as 1 ‘Time: 3 Hours |. There ar 35 questions in all, ll questions ae compulsory. This question paper bas five sections. Section A, Section B, Section C, Section D, Section E. All scctons are compulsory. Section 4 contains 18 questions of | mark each, Section B contains 7 questions of 2 marks ea Section C contzins 5 questions of 3 mazks each, Section D contains 3 long questions of marks each and Section E contains two case study-based questions of ¢ marks each. ‘There is no overall choice. However, en interal choice has been provider hhave to stiempt only one of the choices in such questions Use ofcaleuators is not allowed. insetion B,C, DE, You SECTION A tied to « stvng of length ‘? is rotated ina cree of radius‘ having angular 1 A stone of mass velocity as "a". ts near velocity ‘ys. (@2v 2m (02a O20 According 19 Hooke's lw of elasticity if stress sineresed the aio f ices to strain 1 @) Remains constant (b)ineeases(@)devreases—(€) becomes zr0 “The dimension of‘, the gravitational constant is : 1 @M'LTy Omer) @m'lr) @ [Lit collides with another particle at rest of samme mass. ‘A paricle of mass ‘m’ moves with velocity 1 ‘The velocity of second particle aftr elastic collisions @n O22 O%n Wz ‘Three masses of 2 ke, 4 kg and 4 kg are placed at tree points 1,0,0), (11,0) and (0.1.0) jon vector of is centre of mass is 453 @ISI+3S 1 of@ body at maximum respectively, the po @asirss} (@)35+] 2 ‘A body having simple hazmonie motion, the magnitude of acelerat displacement is (@ Zero (6) Minimum ‘The value of | ksh is___ joules. (36x10 (36x10 — (€)3.6x 10° (©) Maximum (@)None ofthese (36x10 1é volume corectly shows isochoric change? Which of the following graphs between pressure an :“4 ‘same 2s that 2 | Q9 Thedimension ofan impulse (@) Momentum / (@ Foxe @)Kineic Enewgy— (@)Velosiy " | 10 ifmass ot cart is 80 times tat of moon and is diameter i double that of moon and son can, | 9.8m then the value of "on moon is 098m! 98m |AIM (60.49 mist QAI Slope of poston ime graph gives (Tine (@ Displacement (Velocity (@ Atsaleraion Qu2 Which ofthe following graphs ea represen one dimensional motion of «pte G@FigueA ——(b) Figure (e) Figure A and B both —_(¢) None of these | Q.13__Atwhat value of temperature, the Celsius and Fahrenheit seales ae showing the same value? 1 | (®)-10 (20-40 (@)-80 Q.14Anabsolute zero isthe temperature at which. 1 (@) molecular motion increases (© molecular motion ceases e (6) Alliguids freeze (None ofthese cach othe. 1 | 15. Ifthe cross product oftwo vectors is zero then the two vestors are (@)Paraliel to (b) Perpendicular to (@) Making 30° with (@) Making 45° with ‘Two statements arc given ~one labelled Assertion(A) and the other labelled Reason). Select the correct answer for Q.16 to Q.18 from the codes (a), (b), (c) and (a) as given below. a) Both A and R are true and R is the correct explanation of A ) Both A aad R are true and R is NOT the eorreet explanation of A ©) Ais true but Ris false 4) Ais false but R is true Aseria irs et tamer Meson rede sen) | Qu6 ‘work done also gets doubled. ] Reason (R): Work isa scalar quantity. 1 | | Q.7 Assertion (A): Snow is better insulator than ice 9 Reason (R); Snow contains ar packets and ar is good insulator of heat, 1 Q.18 Assertion (A): Bodies of larger mass need greater inital effort to put them in motion | Reason (R): Inertia doos not depend on mass. 3 | SECTION B Q.19 Prove that the rate of change of angular momentum isthe torque acting on the body. 2 2 Q.20 How will you show that steel is more elastic than rubber? G21 Cheak ti corecness of equation m= (2g) [where is acceleration due gravity and ris rads] 2 (22 State and prove work energy theorem. 2 23 Waiteany four assumptions of int theory of esses. 3 Bos A carving longs rah highway with peed of 26 kms brought oa tp within a distance Joo t What isthe reardtio ofthe cr (seumed uniform) and how long does ite for caro | 0p? | OR ‘Aconstant retarding free of $0 is applied oa body of mass 20 Kg moving inialy wi of 15 m5, How long does the body take sop? 2A Consider displacement equation of SHM of a body and find out the velocity fori. Also find, at . which position the velocity becomes maximum, . oR > What are beats? Write its equation / SECTION C Q26 Calculate the Rotational Kinetic Energy for a given rigid body 3 Q.27 What isthe relation between coefficient of linear expansion and coefficient of superficial expansi Obtain it fora given square plate of length ‘7. ™ men OR (© Animals curl into a ball during winter season. Why? | (i) State Wien's displacement law for black body radiation 3 Q.28 Wit firs law of thermodynamics and apply it to an adiabatic process. Draw conclusions from it 3 29 Obtain the equation for standing waves and find out the condition for nodes and antinodes. 3 ©3066) Siate anc prove Newton's 2"law of motion and 3 | (b) Show that mass is a measure of inertia. oR Find out the value of safe velocity of a ear moving on a levelled circular road. SECTION D 31. (@) Derive the formula for terminal velocity when « spierical body is allowed to fall freely in a | liquid. (Draw proper diagram) (0) Define cohesive and adhes forces and explain why water wets the surface oR | (@) Consider non viscous incompressible ieal fluid flows ina streamlined manner from one end to ‘another end. Show that, P + % py? + peh = Constant \ (b) Give one example of each with proper explanation: {() Bernoulli's theorem (i) Surface Tension ¢ 32. (@) Show that the path of an oblique projectile is parabolic in nature. {@ A cricketer can throw a bal to a maximum horizontal distance of 100 m. How much high sbove the ground can the cricketer throw the same ball? 5 OR {@) Define the following terms and derive the formulae forthe following : () Time of ight Gi Horizontal range (tae ealing of long halls 20m igh. Whats themximum brzontl distance tata bal | oo en geed of 40 as can go without hing the ceiling af he hall(Take B= 10 m8) 93 tg cba ome for clr eo ravi at dep and prove tat eres with oi ait arth o be asphere of uniform mass density. How much would a body weigh half way ooanscrvrde the cente ofthe Earth ifit weighed 280 N onthe surface? | OR CObiain the