BANSAL CLASSES ORGANIC CHEMISTRY PRIVATE LIMITED (PETES Target JEE Adv. 2023 | Ideal for Scholars WORK SHEET - 01 (GENERAL ORGANIC CHEMISTRY Q2 Q3 Q4 [SINGLE CORRECT CHOICE TYPE] Choose the anti-aromatic compound [ \ 9 (A) [\ (B) © () 0 H CH, ° ‘Which of the following show addition reaction more readily than substitution reaction when compared toothers? (A) Borazole (B) Benzene (©) Pyridine (D)Phenol Most stable carbocation is? we we © AN Ms py oa Which of the carbanions is least stable? “j (B) NS On oA Choose the free radical, which is more stable than benzyl radical? CH, : LL CH, : ° ae “ O ®) ©" | San oy Q) cn, CH, [DIBANSAL CLASSES Private Ltd, ‘Bansal Campus’, A-17 (A), Road Nout, LPIA., Kote-08] Page #1Qe Q7 Qs Qy Q.t0 Qu ‘Which among the following wont exist (least stable)? e © (ay ) © (D)Aandc ‘Choose the position at which an electrophile may attack oO i] (A)3 (B)6 (2 (Ds 12.5 gof metal carbonate on decomposition preduced 7g of metal oxide, Equivalent weight of metal is? (A)20 (B)30 (©) 40 (D) 50 Choose the correct statement? (A) D-glucose and L- fructose are enantiomers (B) cis —2—butene and | —butene are diasterzomers (C) COs anhydride of HCOOH (D)-NHCOCH, is stronger +R group than-OCOCH, Choose the incorrect statement? (A) cyclobutadiene has 2 different C —C bond lengths (B)no. of planes of symmetries in cyclohexane: chair > Boat > Twist boat form (ethyl carbocation undergoes disproportionation to give ethane & ethene (D)no. of oxygens per silicon in cycling silicones is 1 [PARAGRAPH TYPE] Paragraph for question no. 11 & 12 Many reactions in organic chemistry proceed through carbocation intermediates like etc. Inthe process they undergo rearrangement to give stable cation before giving product Which of the carbocation undergoes rearrangement to give stable carbocation? CH, tlh I ( ® 0 Cl (A) (@) © (D) ohn yt [DIEANSAL CLASSES Private Ltd, ‘Bansal Campus’, A-17 (A), Road Nout, LPIA. Kota-08| Page #2Qi2 Qs Qi4 Quis Q16 ‘No.of hyper conjugation structures possible for following carbocation after it rearranges to more stable form? Ph CH, hy (A)2 (B)4 (5 (D)3 Paragraph for question no, 13 & 14 Free radicals are the intermediates formed during photohalogenation ofalkanes. Mechanism for I such ‘common reaction, CH, + Cl, —*+ C,H,Cl + HCI is Cl > 2Clg : CyHg+Cl® —> Cy Hs + HCI 6 Hs + Cl, —> C3HsCl + CH*., And radicals combine together very readily to sive some neutral product and E, (activation energy) for radical combination is=O free radicals (Dare paramagnetic & neutral (Il) undergo disproportionation (IID) are stabilized by resonance & hyperconjugation Choose the correct statement(s) (A) L&I (By) & I (C)1& Ul (D) 1, 1 & Ul In the reaction & mechanism described in paragraph what are all possible products/side products? OCH (i) CH, (Ill) CH, (A)onlyl (Bll (Leh (D)L US Paragraph for question no. 15 & 16 Optical activity is the property of asymmetric molecules, ‘Choose the one which is asymmetric? CH, cl | Au Ty lO (C)F-HC=CHCL of IL F ~~ SCH, Which of the following has no meso form? (A) Tartaric acid (B) Glyceraldehyde (©)1,2~dichlorocycloproane (D)2,3~dichlorobutane [DIEANSAL CLASSES Private Ltd, ‘Bansal Campus’, A-17 (A), Road Nout, LPIA. Kota-08| Page #3[MATCH THE COLUMN] Quy Column T Column Tr P) Q Planar oO @ XY 2) Non planar 7» 0 3) | __Less stable than corresponding open chain i analogue a, 7? no (A)prlq>2jr34:533 (C)pr4q>3rohs72 (B)p>2:q>liro>3;s34 (D)p>3:q> 412s Quis Column Column I P) H,C=C=CH, 1) | Can show geometrical isomerism a CH, | 2) ‘Can show optical isomerism 7 CL 3) Has no chiral carbonis) 3) 4) | Has at least one plane of symmetry A)po4iqo2irokisol (C)p>4iq>3r3ljs32 (B)p> lig>3.r>2:so4 (D)p>2%qolro4s33 [lleavent cuneate prvate tia Baraat ou ‘A-11 (A), Road Now, 1PLA., Kota-05 Page #4Qs Column T ‘Column 1 PI | H,C-CH=CH -CH=CH, | 1) ‘Only 1 type of C-C bond length a 2) | No.of hyperconjugation structures is zero r) 3) Is stabilized by resonance 4) Is stabilized by hyperconjugation A)polqotro4s52 (CO)pr2qrliro3;so4 Ppr2tqo4ro2zsol (D)p34.q>21>3:so1 Q.20 Column I Column I P) 0, Dy Nucleophile q Br 2) Electrophile ny ow 3) ‘Ambident nucleophile | ca {4 Neither nucleophile nor electrophile (A)p > 1q> jr 33;s 4 (B)p>3:q> Lr 34:8 32 Opr4qr2%rohso3 D)p>%qrhro3so4 ANSWER KEY Qi B Q2 A Q3 ¢ Q4 D Qs D Q6 A Q7. 8B Qs A Qo D Qi0 Cc Qu B Qi2c QB D Qi Db Qis D Q16 B QI7 A Qis ¢ B Q20 D [DIBANSAL CLASSES Private Ltd, ‘Bansal Campus’, A-17 (A), Road No-1, LPIA. Kote-08| Page #5