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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 1: Identification of the substance or mixture and of the company

1.1 Product Identifier


Product name : Argon, compressed
Chemical name : Argon
Chemical formula : Ar
CAS no. : 7440-37-1

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Industrial and professional. Balance gas for mixtures. Blanketing gas.
Calibration gas. Carrier gas. Combustion, melting and cutting processes.
Fire suppressant gas. Food packaging gas. Inerting gas. Inflation systems.
Laboratory use. Laser gas. Pressure head gas, operational assist gas in
pressure systems. Process gas. Purge gas. Test gas. Consumer use.
Shielding gas in gas welding.
It is the responsibility of the end user to ensure that the product as supplied
is suitable for its intended use.

1.3 Details of the supplier of the safety data sheet


Supplier name : Linde HKO Limited
Address : 12 Chun Yat Street, Tseung Kwan O Industrial Estate, Tseung Kwan O,
Kowloon, Hong Kong
Phone no. : (852) 2372-2288
Fax no. : (852) 2372-2508

1.3 Emergency telephone number


Emergency no. : (852) 2661 0920 (24 hours)

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008


Gases under pressure (Compressed gas) : H280: Contains gas under pressure; may explode if heated.

2.2 Label Elements


Pictograms :

Signal word : Warning


Hazard statements : H280: Contains gas under pressure; may explode if heated.
Precautionary statements
General : None
Prevention : None
Response : None
Storage : P403: Store in a well-ventilated place.
Disposal : None

2.3 Other hazards


Asphyxiant. Effects are proportional to oxygen displacement.

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 3: Composition/ information on ingredients

3.1 Substances
Chemical name : Argon
Chemical formula : Ar
CAS no. : 7440-37-1
EC no. : 231-147-0
INDEX no. : ----
REACH registration number : Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH),
exempted from registration.

Ingredient(s) CAS No. EC no. Purity


Argon 7440-37-1 231-147-0 ≥99.99%

3.2 Mixtures
Not Applicable

SECTION 4: First Aid Measures

4.1 Description of first aid measures


Inhalation : In high concentrations may cause asphyxiation. Symptoms may include
loss of mobility/consciousness. Victim may not be aware of asphyxiation.
Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial
respiration if breathing stopped.
Eye contact : Adverse effects not expected from this product.
Skin Contact : Adverse effects not expected from this product.
Ingestion : Ingestion is not considered a potential route of exposure.

4.2 Most important symptoms and effects, both acute and delayed
Respiratory arrest.

4.3 Immediate medical attention and special treatment needed


None

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 5: Firefighting Measures

5.1 Extinguishing media


Suitable extinguishing media : Material will not burn. In case of fire in the surroundings: use appropriate
extinguishing agent.

5.2 Special hazards arising from the substance or mixture


None

5.3 Advice for firefighters


Special fire fighting procedures : In case of fire, stop leak if safe to do so. Continue water spray from
protected position until container stays cool. Use extinguishants to contain
the fire. Isolate the source of the fire or let it burn out.
Special protective equipment for : Firefighters must use standard protective equipment including flame
firefighters retardant coat, helmet with face shield, gloves, rubber boots, and Self-
Contained Breathing Apparatus (SCBA).

SECTION 6: Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures


Evacuate area. Provide adequate ventilation. Prevent from entering sewers, basements and workpits, or any place
where its accumulation can be dangerous. Wear self-contained breathing apparatus when entering area unless
atmosphere is proved to be safe.

6.2 Environmental Precautions


Prevent further leakage or spillage if safe to do so.

6.3 Methods and material for containment and cleaning up


Provide adequate ventilation.

6.4 Reference to other sections


See also sections 8 and 13.

