CAL Data Be Hence.

Z=0.lcm
0m. Sstem: Calculate
bylop Hhick under N,= Na arg MI
n-=5.9XI5m³ls. faken sotpeste ML H
Mnd
L55]l B65 8
The aids l9.le5
R+(D0-12 )I00 ltmol)(kg andML
Ma
Putanol as undinectional m -ht ABChrq 55.
o
o44l oq dius ol ratt 435
XI0 2 kg
- and ion the atex ot lkmol
koater and tim C-kmol/m
coe whenstcacyditusionkmal/m²
CB) o.0.992
992 Iha)
otaue he
state of
toncenrai
qlcc Butanol s 25XID Mz
upectiely x0X
0.4592 060.9/1q.les6)+
IS/12.2929)(1010 Chalkomol) M
condtouButanol 1s36:5
kal492m fa in 'X55.
nepectivel. Aatea 3724 +[100-)
bo in 435 2 N0.:
DATE PAGE

d thraqhqlmhr
S.9 anRurtd l0. X kalkmol
xI 06
meart a at 3
at -0021)
nal olem
Burkim so
o he c
 mol.
may mol.bwt)(ro) PAGE NO.:
DATE PAGE NO.:

DATE

Ttnd mole traction valua System:NH3ca)- Aiate)

Datai
Temp 245 k. ya, 50 produtB e 0.5
P =1atm
ABO.tz_ cms
T tnd m, and M, lkglkmol) Z= lmm:6m.
BAsis ID0 bq
= 19,4234 k¡lkmol Eapnusion
100
N AB.c nl-yA)
M= (-ya)
RT 8.31tXIoX4S
= 0.04l3 l. 3 kgnokfm
942
MI \(94?36
+
8.5st9)2 -5).65t bund L-0.5
= 0.5153

5.9X0"x5).65 Xlo.i-0.09)
In/)
toxo.9214 2alculate thre aate ot diusion ot wata vapoL, teom-ihe uata sustace
NA 0.019¢ kmal {m²s at the botom cf a Detl Gm deep to day a, anirg ove thre topot
NA = .0146 kmol x 4 the kel. Assume the entre system ai aim pnessure ahd 12 ktenp
k/mol ! re vell diametut3m, nd the tedal amount o Aates eapsta
m'hr
nstcand. faom -the stuzfac ot the well. The dtlicirsts of wata in.
ab k Q25t Xtö* ms and -the partbl pa od wate bete in ala
Pcblemson Oniston in Cases. lat this demp is o.031G baa.

LAmaia qas is
ot ah ohich t difusng ch a otant ate
Hough a stagnan
Oata
a latm L-al325 X10' Pa or Nm
4 mm
ht qas conetains so/ bs thickIhe condittons ae -tizeds
adume ot NHa at one ot tte
stagnantlaeAmmanla
ate ard -the
ditus touncdas
boundayta quiaty oell dia 3 m.

paeuneconcent
t at on
Tenp teSK and ts hegligible at trat pke .25 KIOms.
(Onde thex conditau
ctmesphentc
RT PB,m.
 PAGE N0.:
DATE PAGE NO.:

DATE

Nà As(pAL- pAz)
PBL RT2
lQ13,25- 3Ia0 =
3.6325 xib' : G.15X16 (55- Ae)
8.314X248 X0-02
pA R.33 kPa.
Xl.01325Xo CONECIIVE MASs TkANSFER.
chunts ol flud or
eddrra
Incacase flon nate
(b¡ k) Flutd oL lth lud Cimmtscible)
ata euapozated pseond 2
Flutd oe solid obËects.
mis
Chasactezatton.
Tusbulent zone Gulof eddes)
teads statz thaough a tibe
andontainin eliun
Methane ditusts at
Thanstbn zone/Buf zone
poind he pauial pn od methane s 55 kla at point 2,D.
mapast paatal pa k15 kla. Total Cnd the
No eddiea).
G5XI6 ma Calalat: lz ot mathane ah stcady state t
EcD_Case ond tuzthea alculate he patal pAwr ta poit Eks 1 aus ton molec1dan pnocee is given by
D.02 m apaat trom point 1
dz
ata: Bd -tusbulent ones, - (OAEt Em). dCa
Z =03.b0 m. da.
P1atm 10l.32 a whee Enm is mass cddy attusivtts dnd Em= Em
DA 55 Pa Ja-a -- (OnatEm d
LA2
T- 298 k