formula for escape velocity of a satellite. ; ; a ‘A body weighs 63 N on the surface ofthe Earth, What isthe gravitational foes ont due tothe Earth at a height equal to half the radius of the Earth?SECTION 34 CASE STUDY. FRICTION Read the paragraph and answer th fllowing questions. ‘Whenever a by slides over the surface of other fore stars seting between the surfaces und vies to ‘oppose the relative mation between them. Ths opposing force is called as Frictional Force. Iisa se. adjusting fovee Friction can be classified into two main types as External and Internal friction. Th extemal friction is i} again divided into thre types a8 Static Limiting and Kinetic, The Kins fiction is wgain of two types Sliding and Rolling ton. According othe law of limiting Fiction, the fore of limiting ction is directly proportional to Noemal Reaction R. There isa constant between the two called as, coefficient of limiting rieton. ‘There are many advantages and disadvantages of friction, Sometimes we requir friction but most ofthe times we don’ ned it. One can deerease or increase the friction by different methods as pr the need and requirement ofthe situation 1) Write the formula fr eoeicient of ton also writ its unit 2) Write he oer name for Mud tion 2 5) Sling ction is more than rolling ction, why? 1 on 3) Write rwo methods to increase and decrease the ition, | 38 cAsEsTupy.-sy Read the paragraph and answer the folowing questions. ‘A body can have many types of motion. One of such motion is periodic mation. A motion which repeats ‘self again and aenin fle a regular interval of time is called as periodic motion ‘A'motion which repeais itself again and again abou its mean position is called as oscillator ot vibratory ‘oti. But when a body performs oxiltor mation na staight line on both sides of meun positon is | called as Simple Harmonie Motion (SHIM) In SHM restoring force is properonal othe displacement. Also fore or acceleration is directed towards mean position. The motion of siple pnd x SH ad sctlenton ~-gY/. ts ae observed tht the aif, «motion the magnitude of aecelration of rarmonie motion, the mat \ (a) Nowe ofthese é (All igus freeze QI2_Ateody having simple Aisplacement is (ayZew (by Minimum Ce) Maxim TAB ~ RB hen the angle between K and His ys (HAST (GOT (9 14 The quantity "Force x Velocity’ is called a __—. (a) Work (o) Moment («) Energy (2) Power Q.1S Which ofthe following graphs between pressure and volume co rectly shows isochoric change” 1 « ‘Two statements are given ~ one labelled Asserton(A) and the other labelled Reason(R). Select the correct answer for Q.16 to Q.18 from the codes (2), (0), (c) and (d) as given below. '®) Both A and R are true and Ris the correct explanation of A 1) Moth A and R are true and R is NOT the correct explanation of A |) Alstrue but Ris fatue | 4) Ala fatse and Ris trve | 16 Assertion (A): Snow is beter insulator than ie. 1 ‘Reason (R); Snow contains air packets and aris good insulator of heat, 0.17 Amserton (A): Bodies of larger mass need grester initial effort to put them in motion. «@ ‘eavon (R); Inertia does not depend on mass. 1 | 18 Amertion (A) Ifthe force and displacement of pate inthe direction of free are doubled, thes ‘work done also gets doubled. 1 Reason (RY: Work is a scalar quantity SECTION B @.19 Obtain the relation between torque and moment of inertia. 2 0.20 How will you show that steel is more elastic than rubber? 2 0.21. The speed of sound in air is 330 ms, conver it ino kv by using dimensional metho. 2 2 0.22 Write any four assumptions of kinetic theory of gasses 023 Acar moving along asraght bighway with sped of 126 km/hr is brought oa stop within distance doom What isthe retardation ofthe car (assumed uniform) and how long does it take for cao sip on ‘A constant retarding force of 50 Nis applied toa body of mass 20 Kg moving initially seth speed of 15 mvs. How long does the body tke to stop 0.24 “Abody of mass mis moving witha velocity" Calculate find out the eneray possess by ths ‘oy (Initaly the body is at rest) 2 2 awes Q27 Qos Q29 gal 33 Plot the corresponding re 1) ita ete fr lpoation ge eh ofthe ellowing simple harmonic motion Inet N= cost 1) eed a) peo yo mo x= eon ‘What are beats? Write its equation. os SECTION C What is radius of gyration? F 1s radius of gyration? Explain and find out the formal fo it a oR Seca pe Nay = mat wag se pak ct ball es ey rat, We? i Sc W's eaphesent fr bi bay il 3 ‘equation for standing waves and find out he condition For nodes and antinodes, 3S \Write first law of thermodynamics and apply ito an aabate process. Draw conclusions om 3 . or Sathya equipo of ns und detine degrees of freedom and apply it to diatomic and nr aber town ona lass window pane breaks tint pices but bullet fom» Eun when passes through it makes a clean hole. Why? ra penned als tothe earth the earth also moves upto meet the earth's mation 05 noticeable. Why? 3 SECTION D {a) Obtain the formula for escape velocity of satellite (oy weighe 63 Non he srface of he Earth What tbe rotational os= 08 uct the rrarth ata height equal t half the radius of Eat 5 on {@) Oban forma for acceleration deo gravity at depth and prove aL creases with depth Ath ming eho bea sphere of uniform mas densi How mish wos body weigh hall sen omrds the eet of the Earth i weighed 250 X09 surface? Wo Derive the formula fr teinsl velocity when spherical Body 6 ‘allowed to fall freely in Tiguid. (Draw peoper diagram) 5 {Explain in short, the working of hydraulic Ui. oR 4) Consider non viscous incompressible ideal uid flows ina streamfined manner from one en 1 weetherend, Show that P+ 2 pV" + eu = Constant {by Give one example of each with proper explanations (i) Bemoulls theorem Gi) Surface Tension (2 ow that the path of an blige proesile sparabois 0 A, 1a) eviekeer can throw a Dal 10a maxima hoz sans {of 100/m, How much high above the ground ean the cricketer throw te same al) OR (a) Define the following terms and derive the formule or hE following: (i Time of fight (ii) Horizontal range {by Te eifng of «long halls 20 high, Whats the mas horizontal distance that a ball ose ath a speed of 40 scan go without iting he eine