SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

1.1 Product Details

Product Name : Nitrogen, Compressed

Chemical Name : Nitrogen
Common Names : Nitrogen Gas, Gaseous Nitrogen, GAN
Chemical Formula : N2
CAS Number : 7727-37-9
Uses : Inerting, carrier gas, food and medical application.

1.2 Company Identification

Manufacturer Name : B.I.G Industrial Gas Sdn Bhd (62396-A)
Manufacturer Address : Lot 2225, Section 66, Jalan Dermaga,
Pending Industrial Estate,
93450 Kuching, Sarawak, Malaysia

Distributor Name : B.I.G Industrial Gas Sdn Bhd

Distributor Address : Lot 977, Block 26, Tanjung Kidurong,
P.O. Box 1106, 97008 Bintulu, Sarawak, Malaysia

1.3 Emergency Contact : 082 486321 (Kuching), 086 252430 (Bintulu)

SECTION 2. HAZARD IDENTIFICATION

2.1 Classification of the substance or mixture

Classification according to OSH CLASS Regulation 2013.
Physical Hazards
Gases under pressure Compressed gases
2.2 Label Element

Signal Word : Warning

Hazard Statements : Contains gas under pressure
May explode if heated
Precautionary Statement : Prevention

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SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

None
Response
None
Storage
Protect from sunlight. Store in a well-ventilated
place.
Disposal
None
Hazards not otherwise : None
classified

SECTION 3. COMPOSITION AND INFORMATION ON INGREDIENTS

3.1 Substance
Ingredient % Purity CAS Number Impurities or
additives
Nitrogen Formula: N2 100% 7727-37-9 None
(Main constituent)

Note : % Purity is for classification purposes only. For actual purity of the supplied substance, please refer to
other documentation.

SECTION 4. FIRST AID MEASURES

4.1 Measures to be taken in case of contact

Eye
Adverse effect is not expected with this substance.
In case of exceptional contact, immediately flush eye with plenty of water for at least 10
minutes. Get medical attention if severe or sudden eye pain develops.
Skin
Adverse effect is not anticipated with this substance.
Ingestion
Not considered as a potential exposure route
Inhalation
Nitrogen gas asphyxiation occurs to personnel when exposed to a high concentration. PROMPT
MEDICAL ATTENTION IS MANDATORY IN ALL CASES WHEN NITROGEN IS INHALED UNDER
PRESSURE. Do not enter enclosure or confined space when there is a high possibility that
nitrogen gas being released inside that space. When attempting to rescue a person in the
confined space, use Self Contained Breathing Apparatus. Rescue only by trained person.
Unconscious person should be assisted to uncontaminated area and inhale fresh air. Quick

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SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

removal from the contaminated area is most important. Further treatment should be
symptomatic and supportive. Apply artificial respiration.

4.2 Important symptoms or effect

Victim may not be aware when he is exposed to nitrogen gas. Exposed to high concentration
with low oxygen content cause asphyxiation. Symptoms are unconscious, loss of mobility and
respiratory arrest.

4.3 Immediate medical attention or special treatment needed

None

SECTION 5. FIRE FIGHTING MEASURES

5.1 Fire and explosion hazards

Cylinder may rupture violently from pressure when involved in a fire situation.

5.2 Extinguishing media

Spray water to keep cylinder cool. Appropriate extinguishing agent such as dry powder, foam or
carbon dioxide shall be use.

5.3 Specific hazards arising from substance.

None.

5.4 Fire fighting instructions

Firefighters should wear self contained breathing apparatus (SCBA) and protective clothing and
standard equipment. Continue to cool fire-exposed containers until well after flames are
extinguished.

Conditions of Flammable: Not flammable

Flash Point: None Method: Not Applicable Auto ignition temperature: None
LEL (%) : None UEL (%) :None
Sensitivity to mechanical shock: None
Sensitivity to static discharge : None

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Evacuate the area. Ensure adequate air ventilation. Prevent from entering sewers, basements
or work pits. Stop the leak if it is safe to do so. Evacuate all personnel from affected area.
Wear self contained breathing apparatus when entering the area. Use gas detectors.

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SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

6.2 Environmental precautions

Stop the leak if it is safe to do so.

6.3 Methods and material for containment and cleaning up

Provide natural or forced ventilation.

SECTION 7. HANDLING AND STORAGE

7.1 Precaution for safe handling

Only trained personnel familiar with high pressure gas hazards are allowed to work with
nitrogen and its equipment. Nitrogen is an inert gas and can be used with all materials of
construction. Pure nitrogen only slightly lighter than air and readily mixes with air at room
temperature. Ensure enclosure or confined space are well ventilated before attempting to enter
the area.
When opening nitrogen cylinder valve, ensure that you are in well ventilated place. Slowly open
the valve. Shut off cylinder valve and secure the cylinder when not in use.

