© Cau go chét - Dai cong hod hye in eta NO VO bE mat durye cho bon cong thite: 9 tia kh (K); iki vgn cia phn tar Khi (kg) 4+ ky hiing s6 Boltzmann «= 1,3806.10"(J.K-P, + Cho biét: x= 3,14, a, Xie dinh don vi cita Zsému (bigu din theo don vi m vas). ant [ge [ Pas A Nive ao a), Nimet — Ban at Guia td on | ag ter Naps Taine apn a | ag? Cenyad! Co Replace |? phan bie 4. A Ta hop chat tgo nén tir 2 nguyén 18 X vi ¥, tig ban kinh ion X va Y trong tinh thé li ry : ry = 1,772. Té bao tinh thé A 06 46 dic khit la 68.27%, duge m6 ta ¢ hinh bén, dang hinh hép chi nhgt voi a= b= 4.59 gia cho kem chéng ning, déng théi A cd vai trd to lon trong nén cong nghiép luyén kim, d§c bigt trong nginh hing khéng. Xe dinh ban kinh ion X, ¥ trong A. Xac dinh céng thite chat A. ME we er ag OAS A) t Aye ABR pe padhao : V, oro) > Ye Myth | oy thas A i hd =o Crys 068e 6 8,athe se) =) ™M Fenny Hib ALIS De (| W Dy Pye AL = ase Sql = = ARN 9 | =) W)=) WIRE? Anas an afie eal i | ys f Pua! OOH sdb) mA: S10 2 . \ cA S e 8 c\~) Q2-1 Hoa bi f ¥ ing) e y 2 ] | Ciu2: Lb —. i oe Thang diém | . | Diém chim | | 1. Trong 18 bao sinh hoe, ning lugng thoit ra bai qui trinh ox: héa cia mau duge lu tnt trong adenosine triphosphate (ATP hoéc ATP), Hoat ding chi yéu cua ATP ld khi ning mit nbém phosphate eudi cung bo gud trinh thay phin va hinh thinh adenosine diphosphate ( ADP hoc ADP* ATP + HzO -+ ADP™+ HPOS + 150" = Tai pH = 7 VA 37°C ning lung Gibbs vi enthalpy cia qua trinh thay phin Lin lugt li: A,G= -31 20 kJ.mot", Trong digu kign nay, Khi thiy phin 1 mol ATP* thu duge 31kI ning duge diing dé thye ign céng c6 ich( vi dy cho qui trinh ting hop protein tr cic amino _acid hode cho sy co ca va nhimg hot ding tide cua no BO) a, Tinh va ‘A310K ATP tai pH ¢ dinh dau cua entropy cua qua tinh thay phin 2 45 justi! | b. Gia sir ving, ban Kinh cia 1 bio sinh hoe dign hinh if 10m va chia trong no 10° phan wr ATP b thay phin mdi gidy. Tinh mit d6 cp nang lugng cia té bio theo don vi Wim’, ( so sinh voi mit d3 cp _nding lugng cia mot pin may tinh 6 thé tich 100em' eéng suit 15WW ). Les we AL = 150000 Whe hge Bh wel Sieg cate ay ia oe [re stern Ate’ ba: yn A= 4 4 ay. Pe asain C = oS "1660308 ul 5 ae ce bo) goa als Ang = 4.660308. 34 WF = “HUE ‘ do 140 ba: [esis = 4a,Qgt ult War 2 QQ VBy fmt cua Ae! baw mid Aso nia B cub (UP «. Qua trinh hinh thinh glutamine tir glutamate va ion amonium cén ding 14,2 kJ,mol" nang lugng. Ning lung nay duge chuyén tir qué trinh thay phin ATP thanh ADP xidc tic béi enzyme “ glutamine synthetase ", Bao nhigu phin tu ATP phai bj thay phan dé tgo durge | phan tir glutamine. och has pio es© Q2-3 2. Phan img Heck la mét phan img ghép cap chéo, duge ding dé tao ra cc lién két don carbon-carbon, Phuong trinh