Eaprsion Jaz Czo-z) = (OAs+ En) (CaL -CAz)

Nh= na (pA-pAa)
625X165-15)E
8.3It X24& X
3.632SAD mis. (Za-Z)
B.03
(m)
 k qudhlHI seerrttons NO
DATE
havngan ilsa chout PAGEN0
DATE

Aa).
Jh:(octtcient CCai-
concetrattfon qncctont
TA:Coeicknt
coelf iend Eluz
Conc qyatient
Na e PL pA-Aa) to tunb ulnt coses.
k:Indiidual/ Eilmmast_transter-toicion
|K
Qeall.maar transtr_corltcdent.
20h1l2s Mass transfee lm coctficient &detined as the mau ol
Eeche myhitkneu_(EET): @mporent transieud in und ine kom hulk ol one pha
Sold henzZaic Qud. to an itaphaue of unil aua(a in qppos te duecti)sle
tdezit
ud
U.
-he walu of dniing-re t uniy.
iquid
ELD
phascti VCD

(a-Ma, conC mol factn

Nn = k, CA1- n2).

UCD.
N y Cge- yo). Naky(yanya:)
Dsl d diluson.
undeu uias daikag ue
Euz qualtons, MT(oetts f2 gas &liqud hasea
Phase Daiting -tozce
Gas conc.c N ke Cor-h2)Na keCtA-Cn2) mls
liqutd conç. dif kmd/mis.pa.
Cqas pathcd p m/s
lyuid (on. dif
keu- yea)
Gasmole fracin Nk (-y) Ne:
 PAGE NO:
DATE
PAGE O
DATE 22 ) 23
Eqiolan ccmpenint atsin
DWy do transpezt prcpete aisi 2
ABecause ct mplecules thet ae Constanthin motn
lby de analges bh momTi AT and nT inmpontant 2
ricempenent dttusin Transfr
Aem- teat Transfe
(pa- Cad k(ya-saa)
ky (za-Iaa)
lquds N kela-)= k dz A
dz

A
dz
4-dtsG)
" a-a) =h-ya) dz
-A) Hhr the patCSser h the ame unt ,x a
tbeeke analegyeatt bh thee tc pnotues.

Dihensicnizss nube
Tnezta faNe
Vis ceus -bxe

3
Theseral Lerduch Hy
kk
RT schmidt ng Nsc l
RI

m hh
(neglect om
Ketnolds
Gnstunt )
Rayralee Mat
bw Transte,
momentumI: )Vebeitypnohlk, DCny
ole ef -alt4I
Transkes,
I:-Yd(u)
Heat Mament
Thonstes
umMoment Al) |AssumptiasTraneler.
krynelds
cula
aUmd d dusivtte,
T:-(0tE)du
P. and has uds th um tuvbulert
tams) Cp -thz UUmox. depicad
Chemical in analsgy
ulus. condutb A
Tianste_and
Hluid C
Temp core
the hh
and
prohileand is
dz flaning and £ngg hBpesent memantim
dz mehanism pNOCLLL tteat
not
inside in dz Transt e
gpen same. one "Dbansa,
of All dz protie
tondut a chahnes
taanster (m) -leatTanstc
dssecia-led -0
a DATE
to molerular
Iu, PAGE
H0A
vtutirg
Taee
with

the J4
nadial ‘is
2 Uarg
Tp.(g-Tg
2.
Uarq analogous
positons Tp.dT du=
h(Taug-Te)
h 2h.
to(A) dz
in
a
h)_the dz
dT
conduit
nattoMA)

DATE

is
same
tr
all
 PAGE N0.:
PAGE NO.:
DATE 23 ||123 DATE

Tianster
Nomentum Tanste and mass wK
MomenhumTranstor, T:-.d(u) 2

dz Molecula piuam bubstte in 0)

du)
mamenkum TransBer, T: -(9+£t). de =1.

