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DESALINATION

ELSEVIER Desalination 138 (2001) 299-306


www.elsevier.com/locate/desal

Optimization of seawater RO systems design

Mark Will*, Kenneth Klinko


Hydranautics, lnc., 401 Jones Road, Oceanside, CA 92054, USA
Tel. +1 (760) 901-2548; Fax +1 (760) 901-2578; e-mail: MWil~Hydranautics.com

Received 21 February 2001; accepted 7 March 2001

Abstract

The trend of investment and water cost in RO seawater systems is being evaluated. The cost data used for this
evaluation are based on published information from operation of actual RO seawater installations and recent studies.
The effect on process economics of major design parameters: recovery rate and feed water salinity based on three
representative seawater water sources: Mediterranean, Atlantic and Pacific Ocean on energy consumption is analyzed.
The objective of this evaluation is to determine economic feasibility of operating of seawater systems at higher
recovery rates versus process optimization based on prevailing economic parameters. The optimized system design
will be compared with the design of recent large seawater installations: 10,000mVd plant at Eilat, Israel, 40,000mVd
seawater plants at Larnaca, Cyprus and the design proposed for the 95,000mVd RO plant at Tampa, Florida.

Keywords: Reverse osmosis; Cost evaluation

1. I n t r o d u c t i o n are recently built or awarded large (10,000-


95,000mVd) RO seawater projects: Eilat (Israel),
The economics of seawater desalting using
Lamaca (Cyprus) and Tampa (Florida, USA). In
reverse osmosis technology have been con-
these projects the desalted water cost is signifi-
tinuously improving with a reduction of product
cantly below $1.0/m 3 ($3.8/kgallon). Low water
water cost as a result of lower investment costs
cost is a result of lower investment and operating
and decreased power consumption. The practical
cost. The lower capital investment cost has been
examples o f the decreasing desalted water trend
achieved by more efficient system designs and
better selection of materials for construction.
*Corresponding author.

Presented at the European Conference on Desalination and the Environment: Water Shortage, Lemesos, Cyprus,
28-31 May 2001.

0011-9164/01/$- See front matter © 2001 Elsevier Science B.V. All rights reserved
PII: S001 ! - 9 1 6 4 ( 0 1 ) 0 0 2 7 8 - 8
300 M. Wilf, K. Klinko / Desalination 138 (2001) 299-306

Power consumption has decreased due to following components: equipment amortization,