phan img tng quat durge cho dui day: Pd(OAcle wx + AR ae ANAAR = X ki higu cho m6t nhém réi di rit wt (vi dy nhur iodide, bromide ho¥e tosylate). Day li phan img duge xiie tte béi palladium, c6 co ché rat phite tap. Sau day, phan img Heck ciia phenyl iodide vor n-buty! acrylate duge nghién citu chi tiét hon, Mét cor ché kha di due dura ra dudi day trong chu trinh xic tic cia phan img. ki, ka vi ks ki higu cde hing sé te d6 cita cic phan img co ban tong img. L ki higu cia ‘mét phdi tirtrung hda, khéng tryc tigp tham gia vio phan tg, vi dy nhu PPh. n-butyl acrylate eiing la ‘mét phdi tir trung hoa, géc pheny! 1d m6t phéi tir dign tich -1 °, ‘om 1. Véi mai tiéu phan palladium hogt déng (1 dén 3), hy chi ra trang théi oxi hoa eda palladium trang thai oxi héa hay ghi oxide héa day. Bm A: Pd bs Ap dung trang thai gid-Gn djnh (quasi-steady state) cho efe trung gian 1, 2, 3, chimg minh ring su tigu thy phenyl iodide 06 thé bigu dién theo: Phi} ykakey (PHIL TAL [Pages dt Wak (AD + Fee PN TAY + kk PIT2 Q2-4 cocyasn Tt, bag 0 Sb atu oo cot too ] 5 ayvan - ae oUt I+ eee 0a) aay = RALAPHTI-h pad isl=o @ = ky (QIAI- &o23) = @) => t=O ALT) j eord Suda v0 Hit 4 Agr “hon Ww: Cas = Ul tLadt ey) = Cafe kitts 4, ? Tae Wilags Abyl _ LPT Ve, +4 WhTI hey + eH Mbt Anak: —0Mh EI. AyC COURT] he tus = ~ Ath . ele, CIRTIEAIL? one BORE? 4 ged) Af otd + dk f7 Q 2-5 ¢, Xae dinh bac phan img bie ndng do cua A rat nho. Bai lam: ue GAT nae mh oy Sth Ub, by LT DEAILI Dye bes “he REA ALI = Ayhy by UOas Bye Ba Mo OdIgos = const => Pad diy baot.© Q3-1 Hou hyc phan tich 1, BE nghiém city GFAJ-I (ent loat vi khuin 6 khd ning chyu duge nbng 46 cao arsen thi nghugm, ngutin te wén hanh pha céc dung dich bing cach tron dung dich NaOH 0,5 M (d ven dung dich HAsO. 0.5 M (dung dich By Thém mot lugng thé tich xc ¢inh dung dich A va B vo trong binh éinh mac ven thé tich 100 mL. Saw 6 thém vao nude cit Gin vach vi trim ki. Ke qua thu duge dung dich C vai pH = 10.4 va ting ming 65 As(V) 1a 0.98 4 ‘4. Tinh thé tich (ml.) dung dich A va B 3 duge ding éé pha du Cho bidt: HsAsOs co pKa) = 2,19; pKa: = 6.94; pKay = 11,5. fustins To COB, = 2UASIC pics | 0,5 Ve = 204-Vc im | Vg “o.04 100 = BCrenL) | GN v | Os Zy CURIS OS Ye 4 | ae, Pe Os = he | , ‘400 oe td ton to | Wathat e ee = Fg. Ie cape] BP 231s (? fea has cot} aattrely J 4 foe a > Nabi phdosing % FE |=) 06M = o.oum1a.2aKl dich C rae = 9904 v S. 4 | ti uP sn irda Chey lye “ & me) parry cl), Cog) hang =) Vr 10156 Go oe Beet es | Bnet ach Ln, | By gig. tse Site dubs E. =) ANY no 7? Wamwg 32 O08 dat | ons ~ Mot trong nhimg phuong phip mi cic doanhnghigp Tuya kim sir Gung d¥ Topi Ba ansenie Kin nae ‘thai la ket tha ching dudi dang Cas(AsO.)s (Ksp = 7.24-10°?. Nhuge diém cia vige ding