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Effect of NOx On Yellowing (Xuejun Zou)
Effect of NOx On Yellowing (Xuejun Zou)
Abstract: Rapid yellowing and degradation of pulp and paper products have usually been asso-
ciated with the effect of light or extreme heat. In this study, we found that exposure to NOx, even
at very low concentrations can cause rapid yellowing and degradation of pulp or paper. This result
explains the rapid yellowing and degradation often observed during overseas shipping or short-
term storage. To prevent this, it is recommended that NOx concentration should be monitored and
controlled, and/or paper should be properly wrapped during shipping and storage.
APID YELLOWING and degradation of oxides such as N2O3 and N2O4 are formed at
TABLE II. Properties of handsheets after exposure to 20 FIG. 1. Brightness as a function of exposure time at differ-
ppm of NOx for 3 days. ent NOx concentrations (spruce BCTMP).
Sample pH Brightness Increase in nitrate
(%) content (mg/g)
BCTMP
(no yellowing) 85 1.36
BCTMP
(yellowed during storage) 77 1.92
BCTMP
(after artificial exposure) 60 4.40