orbitals. Effective nuclear charge experienced by outermost electrons
increases and size of period 5 and 6 elements is nearly the same.
Q. 27 Assuming complete ionization, the same moles of which of the following compounds will
require the least amount of acidified for complete oxidation?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
In only required for oxidation of because in sulphur is in its maximum
oxidation state so requires the least number of moles of for oxidation.
While in the case of , sulfur has an oxidation state of +4 and will oxidize to ion having an
oxidation state of +6.
For, , C will oxidize to from oxalate ion changing oxidation state from +3 to +4.
Similarly, , Nitrite ions will oxidize to nitrate ions changing oxidation state of N from +3 to +5.
the correct answer is option 1.
Option 1:
alkenes
Option 2:
alkyl copper halides
Option 3:
alkanes
Option 4:
alkenyl halides
Correct Answer:
alkanes
Solution:
As we learnt in
- wherein
(alkane)
Q. 29 fG
0 at 500 K for substance ‘S’ in liquid state and gaseous state are +100.7 kcal mol −1 and
+103 kcal mol−1 , respectively. Vapour pressure (in atm) of liquid ‘S’ at 500 K is approximately
equal to : (R=2 cal K−1 mol−1 )
Correct Answer:
0.1
Solution:
Δ G of equilibrium
At Equilibrium
and
Q. 30 Given:
Correct Answer:
-56.2
Solution:
The given reaction can be obtained by multiplying the second reaction with 3 and adding with the first
equation
Option 1:
A and D
Option 2:
A and B
Option 3:
B and C
Option 4:
C and D
Correct Answer:
A and B
Solution:
As we learnt,
and,
Option 1:
sp, sp3 and sp2
Option 2:
sp2, sp3 and sp
Option 3:
sp, sp2 and sp3
Option 4:
sp2, sp and sp3
Correct Answer:
sp, sp2 and sp3
Solution:
Dettermination of shape of molecules using VSEPR Theory -
For
For
Q. 33 Which of the following pairs of ions are isoelectronic and isostructural ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Both have 42 electrons and trigonal planar geometry.
Q. 34 During change of O2 to ion, the electron adds on which one of the following orbitals?
Option 1:
orbital
Option 2:
orbital
Option 3:
orbital
Option 4:
orbital
Correct Answer:
orbital
Solution:
The incoming electron during change of to will enter in .
Q. 35 Gadolinium belongs to the 4f series. Its atomic number is 64. Which of the following is the
correct electronic configuration of gadolinium?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Electronic configuration -
Option 1:
a mixture of anisole and
Option 2:
a mixture of benzene and
Option 3:
a mixture of toluene and
Option 4:
a mixture of phenol and
Correct Answer:
a mixture of benzene and
Solution:
As learnt in
Zerewitinoff Method -
- wherein
Alkane is obtained.
- wherein
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
or
Therefore ;
Option 1:
by heating phenol with and
Option 2:
from aniline by diazotization followed by heating the diazonium salt with
Option 3:
by direct fluorination of benzene with gas
Option 4:
by reacting bromobenzene with solution.
Correct Answer:
from aniline by diazotization followed by heating the diazonium salt with
Solution:
As we learnt in
By Sandmeyer's reaction -
In the reaction benzene diazonium chloride is treated with cuprous chloride cuprous bromide.
Option 1:
and
Option 2:
and
Option 3:
and
Option 4:
and
Correct Answer:
and
Solution:
Diamagnetism -
When substance unaffected by a magnetic field or the central metal atom doesn't have unpaired e- called
Diamagnetic substance or character.
- wherein
No unpaired e-
Any species where central atom has no unpaired e- s is diamagnetic and thus colourless , e-
config. of
therefore, no unpaired e- s in
Option 1:
2-iodopropane
Option 2:
Allyl iodide
Option 3:
Propene
Option 4:
Glycerol triiodide
Correct Answer:
2-iodopropane
Solution:
When glycerol is treated with an excess of HI, it produces 2-iodopropane.
In the first step, a molecule of glycerol reacts with 3 HI molecules to form an unstable 1,2,3-
triiodopropane. This loses a molecule of iodine to form allyl iodide.
Allyl iodide adds a molecule of HI to obtain an unstable molecule which loses a molecule of iodine to
form propene.
