PUNJAB COLLEGE OF SCIENCE AND COMMERCE GOJRA

NAME ROLL NO

CLASS 1st YEAR [CH= 11] TIME: 60 Minutes MARKS (38)

QUESTION NO.1 CHOOSE THE MOST SUITABLE OPTION

(10X1=10)

NO. STATEMENT A B C D
1 In zero order, the rate is Temperature Concentration of Concentration None of these
independent of: of reaction product of reactant
2 The unit of the rate constant Zero order First order Second order Third order reaction
is the same as that of the reaction reaction reaction
reaction in:
3 For a chemical reaction in First order Second order Third order Pseudo first order
which one of the reactant reaction reaction reaction reaction
also act as solvent, the order
will be:
4 The unit of rate of reaction is Moles dm3s−1 Moles dm−3s−1 Moles−2 dm−6 s−1 Moles dm3s−2

5 The radioactive disintegration Zero order First order Second order Third order reaction
235
of 92U is: reaction reaction reaction
6 After three half-lives of 25 % 50 % 12.5 % 6.25 %
reaction, the percentage
fraction of amount left is:
7 For exothermic reaction, the Equal to that Greater than Less than that None of the above
energy of activation for of backward that of backward of backward
forward reaction is: reaction reaction reaction
8 The unit of slope in Arrhenius K−1 O
F O
C K
plot to calculate the energy
of activation is:
9 According to collision theory, Number of Number of Concentration None of these
the rate of reaction is equal collision effective of reactant
to: collision

10 The energy of activated Equal to Equal to product Greater than Less than reactant
complex is: reactant reactant & & product
product
11 Activation energy is E a = Slope × E a = −Slope × −Slope None of these
Ea =
calculated by the formula: 2.303 R 2.303 R 2.303 R

QUESTION NO.2 ANSWER THE FOLLOWING QUESTIONS (8X2=16)

1) Differentiate between average and instantaneous rate of reaction.

2) Define pseudo first order reaction and give example.
3) How rate of a chemical reaction is determined by dilatometric method and refractometric method?
4) How the half-life period is related with initial concentration of reactants for 1 st, 2nd and 3rd order reactions?
5) How is the rate of reaction influenced by surface area?
6) How enzymes act as catalysts? Write two characteristics of enzyme catalysis.

QUESTION NO.3 ANSWER THE FOLLOWING QUESTIONS (2X04=08)

a) Explain effect of temperature on rate of reaction by Arrhenius equation.
b) Discuss types of catalysis with at least one example of each.