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Reliability, security of supply, low fuel costs, and competitive cost of electricity make a good case for coal-
fired power plants.
Requests for sustainable use of existing resources and concerns about the effect of CO2 emissions on global
warming have strengthened the focus of plant engineers and the power industry on higher efficiency of
power plants.
Efficiency has more recently been recognized as a means for reducing the emission of carbon dioxide and
its capture costs, as well as a means to reduce fuel consumption costs.
USC power plant is an option for high-efficiency and low emissions electricity generation.
USC steam conditions are characterized by 250 bar and 600C main steam and 600C reheat steam
conditions.
It is based on increased steam temperatures and pressures, beyond those traditionally employed for
subcritical plants.
Every 28C (50F) increase in throttle and reheat temperature results in approximately 1.5% improvement in
heat rate.
Besides increasing the steam parameters, optimizing the combustion process, reducing the condenser
pressure, and improving the internal efficiency of the steam turbines are some of the well known means for
raising the overall plant efficiency.
Due to the efficiency penalties associated with carbon capture and storage, such improvements are more
than ever needed to ensure a sustainable generation of electricity based on coal.
Steam Turbine 8. USC Turbine 3 / 93
HIoPE
Improvement in Improvement in
Mechanical Efficiency Thermodynamic Efficiency
Reduction of Increasing of
• Aerodynamic losses • Main steam temperature
• Leakage losses • Main steam pressure
Increase in efficiency have been achieved largely through two kinds of advancement: (1) improving
expansion efficiency by reducing aerodynamic and leakage losses as the steam expands through the turbine;
and (2) improving the thermodynamic efficiency by increasing the temperature and pressure at which heat is
added to the power cycle.
Specific design details will also determine the number of flows in a turbine section, the number of stages,
and the LSB length.
Supercritical steam cycles: Operating pressure is higher than critical pressure of water. Water to steam
without boiling.
Ultra-supercritical steam cycles: Steam temperatures above 1100°F as defined by Electric Power Research
Institute (EPRI)
Concept of USC
Critical point for water : 3208 psia/705°F (22.09 MPa/374.14C)
The surface tension property of water becomes zero at the critical point.
Therefore, there is no clear distinction between the liquid and the gaseous phase.
TE
p TK
USC
TS SC
K
TO Superheated steam
Water
Subcritical
C E
A B D
Wet steam
o f x g h
Characteristics of Supercritical
P-h Diagram
Comparison of Cost
Source: Best Practice Brochure (DTI, 2006)
Load factor % 85 85
Steam Cycle
Simple Reheat Supercritical
800 10000
60 Power Output
600 1000
Temperature
Thermal Efficiency [%]
50 500
40 400 100
Thermal Efficiency
30 300
200 10
20 Pressure
100
10
0 1
0 1920 1940 1960 1980 2000 2020
Thermal stress.
Probability of greater potential for turbine water induction through the main steam system compare to drum-
type subcritical units.
In 1957, the first USC units were put into commercial operation in USA and UK.
In 1959, Eddystone 1 (Philadelphia Electric Co.) was erected and commissioned in 1960.
• Net plant efficiency: 40% (HHV, without environmental system auxiliary power)
• Throttle steam conditions were changed because of serious mechanical and metallurgical problems.
• Most of the problems were due to the use of austenitic steels for thick section components operating at
high temperatures.
• It is well known that austenitic steels have low thermal conductivity and high thermal expansion resulting
in high thermal stresses and fatigue cracking.
• These problems and initial low availability of many USC power plants temporarily dampened utilities in
building USC power plants and consequently most utilities reverted back to subcritical power plants.
• Additionally, USC plants have another problems compared to subcritical units, such as higher
maintenance costs, lower operational flexibility, lower reliability of steam turbines.
• Many problems were related to the steam turbine control valve wear and tear, to the turbine blade
thermal stress, to the solid particle erosion of blades and valves, and to more complicated start-up
procedures.
• USC units are also more sensitive to feedwater quality. Therefore, full-flow condensate polishing is
required to protect the turbine from stress corrosion cracking.
• After that, through more than 45 years of practices, USC technologies have been unceasingly
developed and gradually perfected.
• Operational experience worldwide has brought the evidence, that present availability of USC power
plants is equal or even higher than those of subcritical ones.
• A net plant efficiency of 44.6 to 45.6% is possible with boiler fuel efficiency of 89 to 90% and auxiliary
power between 6.5 to 7.5% of gross generation.
• For 700C plants, it has been reported that double reheat has an efficiency improvement of only 0.7%
(HHV). The double reheat cycle has provided 1.5 to 2.0% of efficiency gain above single reheat at
538C (1000F) throttle conditions.
• The cost/benefit for double reheat will need more evaluation and the first A-USC plant will more likely be
single reheat and employ double reheat when justified later.
6
2400 psig (165 bar)
5
Comparison
3
2400 psig/1000F/1000F
versus
2 2.8 % 4500 psig/1100F/1100F
2.8% + 2.4% + 1.6% = 6.8%
1
Sub-Critical
0
1000 1100 1200
Temperature, F
100
IGCC + Fuel Cell
80 IGCC
60
Large Coal Unit SC USC
40
0
2000 2005 2010 2020 2030 2040 2050
The construction of new coal fired power plants has reduced greatly in US.