improved efficiencies of high-pressure pumps, energy usage, consumption of chemicals, mem-
power recovery turbines and optimization of brane replacement and cost of operation and
recove~ rate with resqect to reqtffred feed ntaintenance, The desalted water cost decreased
9ressare. A t ate ~revaitia~ 9rfces o f sweater conCintmusly over ¢~e years (o~¢owing lower
membrane dement~ the major water ~osl ~onlrJ- con~bmJcvo o f e~ae~b oY ~be cost categories.
bution results from the cost of process equipment Equipment cost decrease is a result of more
and power consumption. The seawater RO efficient system design. More effective pre-
process parameter which has the largest effect on treatment equipment is being used together with
investment and operating cost is the permeate simplified train design. It is a/so more frequent
recovery rate. The feed flow is inversely propor- to utilize sites with existing supply of seawater
tional to the design recovery rate; therefore, the feed. For example, it is more common to locate
recovery rate directly affects the size and cost of RO system on the sites of operating power plant
all process equipment and power consumption. or seawater distillation systems and utilize
However, in seawater RO systems, the recovery common intake and discharge structures
rate carrao¢ /~e (r~ereased a¢ ~c(/?, as t~fgtter (condenser oug(et(. Oecrease or" 9ower usage
recovery results in higher average feed salinity, results from the use of more efficient pumps,
which results in higher osmotic pressure and turbines and motors and operation at recovery
increased permeate salinity. The system recovery rate close to the minimum of power con-
rate has to be optimized with respect to membrane sumption. Usage of chemicals has been reduced
performance and process economics. The design due to recognizing that the scaling potential of
objective is to produce required permeate salinity seawater is negligible under RO operating con-
and to balance between decreasing equipment ditions. Higher recovery rate also contributes to
cost and increasing power consumption. With lower dosage rate of chemicals used. Membrane
iaerea~irr~ reco~cery race ¢?fe e~iqarert¢ s(r_e and req&cemen¢ cost (o?~ows Me tread o~f decreasing
cost decreases due to lower feed flow. However, cost of membrane elements and lower replace-
the specific power consumption initially decreases ment rate for long-term contracts. Operation and
~~.~e~ ~ ~fi~' Cx~e.~, . ~ e r degree of
and eventually increases. This trend is due to the process automation and remote monitoring of
necessity to operate RO membranes at higher performance. Historical values of capital cost of
feed pressure with increasing osmotic pressure at RO seawater systems, starting over two decades
a higher recovery rate. Recent developments of ago, are provided by Leitner [2]. The listing
R O seawater technology, improvement o f mem- includes large seawater R O systems in Middle
brane salt rejection, introduction of membrane East, US and Spain. The systems in Middle East
elements that are capable of operating above outnumber installations at other locations. The
70 bar (1000 psi) and availability of directly driven capital cost ranges from $700/m3-d (Key West,
interstage booster pumps, provide additional Fl) to $2500/m3-d (Jeddah, SA), with majority of
flexibility in optimization of the operating para- the entries at $1,100/m3-d level ($2.66/gpd,
meters. $9.46/gpd and $4.40/gpd respectively). Leitner
evaluated representative water cost, at an Arabian
Gulf location, as being $1.31/m 3 ($4.97/kgallon)
2. Product water cost
~fa- ~%st~n- ~ 2F.~db%'~-?6~ ~.ff~qh%'3D) product
The cost of water produced in seawater RO capacity. This 1989 water cost estimation can be
systems is the result of contribution from the compared with the water cost produced in
M. Will, K. Klinko / Desalination 138 (2001) 299-306 301

current large RO systems. The entries in Table 1 will be provided using a system of multiple
include water cost values for recent operating pumps, variable speed drives and permeate back-
plant (Eilat) and contractual values for projects pressure.
being completed recently (Larnaca, Cyprus) and
to be built in the near future (Tampa, Florida).
3. Parameters of the R O process
The Eilat plant is a single pass system, which
processes Red Sea seawater blended with con- The operating parameters for seawater RO
centrate of the local brackish water plant system are mainly a function of feed water
(combined feed salinity 36,000ppm TDS) at 50% salinity and temperature. For example, for sea-
recovery rate. Operation with blended feed results water feed of about 38,000ppm TDS salinity and
in lower product water cost due to operation at water temperature in the range of 18-28°C, the
higher recovery rate and lower feed pressure. RO systems are designed to operate at a recovery
The availability of RO concentrate is limited, rate in the range of 45-50%, with an average
and therefore, the future RO units at this location permeate flux in the range of 7-9gfd (11.9-
are designed to operate on sweater only (about 15.01/m2-h). At the above operating conditions,
42,000ppm TDS) at 45% recovery rate. The the feed pressure is in the range of 800-1000psi
design of Lamaca and Tampa plants is of two- (55-70bar) and permeate salinity is in the range
pass configuration. of 300--500ppm TDS. For a given feed water
The Larnaca plant is designed to process salinity and salt rejection of the membrane
Mediterranean seawater (about 40,500ppm TDS) elements used, the permeate salinity is a function
at 50% recovery rate. The additional processing of feed water temperature, recovery rate and
of permeate is required to reduce boron concen- permeate flux. An increase in feed water
tration in the permeate below 1ppm. At the temperature results in an increased rate of salt
Tampa site the feed water is of variable salinity, and water diffusion across the membrane barrier
ranging from 18,000ppm TDS to 31,000ppm at the rate of about 3-5% per degree Centigrade.
TDS. Partial second pass processing is necessary Because RO plants usually operate at a constant
to maintain chloride level in the permeate below flux rate, the changes of permeate salinity
100ppm over the whole range of feed water closely follow the changes in feed water
salinity and temperature. A wide range of feed temperature [1]. Permeate salinity is inversely
salinity combined with fluctuation of feed water proportional to the average permeate flux.
temperature creates a significant challenge for Higher permeate flux increases the dilution of
the design of high pressure pumping system. The salt ions which passed through the membrane,
required range of feed pressure to the membranes and therefore results in lower permeate salinity.