Option 1:
4
Option 2:
2
Option 3:
5
Option 4:
3
Correct Answer:
3
Solution:
The common stable oxidation state of all the lanthanides is +3. It is attained by removing the outermost 2
electrons of 6s electrons and 1 electron from 4f electrons. It is due to the high energy difference in 4f and
6s, it is difficult to remove more electrons from the 4f sub-shell.
The oxidation state of + 2 and + 4 are also exhibited by some of the elements. These oxidation states are
only stable when stable 4f0, 4f7, or 4f14 configurations 4f0, 4f7, or 4f14 configurations are achieved.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt ,
Knoevenagel reaction -
Modified aldol condensation with nucleophilic addition between an aldehyde or ketone and an active
hydrogen compound, resulting in C-C bond formation.
- wherein
Option 1:
16
Option 2:
32
Option 3:
64
Option 4:
86
Correct Answer:
32
Solution:
Temperature Coefficient -
In homogenous thermal reaction, the rate constant of the reaction becomes double / thrice by changing
the temperature by .
- wherein
Formula:
So rate of reaction doubles by rise in which means that temp is increased by so rate of
reaction becomes times.
Q. 44 for a reaction
Option 1:
2
Option 2:
1
Option 3:
Can not be more than 2
Option 4:
Can not be determined
Correct Answer:
Can not be determined
Solution:
Order of a Reaction -
The order of a reaction is determined as the sum of the powers of the concentration terms that appear in
the experimental rate equation. It is an experimental quantity.
Formula:
The order has a relation with stoichiometry & is determined experimentally. It can be
zero/fraction/negative/positive
So, for the given reaction order can not be determined because experimentally determined stoichiometry
of powers of the concentration is not given.
Option 1:
Molecularity and order of reaction both are 2
Option 2:
Molecularity is 1 but order of reaction is 2
Option 3:
Molecularity is 2 but order of reaction is 1
Option 4:
Molecularity and order of reaction both are 1
Correct Answer:
Molecularity is 2 but order of reaction is 1
Solution:
As water used is in large excess thus, the order depends only upon the concentration of RCl.
However molecularity is the number of reactants taking part in a reaction, thus, here is equal to 2.
Q. 46 The rate law for a reaction between the substance A & B is given by
On doubling the concentration of A and halving the concentration of B, the ratio of the new
rate to the earlier rate of reaction will be as:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given, expression for rate
Therefore, option(1) is correct
Q. 47 Which of the following pairs of d-orbitals will have electron density along the axes?
Option 1:
d z 2, d x
Option 2:
dxz, dy
Option 3:
dz 2 , dx2 - y 2
Option 4:
dxy , dx2- y2
Correct Answer:
dz 2 , dx2 - y 2
Solution:
The shape of d orbitals :
Option 1:
2
Option 2:
6
Option 3:
10
Option 4:
14
Correct Answer:
6
Solution:
Each orbital contains 2 e.
n = 1 , l = 0 . m = 0 = 1s2
m has 3 value means 3 orbitals and each orbitals can have 2 electrons.
So total 6 electrons.
Q. 49 The formation of the oxide ion O2-(g), from oxygen atom requires first an exothermic and
then an endothermic step as shown below:
Option 1:
Electron repulsion outweighs the stability gained by achieving noble gas configuration.
Option 2:
ion has comparatively smaller size than oxygen atom.
Option 3:
Oxygen is more electronegative.
Option 4:
Addition of electron in oxygen results in larger size of the ion.
Correct Answer:
Electron repulsion outweighs the stability gained by achieving noble gas configuration.
Solution:
The first electron gain enthalpy of the Oxygen atom is negative, as when the electron is added, the
attractive forces between the incoming electron and nucleus outweigh the repulsions in between
electrons.
But on adding the second electron, the repulsions take over attractive forces, hence it's an endothermic
process.
Q. 50 The correct statement regarding a carbonyl compound with a hydrogen atom on its
alphacarbon is :
Option 1:
a carbonyl compound with a hydrogen atom on its alpha - carbon never equilibrates with its
corresponding enol.
Option 2:
a carbonyl compound with a hydrogen atom on its alpha - carbon rapidily equilibrates with its
corresponding enol and this process is known as aldehyde - ketone equilibration.
Option 3:
a carbonyl compound with a hydrogen atom on its alpha - carbon rapidly equilibrium with its
corresponding enol and this process is known as carbonylation.