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 7: Handling and Storage

7.1 Precautions for safe handling


Only experienced and properly instructed persons should handle gases under pressure. Use only properly specified
equipment which is suitable for this product, its supply pressure and temperature. Keep equipment free from oil
and grease. Open valve slowly to avoid pressure shock. Use only oxygen approved lubricants and sealants. Use
only with equipment cleaned for oxygen service and rated for the pressure. Refer to supplier's handling
instructions. The substance must be handled in accordance with good industrial hygiene and safety procedures.
Protect containers from physical damage; do not drag, roll, slide or drop. Do not remove or deface labels provided
by the supplier for the identification of the container contents. When moving containers, even for short distances,
use appropriate equipment eg. trolley, hand truck, fork truck etc. Secure cylinders in an upright position at all times,
close all valves when not in use. Provide adequate ventilation. Suck back of water into the container must be
prevented. Do not allow backfeed into the container. Avoid suckback of water, acid and alkalis. Keep container
below 50°C in a well ventilated place. Observe all regulations and local requirements regarding storage of
containers. When using do not eat, drink or smoke. Store in accordance with local/regional/national/international
regulations. Never use direct flame or electrical heating devices to raise the pressure of a container. Leave valve
protection caps in place until the container has been secured against either a wall or bench or placed in a container
stand and is ready for use. Damaged valves should be reported immediately to the supplier. Close container valve
after each use and when empty, even if still connected to equipment. Never attempt to repair or modify container
valves or safety relief devices. Replace valve outlet caps or plugs and container caps where supplied as soon as
container is disconnected from equipment. Keep container valve outlets clean and free from contaminates
particularly oil and water. If user experiences any difficulty operating container valve discontinue use and contact
supplier. Never attempt to transfer gases from one container to another. Container valve guards or caps should be
in place.

7.2 Conditions for safe storage, including any incompatibilities


Containers should not be stored in conditions likely to encourage corrosion. Stored containers should be
periodically checked for general conditions and leakage. Container valve guards or caps should be in place. Store
containers in location free from fire risk and away from sources of heat and ignition. Keep away from combustible
material.

7.3 Specific end uses


None

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 8: Exposure Controls/Personal Protection

8.1 Control parameters


Occupational Exposure Limits : No exposure limits have been established for this product.
Biological limits : No biological limits have been established for this product.

8.2 Exposure controls


Appropriate engineering controls : Consider a work permit system e.g. for maintenance activities. Ensure
adequate air ventilation. Provide adequate ventilation, including
appropriate local extraction, to ensure that the defined occupational
exposure limit is not exceeded. Oxygen detectors should be used when
asphyxiating gases may be released. Systems under pressure should be
regularly checked for leakages. Preferably use permanent leak tight
connections (eg. welded pipes). Do not eat, drink or smoke when using the
product.

Individual protection measures, such as personal protective equipment.


Eye protection : Wear safety glasses.
Hand Protection : Wear leather gloves.
Body protection : Wear coveralls and safety boots.
Respiratory Protection : Where an inhalation risk exists, wear Self Contained Breathing Apparatus
(SCBA) or an Air-line respirator.

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 9: Physical and Chemical Properties

9.1 Information on basic physical and chemical properties


Appearance
Physical state : Gas
Form : Compressed gas
Colour : Colorless
Odour : Odourless
Odour Threshold : No data available.
pH : No data available.
Melting Point : -189 °C
Boiling Point : -186 °C
Sublimation Point : No data available.
Critical Temp. (°C) : -122.0 °C
Flash Point : No data available.
Evaporation Rate : No data available.
Flammability (solid, gas) : This product is not flammable
Flammability limit - upper (%) : No data available.
Flammability limit – lower (%) : No data available.
Vapour pressure : No data available.
Vapour density (air=1) : 1.38
Relative density : 1.4
Solubility (in Water) : 61 mg/l
Partition coefficient (n- : No data available.
octanol/water)
Autoignition Temperature : No data available.
Decomposition Temperature : No data available.
Viscosity
Kinematic viscosity : No data available.
Dynamic viscosity : No data available.
Explosive properties : No data available.
Oxidising Properties : No data available.

9.2 Other information


Additional information : Gas/vapor heavier than air. May accumulate in confined spaces,
particularly at or below ground level.

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 10: Stability and Reactivity

10.1 Reactivity
No reactivity hazard other than the effects described in sub-section below.

10.2 Chemical Stability


Stable under normal conditions.