rf the halla(Take g= 10/8)SECTION E, Q34 CASE STUDY: FRICTION | Whenever a body sides over the surface oF other, a force stars ating between the surfaces and tries vo ‘oppose the clative motion between them, This opposing free i called as Frictional Force. Iisa self tera friction is adjusting force Frition can be classified into two main types as External and Internal friction. Th again divided into tree types as Static, Limiting and Kinetic. The Kinetic friction is again of two types | Sliding and Roting friction. ‘According tthe law of limiting feton, the force ofimiting friction is diestly proportional to Norma! Reaction R. Thete isa constant between the twa called 3s, eoefficient of limiting fiction There are many advantages and disadvaniages of ction. Sometimes we require fretion but most of the times we don’t need it, One ean decrease or increase the ition by different methods as per the need and requirement ofthe situation, | Answer the following Questions | D what ype of friction is having a maximum value 2) While taking a turn om the road, fiction i essential. Wit the formula for the sae velo levelled circular road 3) Write dferences between sliding friction and rolling ition, (Any 2) OR 3) Write two advantages and disadvantages of friction, 4 Q35_ CASE STUDY : SIMPLE HARMONIC MOTION {A body ean have many types of motion. One of such motion is periodic motion. A motion which repeats itselTagain and again after a regular interval of time is called as periodic motion, ‘A motion which repeats itself again and again about its mean position i called as oscillatory or vibratory notion. But when a body performs oscillatory motion in a straight line on both sides of mean positon is called as Simple Harmonie Motion (SHM) ected towards In SHM restoring force is proportional tothe displacement. Also force or acceleration is ‘mean postion The motion of simple pendulum is SHM and acceleration =-gY/L. It is also observed thatthe uniform @ circular motion of body shows simple harmonie motion Answer the following question. 1) Define time period ofan oscillatory motion. 2) What is amplitude of an oscillatory motion 3) “All oscillatory motions are periodic in nature but all periodic motions are not oscillatory”. Justi oR '3) Find out the time period of a simple pendulum from the given figure, en egye ‘Time Allowed: 3 Hours Mi SET-A ‘TERM ~ II EXAMINATION (2022-23) CLASS - xr CHEMISTRY (043) General Instructions:- -Lihere are 35 questions inthis question paper with internal choice 2.SECTION A consists of 18 multiple-choice questions carrying 1 mark each, SECTION 8 consists of 7 very short answer questions carving 2 marks each, 4 SECTION Cconsists of S short answer questions errying 3 marks each. S.SECTION D consists of2case- based questions carrying 4 marks each, SECTION € consists of3 long answer questions carrying 5 marks each, 7All questions are compulsory. > suscottog tables and caleulatorsis not allowed See eer Qa Q2 3 SECTION - A (he following questions are multiple choice questions with one cornet answer Each question catres 1 mazk. There is no internal choice inthis section) Methane on combustion gives the mixture of @co ()CO+N: (© CO+H0 (@co+ FO In an electrophilic substitution reaction of nitrobenzene, the presence of nitro 1 group. (a) Deactivates the ring by an inductive effect. (&) Activates the ring by an inductive effect. (©) Decreases the charge density at ortho and para position ofthe ring relative to meta position by resonance. (d) Increases the charge density at meta position relative to the ortho and para position of the ring by resonance. thas highest boiling point. (@) n-hexane (b) mpentane (©) 2-methyl butane (@22-dimethyl propaneQs Qs Qe or as What isthe correct order of decreasing stability of the following cations? © Chy.oH-cHy ( (CHype* (tn crRCHLC-H, (@ > 1a (but (OmbpH (bua Calculate the oxidation number of Sin HsS0«: a +6 @a ss Jina process 701 of heat is absorbed by a system and 398) of work is done by the system. What is the change in internal energy forthe process? (@) +1085) ©) 2085), (9 +307) (307) A reaction occurs spontaneously if 4. TAS* Hand both AH and AS are positive 4 TAS> Hand both AH and AS ace positive fil TAS < H and both AH and AS are positive iv. TAS > H and AH is positive and AS is negative (land @ivandi (Oitiand iv (only i Photoelectric effect established that light (@) behaves like particles (©) behaves like magnetic fields (6) behaves like waves (4) behaves like raysQs Quo Qu 12 a3 a ee ‘The atomic number of the element unnilennium is (a) 102 () 109 © 19 (@) 108 (Choose the correct option. Across the period, atomic radi decreases due to (@) increases in nuclear charge (©) decrease nuclear charge (6) increase in atomic size (@) decrease in atomic size The judge inthe court suspected thatthe document has some changes. To ‘check that, the judge asked the forensic department to check the ink used at two different places. Which technique is suitable to detect? (@) Distillation {b) Solvent extraction (© chromatography (6) Allof these Caleulate the molarity when 5g NaOH dissolved in 200m of water (@) 0.605 (0) 0615 M (©) 0625M (0.652 What law states, "equal volume of gases atthe same temperature and pressure should Contain equal number of molecules. {2) Avogadro's law (©) Gay Lussac's law (6 Dalton's low (€) Boyle's law 1a0 14 The only series of ine appear inthe visible region ofthe electromagnetic spectrum of hydrogen is () Lymen series (©) Paschen series (© Phund series (@) Balmer series 3 Q:5 Assertion (A): Butane anl 2-methyl butane are homologues. ‘Reason (R): Butane isa straight-chain alkane while 2-methyl butane isa branched-chain alkane. ° () Both A.and R are true and K isthe correct explanation of A. () Both A and R are true but Ris not the correct explanation of A. © Ais true but Ris false, (2) Ais false but Ris true. QA6 Assertion (A): Inductive effect is responsible for the dipole moment in the molecules, Reason (R): All inductive effects are permanent polarisations in the ground state, (@) Both A and R are true and R isthe correct explanation of A, (©) Both A and R are true but Ris not the correct