phurong phip ny la d® tan ctia Cax(AsO.): cin phy thude ding ké vio pH, do dé ma khi diéu kign béa ngoai thay di ing ¢ thé khién Cay(AsOs)stré thinh nguba arsenic giy 8 nhigm mai trromg. ~ Cho 100 mL dung dich dgm c& pH = 5,6 khong chia arsenic vi calcium vio mgt miu Ca AsOu)s co khdi lugng 10 gam. b, Tinh di tan (g/L) cia Cay( AsO.) trong dung dich dim. - Giii sir; Thanh phin cia dung dich dgm khéng tham gia vio eéc cin bing canh tranh, uwOC AD teary celle Cu, ta et M) yc (Aso ni eran 5 ays 5 as sack ae HASOG bho & Abas to Khe Os, 5 hy “i ik Aigpidg FAVS Urait et Hy oat Ayo = 4th 4or ee a =U os BEI =)$= + aesos cM) B3al aT "s A heat. As one Sz trsdy JH CHhCeR] 5 + Lt aie Uihso4) ase cm eee Web ally 3 + ors 2. Cye pho Ii mge ki thuat duye ip dung dé xie dink 6 Kim Tool, ThE ién thign (vi trong exring d9 dong 2, 25 7H trong dung dich, s@ €6 syetaing, - | / ‘Voi ndng 46 eiia ion L/ ———. sémg) phy thuge vito yy di thé two curing dp Ine J = UE hove cutmg A bai thé So dd dung cy dé phan tich sy phin cyte: 1 ~ té bio dign hod (vai dign ewe 18 bé thuy ngiin; 2 ~ dign ‘eye thu ngiin nhé gigt; 3 ~ b9 do pin; 4 ~ bp do thé; 5 ~ ngudn din.© Q41 Hoa hoc phan tich . ¥ 41 42 Tong Cau 4 7 ns G07 [thane diém [2 2 Ey ‘Diém cham 1, Mot dung dich chira ding thai ca Fe?’ va Fe’ 6 ndng d6 ban dau déu bing 0.1 M; dum pH cia dung ch lén gia tri pl = 10 (coi thé tich cua dung dich khong dé 1. Tinh néng d6 cdc ion sit va thé oxid hod khir cia ejip Fe’ ‘Tich sé tan cia Fe(OH): va Fe(OH); Hin lugt bing 10°! va 10%. B = Cho bid Phnnee tat ragh=0 sos = totJ= af Ceet wit an vy L fepgt Coe 2” 20,4 Ure we = Co! Atuin ROW, Som, I) R27 = Ksem er. -i0\ DAP (OP ye ce d= "Seong (0 ity fora Te ae RY t42 98 hu pedysrrnb. horost Ewtipt= Foye SE eet = ope 00g = 0185600)© Q4-: b. Ngudi t dua mot lugng dur mat sit vio dung dich trén (pH vin duge gitt khong déi 6 pH = 10). Hig tugng gi cd thé xay ra tai thoi diém 46, gidi thich? = Tinh néng d6 cdc ion va thinh phan cia két tiia @ trang thai cudi. Bai lam: Ta. Hy: Egat ge ER he (Go ob pra ay ny: G+ RAZR OU) Be Be Me Say ACE Rs “Ef =) be to 2 QCOAT TOW) 18 E = (0 Cssr 5 iC vt q> ES enn Vii ~harnevSh, d2mat Did, “J val “run, Friel, an et ah Bax, Bint Aron archi Sal wai CRI = OTH > wrtys (RS ; 3-15 okT=- Go — 0 M \ (8© Q43 2. Phuong phap chuiin 46 iodide va chuiin 46 véi methyl da eam (MO) durge sir dung dé xéc dinh him lurgng chlorine hogt dng trong nude. Trong trudng hgp dau tién, chuyén 0,5 gam KI vio 100 mL nude cin phin tich, h¢ duge gitr 6 pH 4,5 bai dém acetate, r8i chudin d6 iodine gidi phéng bing dung dich Na2$:03 0,005 M. Khi chuiin 46 visi MO thi nhé 2 - 3 gigt HCI 5 M vio 100 mL nude can phiin tich, roi chuan dé voi dung dich MO 0,005 % - bj mat mau trong diéu