1

YAKEEN-2.0
GOC
[DPP-01]

1 The inductive effect - 7. Which is the correct order of increasing basicity ?

(A) implies the atom's ability to cause bond (A) CH3CH2CH3 < CH3CH2SH < CH3CH2OH <
polarization CH3CH2NH2
(B) increases with increase of distance (B) CH3CH2CH3 < CH3CH2OH < CH3CH2SH <
(C) implies the transfer of lone pair of electrons CH3CH2NH2
from more electronegative atom to the lesser (C) CH3CH2NH2 < CH3CH2SH < CH3CH2OH <
electronegative atom in a molecule CH3CH2CH3
(D) implies the transfer of lone pair of electrons (D) CH3CH2CH3 < CH3CH2OH < CH3CH2NH2 <
from lesser electronegative atom to the more CH3CH2SH
electronegative atom in a molecule
8. The inductive effect of the groups: NH3 ; –D;
2. In which of the following compounds is hydroxylic CO3 ; –COOH are respectively
proton the most acidic ? (A) –I, +I, +I, –I
F (B) –I, –I, –I, +I
(A) O (B) I O (C) +I, No effect, –I, –I
H H
(D) +I, –I, –I, –I
O O 9. Which of the following belongs to +I group?
(C) H (D) H

F F
(A) –OMe (B)  NH3

3. Decreasing – I power of given groups is -

(a) –CN (b) –NO2 (c) –NH2 (d) –F (C) (D) –OH
(A) b > a > d > c (B) b > c > d > a
(C) c > b > d > a (D) c > b > a > d 10. Choose the correct statement
(A) I effect operates in both 𝜋 and 𝜋 bonds
(B) I effect creates net charge in molecule
4. Which among the given acid has lowest pKa value - (C) I effect transfers electron from one carbon to
(A) Chloroacetic acid (B) Bromoacetic acid another
(C) Nitroacetic acid (D) Cyanoacetic acid (D) I effect creates partial charges and it is distance
dependent
5. Arrange basicity of the given compounds in
11. The increase in number of alkyl groups
decreasing order - (A) Increases the stability of carbanion
(a) CH3 – CH2 – NH2 (b) CH2 = CH – NH2 (B) Decreases the stability of carbanion
(c) CH  C – NH2 (C) Remains the same
(A) a > b > c (B) a > c > b (D) None of these
(C) c > b > a (D) b > c > a 12. Arrange the following groups in the order of
decreasing (–I) effect.
6. Consider following acid (A) CN > F > Br > Cl > COOH > I > H
ClCH2COOH, CH3COOH, CH3CH2COOH (B) COOH > CN > F > Br > Cl > I > H
I II III (C) H > COOH > CN > I > Cl > F > Cl
(D) CN > COOH > F > Cl > Br > I > H
Correct order of their pH value
(A) III < II < I (B) I < II < III
(C) I < III < II (D) II < I < III
 2

13. The +I.E. (inductive effect) is shown by: 16. The most acidic hydrogen among given compounds is:
(A) –CH3 (B) –OH
(C) –F (D) –C6H5 (A)

14. The –I effect is shown by:

(A) –COOH (B) –CH3 (B)
(C) –CH3CH2 (D) –CHR2
(C)
15. The increasing order of +ve I-effect shown by H,
CH3, C2H5 and C3H7 is:
(A) H < CH3 < C2H5 < C3H7 (D) Cannot be predicted
(B) H > CH3 > C2H5 >C3H7 17. The most acidic compound among following is:
(C) H < C2H5 < CH3 < C3H7 (A) F – CH2 – COOH
(D) None of the above (B) Cl – CH2 – COOH
(C) Br – CH2 – COOH
(D) I – CH2 – COOH
 3

ANSWERS

1. (A)
2. (D)
3. (A)
4. (C)
5. (A)
6. (B)
7. (A)
8. (A)
9. (C)
10. (D)
11. (B)
12. (D)
13. (A)
14. (A)
15. (A)
16. (A)
17. (A)

Any issue with DPP, please report by clicking here- https://forms.gle/t2SzQVvQcs638c4r5

Please share your feedback on PW Teachers- https://forms.gle/jEBFswBuki4Ut2Lk6

PW Mobile APP : https://physicswala.page.link/?type=contact-us&data=open

For PW Website : https://www.physicswallah.live/contact-us