Ja e -(Oats t E. da
Tarblent 2CCavq lw)
ke'
Mas Transter

fon-the tuids ot constant densty In cancdusim,

[:-(tE)Ldu f-k= h
dz 2
Lag
dz
Nealect and rB sine only tubulenk. coN is pescnt NNVh.D - hl
K k k
JA -Em. dlaldz
iuide by 9
! Npr si theAmal ditfusits pnedominatea
JA En daldz 14 Nhr)4, mamentum difusists podonminate and
J4 Npr=1 tabulent onclittn pnevail
Jh e taabulert paDieLseA (Np=1), Nst h
lang
Psandtls nalgy
Sinte Tia auumed h be analoaus to Ja we mn -fake he Fis an eztensioa ot Reynold analeqy eb0th moleulae tenma
as e
inSide a concurt uheh id is to loing Npr -0
K
A du
Npr-at)
(k/R.G)
JA
atie menmentum Athusity to thesal diusiety.
 glms
PAGE NO.:
Schmicth numbes. DATE

Replace denominat ot by (Npr )

Nst
ata Qf pmome ntum difhucivily to mass CNpr)s
Nsc à the

ditfusivy 2
(Ns9 NÍc)

Replace de nomibater of 0 by Nse )3

tublent tumi ui) he nedhicd too.
Nsc)3
\bn Karman's analagy CHo thansittn zones).
Chiton- lolbuan J-Bacta analoqy
J tacba: fluz. Uauq
Ipi teat 4luz.

This onalaqy is mt based en assumpttns.

MOst idely ased. siaple data- based and wald
Patubdu'
1A clnde of natt'alene o05 m inna diameha and p.Gm lkng ta
Ià heat transtey, h i s beld n a puze ain streonn fbwirgat a velecty of Gms ati
mselated os a dimensionks Ja facta am pesstDe and t00'c temp. Vapaun pnNUAE d naplthakne at Ihu
Aemp and Pa is 10 mm t and dlus ivity of naphthalne à 51
In masr X6 m Calaula thr aab dseblimattan d haphthalene in
transf, k is coAceted as a dimen Sionlbs b fatt by using hre tollouig daa.
Jok
Futhe Nsk ase =.093 Ne) 2
System Naphihalene - Air
 PAGE NO:
DATE PAGE

Co is ab:cabd om aa bu utt -itLEihg ot mand osc

temptuTe The mass traniea cceit ky ha bun sttmgtrd o be
atm. fAL
T:313K

Sastemla wt.
4.31O4. Doia:
PA 2m
T: 25C: 02s K
se tt elkuinq rtin
2

2(^s)h
anvensiors.

Cersidu.
Thrbu.
11436 XIO 3512XI6 kmelu
ke - ky
2 san
kelya- yan)
 PAGE NO.:
DATE PAGE No.:

naphthalene meanwnin tm' is

DATE 24H 22.
athinplate ot sahd 30 cmls
ot aà flowin at
UNIT-I INTERPHASE MA6S TRANSEER..
steam
paallel to thr zhmpnesruze The plat ot naphthalene is
B00 K ad t naphthaleaso a Butk Bulk
date Qas phase siquidphase.
ab phas by ushg the atleung diluscg
A
9axtot ms Solute

aptur pr ot naphtbane at thzse rmdH De bomtt.

-0. 25

een. istzm Napbthalene - Aa Dictanre uom inkochanc

Kith chennital eactianms, Acaistane from inteuphas is considable.
A= m
wthout chemital seacltnns, intzuphaue zusistane is neglected.
vithaut thermi cal 2eactin, suactants a ud to analyse nesstane
Te300 k
pzoch suppert acttam s unfactants.
P=lotm fo neststance i.e hegligible
whce H ` tenas constant
LRSXIS Lapplied onls fr aiute solutiaul
Values ot concentratrzn an inte phase ae Lquilibainm values
S0X5.qxo
Assumptn - Resistan oieud by inkzaphae k hegleckad.
2

tJse of transte cocttcients and inteaphase concz ntzattoas

2
) ECD.
(29266 X
IT)
RT Na kyCyaa - yai) kzCzhi -Z )
R314 X300 Reasange eqO
Rat cf sulinatin-N)Gtca)
3.238xIo kmo
S.
gn4 and Int i Bulk phase compastens
Cobtained by sampling techniu).
kx and ke : obtaind bs betted kall bwe
 PAGE NO:
DATE
PAGE NO.:
DATE

Tial and Euon mcthod

(a-hi) Assume (l-aim and Cl- ya)im =1.
tang - ka/ky 2 Eind intuçhase Loncentaatraa.
ind slope and daw line
Vac ttose inteuphase corcentratiana and -fnd anathes slope.

eky.Cag-ai) kalai- R)-0

Contensions:

Note:
yam=l-yalin

(-Xh)im

In - a )

In•l-X»L]

(i-)im
kg
(I-yain