explanation of A, (© Ais true but Ris false. (@) A is false but Ris true. Q17 Assertion (A): Weak acids have very strong conjugate bases while srongacils 1 have weak conjugate bases. Reason (R): Conjugate acid base pair der only by one proton. (@) Both A and R are true and Ris the correct explanation of A, (©) Both A and Rare true but R is not the correct explanation of A. (© Ais true but Ris false. (@) Ais false but Ris truea Reson Niogen asl dpe (Bah and Rarer and isthe cessation oA (9 Both and Rare ue but Rs athe contention oA 1 (9Aistrebut kite @Aisae Rise ION (This section contains 7 questions with the internal choice in two questions. The following questions are very short answer type and caery 2 marks each) 19 Write two differences between molarity and molarity 2 20 Calculate (a) wave number and (b) frequency of yellow radiation having 2 wavelength of 800A, (LA°=10'm) or Give answer of following questions: (@) In atomic orbital has n=3,What are the possible values of and i? (6) Using 5, p, d notations describe the orbital wth the following Quantum mumbers, nS 3 Q21 Consider the following species 2 N®, O% F; Nar, Mg? and AP* (@) What is common in them? (b) Arrange them in the order of increasing fonic radii? Q.22 Explain why (any two) (@) Why dipole moment of BeCl molecule has zero dipole moment? {(©) Why water molecule is higher boiling point? (© Why helium doesn't form diatomic molecule? jum constant Ke for the reaction, at $00 K is 0.061. Ata particular time, 2 tie analysis shows that the composition of the reaction mixture is 3.0 mol of Nz 12.0 molof He and 0.50 mol of NHo Is the reaction a equiibsium? If notin “vhich direction does the reaction tend to proceed to reach the equilibrium? Or O23 (@) Why Hl is more acidic then HF? {) Write conjugated acid and base of HSOsQa 25 226 a7 28 Q29 Q30 n Hyclrogen iodide gas an (© Hydrogen gas reacts with iodine gas to form Hyclrogs gasand liberates energy. According to Lechateliers principle what isthe effect o¢ followings on equilib (@ Increasing pressure (i) Decreasing temperature What are reactive intermediates? How are they generated by bond fission’ The combustion of one mole of benzene takes place at 298 kand 1 atm. After combustion COs gas and 140 liqid are produced and 32570 kJ of heat is erated, Calculate the standard enthalpy of formation of benzene. Standart esthalpy of formation of CO> gas and HO liquid are 393.5 KJ mol * per mote and - 285.3 KJ mol? respectively. SECTION -c (This section contains 5 questions with the internal choice in to questions ‘The following questions are short ansuver type and carry 3 marks each) An organic compound containing C, H and O has 49.3% carbon, 684% hydrogen and its vapour density is 73, Molecular formula of the compound is? Explain why: (6) Why half field orbitals are more stable? (b) What is hunds rule of maximum multiplicity? (6 Write the electronic configuration of chromium ( Atomic numbers 24) Balance the following redox reaction in acidic medium, (by any one method) Fe" (ay + COP tg) —— Fag + Ca Or (@) Whatis disproportion reaction give an example ofthis, (b) Thermal decomposition of calcium carbonate isnot a redox reaction Explain? Elements A,B, Cand D have alomc numbers 12, 17,20 and 18 respectively. On the bass of electronic configuration, write to which group and which period of the periodic table each element belongs. ‘Complete the following equation: (@) CHy-CHeCH: +B; )CHech+H: —“,came cH +0%g) / Mustrate th or te the followi fing name reaction 1 (2) Frieda crat Wpeiminaton (6 Ware reaction o sect (The following questo BCHION-D bloom cena o quetons, Fach question ha amine and io ate punnge crt andar he gure that allo) 31 A satura 31 A satutted solution of sao clo preciaes Sg increased A at eg hlois on eval om te ani ICL. Which Fel taketh scum cir ative Bee PO “te common ion eect ea ee tin ae parila om prepa sparingly soluble wate ate Pe ow ale of sty Prose! etmation. Thus, # ae ec pate aver ion 38 iver itsiyydroxide and Cae a supa eae es “Fe solubility of s0l84e ta particular sven isthe Manin ‘centration that may be achieve inasPagven conitions when the dns voces iat equiibrium: Wen # 9 aegis concentration sequal ability, the solution ssid 10 PS cote orth tat sole eRe sw ey: Reavis ess thar its sokubi+ the solution is 318 ot olin that contains a flalivel te ration of solutes called SIS + fone ith acelatively BBN cores atin a calle concerts \ (a Diereniate the suions depending upon the so (o) Explain theft of common alton the solubility ofthe fons sas: (©) What is common fon { common ion when solubility sfect? What is effect of product has very IW valde? bility f the salt OR () The molar solubility ‘of Pobre is 217 x 10° Mata cetait temperature Caleulate Key for PBF:ne up oat of weak hk pibonds. They deploy a° teed, Eletropiles (Electron seeking aaa ht the doublebonded molecules inthis eaton ate Fae eet an pdt ras has ais nent 2, sreatlon rections ror certain conditans. Ozonalysis and OSA aaeran tc ial played HX Br, HDs HL, and HAO) anor) Treecee tn eyes of ein estiane mason ane a Tarkeooy ‘Tas banrevntby vention eoriae when HX aed Yo a aero HY vnth Hrbonding tothe double bods ls substituted carbon atom and Toning tothe athe double bonded arbor atm vat onic mechani WNP He (nol HCL, Hor 120) is ntroduced to an alkene or alkyne, Br ataches the les subattated double-bonded carbon, whereas Hinks othe other carbon atom, resulting in the anti-markovrikov reaction. This is where the rmarkovnikov and anti-markovniko. a2 Atkenes a reactions due tothe presence of (A) What would be the major product when the prop T-yne reacts with HB, if the reaction obeys Markovnikov rule? (8) How will you prepare butan-1-ol from but-L-ene ? (© Complete the following reactions: Qcr= crt Bn ocey-cx~cn-cexa oe perry (ip Explain the mechanism of Markovnikow re SECTION-E vu (the following questions ae Tong answer type an carry 5 marks each. Two questions have an internal choice) qs) planta draw the mela oa diagram of Or molecule Explain the 5 followings: ') Magnetic nature ) Bond order (ay Draw formation of and bonds in etnene alesse? oR {@) Why $F molecule shape is see-saw? Which hybridisation present in SF molecule? {&) Why ice floats on wates? ne sucrare of lings and we saps ae? (@)BCb (o) HxO ——— ssou — fusion of an organic compounet with metallic em for testing nitrogen, sulphur and halogen (8) 0.2780. c 8 of an organic chloro comy 7