Option 4:
a carbonyl compound with a hydrogen atom on its alpha - carbon rapidly equilibrates with its
corresponding enol and this process is known as keto - enol tautomerism.
Correct Answer:
a carbonyl compound with a hydrogen atom on its alpha - carbon rapidly equilibrates with its
corresponding enol and this process is known as keto - enol tautomerism.
Solution:
This is called keto - enol tautomerism.
Q. 51 The peptide that gives positive ceric ammonium nitrate and carbylamine tests is:
Option 1:
Ser-Lys
Option 2:
Gln-Asp
Option 3:
Lys-Asp
Option 4:
Asp-Gln
Correct Answer:
Ser-Lys
Solution:
As we have learnt,
Red coloration with Ceric ammonium nitrate confirms the presence of alcohols
Foul smelling isocyanide obtained in the Carbylamine Reaction indicates the presence of Primary amines
Thus,
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
is Hinsberg's reagent,
Hinsberg's reagent is used for the detection of primary, secondary and tertiary amine
Therefore, Option (3) is correct.
Q. 53 At which carbon number in the chain does fructose contain a ketone group ?
Option 1:
1st
Option 2:
2nd
Option 3:
3rd
Option 4:
4th
Correct Answer:
2nd
Solution:
As we have learned
Q. 54 What quantity (in mL) of a 45% acid solution of a monoprotic strong acid must be mixed with
a 20% solution of the same acid to produce 800 mL of a 29.875% acid solution?
Option 1:
320
Option 2:
325
Option 3:
316
Option 4:
330
Correct Answer:
316
Solution:
45% acid solution means 45ml of acid dissolved in 100ml of solution.
Suppose if 45% ACID solution is present in V volume in the final solution after mixing. then if the total
volume of the final solution is 800 then another acid solution of 20% acid must be (800 -V) volume.
Now,
As we have learnt,
Q. 55 1 gram of a carbonate (M2CO3) on treatment with excess HCl produces 0.01186 mole of
CO2. The molar mass of M2CO3 in g mol−1 is :
Correct Answer:
84.3
Solution:
As we have learnt,
Number of Moles -
No of moles = given mass of substance/ molar mass of a substance
Q. 56 Suppose the elements X and Y combine to form two compounds XY2 and X3Y2. When 0.1
mole of XY2 weighs 10 g and 0.05 mole of X3Y2 weighs 9 g, the atomic weights of X and Y are:
Option 1:
40, 30
Option 2:
60, 40
Option 3:
20, 30
Option 4:
30, 20
Correct Answer:
40, 30
Solution:
Let the atomic weight of X = x
then,
and
On solving, we get
Q. 57 Suppose the elements X and Y combine to form two compounds XY2 and X3Y2. When 0.1
mole of XY2 weighs 10 g and 0.05 mole of X3Y2 weighs 9 g, the atomic weights of X and Y are
Option 1:
40, 30
Option 2:
60, 40
Option 3:
20, 30
Option 4:
30, 20
Correct Answer:
40, 30
Solution:
Let the atomic weight of X = x
then,
and
On solving, we get
Q. 58 Amongst the elements with following electronic configurations, which one of them may have
the highest ionization energy?
Option 1:
Ne [3s23p2]
Option 2:
Ar [3d104s24p3 ]
Option 3:
Ne [3s23p1]
Option 4:
Ne [3s23p3]
Correct Answer:
Ne [3s23p3]
Solution:
Option (d) has the highest ionisation energy because of extra stability associated with half-filled 3p-
orbital. In option (b), the presence of 3d10 electrons offers shielding effect, as a result the 4p3 electrons
do not experience much nuclear charge and hence the electrons can be removed easily.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
HCOOH + C2H5OH
Option 2:
CH3COOH + C2H5OH
Option 3:
HCOOH + CH3OH
Option 4:
CH3COOH + CH3OH
Correct Answer:
CH3COOH + CH3OH
Solution:
As we learnt ,
- wherein
Maths
Q. 1
The value of is equal to:
Option 1:
560
Option 2:
680
Option 3:
1240
Option 4:
1085
Correct Answer:
680
Solution:
As we learnt,
Correct option is 2.
Q. 2 If the Rolle’s theorem holds for the function in the interval [-1,1] for
the point , then the value of is :
Correct Answer:
-1
Solution:
As we have learned
Rolle's Theorems -
3.