Table 1
Water cost in recent RO projects
Location Permeatecapacity, Status Recoveryrate Total water cost,
m3/d(MGD) (configuration) $/m3($/kgallon)
Eilat, Israel 20,000 (2.6) First phase (10,000 m3/d) 50% (singlepass) 0.72 (2.72)
operational since 1997
Eilat, Israel 20,000 (2.6) Under design 45% (singlepass) 0.81 (3.06)
Larnaca, Cyprus 40,000(10.6) Commissionin March, 2001 50% (partial double pass) 0.83 (3.14)
Tampa, FL, USA 94,600(25.0) 2002 60% (partial doublepass) 0.55 (2.10)
302 M. Wilf, K. Klinko / Desalination 138 (2001) 299-306

The average permeate flux rate in seawater


systems is maintained at relatively low values: 7-
9 gfd (11.9-15.0 l/m2-h) for surface seawater feed
and 9-10gfd (15.3-17.01/m2-h) for seawater from
beach wells. The difference in flux rates between
the two water source types results from better
quality of the well water and therefore, a lower
fouling rate for the membranes. These flux values
are relatively low and only about 50% of the
permeate flux values used in brackish RO sys-
m~
tems. Attempts to operate seawater systems at
significantly higher flux rates have usually IIm~/nm,%
resulted in irreversible flux decline. Until recently,
the design recovery rate of new commercial Fig. 1. Projected permeate salinity for Mediterranean
seawater RO systems has been increased subse- feed, 20°C at permeate flux rate range 8-I 1 gfd.
quently to the availability of membrane elements
with increasingly higher salt rejection. So far, the
maximum recovery in seawater RO systems has
been mainly limited by the membrane salt rejec-
4. Process economics
tion or the ability to produce permeate water of
potable quality. Fig. 1 displays permeate salinity Recovery rate has a major impact on the
as a function of recovery rate and permeate flux. economics of the seawater RO process. The size
The calculation were conducted for Mediter- of all process equipment which is determined
ranean seawater feed of salinity of 40,500ppm according to feed or concentrate flow will
TDS and feed temperature of 20°C for a recovery decrease with increased recovery rate. This
range of 40-60% and flux rate of 8-11 gfd. applies to the size of the feed water supply system
Nominal 99.7% salt rejection membrane elements and power consumption of intake pumps. The
were used. For calculations of permeate quality, size of all pretreatment equipment; storage tank,
the membrane salt passage was increased by 30%. booster pumps, filtration equipment and chemical
This is to account for projected 10% per year salt dosing systems is determined according to the
passage increase during 3 years of an average feed flow. The same considerations apply to
membrane life. As expected, a higher recovery sizing of concentrate piping and of the outfall
rate requires operation at an average flux rate facility. The design permeate flux rate affects the
above the standard value of 8gfd. This is to number of membrane elements installed, number
maintain permeate salinity of 400ppm TDS, of pressure vessels, manifold connections and
especially during the periods of higher feed water size of membrane skid. The effect of the recovery
temperature. The obvious questions are what is rate on investment and water cost will be
the optimum recovery rate of seawater syst.~,ms examined in an example for a 6mgd (22,700mVd)
in respect to product water cost, is such recovery system operating on three representative seawater
achievable with the current performance of com- sources. The cost estimation of the conventional
mercial seawater membranes, and is it possible reference design is based mainly on the data
to operate RO membranes on surface seawater at developed by G. Leitner [2], P. Shields and I.
a higher flux rate. Moch [3].
M. Wilf, K. Klinko / Desalination 138 (2001) 299-306 303