10.3 Possibility of Hazardous Reactions


None.

10.4 Conditions to Avoid


None

10.5 Incompatible Materials


No reaction with any common materials in dry or wet conditions.

10.6 Hazardous decomposition products


None

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 11: Toxicological Information

11.1 Information on toxicological effects


Acute toxicity
Oral : Based on available data, the classification criteria are not met.
Inhalation : Based on available data, the classification criteria are not met.
Dermal : Based on available data, the classification criteria are not met.
Skin Corrosion/Irritation : Based on available data, the classification criteria are not met.
Serious Eye Damage/Eye Irritation : Based on available data, the classification criteria are not met.
Respiratory or Skin Sensitisation : Based on available data, the classification criteria are not met.
Germ Cell Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Reproductive toxicity : Based on available data, the classification criteria are not met.
Specific Target Organ Toxicity
Single Exposure : Based on available data, the classification criteria are not met.
Repeated Exposure : Based on available data, the classification criteria are not met.
Aspiration Hazard : Not applicable to gases and gas mixtures.

SECTION 12: Ecological Information

12.1 Toxicity
No ecological damage caused by this product.

12.2 Persistence and Degradability


The substance is naturally occurring.

12.3 Bioaccumulative Potential


The subject product is expected to biodegrade and is not expected to persist for long periods in an aquatic
environment.

12.4 Mobility in Soil


Not applicable.

12.5 Other Adverse Effects


No ecological damage caused by this product.

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 13: Disposal Considerations

13.1 Waste treatment methods


Disposal method : Do not discharge into any place where its accumulation could be
dangerous. Cylinders should be returned to the supplier for disposal of
contents.

SECTION 14: Transport Information

ADR/RID
14.1 UN Number : UN 1006
14.2 UN proper shipping name : ARGON, COMPRESSED
14.3 Transport Hazard Class(es)
Class : 2
Label(s) : 2.2: Non-flammable, non-toxic gases
Classification Code : 1A
Hazard No. : 20
14.4 Packaging group : None
14.5 Environmental hazards : Not Applicable
14.6 Special precautions for user : None

IMDG
14.1 UN Number : UN 1006
14.2 UN proper shipping name : ARGON, COMPRESSED
14.3 Transport Hazard Class(es)
Class : 2.2
Label(s) : 2.2: Non-flammable, non-toxic gases
14.4 Packaging group : None
14.5 Environmental hazards : Not Applicable
14.6 Special precautions for user : None

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

IATA
14.1 UN Number : UN 1006
14.2 UN proper shipping name : ARGON, COMPRESSED
14.3 Transport Hazard Class(es)
Class : 2.2
Label(s) : 2.2: Non-flammable, non-toxic gases
14.4 Packaging group : None
14.5 Environmental hazards : Not Applicable
14.6 Special precautions for user : None
Other information
Passenger and cargo aircraft : Allowed
Cargo aircraft only : Allowed

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Not Applicable

14.8 Additional information


Transport precautions : Avoid transport on vehicles where the load space is not separated from the
driver's compartment. Ensure vehicle driver is aware of the potential
hazards of the load and knows what to do in the event of an accident or an
emergency. Before transporting product containers ensure that they are
firmly secured. Ensure that the container valve is closed and not leaking.
Container valve guards or caps should be in place. Ensure adequate air
ventilation.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Local legislation : Dangerous Goods Ordinance (Chapter 295)

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Safety Data Sheet

Argon
SDS No.: HKO-003G Revision date: 15/11/2022 Version no.: 03

SECTION 16: Other Information

Other information : Before using this product in any new process or experiment, a thorough
material compatibility and safety study should be carried out. Ensure
adequate air ventilation. Ensure all national/local regulations are
observed. Whilst proper care has been taken in the preparation of this
document, no liability for injury or damage resulting from its use can be
accepted.
Revision date : 15/11/2022
Disclaimer : The above information is believed to be correct. This information should be
used to make an independent determination of the methods to safeguard
workers and the environment.

End of document

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