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ConceptTest 1

4 2
When “18.73 x 22” is typed into a calculator, the result is: “412.06”.
How should you report this number?

A. 412.06
B. 412.06000
C. 412
V
D. 410
E. 400
ConceptTest 2

d
When “9.2 + 1100” is typed into a calculator, what answer should
be reported?
1109 .
2

V
A. 1109.2
B. 1109
C. 1110
D. 1100
ConceptTest 3

Data are plotted exponentially in the form

y = 12exp4t
where t is in seconds (s). Which of the following is true?

A. 4 is unitless
V
B. 4 has the units s-1
C. 12 is unitless
D. y has the units s
ConceptTest 4

1
Consider the following expression: = 𝑎 𝑇 − 4 −𝑏 K
-


where P is in bar and T in K 𝑃 bark K
bar Kb = 1

b
What are the units of the constant “b” in the A.Uunitless
= o
C. bar
following equation? B. 1/bar D. -1/bar

What are the units of the “4” in the following A. unitless C. 1/ K


equation? VK
B. D. K 𝑏

What are the units of the constant “a” in the A. unitless C. K / bar E. Kb / bar
following equation? V1/bar
B. D. bar / Kb
ConceptTest 5
1 J1ml
 −E 
s
-

−3
Consider the following expression: k = 5.4 * 10 exp 
 8.314T 

where k is in s-1, E is in J/mol, and T is in K S 1


-

A. unitless C. J/mol
What are the units of “5.4 X 10-3”?
V
B. s-1 D. s/mol

A. unitless VJ/(mol·K)
C.
What are the units of “8.314”?
B. 1/K D.(mol·K)/J
ConceptTest 6

The rate at which a gas passes through a semi-permeable membrane


is determined by its diffusivity D (cm2/s). D varies with the membrane
temperature T (K) according to the Arrhenius law −E 
D = D0 exp  
cmys  RTK
−E −E 
What is the linear form of the equation? A. D = D 0 exp 
 RT 
C. D = ln D0 exp 
 RT 
Vln D = ln D
B. o −
E
RT D.
−E 
ln D = ln Do + ln 
 RT 

What is the slope of the linear form of this A. Do V


C. (-E/R)
equation? B. ln Do D. exp(-E/R)

What is the intercept of the linear form of A. Do C. (-E/R)


this equation? Vln Do
B. D. exp(-E/R)
ConceptTest 7

The expression below can be used to calculate the conversion,


X, for a reaction as a function of space time, t. As the temperat
ure increases, the quantity tk becomes >>1. Estimate X at high
temperature.

A. X = 0.0 k
B. X = 0.1 X=
V 1 + k
C. X = 1.0
D. none of the above
ConceptTest 9

According to a power rate law for a bimolecular reaction, the


rate r = kP𝛼 . What does the plot below suggest about the
power rate law model for the data being plotted?
ur =
hkt ha p
Vα = 0.7.
A. Slope = 0.7

B. k is dependent on α

ln(r)
C. more data should be c
ollected
D. power rate model does
not fit the data.
ln(p)
ConceptTest 10

The variables y and x are related by the equation


y2 = C1exp(C2x)
How should the data be plotted to solve for the constants C1 and C2?
mly = uc , + cax
A. y vs. x ; slope = C2 and y-intercept = C1
2
ny =
ha tc
2x
B. y vs. x ; slope = C1 and y-intercept = C2
uy =
소 enci fIGx
C. y2 vs. x ; slope = C2 and y-intercept = C1
D. ln(y2) vs. x ; slope = C2 and y-intercept = C1
~
E. ln(y) vs. x ; slope = ½ C2 and y-intercept = ½ ln(C1)
ConceptTest 11

For the function −E


k = Ae RT

which will generate a linear plot and what will the slope be? A, E,
and R are constants.
hk
A. k vs. e(-E/RT), slope = A
=
UA -


B. ln(k) vs. (-E/RT), slope = A
V
C. ln(k) vs. (1/T), slope = (-E/R)
D. k vs. (1/T), slope = (-E/R)
E. ln(k) vs. T, slope = ln(A)
ca) D =
DoexPL -
E /RT )

[cma/s ) Docms/s
E molcal
1 E터 lmolcal


-
=
RT mcal
1 K K

cbliu) ln ) -
UDo -

1
RTE
hD
plot
-
vs
T

slope -
RE

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