7.2 Condition for the safe storage, including any incompatibility

Protect cylinders from physical damage. Store in cool, dry, well-ventilated areas away from
heavily trafficked areas, emergency exits, and flammable combustibles. Do not allow the
temperature where cylinders are stored in exceed 125°F (52°C). Cylinders should be stored
upright and firmly secured. Practice a “first in- first out” inventory system to prevent full
cylinders being stored for excessive periods of time. Post “NO SMOKING OR OPEN FLAMES” sign
in the storage area or use area.

SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

8.1 Control Parameters

Nitrogen is not listed in exposure limit data.

8.2 Appropriate Engineering Control

It is necessary to develop a risk assessment to a well defined situation or activities and to
recognized the risk of asphyxiation due to high concentration of nitrogen in atmosphere.
General Ventilation
Consider a Permit to Work system. A good general ventilation should be sufficient to control the
nitrogen-rich environment. Check system for leakage on regular interval.

8.3 Individual Protection Measures

Eye Protection
Safety goggles or glasses as recommended in a risk assessment of the job.

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SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

Skin Protection
Protective hand glove made of leather or cotton and fabric should be sufficient.
Body Protection
Personal protection for the body should be selected based on the task being performed and the
risks involved.
Respiratory Protection
A positive pressure self contained breathing apparatus shall be used in case of emergency to
prevent inward leakage of dangerous gases.
Other/General Protection
Appropriate footwear and additional skin protection measures should be selected based on the
task performed and the risk involved.

8.4 Hygiene Measures

Do not drink, eat or smoke at the nitrogen working area. Practice a good industrial hygiene and
safety procedures.

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SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

PARAMETER VALUE UNITS

Physical state (gas, liquid, solid) : Gas -
Form : Compressed gas -
Odor : Odorless -
Odor threshold : Not applicable -
pH : Not applicable -
Melting point : -210 / -346 °C / ° F
Boiling point : -196 / - 320 °C / ° F
Flash point : Not applicable -
Evaporation rate : Data not available -
Flammability (gas/liqud) : Substance is not flammable -
Flammability limit
Upper (%) : Not applicable -
Lower (%) : Not applicable -
Vapor pressure : Data not available -
Vapor density : 1.2506 x 10-3 g/cm at STP
3

Relative density (air=1.205 kg/m3) : 0.9669 at NTP

Solubility in water : 20 mg/l at 25°C
and 1 atm
Partition coefficient (n-octanol/water) : Not applicable -
Auto ignition temperature : Not applicable -
Decomposition temperature : Data not available -
Viscosity
Kinematic : 15.73 x 10-6 m2/s at 25°C
Dynamic : 1.782 x 10-5 kg/m-s at 25°C
Molecular weight : 28.01 g/mol

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
No specific data related to reactivity for this substance.

10.2 Chemical Stability

The substance is stable under normal conditions.

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SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

10.3 Possibility of Hazardous Reaction

None.

10.4 Condition to avoid

No specific data.

10.5 Incompatible Materials

None.

10.6 Hazardous Decomposition Products

Under normal condition of use, hazardous decomposition should not be produced.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 General Information

Generally, nitrogen is a simple asphyxia. It replaces oxygen in atmosphere.

11.2 Information on likely Route of Exposure

Acute toxicity - Oral
No known effects from this substance based on current data. Classification is not possible.
Acute toxicity - Dermal
No known effects from this substance based on current data. Classification is not possible.
Acute toxicity - Inhalation
No known effects from this substance based on current data. Classification is not possible.
Skin corrosion or irritation
No known effects from this substance based on current data. Classification is not possible.
Serious eye damage or eye irritation
No known effect from this substance based on current data. Classification is not possible.
Respiratory sensitization
No known effect from this substance based on current data. Classification is not possible.
Skin sensitization
No known effect from this substance based on current data. Classification is not possible
Germ cell mutagenicity
No known effect from this substance based on current data. Classification is not possible.
Carcinogenicity
No known effect from this substance based on current data. Classification is not possible.
Reproductive toxicity
No known effect from this substance based on current data. Classification is not possible.
Specific target organ toxicity - single exposure

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SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

No known effect from this substance based on current data. Classification is not possible.
Specific target organ toxicity - repeated exposure
No known effect from this substance based on current data. Classification is not possible.
Aspiration hazard
No known effect from this substance based on current data. Classification is not possible.