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tom (©) tut (0 Min (ten Methane on combustion gives the mixture of e..-. @co () CO+N (©) COr+ HO (@co+H0 Ia Process 701] of hea is absorbed by a system and 394) of work is done by ‘hesystem. What isthe change in internal energy forthe process? (0) +1095) (b) -1095), (© +307) (@)-307) A reaction occurs spontaneously if: i TAS H and both AH and AS are positive i, TAS > Hand both AH and AS are positive TAS Hand aH is positive and AS is negative (a)iand ii ()ivandi (0 itéand iv (4) only itQuo m0 he ortho and para In an electrophilic substitution reaction of ‘nitrobenzene, the presence of nitro ‘roup. (@) Deactivates the ring by an inductive effect (©) Activates the ring by an inductive eect (©) Decreases the charge density at ortho and para Position ofthe ring relative (0 meta position by resonance (0 licteanes the charge density at meta pion relative to Position ofthe ring by resonance The atomic number of the innilennium is (a) 102 (©) 109 19 (€) 108 (Choose the correct option. Across the (2) increases in nuclear charge () decrease nuclear charge (6) increase in atomic size (A) decrease in atomic size ‘The judge in the court sus heck thatthe judge asked the forensic department tocheck te ‘wo different places. Whi (4) Distillation () Solvent extraction (chromatography (A) Allof these ich technique is suitable to detect? Period, atomic radi decreases due to: ected thatthe document has some changes. To ink used atQuz 13 Qu Qs 16 "he only seis of tin appear in the wise ein of te electromagnet Pectrum of hydroyen ne i (©) Lymen seri (6) Paschen series (©) Phuna series (4) Balmer series ‘What law states, * What lw stats, "equal volume of gases al the se emperatre and pressure ould Contain equal numberof moles. " (2) Avogadro's law (6) Gay Lussac's aw. {€) Dalton’s tow (@) Boyle's law Calculate the molarity when 5 NaOH dissolved in 200 ml of water @) 0.605 mM (©) 0615 M (©) 0625 M (4) 0.652 M Assertion (A): Weak acids have very trong conjugate bases while strong acids have weak conjugate bases Reason (R): Conjugate acid base pair differ only by one proton. (@) Both A and R are true and Ris the corzect explanation of A. (b) Both A and Rare true bot Ris not the correct explanation of A. (6) Ais true but Ris false. (@) A is false but Ris tue. ‘assertion (A) Inductive effet responsible fore ciple moment in the molecules. Reason (R: All inductive effects are permanent polarsations in the ground state. {@) Both A and Rare trucand Ris esos! explanation of A. {b) Both A and Rare trve but RENO! the correct explanation of A, (eA is true but Ris false (a) Ainfalse but Ris HeQU7 Assertion (A): Butane and 2-methy! butane are homologues, 1 Reason (R): Butane isa straight-chain alkane while 2-methyl butane is a branched-chain alkane. (@) Both A and R are true and Ris the correct explanation ofA. (©) Both A and R are true but R is not the correct explanation of A. (© Ais tue but Ris false (@) A is false but Ris true \ QS Assertion (A): The ionisation enthalpy value of nitrogen issmaller than oxygen, 1 Reason (R): Nitrogen has half field p orbital (@) Both A and R are true and R is the correct explanation of A. (©) Both A and R are true but Ris not the correct explanation of A. (© Ais true but Ris falve. (2) Ais false but Ris true SECTION-B (This section contains 7 questions with the internal choice in two questions. The following questions are very short answer type and carry 2 marks each.) 19 Consider the following species N®, 0%, F, Nat, Mg? and AP* (@) What is common in them? (©) Arrange them in the order of increasing ionic radi? 0.20 Calculate (a) wave number and (b) frequency of yellow radiation having 2 wavelength of 58004®. (1A* =10-%) oR Give answer of following questions: What are the possible values of land ml? I with the following Quantum {@) In atomic orbital has (@) Using 5, p.d notations describe the o numbers. n=5 1-3 21 What ace reactive intermediates? How are they generated by bond Fission?Qn Qt 25 Q26 Qa 28 Explain why (any two) {@) Why dipole moment of BeCl: molecule has zer0 dipole moment? (©) Why water molecule is higher boiling point? (© Why helium doesn't form diatomic molecule? Equilibrium constant Ke for the reaction, at 500 K is 0.061. Ata particular time, the analysis shows that the composition ofthe reaction mixture is 3.0 mol of Ne 2.0 mol of Hz and 0.50 mol of NHsIs the reaction at equilibeiuen? If not in ‘Which direction does the reaction tend to proceed to reach the equilibrium? Or (@) Why Hl is more acidie then HF? (©) Write conjugated acid and base of HSOs (6) Hydrogen gas reacts with iodine gas to form Hydrogen iodide gas and 'berates energy. According to Lechateliers principle what is the effect of followings on equilibrium: (@ Increasing pressure (i) Decreasing temperature Write two differences between molarity and molarity ‘The combustion of one mole of benzene takes place at 268 k and 1 atm. After combustion CO: gas and HO liquid are produced and 3267.0 KJ of heat is berated, Calculate the standard enthalpy of formation of benzene, Standard enthalpy of formation of COs gas and HO liquid are 393 5 K] mol? per mole and -285,83 KJ mol" respectively, SECTION -c (This section contains 5 questions with the internal choice in two questions, ‘The following questions are short answer type and carry 3 marks each.) Elements A, B, C and D have atomic numbers 12, 17, 20 and 18 respectively. On the basis of electronic configuration, write to which group and which period of the periodic table each element belongs. Explain why: (@) Why half field orbitals are more stable? (@) What is hunds rule of maximum multiplicity? (6) Write the electronic configuration of chromium ( Atomic number 24) Balance the following redox reaction in acidie medium. (by any one method) Fee ig) + COR og) —— Fees + Cap Or (a) Whatis