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Roll No. m gBdEdddcoqr,
No. of pranted pages : 8
e

13O 43O (IOXI

2022
rrn#r B$fl=T t*6nfu51
CHEMISTRY (Theory)
qrq,sErual lEurto: ZO

Time:3 Hours | [Max.Marks : 70

Frdqr : (i) f,fl qa;iqrCe-m so cqqdt qrff cs{ sFrdrddl
(ii) vrqri@r r Q e il6 e-d-fi lrc t 3i66rdt cr{<iwr 9 t 18 il6 c-d-6eqq
z aiol or t. c{q {sr g t ez a-o c-d6 cs{ s 3i6t or t aefi cqi g@r za
t

t so d-6 c-d-6 esqs siol o'r tl

(iii) c'+t'*@T t ta a-oo-gffio cpr.f;t Fi-ird6cr{b3-friiarfr-6-frfrA
rd dt *r& ft'o-cq sqfi rr< 9fu"6r d frfuut
(iv) e$-ezi C sqq c{ 6t$ fr-6-N Tfr * d?nfr z si6.t ETd d ee=iiC, 3 3i6t dr&
at{ eq{iti:t< s 3i6t ild ffift cc-ii fr 3fl.ilR-6 ko-s s66 6r, rqT tt t-$
yq=it { &-d-d uo B-o-cq mr fr r.r< alfrul
(v) qfr $rscq6 d fr dTr er<fi 6T c-qtrT o-{ soi dt s-cgd-e< b 3qdl 6}
srjqfrq6'tr
Note: (i) There are in all 30 questions in this question paper. All questions are
compulsory.
(ii) Question No.1 to B carry one mark each. Question No.9 to 18 carry
two marks each, Question No. 19 to 27 carry three marks each and
Question No. 28 to 30 carry five marks each.
(iii) Question No.1 to 4 are multiple choice questions. Here four options
are given in each question. Write the correct option in your answer
book.
(iv) There is no overall choice in question paper, however, an internal choice
has been provided in two questions of 2 marks, three questions of 3
marks and all questions of 5 marks each. You have to attempt only
one of the given choices in such questions.
(v) Use log tables, if necessary. Use of calculator is not permitted.
l ll [P.T.o.
 .*a,U*A*)
lrEqarZsilq glffi
+d'i.
Roll No. tl [Tt gE"Edaildql,
No. of printed pages : 8
e

13O 43O (IOXI

2022
Krffr fr6r.T (ffi<ol
CHEMISTRY (Theoryf
srq,gqual lErrto: zo
Time:3 [Iours ] [Max.Marks : 70
Frdqr, (i) Ffl qa;iqrtte-d so csqdt qrff cyq 3[Frarddl
(ii) ssn ri@r t t e il6 ndo ssi' t si66ltt csi ri@r 9 t 18 il6 c-d-6eq{
z siai or t. c{c s@r 19 t 27 a-o c-d6 eq{ s 3idii 6T t d'aT c{i d@r ze
t so il6 q-d.-6 eq{ s eio} or tt
(iii) s'sq riqT t t a a-o cgffio wc dt Fi-i e-d6 cs{ b ffir tqx fd-o.-N ftO'
gko.r d frfuut
3rqfi rd<
(iv) e€{-e-{ f e..q.q lr( dr$ B'6-d q-& * dprrft z ei6.i aTd d ee=itd, 3 3i6t a'r&
at{ cq{tif :rt< s 3i6i ild sfr ccri fr 3Tr<R-o. frore yalq fuqT rTqT tt t-$
crii d bdd uo B-o-cq mr r1r+t fiftut
(v) qfr sirdpqfi E) d dTr er<fi 6T c-frrT 6< s6fr dt s-o-gdidi b 3cdFT #
srgqftq6'*l
Note: (i) There are in all 30 questions in this question paper. All questions are
compulsory.
(ii) Question No.1 to 8 carry one mark each. Question No.9 to 18 carry
two marks each, Question No. 19 to 27 carry three marks each and
Question I\o. 28 to 30 carry five marks each.
(iii) Question No.1 to 4 are multiple choice questions. Here four options
are given in each question. Write the correct option in your answer
boo k.
(iv) There is no overall choice in question paper, however, an internal choice
has been provided in two questions of 2 marks, three questions of 3
marks and all questions of 5 marks each. You have to attempt only
one of the given choices in such questions.
(v) Use log tables, if necessary. Use of calculator is not permitted.
I1l [P.T.o.
1 frqftfu+ d 6tq effi frerzrq 6T frqlur o-<m t- 1