5. Parameters of RO system performance Power cost $0.06/kWh


calculations Annual membrane replacementrate . 20%
Membrane replacementcost $700/element
The evaluation was conducted for three Cost oftrealment chemicals $0.05/m3
representative seawater sources: Mediterranean; ($0.19/Kgal)
Efficiencyof pumps 83%
approximate salinity 40,500ppm TDS, Atlantic
Efficiencyof ERT 83%
Ocean; approximate salinity 38,500ppm TDS and Efficiencyof electrical motors 94%
Pacific Ocean; approximate salinity 34,000ppm Average permeate flux rate 13.5 l/m2-h(8gfd)
TDS. Calculation o f membrane performance was
conducted for the RO system recovery range of
6. System cost
40-70%.
Equipment cost was estimated for a RO Table 2 summarizes equipment cost for the
system treating seawater feed from open intake, 22,7000m3/d (6 mgd) RO seawater system
utilizing conventional pretreatment with two stage utilizing conventional pretreatment. The basic
gravity filtration. The equipment cost data was case equipment cost was estimated for the RO
based on published cost estimation [ 1,2] and other system design at 45% recovery rate. With
communications. increasing recovery rate the size and cost of
Product water cost was calculated based on equipment decreases. However, the rate o f cost
the following cost parameters: decrease declines with increasing recovery, con-
Plant life 20 years verging to very small savings at the high recovery
Interest rate 8% end.

Table 2
22,700 mVd (6 MGD) seawater RO system cost estimation

Recovery rate, % 40 45 50 55 60 65 70
Equipment
Intake and outfall 1303 1200 1132 1043 981 928 881
Pretreatment~ 3258 3000 2787 2607 2453 2319 2202
Membranes 1500 1500 1500 1500 1500 1500 1500
RO trains: 4600 4600 4600 4600 4600 4600 4600
Pumps and motors3 1609 1600 1592 1584 1663 1746 1834
MCC 1000 1000 1000 1000 1000 1000 1000
Instruments and control 600 500 600 600 600 600 600
Auxiliary equipment 500 500 500 500 500 500 500
Product water treatment 400 400 400 400 400 400 400
Site development 2800 2800 2800 2800 2800 2800 2800
Indirect cost, 20% 3514 3420 3382 3327 3299 3279 3263
Total cost, K$ 21084 20520 20293 19960 19797 19672 19580
Total cost, $/m3-d 928.8 904.0 894.0 879.3 872.1 866.6 862.5
Total cost, $/gpd 3.51 3.42 3.38 3.33 3.30 3.28 3.26

Two-stage gravity filtration; 2Two 3 MGD trains; 3 IncludesERT


304 M. Wilf, K. Klinko / Desalination 138 (2001) 299-306

7. Feed pressure requirements energy requirement vs. recovery rate. The energy
includes electricity consumed by intake pumps,
The feed pressure requirements depend on the
pretreatment system and high pressure feed
osmotic pressure of the feed water (feed salinity),
pumps. The minimum energy value is at about
feed water temperature and the design permeate
50-55% recovery rate and varies with feed water
flUX.
salinity.
Fig. 2 presents the osmotic pressure o f the
The following water cost components are
concentrate vs. recovery rate for the three feed
affected by the recovery rate: energy, chemicals
water sources evaluated. Fig. 3 displays required
and capital cost. Fig. 5 shows a plot o f the
feed pressure for a given water source and
combined contribution to the water cost o f these
recovery rate calculated for an average permeate
three components. Because chemicals and capital
flUX rate of 13.51/m2-h (8gfd). The pressure
cost decrease with increasing recovery rate, the
requirement was calculated for a single stage
minimum value o f water cost shifts to higher
array system. For two-stage system the feed
recovery rate as compared to the energy vs.
pressure will be higher due to additional pressure
recovery plot (Fig. 4).
drop across the second stage.

8. Energy requirement and water cost 9. Total water cost

The energy requirement is directly related to The total water cost includes recovery
feed pressure and feed water flow. Higher sensitive components such as energy, chemicals
recovery rate requires higher feed pressure to and capital. It also includes operation and main-
overcome increasing average osmotic pressure. tenance cost and membrane replacement con-
However, the feed flow rate decreases with tribution, which are not directly affected by the
increasing recovery. Fig. 4 shows the plot of recovery rate. Fig. 6 shows the plot o f the total

11o . . . . . . . . F ...........