disproportion reaction give an example of this. 6 3(0) Thermal decomposition of 0 ir a yposition of ealelunn carbonate iy How texto weacton, 229 An organic compous " 29 An organic compound containing C Hand © hap 44% catbun, 6% , hydrogen and its vapour denity (73, Molecular foruala of the compourl is? Q30 Complete the following equation () CHh-cHecrt rte craps, or | e. (9) Chis) + Ox) . eo or Mlustrate the following name rea : te the flowing nae (a) Friedal craft alkylation : (b) B elimination (© Wurtz reaction SECTION -D (The following, questions are case-based questions, Hach question has an internal cholee and carries 4 (141+2) marks each, Read the passage earefully and anwer the questions that follow.) Q31 A saturated solution of sodium chloride is precipitates! due to increased concentration of chloride ion available from the dissociated of FICL, Which help to make the sodium chloride active greater purity. The common ion effect, e also helps to finish the particular ion precipitate as sparingly soluble water, ‘with very low value of solubility product for gravimetric estimation, Thus, we can precipitate silver ion as silver chloride, ferric ion as its hydroxide and parium ion as its sulphate for quantitative estimation, The solubility of a solute ina particular solvent isthe maximum concentration that may be achieved under given conditions when the dissolution process i at equilibrium, When a solute’s concentration is equal o its solubility, the solution is said to be saturated with that solute. Ifthe solute’s concentration is Jess than its solubility, the solution is said to be unsaturated. A solution that contains a relatively low concentration of solute is called dilute, and one with a relatively high ‘concentration is called concentrated. (A) Differentiate the solutions depending upon the solubility ofthe salt, ions salts (B) Explain the effect of common salt on the solubility of thecommon ion when solubility (©) Whats common ton effect? Whats effect of com product has very ow value? or Stain temperature (€) The molar solubility of Pobre is 217x109 M a a certain temp Calla oy for PbBes ‘on cases de poo a wy libs Tay py aon "reactions due tothe presence of such bonds. Eletrophiles (Electro cng srs) raed tothe doe ens mle nti reacties the production ofa new product I also has the abiltyto undertake free racial substitution reactions unde certain conditions, Ozonelysis and oxidation Feactions are also vividly displayed HX (HBr, HBr, HL and HO) and alkenes undergo two types of addition reactions: markoveikoy and ant-markovnikov. ‘The Markovnikov reaction occurs when HX is added to. an alkene or alkyne, ‘with H-bonding to the double bond’ less substituted eatbon atom and X e bonding to the other double bonded carbon atom via an ionic mechanism, When HBr (not FICL, HI, oF #120) is introduced to an alkene or alkyne Br attaches to {he less substituted double-bonded carbon, whereas 1 inks to the other carbon atom, resulting inthe antimarkovnikoy rection, This is where the ‘arkovnikov and antvmarkovnitoy, (A) What would be the major product when the prop 1-yne reacts with HBr, if the reaction obeys Markovnikov rule? (B) How will you prepare butan-1-ol from but-l-ene ? (©) Complete the following reactions @ CH= CH + Br o ’ (@) OB -CH=cH- cH + 20h oR (ii) Explain the mechanism of Markovnikov rule, SECTION - (Phe following questions are long answer type and carry 5 marks each, ‘Two questions have ‘an intemal choice ) (293 a) What is the relation between change in enthalpy, entropy and gibbs energy. 5 | © whats extensive and intensive properties? give one example ofeach? © Hg) ——+ 2H)Q35 (03780 g an on Care ee EN hoo compound e070 snr cede ‘ rn Cale the percentage cheep ‘mpound. (Molar mass OF silver=108 gram.) " oR (OWhat is Postion somerisn, Give an example thi? (i) Draw structure of followings: (@) 3-0xoheptan-Lal © ©) pent en-t-yne (8) Write 1UPSC name of the following {9 Explain to draw the molecular orbital diagram of; molecule Bepain the followings: ) Magnetic nature b) Bond order (ii) Draw formation of o and n bonds in ethene molecule? oR (@) Why SF. molecule shape is see-saw? Which hybridisation present in SF, molecule? (b) Why ice floats on water? (6 Draw structure of followings and write shapes name? @ BC () HOSET-a ‘TERM - I EXAMINATION (2022-23) CLASS XI Biology (Code-044) ‘Time Allowed: 3 Hours ‘Maximum Marks: 70 All questions are compulsory The question paper has five sections and 38 questions. All questions are compulsory. 1 Z 3. Section—A has 16 questions of 1 mark each, 4, Seetion—B has 5 questions af 2 marks each, 5. Section—chas 7 questions of | marks each G # a Seetion—D has 2 case-based questions of 4 marks each Section has 3 questions of 5 marks each, ‘There is no overall choice. However, internal choices have béen provided in some Questions. student hastto attempt only one af the alternatives in such questions, 9. Wherever necessary, neat and properly labeled diagrams should be drawn. Genus represents which ofthe following ~ 4 An individual plantor animal b. A collection of plants or animals ©. Group of closely related species of plants or animals d. None of these Which of the following is oviparous? a. Platypus bBat Elephant. Whale Who proposed the fluid mosaic model of plasma membrane? a. Camilio Golgi b.Singer and nicolson. cSchleiden and schwann _d, Robert brown “Meiosis occurs in organisms during which type of reproduction? ‘a. Sexual reproduction bVegetative reproduction b, Both sexual and vegetative reproduction . None of these Which pigment acts directly to convert light energy to chemical energy? a. Chlorophyll a b.Chlorophyllb 110 a 2 ©Xanthophyit ieee Cessna aroteno €2n be measur rameters to measur ge gin MOUS Ay, which OF these CaN BE Ue ay @ Incre ase in cll number 3 Increase cl size © Increase length and! we &: alltheabove "Bh In breathing mo : thing movements, air volume can be estimated by which device? & Stethoscope b. Hygrometer © Sphygmomanometer 4. Spirometer Which is the commor eh symptom observed in people infected with dengue fever? Significant decrease in REC count , Significant decrease in WBC