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LAKSHYA (NEET)
Electrochemistry DPP-01

1. E for the half cell Zn2+  Zn is –0.76 e.m.f. What combination of two half cells would
of the cell Zn  Zn2+ (1 M)  2H+ (1 M)  H2 result in a cell with the largest potential?
(1 atm) is: (A) (i) and (iii) (B) (i) and (iv)
(A) –0.76 V (B) +0.76 V (C) (ii) and (iv) (D) (iii) and (iv)
(C) –0.38 V (D) +0.38 V
6. Given electrode potentials:
2. The standard electrode potentials for the
reactions: Fe3+ + e  Fe2+ E = 0.771 volts

Ag+(aq) + e–  Ag(s) I2 + 2e  2I– E = 0.536 volts

Sn2+(aq) + 2e–  Sn(s) E cell for the cell reaction 2Fe3+ + 2I– 
2Fe2+ + I2 is:
at 25C are 0.80 volt and –0.14 volt,
respectively. The standard emf of the cell Sn (A) (2  0.771 – 0.836) = 1.006 volts
 Sn2+ (1 M)  Ag+ (1 M)  Ag is: (B) (0.771 – 0.5  0.536) = 0.503 volts
(A) 0.66 volt (B) 0.80 volt
(C) 0.771 – 0.536 = 0.235 volts
(C) 1.08 volt (D) 0.94 volt
(D) 0.536 – 0.771 = –0.235 volts
3. The standard oxidation potentials E, for the
7. The standard reduction electrode potentials
half reaction are as:
of Fe2+/Fe and Sn2+/Sn are –0.44 V and
Zn  Zn2+ + 2e– E = +0.76 volt –0.14 V respectively. What will be the
Fe  Fe + 2e
2+ –
E = +0.41 volt standard E.M.F. of the following cell
reaction Fe2+ + Sn  Fe + Sn2+
The standard emf of the cell:
(A) 0.3 V (B) –0.58 V
Fe2+ + Zn  Zn2+ + Fe is:
(C) +0.58 V (D) –0.30 V
(A) 0.35 volt (B) –0.35 volt
8. The standard electrode potentials of the two-
(C) +1.17 volt (D) –1.17 volt
half cell are given below:
4. E(Ni2+/Ni) = –0.25 volt
Ni2+ + 2e–  Ni; E = –0.25 V
3+
E(Au /Au) = 1.50 volt
Zn2+ + 2e–  Zn; E = –0.77 V
The emf of the voltaic cell.
The emf of cell formed by combining the
Ni/Ni2+ (1.0 M)  Au3+ (1.0 M)  Au is: two half cells would be:
(A) 1.25 volt (B) –1.75 volt (A) –1.02 volt (B) +0.52 volt
(C) 1.75 volt (D) 4.0 volt (C) +1.02 volt (D) –0.52 volt
5. For the following E values of half cells 9. The standard electrode potential value of the
(i) A3–  A–2 + e; E = 1.5 V elements A, B and C are 0.68, –2.50 and 0.50
V respectively. The order of their reducing
(ii) B+ + e  B; E = 0.5 V power is:
(iii) C2+ + e  C+; E = 0.5 V (A) A > B > C (B) A > C > B
(iv) D  D2+ + 2e; E = –1.15 V (C) C > B > A (D) B > C > A
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10. The standard reduction potential at 25C of
Li+/Li, Ba2+/Ba, Na+/Na and Mg2+/Mg are –
3.05, –2.73, –2.71 and –2.37 volt
respectively. Which one of the following is
the strongest oxidizing agent?
(A) Na+ (B) Li+
12. The standard reduction potentials at 25C for
the following half reactions are given against
each:
(i) Zn2+(aq) + 2e–  Zn(s), –0.762
(ii) Cr3+(aq) + 3e–  Cr(s), –0.740

(C) Ba2+ (D) Mg2+ (iii) 2H+ + 2e–  H2(g), 0.00

11. The reduction potential values are given (iv) Fe3+ + 2e–  Fe2+, 0.77
below: Which is the strongest reducing agent?
3+ 2+
Al /Al = –1.67 volt, Mg /Mg = –2.34 volt (A) Zn (B) Cr
2+ –
Cu /Cu = +0.34 volt, I2/2I = +0.53 volt (C) H2(g) (D) Fe2+(aq)
Which one is the best reducing agent? 13. The standard electrode potential of Zn, Ag
(A) Al (B) Mg and Cu are –0.76, 0.80 and 0.34 volt
respectively, then:
(C) Cu (D) I2
(A) Ag can oxidise Zn and Cu
(B) Ag can reduce Zn2+ and Cu2+
(C) Zn can reduce Ag+ and Cu2+
(D) Cu can oxidise Zn and A

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ANSWERS
1. (B)
2. (D)
3. (A)
4. (C)
5. (B)
6. (C)
7. (D)
8. (B)
9. (D)
10. (D)
11. (B)
12. (A)
13. (C)

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