(i) Nacr (ii) qdT. (iii) Erd (iv) dR+crfrc

Which of the following prepare colloidal solution-
(i) NaCl (ii) Glucose (iii) Starch (iv) Barium Nitrate
2 Mdi-dsdiifrdqdHdmift - 1

(i) F:{'6T s?T t 3rftr6 sg+n< dar tt

(!i) i a-o b sTpr Elfitfrq d-{l d-irA dt
(iii) d E?r 61 keffi-a o-G d t

(iv) sq'tt6t$T€t
Alcohol are soluble in water because -
(i) they have higher molecular weight than water.
(ii) they form Hydrogen Bond with water,
(iii) they displace water.
(iv) None of these.
3 Ko[Fe(cN)uJ dFr6 tt ardq wqpJ re # sqe-6dq\-d-i ri@T t - 1

(i) 4 (ii) 10 (iii) 6 (iv) S-{Iitdr-$Tdf

The Coordination Number of central atom Fe in K4[Fe(CN)6] compound is-
(i) 4 (ii) 10 (iii) 6 (iv) None of these
4 o.dft-q@T6 - 1

(i) 4so7o ErdfrEEs frtr{q (ii) aoozo qrSfrEEE frtrqr

(iii) 4oo/oiretftrogsftmqq (iv) Fritot$c-fr
What is Formalin-
(i) 40olo Formaldehyde solution (ii) 30o/o Formaldehyde solution
(iii) 40olo Acetaldehyde solution (iv) None of these
5 funif dmAiibqrqfrfust
Write name of any two Proteins.
6 doquT ild 6uH t+H b raqT,{ wii aqf-A fia 1

Why do the transition elements exhibit higher enthalpies of atomisation?

430 (rox) t2t

 7 Fqfrfua dffi d sTprfuo, Bea-o aer E&oo tqtq q-d-dTFu- 1

Identify Primary Secondary and Tertiary amine in following compounds-

(i) crH, - N- CHTCH3 (ii) cH3NHCHTCH3 (iii) cH3cHrNH,

C,H,
B' fuan 3r.-sr d-d ti Tqi q{ R'trdT d R-dB Hr<. Nacr b ft-f,qc d Rrsg firdr d, @ti? 1

Excoriated egg inflates in water whereas deflates in concentrated NaCl Solution,

whv?
e. d-dHqnFioqFft cFderTq-{!-dRid 6ra f, E-dB d-d}uer-{ 6ffi ufrerrq-+u-cfrta
o€drsEadBst 2
Haloalkanes shows nucliophilic substitution whereas Haloarens shows
electrophilic substitution. Expla i n.
ro. frm< qrqrql fr flf, 3rreTr { qlf *{fu d-6eftF (4d,0) dt 3nc Sfr 6-6 sa5-A d fu qe
uo Soqur a-o te Z
silver atom has completely filled d-orbitals (4d10) in its ground state. How can
you say that it is a transition element?
11. (6) ammB'gtsnc@rsrflAdl 1

What do you understand by Lattice point?

tsl uo-odrGuord3rFrdqrFTdor{idrd 5ilqild.r{dl .l

Name the parameters that characterise a unit cell.

12. smdlsdefiihb-eds olera-gdl 2

Explain Schottky defect and Frenkel defect.
r:. sealHe - t+L=2
Clarify -
(6) tfu-d d-dEB UAq dt W S sd C arfrqfrq dr eita
Alkyl Halides though polar are immiscible in water. Why?
(s) @T Etdr * aE dt&frq mr s-o-srqqcq bqr aror tl
What happens when Chlorobenzene is subjected to Hydrolysls.

430 (rox) t3I lP.T.O.

 s. ffi{ 22 s 6Tf{ &rffi\.{f,s d Te 6} dr ffi{ r.i ordc ffi{Es b a-qqiq
qE zz s 1

sftctddrrqiTolftur z
calculate the Mass percentage of benzene and carbon tetrachloride if 22 g of
benzene dissolved in 722 g of carbon tetrachloride.
3Terqr (oR)
€-6frd{ ( 030 s ) egfi a-o i 6 x 1 o-3 s 3ffid-{ g-e t I 3fi-ffifr-{ fr qi<dT fi fi sq..
1 . .