count ‘Significant decrease in platelets count 4. Significant increase in platelets count Which of the following pairis wrong? a Uricotelic~ birds b, Ureoelie- insects c-Ammonotelic - tadpole 4. Ureotclic- elephant Ribs are attached with which of the following? & Seapula b.Sternum Clavie dum Which part of the internal ear is responsible for hearing? a, Cochlea b.Semicicular canal CUtrieuus 4 sects Which hormone is esponsible forte normals wox cycle? a Epinephrine » Gastin f d. Insulin Melatonin In the following questions, # statement of assertion is followed by a statement of reason. Mark the correet choice xs: : " {@) both assertion and reason ace trie and reason isthe correct explanation of asenton. {if both asserion and reason are tr but reson isnot the comestexpianaion of {6) I the assertion is true but the reason is false, (4) Ifthe assertion is false but the reason is true 11B Assert Renan Methanogens are present in the gutof several ruminant animals ? eas ruminanes” MOG help in the production of methane fam dung of 14 Assertion - nh ST liens ace Reason tn "Re¥mese inflorescence the main axis terminates ina lower, 15 Assert ion -The woe Mean THe Wood iat scary sem 1 a “ssondary growth occurs in mest ofthe monact rots an stems Assertion - Plants hy ; 2 TR MY oped sitoy gan 1 Neon —Thereinvay te wangpatelpe poe plant pat toanothe. StcTION B e 17 Why are the class cation ystems changing every now and then? 2 18 Whatisapical meri ® aPlal meristematic tissue writing its aation and funeion? 2 7 ti What ae the characteristics o prokaytc ale 2 20 Write note on the economic inporane of gynperne 2 on Write a note onthe pectoral and pelvic pee 21 Distinguish between Cardiac muscle an stated muscle 2 on What are macromolecules? Give examples =» SECTION 22, Find out what do the terms alga bloom and ets’ signi 3 23. Explain briefly the following terms with suitable examples: 3 (@) Diplontc yop ~ 24 Why are xylem and phloem called complex issues? 3 ; vision of abou. Explain 3 25. Multicellular organisms have division i cen aerobic and anaerobic respiration. 3 26 Write any three differonces between — covery, physiological functions and agricultural/hortcultual 3 27 Write anote on discovery, hy 3 eee’ _— a 2» applications of any two of them, (Aavine (i) Giberalicacid—() Cyekinns Gy Adan nc on Define the folowing Brrcerne lant) Ende gland rae How is respiration regulated? on magni the dilferint ypes of movements exhibited bythe cells of human body? 2 SECTION D Jimont all enzymes are proteins. There are some nucle acids that behave ike Straten, ne ae called ribozymes. An enzyme like any preci ht a pany “amino acid sequence ofthe protein. An enzyme like any preter, bas the secondary and the tertiary structure. When you look at Pe y fh chan, 20 ill tice thatthe backbone of the protein chain folds upon isl Lhe chain criss-cross itself and hence, many crevices or pockets are rece Onc IAG) Pocket ithe ‘aetve site’. An active site ofan enzyme isa erevice or poked into which the substrate fis. Thus enzymes, through thir active site, cealyoe ‘actions ata high rate Enayme catalysts differ rom inorganic catalyst in any ways, but one major difference needs mention. Inorganic catalysts mene sificently at high temperatures and high pressures, hile enzynes get damaged at high temperatures (say above 40°C). However, enzymes. isclated feat exganisms who normally live under extremely high temperatures (ey, hot vores and sulphur spring), are stable and retain thee catalytic power even at high temperatures (upto 80-H0°C), Therma stability is thus an important yuality of ‘such enzymes isolated from thermophilic organisins. 1 is the pocket-like region of an enzyme into which substrate ‘molecules bind, (apProtein ste (b) Covfactors _(c) Coenzyme ——_(d) Active site 2What is ribozymes? 3. Explain how Enzyme catalysts dilfer from inorganic catalysts? Malfunctioning of kidneys can lead to accumulation of urea in blood, a condition «called uremia, which is highly harmful and may lead to kidney failure. In such Patients, urea can be removed by a process called hemodialysis. During the ‘Prgress of haemodialysis, the blood drained from a convenient artery is pumped into a dialysing unit called artificial kidney. Blood drained from a convenient artery s pumped into a dialysing unit after adding an anticoagulant like hepati. 4contains, Sse cellophane tube fluid) hay; * same composition us cellophane ‘surrounded by a fluid (dialysing, i hat of plasma except the niteogenous mentbrance ofthe tube allows the passage of his method isa boon for thousand World Kidney tay ” te method in the correction of acute Feral failures (kid 1M 2. What is mean by uremia? 3: What is heparin? Explain its uso? and extracellular digestion? 5 on ‘irculation? What is its significance? What is meant by double, 42 Write semi-technical description of family Fabaceae and also draw their floral agram and write floral formula oR lowing: (any two) (Eye (4) Ear 39 List the main ditferences between, nitosis and mei Draw labeled diagrams ofthe fol (@) Neuron) Brain 5 oR | "Wee any ive dlierences between eyetic an ‘noneyclic photophosphorylation,sere "TERM -I EXAMINATION (2022-23) CLASS -X1 c Biology (Code-044) ‘Maximum Mark: 70 “Time Allowed: 3 Hours SO ae ‘Genera nstrectons; Al questions are compulsory A ras ve sections and 33 questions. All question re compuliory Seaton A hes 36 questions of mar 3c Seaion—8 has S questions of2 mart each, Section Chas? questions of 3 mark each, Section has 2 eave-brsed question of mart eh Secon —£ has 3 question ofS marks exc sec oeral choke, However, Internal choices have been provided a sore re tadent esto attempt ony one fhe alteratines in such questo 9, Minera necessary, neat and propery ele diagrams shoul be awn SECTION A sms during which type of reproduction? Os FRAP Oe: Meiosis occurs in organi ‘Sexual reproduction ‘Vegetative reproduction Both sexual and vegetative repre duction None of these [Which of the following pair is wrong? a. Uricotelic- birds b. Ureotelic insects cc, Ammonotelic -tadpole d. Ureotelic elephant Wich part of the internal eat i responsible for hearing? ‘a. Cochlea b. Semicircular canal ¢. Utriculus . Sacculus Wich the commen symptom observed in people infested with dengue 1 Efever? ‘ Significant decrease in RBC count Significant decrease in WBC count Significant decrease in platelets count Significant increase in platelets count htenergy chemical enerzy? Which pigment acts directly to convert i a, Chlorophyll a b, Chlorophyll b ce. Xanthophyll d, Carotenoid Growth can be measured in various ways, which of these cant Be used as parameters to measure growth? a, Increase in cell number b, Increase in cell size ‘c. Increase length and weight 4. Alltheabove In breathing movements, air volume can be estimated by which device? 