kign nay, Diém cudi cia chudn dg tuong img v6i sy xudt hign mau hong. N-< SON i VF sone cS MO a. Tai sao chudn d@ iodine phai tign hanh o pH 4,5 nhung khéng phai trong méi trrémg co tinh acid cao hon hofe co tinh kiém? Viét phurong trinh cua cdc phan img phy cé thé xdy ra. ee ed ‘Trang mmou'tychbng Ain VHong, ano! “uty es ot oS TREE wet 36, QO asd aur +Meo 9p tet 8+ BHO Ty ay tattle? ae esis by, Viel phurong trinh cae phan ig xay ra trong phép chun do chlorine theo hai phurong phap mo ta Chi y ring cn 0,5 mL dung dich thiosulfate hoge 4,61 mL dung dich methyl da cam dé chun d9 100 mL miu nude chia | mg/L chlorine hda tan, va nitrogen phiin ti lt m6t trong ec sin phim eda phan mg gitta MO véi chlorine.© Q5-1 Héa hoc nguyén té Cau 5: 20% |. hit X trong HNOs de tao thinh dun axit AJ twang ddi mgnh. Axit nay mat made dn thanh anhidrit A2 (chita 23,95% khdi lugng 1a oxi). Dun néng AL voi oleum: thu duge hgp chit sng khi phan tiny. gidta AL va don chdt X trong H»SOc de tuo ra Ad. A3 vi Ad tds tao thdnh nr bi én 18 vii phn tram khoi lugng ciia nguyen t6 X vai oxi trong AB 1a 51.42%; 35.63% vi trong Ad | 25.13% 1, Xie dinh cae hyp chit AL — Ad vi viet phuumg trinh hda hoe eho ede phan dng xdy ra. [sao AQ: RDiy Ope? aie Ge ak HITTITE S | | 9 > ta = 2 068y [> > Mins AB 5 28a guts Bi 52 Tang Pho dng etia don hhoain toiin & 2 6643 Te al 2) ha SbkyAly 2847 YP |, f Retangu! joo sce aca |? 1 ge 9 Gear nth La YrBp Oy". | ['r > Grand. pe | r=2 7 ty Nays Aonyt UXO 40, 2 Type tho yb, 1280, —> L0y.20, c — 1.8 GAOL UF SHO ostagsy,+ Say) age ae 3, aL, Ad Lek | oy MBE = 2A 23 = YB3,Fqub! =) he amt 9 ay pa 2 0c 28, > Garod Od OY - Vay AQ: Ty }M 40, we T:0 “bw ng > AY© Q5-2 = Dun nong hin hop ln huynh vi AgF & 125°C thu duge khi Z1 cé ti khdi hai so véi khi helium bing 25,5. Khi cd mit lugmg du KE, Z1 dé ding phan hoa thanh 22, Cac Lewis acid nhu HF, BFy xe tie sv phan hay Z2 thin lira hun va khi Z3. 2 NoF4 one a BF, zi1 th = (oxide) 4 oN 1,05 nguyen 16 ams 18.2% Bailam: MAA > Ata QSiS= Was Sz I : Fe 2, 8 5c Fy Co Htey> Mau) US: SF USFr =) 8a xt 1B y= 40d ie Oy avs 26 + SOyF, aM: & = Baska | Mom SB cla Vay2>: Sq =) Lor Sh= WW3-B ~ifas Ad ta. od : atte Dio: $4 > eM 80, 2 16:08") 2a: CogeSRF coho] | von=A aes Talia! Sx | ua. oo | i, ie 2 MBy an = WBS qu 9 3" efpr OAK =) J0k xt Bye AOk-32 Soke “ often 24 Bes)450K tao ra Z12. Sau dé Z12 phan img tiép voi Z11 th duge chit i go ra gde ty do hoat dong. Xée dinh Z11 va dé xuit $0,+ G aaa ‘ G2 awe ACS -y A, o> 0 frog) ‘ey Cw, Cy —Ae© ¢. Cac oxide quan trong nhat cua Iuu huynh 1a SO: va SO; ngoai ra con mt vai oxide khong dy nhur S20 va SsO. Vé cdu tric ctia $20 va SxO va dé xudt mot phuong phdp diéu ché SsO tir Bai lam: 8,0: gre 0: Mo -8 Kop Se + o, = 8,0 a wn)