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Because the number of electrons in the first half reaction (3e-) does
not equal the number of electrons in the second half reaction (2e-), we
must multiply the reactions by coefficients so that the electrons will
cancel out when we add them. In this case, we multiply the first
reaction by 2 to yield 6e-, and the second reaction by 3 to yield 6e- as
well.
Carrying this out, we get:
Now we can add the two reactions, and we notice that the electrons on
both sides cancel out.
Solution:
• You are expected to know how to construct and interpret cell notations.
E0cell = E0red (cathode) - E0red(anode) Try to obtain the values from the resource data table on internet
0.80 V - (-0.136V) = 0.936 V
(d) Write the cell notation for the galvanic cell in (c)
2. The following questions pertain to a voltaic cell in which the following
half-reactions occur:
S (s) + 2e- → S2- (aq)
Ca2+ (aq) + 2e- → Ca (s)
• Free energy (G) is the total energy of a system that is available to perform
work.
• When a chemical reaction occur on its own without any external
intervention, we say it is spontaneous. Such reaction uses its free energy
to drive it.
• During a spontaneous reaction, free energy of a reaction decreases, So
free energy change ΔG must be negative.
• Take note that both free energy change ΔG and Ecell determine
whether a reaction is spontaneous or not.
• Voltaic cells uses spontaneous redox reactions therefore ΔG must be
negative and Ecell must be positive.
ΔG = ΔG° + RT InQ
• Where Q is the reaction quotient. The ratio of concentrations at any time
in the reaction mixture. Used to predict how far is the reaction from
equlibrium.
• We use the above equation to calculate free energy change (∆G) using
the concentrations or pressures of products and reactants in the reaction
mixture , provided that ΔG° is known.
ΔG = ΔG° + RT InQ
• At equilibrium, ∆G=0 and Q become equal to the equilibrium constant K.
Hence the equation above becomes,
ΔG° = –RT In K(eq)
The factor 2.303 is used to convert from ln to log
ΔG° = –2.303 RT log Keq
R = 8.314 J mol-1 K-1 or 0.008314 kJ mol-1 K-1.
T is the temperature on the Kelvin scale
At 298K (250C) and we substitute in the value of R the equation is simplified
to
ΔG° = –0.05916 log Keq
ΔG = -nFEcell
Where:
n = number of moles of electrons involved in a redox reaction
F = the Faraday constant = 9.65 x 10 4 C/mol = 96500 C/mol
E = emf of the cell
F=1 Faraday =96500 coulombs
If reactants and products are in their standard states,
ΔG°= –nFE°cell
By substituting into the equation the values for Eocell and n, we can
solve for log K. The anitlog can then be calculated with the aid of a
calculator.
log K = x
K = 10x
a.) Split the reaction into half reactions and determine their standard
reduction potentials. Indicate which would be the anode and cathode.
d.) Calculate E°cell, the standard cell potential, which is given by E°red
- E°ox.
a.) Split the reaction into half reactions and determine their standard
reduction potentials. Indicate which would be the anode and cathode.
b.) Give the net, overall cell reaction and the standard cell potential:
Eocell =
4.) Consider a voltaic cell with Cr(s) and Cr3+(aq) in one compartment
and Zn(s) and Zn2+(aq) in the other compartment.
b.) Calculate the standard cell potential for the overall reaction.
c.) If zinc is the anode and [Cr3+] = 0.010 M, what must the [Zn2+] be
to achieve 0.050V?