1, Stethoscope b. Hygrometer Sphygmomanometer 4. Spirometer Genus represents which of the following - ‘a, An individual plant or animal b. Acollection of plants or animals Group of closely related species of plants or animals P 4. None of these Which of the following is oviparous? a. Platypus ». Bat ©. Elephant d. Whale Ribs are attached with which ofthe following? 1 a. Scapula b. Sternum . Claviele 4. IliumLk ‘Who proposed the fluid mosse model of plasma membrane? ‘Camillo Golgh Singer and nicolson Schleiden and schwann Robert brown n 12. Which hormone i responsible forthe normal sleep wax cycle? ‘a. Epinephrine i, Gastrin Melatonin 4. Insulin In te following questions, «statement of aserion is followed by a sutement of reason, Mark the correct ehoiee 6: ‘Gy irom szeion and reason are tre and reason isthe corect explanation of ssserion. (@) If boi assertion and re anerion. (I the assertion is trv but the reason is fale (@ IF the assertion i alse but the reason is rw, 13. Assertion - Methanogens are present inthe gut of several ruminant animals, ‘Reason Methanogens help in the production of methane from dung of ruminants. son ae tue but reason is not the correct explanation of 14 Assertion - The eymose type of inflorescence has limited growth. Reason -Incymose inflorescence the main axis terminates in a flower. 45 Assertion The wood is actually secondary xylem. Reason Secondary growth occurs in most ofthe monocot roots and stems, 16 Assertion - Plants have no specialised respiratory organs, Reason There is very little transport of gases from one plant part to another. SECTION 17 Whatare the characteriticsof prokaryotic ell? 18 itis ap morta isu writing is loan ae onc? 19 Why are the dasiicaon stems changing ever 0 ad the? 20 Writea note on the economic importance of gymnosperms foes whch hay 1k wor for the fusion of an organi ipritrogen sulphur and halogen ‘nga oro compound ga + Caeulate the percentage ofc ar mass of iver=108 gam ace structure of phenol or dn isomerism. Give an exampe re of followings: sal a-yne came of the folowing i P raw the molecular omit dia tenature der Shion of oan x bonds in et oR solecule shape is e052? \ oatson water? lowings ond WH 32 noOR Describe the important properties of enzymes. two types of epithelial tséues. 21 Describe a on Write a note on the pectoral and pelvic girdle SECTION 22 State two economically important uses of the following, 4. Heterotrophic bacteria b, Archaebacteria 23 _ Explain briefly the following terms with suitable examples:- (0 Diplonic © tsogamy 24 Write any three differences between respiration and combustion. 25. Multicellular organisms have division of labour. Explain. 26 Why are xylem and phloem called complex tissues? 27 Write a note on discovery, physiological functions and ‘gricultural/horticultural applications of any two of them. (@ Auxins (i) Gibberetti acid (i) Cytokinine (iv) Abscisic acid OR ‘ei Define the following: (a) Exocrine gland o (b) Endocrine gland (o) Hormone 28 How is respiration regulated? on ‘What are the different types of movements exhibited by the cells of human body? °30 re infuse acorn sate ee msi Sewer youl noe ta ee ny ate th han ren nes teh ee ocala aa eee ‘crevice or pocket into which the substrate fits, Thus beam vi cre cere Put ine whch tt Ten or a ona pe rea alae re aire cea cy hgh sae while enzymes get damaged at high temperatures (say above 40°C), However, SNe et ncn teas aaa ag Sore ie nn ceuncsaeee er eet Ge 500 Taal say SO ase wt! fom eo es : sete poe gn anne wih at Saanon joPrinats (ieotcen (© Coenzyme . inadtirste 2Whatare ribozymes? Sane +3 Explain how Enzyme catalysts differ fom nore ‘stim. Give an lowings Ramey the following “ult orbital dingraon of Ox mo ‘bonds in etaene motecule? on saw? Which hybrid lation of urea in blood, @ mation 7 of kidneys ean end to seu ‘ Malfunetioning of kidneys Sghy barman may lead ony Tenaiin called emia, called faire. In such patients, urea can be Sry od ine called artificial | dialysing mint a daisng utter rtery is Pit contans a coiled cellophane Tid) having the sae compostion aS se ean inthe dialysing saeatation gradient. Asritrogenous WASH 40° 2 0 blood, The Sena thee subtances reely move out EY SS cleared blood is pumped back to the body eens Th matod 6 boo 5 and write shapes name?the warld.Kidney transplantation is the ultimate method in the correction of ‘acute renal failures (kidney failure}. A functioning kidney is used in ‘ransplantation from a donor, preferably a close relative, to minimise its ‘chances of rejection by the immune system ofthe host, Modern clinical Procedures have increased the success rate of such a complicated technique-Renal calculi is Stone or insoluble mass of crystallised salts (oxalates, etc) formed within the kidney. Glomerulonephvitis is Inflammation ‘of glomeruli of kidney. Name a condition in which crystallised salts are present in kidney? 2.What is moan by uremia? ‘3.Whatis heparin?Explain its use? SECTION E. Write any five differences between intracellular and extracellular digestion? OR Define the following terms with an example. a. Aestivation b. Placentation © Actinomorphie . Superior Ovary &. Perigynous Flower What is meant by double circulation? What sits significance? : on Write short notes on the following, 4 Central Nervous System (CNS) x , Peripheral Nervous System (PNS) List the main differences between mitosis and. oR ‘Write any five differences between cyclic and noncyclic photophosphorylation.