1

ARJUNA (JEE)
DPP-01
General Organic Chemistry
1. The inductive effect of the groups: –NH3; 6. Order of stability of given free radical is:
–D; –CO2Θ; –COOH are respectively H3 C  CH 2 H3C  C H  CH3
(A) –I, +I, +I, –I (I) (II)

(B) –I, –I, –I, +I H 3 C  C CH 2  CH 3

(C) +I, No effect, –I, –I |
(D) +I, –I, –I, –I CH 3
(III)

(A) III > I > II (B) I > II > III

2. Which of the following belongs to +I (C) II > I > III (D) III > II > I
group?

(A) –OMe (B)  NH 3 7. Arrange the following groups in the order
of decreasing (–I) effect.
O
||  (A) CN > F > Br > Cl > COOH > I > H
(C) C  O (D) –OH (B) COOH > CN > F > Br > Cl > I > H
(C) H > COOH > CN > I > Cl > F > Cl
(D) CN > COOH > F > Cl > Br > I > H
3. Choose the correct statement
(A) I effect operates in both  and  bonds 8. The +I.E. (inductive effect) is shown by:
(B) I effect creates net charge in molecule (A) –CH3 (B) –OH
(C) I effect transfers electron from one (C) –F (D) –C6H5
carbon to another
(D) I effect creates partial charges and it is 9. The –I effect is shown by:
distance dependent (A) –COOH (B) –CH3
(C) –CH3CH2 (D) –CHR2
4. The most stable carbocation among the
following is: 10. The increasing order of +ve I-effect shown
 by H, CH3, C2H5 and C3H7 is:
(A) H3C (A) H < CH3 < C2H5 < C3H7
 (B) H > CH3 > C2H5 >C3H7
(B) H 2 C CH 2  OCH 3
(C) H < C2H5 < CH3 < C3H7

(C) H 3 C  C CH 2  CH 3 (D) None of the above
|
CH 3 11. The most acidic hydrogen among given
 compounds is:
(D) H 3 C  C CH 2  OCH 3 Ha
| |
CH 3 (A) H3C  H 2 C  CH 2
Ha
5. The increase in number of alkyl groups |
(A) Increases the stability of carbanion (B) H3C  CH 2  CH  CH3
Ha
(B) Decreases the stability of carbanion |
(C) Remains the same (C) H 3 C  C  CH 3
(D) None of these |
CH 3
(D) Cannot be predicted
 2

12. The most acidic compound among

following is:
(A) F – CH2 – COOH
(B) Cl – CH2 – COOH
(C) Br – CH2 – COOH
(D) I – CH2 – COOH