(ppm) tioargil
6x10-3 g of oxygen dissolved in one liter sea water (1030 g). What is the
concentration of oxygen in ppm.
is. qq3ilfti'b-ffi -1 3f-ffifilT or+en rcftta o-rm'* a-qfu a-<. *drac +r, +3, +s .Tett
+73fi-ffi6<Etrd-€iturfrcdRfdo<idr qrqralBur 2
Fluorine exhibits only -1 oxidation state whereas other halogens exhibit +1, +3,
+5 and +7 oxidation states also. Explain.
16. Fqq-dot3Bdrdr6{qgFdgq-sT$A - L+t=2
Explain the following terms with suitable example -
(o') ffi (q) hffi
Alcosol Aerosol
srsrEr (oR)
er$-EgimrfteqewrflSt 2
Explain Hardy-Schulze law.
17. ffifoalce-eriqtdqdffibrupncilqfrfuu - L+L=2
Write the IUPAC names of the following coordination compounds -
(6) [Pt(NH3),C|(NO,)] (€) K,[Cr(C,O4),J
18. ffi d-gd srqurq frd-qq fi arm6-drden+rr{uro-o-ar of fiqrsrAtssr z
Define Conductivity and Molar Conductivity of an electrolyte solution.
19, (6) ritr'quT€tTwrlb3rFrdeiurF]tdl 1
(a) What are the characteristics of the transition metals?
(q) d- Ef-o b rr€t fr - t+t=2
(i) 6t{ t a-d *o-quy *.:ft b a-e q-& o.} m sot ta
(ii) riow ugt EqT 3-'16 3TRr6icr dFm rggu-#q dfi dl
430 (rox) t 4l
 h
(b) In d-block Elements -
(i) which of the erements may not be regarded as the transition
ele ments?
(ii) why transition metals and many of their compounds are
paramagnetic?
20. 4s g uftr-ft{ wf,oT-d (c,H6o,) o} ooo g sd it fr'flqT rrqil fuerfi b fu6 3i?FrrFr
(^rr) fr rruriT dBEl t Kr(Etd-d.3tfiT{ Rr<i6)=1.86 K kg m6;-r I s
45 g of ethylene grycor (crH.o-) is mixed with 600 g of water. carcurate the
Freezing point depression (aTr) of solution.
K, (Molal depression constant)= 1.86 K kg mol-1.
21. fiffi1fu63{Frfr-qr.6rqrq.fur<i-oqn-of*d}Bg- 3
Cu(s) + 2Ag+ (aq) -+ Cu2+(aq) + 2Ag(s) Eo,qd,=0.46V
Calculate the equilibrium constant of the following reaction _

Cu(s) + 2Ag+ (aq) -+ Cu2+(aq) + 2Ag(s) Eo 1."rr;=0.46V

22. FqFrfuHqRftlfutdrorleruTdit - 1+1+1=3
What are the observations In following cases _

(6) E.'q s-opT fu-ilT gJt 6}mr{& fr-m i + rrqq 6-{dT f, I

When a beam of light is passed through a Colloidal Sol.

(q) iltrdft-d bR-o. 3fi-trr$s rf-d t tga avuua
r.racr fr.mrqr arar tr
An electrolyte NaCl is added to hydrated Ferric Oxide Sol.
(r) 6ffi d-d d t +gd €rxr q-{Fd 6t Ejfr tl
Electric current ls passed through a Colloidal Sol.
2 3. (6) ef r s b drd 3Trf,d b a-at ot ga-+r d d.,f r o b n-ai d qQrq. ffiTfi teloft or qrr
tllql-qdql oq6)-drtrffitl 2
Elements of group 16 generally show lower value of first ionisation
enthalpy compared to the corresponding periods of group 15. Why?
(q) H,o u6 trq defl H,s itg t, wta 1
Why is HrO a liquid and HrS a gas?

$er{r (oR)
430(rox) tsI lP.T.O.
 (6) qs< sr#il-Nrfs qili d cq}.rtendT frfET 6T Edq 6tBEt 7Vz

Describe laboratory method of preparation of Sulphur dioxide.

(E) sffi-r 6T 6t{ ET Fc aE-gu-dtq e-+sn s-dftf-d d{dT t? LVz

Which form of Sulphur shows Paramagnetic behaviour?

z+. frq 3rfirfrffiii 6l EUf ft1BE - 1+1+1=3
Complete the following reactions -
(6) crHrlH, + cHrcoCl
(g) CrHsNH, + HNO,
..:
\ -HCt

(X) C.H'NH, + 38r, /f C

2s. (6) ffi d srfiTm fiBc ffi sha fr sqflrq c-ffr c-dfrfd 6tfr dr 2
Give two reactions that show the acidic nature of phenol.
(q) ffit1tS-fi{+ht+f,d-{ri61{rflrqft-63{fi{hqTfifuur 1

Give chemical reaction for the preparation of phenol from chlorobenzene.