Let f(x) be a function defined on [a, b] such that the curve y = f(x) is continuous between points {a, f(a)}
and {b, f(b)} at every points on the curve encept at the end point it is possible to draw a unique tangent
and ordinates at x = a and x = b are equal f(a) = f(b).
- wherein
We have
Q. 3
if for is equal to :
Option 1:
-9
Option 2:
10e
Option 3:
-9e
Option 4:
10
Correct Answer:
-9e
Solution:
As we have learned
Integration By PARTS -
- wherein
So,
Q. 4 The largest value of r for which the region represented by the set
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
Perpendicular bisector -
- wherein
and are any two fixed points . z is a moving point in the plain which is equidistant from and .so
z will lie on perpendicular bisector
Equation of circle -
= centre of circle
r= radius of circle
z lies on circle.
- wherein
1)
2)
3)
distance =
Q. 5 Let L be the line passing through the point P(1, 2) such that its intercepted segment
between the co-ordinate axes is bisected at P. If L1 is the line perpendicular to L and passing
through the point (-2, 1), then the point of intersection of L and L1 is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
- wherein
Here
Line is
Option 1:
no solution
Option 2:
one solution
Option 3:
two solutions
Option 4:
more than two solutions
Correct Answer:
one solution
Solution:
x +λy −z = 0
λx − y − z = 0
x + y − λz = 0
Option 1:
infinitely many values of λ.
Option 2:
exactly one value of λ.
Option 3:
exactly two values of λ.
Option 4:
exactly three values of λ.
Correct Answer:
exactly three values of λ.
Solution:
As we learnt in
When and ,
- wherein
and
Q. 8 If the differential equation representing the family of all circles touching -axis at the origin
is equals :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
A differential equation can be derived from its equation by the process of differentiation and other
algebraical process of elimination
-
Let the equation of circle is
or
Put a in (i)
Q. 9
The integral is equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Integration by substitution -
The functions when on substitution of the variable of integration to some quantity gives any one of
standard formulas.
- wherein
Put y=
Q. 10
if then is equal to :
Correct Answer:
3
Solution:
As we learnt in
Q. 11 Let P be the relation defined on the set of all real numbers such that
.Then P is
Option 1:
reflexive and symmetric but not Transitive.
Option 2:
reflexive and transitive but not symmetric.
Option 3:
symmetric and Transitive but not reflexive.
Option 4:
an equivalence relation.
Correct Answer:
an equivalence relation.
Solution:
Hence P is Reflexive
Using Equation 1
Hence P is symmetric
Adding Eq 1 and 2
Hence, P is Transitive
So P is an equivalence relation
Q. 12 The sum of the 3rd and the 4th terms of a G.P. is 60 and the product of its first three terms is
1000. If the first term of this G.P. is positive, then its 7th term is :
Correct Answer:
320
Solution:
As we learnt in
General term of a GP -
where
first term
common ratio
Also
put in
Q. 13
The value of
is equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Let
As, ..............( i )
- {From ( i )}
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
- wherein
Option 1:
n2 + 3n − 108 = 0
Option 2:
n2 + 5n − 84 = 0
Option 3:
n2 + 2n − 80 = 0
Option 4:
n2 + n − 110 = 0
Correct Answer:
n2 + 3n − 108 = 0
Solution:
Q. 16 Let
Option 1:
is not differentiable at x = 0
Option 2:
is differentiable at x = 0,but is not continuous at x = 0
Option 3:
is continuous at x = 0 but it is not differentiable at x = 0.
Option 4:
is differentiable at x = 0.
Correct Answer:
is continuous at x = 0 but it is not differentiable at x = 0.
Q. 17
If denotes the greatest integer function, then the integral is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
The area between the curve axis and two ordinates at the point
is given by
- wherein
Hence, the value of integral will be given by area under the curve along with its sign.
Hence,
Option 1:
does not exist.
Option 2:
exists and is equal to
Option 3:
exists and is equal to
Option 4:
exists and is equal to
Correct Answer:
exists and is equal to
Solution:
As we have learned
- wherein
- wherein
and
Q. 19 If y + 3x = 0 is the equation of a chord of the circle, x2 + y2 - 30x = 0, then the equation of the
circle with this chord as diameter is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
First let us find out the end points of this chord of the given circle
Its end points are its points of intersection with the given circle
Now these points are the end points of our required circle
Q. 20 For the curve y = 3 sin cos , x= sin , , the tangent is parallel to x-axis when
is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Slope of a line -
If is the angle at which a straight line is inclined to a positive direction of x-axis, then the slope is defined by
- wherein
is
non-negative, is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
-
So that minimum value of x, y, z are: x = -2, y = -2 and z = -2 which satisfy this inequality.