,® . . . . . +. . . . ~- -~- --- i. + -/.~b


1~ j ~ ...........',............................ i........... i- - / . ~ - . ~ , ~ .....
, I ~ ,s- / i~mic
ii ~ .............. ! . i i i i • ,
E , , ;. . . . . . . . ) ........ t. . . . . . . /(,~'i r- ~ . - # " : .............. :
u ............ ). . . . . . . ! i . - i i

40 40 50 ~ 60 65 70 75

Fig. 2. Osmotic pressure o f concentrate.


M. Wilf, K. Klinko / Desalination 138 (200!) 299-306 305

,,i ..... =: ,7<9- ..... :: //__


---. .,,i,/__
~L-----
'" /'//; -- I"
"~ TM
........ _ . . ~ ./ ~_

3O 4O 60 70
Ibcovery rate, %

M 40 48 M 68 IO M '8) 76
Ibcovery rm, 5
Fig. 4. Energy requirement.
Fig. 3. Feed pressure vs. recovery.

KO

n o p. . . . . . . . . , _.,A.. ..4-~u~

(~.0 ......... - ............ ~................. ,--i-- t~llc ...... _ _ _ /I.0-


~J _ -.-_t~m

3o 40 a N m ao U m is ~ ~ 60 U go U 70
Ibcovery r m , '~ Ibmvory r m , 'it

Fig. 5. Selected water cost ~mLcx)n~ts: energy, ch~c~ds, Fig. 6. Total water cost.

cost vs. recovery rate. The minimum value is at expected, at higher power rate the minimum cost
about 55-65% recovery rate, shifting to slightly shifts to lower recovery. At the lowest range of
higher values at lower feed salinity (Pacific the power rate the recovery rate has little effect
Ocean). on water cost.

10. T h e effect o f p o w e r cost rate 11. C o n c l u s i o n s

The calculations of water cost, displayed in The water cost considerations indicate that in
Figs. 5 and 6, were conducted at the power rate seawater RO systems the optimum recovery rate
o f C6/kWh. Fig. 7 shows the values o f water cost is in the range o f 50-60%. The recovery value
at power rates o f $0.03/kWh-$0.12/kWh for the corresponding to cost optimum depends on feed
mid range o f feed water salinity (Atlantic). As water salinity and power rate. The calculations
306 M. Wilf, K. Klinko / Desalination 138 (2001) 299-306

w
The conclusion of the above evaluation is that
designing seawater RO system for recovery rate
exceeding 55% can only provide cost benefits in
cases of low feed salinity and low electricity
cost. Increasing power cost shifts the optimum of
J
|Tu
the total water cost to lower recovery rates. High
D
cost of intake and concentrate discharge structure
J ,u will shift the optimum to a higher recovery rate.
An additional parameter that has to be
considered is the resulting permeate salinity. For
design cases, when a high recovery rate design
will result in an increase of permeate salinity,
S 40 41 N M N iS 711' which will subsequently require a change of RO
bmvo~.ranlo,%. system design from a single pass to a two pass
Fig. 7. Water cost vs. power cost. configuration, most likely the produced water
cost will be higher than can be achieved in a con-
were conducted under assumptions that high ventional system.
pressure and regular pressure elements are
equivalent with respect to cost, performance and
operational longevity. It is likely that addir.g a
References
high-pressure section to the system for operation
at high recovery and feed pressure significantly [1] M. Wilfand K. Klinko, Desalination,96 (1994) 456.
above 70bar would increase unit capital cost and [2] G. Leitner, Desalination 76 (189) 201.
may increase the membrane replacement cost [3] P. Shieldsand I. Moch, Evaluationof global sea water
component. This would result in shifting the reverse osmosis capital and operating cost, Proc.
minimum water cost toward lower recovery ADA Conference, Monterey, California, August
values. 1996, pp. 44-60.

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