3{elEr (oR)
frqhfu-adFraiib rupec qqfrfuE- 1+1+1=3
Write IUPAC names of the following compounds -

(6) cH: - - - cH,oH (q) cH3 -cH-o-cHrcH3

?H
oH Cl
?'-:n
CH, CH, CH,
CH
CH.

(n)

26. (6) o- l-(ots sq m-ds o1 *roqr frfuu, 2

Write structure of D-glucose and fructose.

(u) D-rqrlsd3rF{bqT Hr bFTQIftfuut 1

Write chemical reaction of D-glucose with HL

3rsrdr (oR)
(61 !ffi swtfr suout qFfr oi erq d* qc-fltttr 1

How do you explain the amphoteric behaviour of amino acids.

430(rox) 16 1
 (qq) DNAdeiTRNAbSBdardewr$r .
Explain Biologjcal functions of DNA
and RNA.
27 (o) :q-$f,€q}-d-q dfutC v{rq.q q..sd
@T rcrr*uT tl vtro eq_sT$nr 1
What is coordination sphere in coordination
compounds? Explain with
exam ple.
(s) totfrd 6r mesf6 $?R t 3rRr6 e)_cr t, oqta 1
The boiling point of alcohol is higher
than ether, why?
(rT) 3iufr'-o. sirgfr b.eTrurt q.-{
c)-&{ or mflosur frBur
1
Give the classification of proteins
on the basis of Molecular shape.
28. ftEqftfuHeftrBureitdnuf afiBE _
1x5=5
Complete the following reactions _
(6) HCooH+Agro_-+
(g) 2cH3cooH ,Pzos ,
qq (heat)
(jT) HcHo+HCN--_+
(S') Hcr= 01 nc eas)
CH3CHO - 2C2H5OH eis
)
(s) 2cH3cHo NaOH (dil. NaO Hl

SIzrirr (oR)
frqgftrfr-qrcii d er-6*a _
1x5=5
{ot #fi-orqr6,6* (q) mfrd;q-{ 3Tq-{q-{ 3rn{BqT
(r') E-se-6-iur (q) Aafua-srvu-cr3rFrB?Tr
(B) id-ffinFiffi}3rFfi"T
Explain the following reactions _
(a) Cannizzaro reaction (b) Clemmensen reduction reaction
(c) Esterification (d) Kolbe electrolysis reaction
(e) Hell-Volhard Zelinsky reaction
2s. (6) 3iltr*- e-6c t aeF6 Uft B + fi qf 0T u,1 Eftr irnrq*_6
$Frb.q.sit strd fr fu 8 r

3
write method of preparation of Nitric
acid by ostward,s process with
chemicar
reactions.
430 (rox)
I7 'l
lP.T.O.
 (q) ftEfrfud <rsrqF-o 3IFIbsBit 61 guf dhu - I

Complete the following Chemical reactions -

(i) Cu + HNo3 (Sl-6 / Conc.) -- -----+

(ii) 12 + HNo3 (gr< / conc') -

-j
seltrr (oR)
(a') crAEtd-{ +s 3fr-ffid;-$T 3ffi€rT dqfdi t dfrc ?rd t<Td-dr{s qdt d-ildT t, adila
t1/2

Nitrogen exhibits +5 oxidation state but it does not form Pentahalide, why?
(E)
Write the reaction of thermal decomposition of sodium azide'
(rr) frqs{F{Bqr}itdpf drBu - t+7=2
Complete the following reactions-

30. (6) u6 cgrrr 618 fr 3{nlhqT 6r ilr Rr<i6 1.15x10-' s-' *l {q 3lFibqr d
3TFr6rt-6 d s g qra q.6-{ 3 c 6}+ iifrfriT s""qq dtqT? 3

A first order reaction has a rate constant 1.15x10*s-1. How long will 5 g

of this reactant take to reduce to 3 g?

(E) {mrqfro 3{FIBqr b tq qs cr+rdEr-di drA 6i-.o.i6Tsd-s dfrul 2

Mention the factors that affect the rate of a chemical reaction'

3rerqr (oR)
(6) FrqfrRra er Rximt o1 FdT$ t 3{FIbqT # 6ffr o1 q-f,dn dBs - 2

Identify the order of reaction from following units of rate constant -

(i) Mol L-1s-1 (ii) s-1

({q) EqH fu serq'ffi & 3IFIBqr d ee.eolo 3{F{B-qI Wf e}i t mn qrq rd sflg
61 10 uqr6tdTtl 3

Show that in a first order reaction, time required for complition of 99'9% is
ten times of half-life of the reaction.

430(rox) 181