Q. 22
If the general solution of the differential equation for some function is
given by where c is an arbitrary constant, then (2) is equal to :
Option 1:
4
Option 2:
Option 3:
-4
Option 4:
Correct Answer:
Solution:
and
Q. 23
If for a continuous function
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
- wherein
Q. 25 Let be an odd function defined on the set of real numbers such that for
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 26
If then k is equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
So,
.......
Adding these
Solution:
As we learnt in
Trigonometric Equations -
The equations involving trigonometric function of unknown angles are known as trigonometric
equations.
- wherein
e.g.
Let, and
and
..............( 1 )
.............. ( 2 )
From ( 1 ) and ( 2 ),
Option 1:
84
Option 2:
336
Option 3:
315
Option 4:
256
Correct Answer:
336
Solution:
As we have learned.
If and are two vectors and is the angle between them , then
- wherein
- wherein
Option 1:
46th
Option 2:
59th
Option 3:
52nd
Option 4:
58th
Correct Answer:
58th
Solution:
Alphabetical order A, L, L, M, S
and
Option 1:
Both statements I and II are false.
Option 2:
Both statements I and II are true.
Option 3:
Statement I is true, statement II is false.
Option 4:
Statement I is false, statement II is true.
Correct Answer:
Both statements I and II are true.
Solution:
As we learnt in
and
So f(x) is continuous at x = 0
Q. 31
If is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
Integration By PARTS -
Replace t by x3
Q. 32
If a>0 and , has magnitude ,
then is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
(a+ib)(c+id)=(ac-bd)+i(bc+ad)
- wherein
given that
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Equation of tangent -
- wherein
Tangent to circle
at
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Given that, g(x) is inverse of f(x)
now,
Q. 35
If then which one of the following statements is not correct ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Multiplication of matrices -
-
For option 3,
Q. 36
The general solution of the differential equation, ,is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
=>P=-cosec2x
I.F. =
Option 1:
Option 2:
9
Option 3:
36
Option 4:
18
Correct Answer:
9
Solution:
As learnt in concept
Let be two curve then area bounded between the curves and the lines
x = a and x = b is
- wherein
Where
Q. 38
If ,for all x in R, then a2 is :
Option 1:
-4
Option 2:
6
Option 3:
-8
Option 4:
10
Correct Answer:
-4
Solution:
Using
If
on expansion,
Now differentiate
Differentiating again
Option 2:
16
Option 3:
8
Option 4:
64
Correct Answer:
16
Solution:
Consider set .
All elements of the set A, defined by x, are also contained in Z, the set of integers. It's also given that the
absolute value of these elements is strictly less than 3.
And also,
Thus,
Q. 40 If m is the A.M. of two distinct real numbers l and n (l, n > 1) and G1, G2 and G3 are three
geometric means between l and n, then
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
and
Now,
Given l + n = 2m .........(i)
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Trigonometric Equations -
The equations involving trigonometric function of unknown angles are known as trigonometric
equations.
- wherein
e.g.
...............( 1 )
Now, and,
Let
Then, ( 1 ) becomes:
Q. 42 The length of the projection of the line segment joining the points (5, −1, 4) and (4, −1, 3) on
the plane, x+y+z=7 is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Projection of line segment joining the points P(x1,y1,z1) and Q(x2,y2,z2) on a line having direction cosines (l,m,n) is
- wherein
Also PQ = BC
Also
Q. 43 ABC is a triangle in a plane with vertices A(2, 3, 5), B(−1, 3, 2) and C(λ, 5, µ). If the median
through A is equally inclined to the coordinate axes, then the value of (λ3+µ3+5) is :
Option 1:
1130
Option 2:
1348
Option 3:
676
Option 4:
1077
Correct Answer:
1348
Solution:
DRs of median
So,
So,
Option 1:
7th and 8th
Option 2:
8th and 9th
Option 3:
28th and 29th
Option 4:
27th and 28th
Correct Answer:
8th and 9th
Solution:
As we have learned
Q. 45 Let a vertical tower AB have its end A on the level ground. Let C be the mid-point of AB and
P be a point on the ground such that AP=2AB. If , then tan β is equal to :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
The height or length of an object or the distance between two distant objects can be determined with the
help of trigonometric ratios.