SECTION 12. DISPOSAL INFORMATION

12.1 Ecotoxicity
Aquatic and Terrestrial
No ecological damage caused by this substance.

12.2 Persistence and degradation

No ecological damage caused by this substance.

12.3 Bioaccumulative potential

Current data not available.

12.4 Mobility in soil

Substance is in gas form. Not applicable.

12.5 Other adverse effect

Effect on ozone layer
None
Effect on global warming
None

SECTION 13. DISPOSAL INFORMATION

13.1 Description of waste residue - treatment

Do not discharge the gas residue to a place where its accumulation could be dangerous to
human. Return the empty cylinder to B.I.G Industrial Gas Sdn Bhd or its authorized distributor
for proper disposal.Disposal of gas container may be subject to national and local regulation.

13.2 Disposal methods

Refer to Technical Publication by AIGA 083/13 Disposal of gases for guidance on the
appropriate disposal methods. Downloaded at www.aiga.org/publications.php.

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Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

SECTION 14. TRANSPORTATION INFORMATION

PARAMETER
UN Proper shipping name
ADR, RID, IMDG : NITROGEN, COMPRESSED
IATA : Nitrogen, Compressed
Transport Hazard class
ADR, RID : 2
IMDG, IATA: 2.2
UN identification number
ADR, RID, IMDG, IATA : UN 1066
Label
ADR, RID, IMDG, IATA : 2.2
Tunnel Restriction Code
ADR : (E)
Emergency Action Code
ADR : 2T
EmS No
IMDG : F-C, S-V
CLASS Pictogram:

Other information
IATA : Allowed in passenger and cargo aircraft.
Allowed in cargo aircraft.
Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code : Not applicable.

Special transport precautions : Avoid transport on vehicle where the load space is not
separated from the driver’s cabin. Ensure there is enough
ventilation, valves are securely closed and in a secure position.

SECTION 15. REGULATORY INFORMATION

Information under OSH Hazard Class : Gases under pressure

Classification, Labelling and Safety Hazard Category : Compressed gas
Data Sheet of Hazardous Chemicals

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Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

Regulation 2013
Not listed in USECHH Schedule I

SECTION 16. OTHER INFORMATION

Key literature references and sources for data :

Asia Industrial Gas Association Publication
i. AIGA 083/13 Disposal of gases
ii. AIGA 067/17 Safe Location of Oxygen and Inert Gas Vents
iii. AIGA 008/11 Hazards of inert gases and oxygen depletion
American Conference of Governmental Industrial Hygienists Appendix B TLVs and BEIs.
Matheson Gas Data Book
Perry Chemical Engineering Book Vol 6.
PubChem Open Chemistry Database website.

Abbreviation and acronyms

CLASS - Classification, Labelling and Safety Data Sheet Regulation 2013.
USECHH - Use and Standard of Exposure of Chemicals Hazardous to Health Regulation 2000.
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
IATA - International Air Transport Association
IMDG - International Maritime Dangerous Goods.
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
AIGA - Asia Industrial Gas Association
MARPOL 73/78 - International Convention for the Prevention of Pollution from Ships 1973 as
modified by the Protocol of 1978 (MARPOL short for Marine Pollution).
IBC - International Bulk Chemical Code
EmS - Emergency Response Procedure for Ships carrying Dangerous Goods
TLV - Threshold Limit Value
BEI - Biological Exposure Indices
STP - Standard Temperature and Pressure is defined at temperature of 0°C (273.15 K, 32°F) and
absolute pressure of 1 atm (101.325 kPa, 14.7 psia)
NTP - Normal Temperature and Pressure is defined at temperature of 20°C (293.15 K, 68°F) and
absolute pressure of 1 atm (101.325 kPa, 14.7 psia)

Compressed gas cylinders shall not be refilled without the express written permission of the
owner. Shipment of a compressed gas cylinder that has not been filled by the owner or his/her
(written) consent is a violation of local regulations. Although reasonable care has been taken in
the preparation of this document, we extend no warranties and make no representations as to
the accuracy or completeness of the information contained herein, and assume no responsibility

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SAFETY DATA SHEET

Document No: BIG/OSH/002/ENG - Nitrogen, Compressed

Date of Preparation: January 2013
Revision Date: 9 February 2023
Revision No: 03

regarding the suitability of this information for the user's intended purposes or for the
consequences of its use. Each individual should make a determination as to the suitability of the
information for his or her particular purpose(s).

First issuance : 3 January 2013

Last revised date : 9 February 2023

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