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Let P(E) = x and P(F) = y
and P (neither E nor F happens)
= P( E' ∩ F')
= P(E').P(F')
= (1 - P(E)).(1 - P(F))
= (1 - x)(1 - y)
So (1 - x)(1 - y) = 1/2
and
Option 1:
4
Option 2:
1
Option 3:
2
Option 4:
3
Correct Answer:
3
Solution:
For two lines to be coplanar
Two values of are possible
Q. 48 If the coefficients of the three successive terms in the binomial expansion of (1+x)n are in
the ratio 1 : 7 : 42, then coefficient of first of these three terms is
Option 1:
Option 2:
Option 3:
Option 4:
None of these
Correct Answer:
Solution:
As we learnt in
and
Now,
Thus (i)
Also, (ii)
n - 7r = 6 (from (i))
n - 8r = - 1 (from (ii))
Thus r = 7, n = 55
Q. 49
The value of is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Q. 50 Consider the following linear programming problem
Maximize
Subject to
Option 1:
P=0
Option 2:
P<0
Option 3:
P=2
Option 4:
P>0
Correct Answer:
P<0
Solution:
As we learnt in
Decision Variables -
-
for
= 0+7 at (0,7)
Z = 16 P + 0 = 16 P at (16, 0)
so that for
are real and distinct, then the set of all values of ‘a’ is :
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
- wherein
So
But
So
Correct option is 3.
Q. 52 An ellipse passes through the foci of the hyperbola, and its major and
minor axes lie along the transverse and conjugate axes of the hyperbola respectively. If the
product of eccentricities of the two conics is then which of the following points does not
lie on the ellipse ?
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we learnt in
Eccentricity -
- wherein
Coordinates of foci -
- wherein
Also
Statement - II :
Option 1:
Statement - I is false; Statement - II is true
Option 2:
Statement - I is true ; Statement - II is true; Statement - II is a correct explanation for Statement-I
Option 3:
Statement - I is true ; Statement - II is true; Statement - II is not a correct explanation for Statement-I
Option 4:
Statement - I is true; Statement - II is false
Correct Answer:
Statement - I is false; Statement - II is true
Solution:
I=
Q. 54 PQR is a triangular park with PQ=PR=200 m. A T.V. tower stands at the mid-point of QR. If
the angles of elevation of the top of the tower at P, Q
and R are respectively 45º, 30º and 30º, then the height of the tower (in m) is :
Option 1:
Option 2:
100
Option 3:
50
Option 4:
100
Correct Answer:
100
Solution:
As we learnt in
Angle of Depression -
If an object is below the horizontal line from the eye, we have to lower our head to view the object.
- wherein
In
Option 1:
straight line parallel to x-axis.
Option 2:
straight line parallel to y-axis.
Option 3:
circle of radius 2.
Option 4:
circle of radius
Correct Answer:
circle of radius 2.
Solution:
As we have learned
- wherein
Given ,
Q. 56 A straight line L through the point (3, -2) is inclined at an angle of 60o to the line
. If L also intersects the -axis, then the equation of L is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
Let the slope of line L be m
On solving
But y + 2 = 0 does not intersect x-axis as it is parallel to it, so th either line is the answer
Q. 57
The intercepts on x-axis made by tangents to the curve , ,which are
parallel to the line y = 2x ,are equal to:
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As we have learned
We have , dy/dx = 2
So, x =
For x = 2
So , (y-2) = 2 (x-2)
x- intercept = 1
Similarly for x = -2
x intercept = -1
Option 1:
1
Option 2:
2
Option 3:
3
Option 4:
4
Correct Answer:
1
Solution:
As we learned,
- wherein
and
- wherein
Q. 59 If the incentre of an equilateral triangle is (1, 1) and the equation of its one side is
Option 1:
Option 2:
Option 3:
Option 4:
Correct Answer:
Solution:
As learnt in concept
- wherein
- wherein
Distance of O from BC
is
= 2 units
Option 1:
Option 2:
Option 3:
3
Option 4:
5
Correct Answer:
3
Solution:
As learnt in concept
- wherein
Equation of a circle -
- wherein
radius = |h|
equartion of circle is
So centre is
AB = 2(AM) =