• Coal fired power plant being retired in response to tighter environmental regulations.
While market for new coal power not favorable now, the past few years have shown how volatile the outlook
for power generation can be
• Gas price is volatile: if all new generation is natural gas fired, electricity prices will fluctuate
correspondingly.
• Gas is a fossil fuel and emits CO2: evenly CCS will be applied to NGCC.
Advanced coal fired USC technology will help stabilize electricity prices and keep them affordable, but if it is
to be available in 2025 needed to work on it today.
USC Technologies
Advantages Considerations
• Increase the plant efficiency significantly • Higher investment cost
• Reduce fuel consumption for a given output • Reliability
• Reduce all pollutant and waste, including CO2 • Operational flexibility
Cycle Optimization
① Reduction of condenser pressure larger heat transfer surfaces, and inclusion of an advanced LP exhaust
hood
③ Reduction of boiler pressure losses and leakages water treatment for water/steam side;
slagging/fouling/erosion reduction for flue gas side
⑥ Improvement of boiler and turbine components technical design advanced steam path technologies for
turbine side
% %
46 0.88 in.Hga
Plant Net Efficiency Based on HHV
Plant Net Efficiency Based on LHV
45 43
Double reheat
44 42
1.9 in.Hga
300 bar/600C
43 41 Single reheat
USC
42 40
120C
1.15
130C 250 bar/540C
41 39 1.25
The cost basis of technological improvements must be known to make an economic evaluation in today’s
competitive marketplace.
One open literature investigated that the ranking of several technology improvement steps for better plant
efficiency. From least cost to highest cost per efficiency improvement, million US$ / % net LHV efficiency,
these were.
2) Increasing to 8th extraction point feedwater heater, raising feedwater temperature, 5.7
Most of the efficiency increase results from increased temperature, not pressure.
Therefore, temperature is the more important factor regarding cycle efficiency than pressure.
900
850
1400F
800
Available Energy, Btu/lb
750 1300F
700
1200F
650
1100F
500
1000F
550
500
0 1000 2000 3000 4000 5000 6000 7000 8000
Pressure, psia
This is because higher main steam pressure results in higher component costs. Thus, the optimum value
should be found.
The thick pressure parts will require a very limited rate of load change and longer start up times. Therefore,
designers should optimize the operating pressure with the design temperature and select materials having
optimum properties and cost.
Starting with the traditional 2400 psig/1000F single reheat cycle, great improvements in power plant
performance can be achieved by raising inlet steam conditions to levels up to 310 bar (4500 psig) and
temperatures to levels in excess of 600C (1112F).
In a reheat cycle, increasing the main steam pressure will improve the cycle efficiency and this is the
incentive for using supercritical steam conditions.
However, the thermodynamic benefit of increased main steam pressure at a given temperature is subject to
diminishing returns because the significant reduction in volumetric flow at these conditions leads to shorter
and wider turbine blade that is subject to higher passage boundary losses and increased steam path
leakage.
These blade losses act to offset the thermodynamic benefits of elevated steam conditions with increased
main steam pressure.
It is generally accepted that increasing the main steam pressure above 300 bar with steam temperatures of
600C/620C does not offer any further economic benefits.
3) Reheat Pressure
Normally, the cold reheater pressure is a quarter of the main steam pressure. Therefore, the selection of the
cold reheat pressure is an integral part of any power plant design. However, it becomes even more important
for plants with USC steam conditions.
The improvement resulting from the use of a HARP can be about 0.5%.
However, economic considerations of the boiler design without a HARP tend to favor a lower reheater
pressure at the expense of a slight decrease in cycle performance. Therefore, the resulting net heat rate gain
is usually larger, approaching 0.6~0.7%.
The use of a HARP results in a lower optimal reheater pressure and a higher optimal feedwater temperature.
Both of these considerations significantly impact the design and cost of the boiler.
As a result, careful optimization need to be done, in considering the use of a HARP, to ensure an
economically optimal cycle selection is made.
For double reheat units without HARP, the best performance would be achieved with the first reheat pressure
of approximately 1450 psi(100 bar).
However, economic considerations associated with the boiler and piping systems would typically favor
reducing this to a lower level.
The typical outcome is that the first reheat pressure is chosen below the thermodynamic optimum while the
second reheat pressure is generally selected slightly above to reduce the LP inlet steam temperature.
3) Reheat Pressure
Double Reheat Cycle with HARP
3) Reheat Pressure
Four-Casing, Four-Flow, Double-Reheat Steam Turbine
RH1 HP
RH2
4) LP Inlet Temperature
The use of advanced reheat steam conditions strongly affects the inlet temperature to the LP turbine section.
An increase in hot reheat temperature translates into an almost equal increase in crossover temperature for
a given crossover pressure.
However, the maximum allowable LP inlet temperature is limited by materials associated with the rotor,
crossover, and hood stationary components. Of these, the rotor material temperature limits are usually
reached first.
In addition, the selection of hot reheat temperature (and corresponding effect on LP inlet temperature)
impacts the amount of moisture at the LSB which factors into stress corrosion cracking considerations.
Once the reheat steam conditions are established, then the LP steam conditions can be determined.
If the resulting crossover temperature is too high, the energy ratio between the IP and LP can be changed to
lower this temperature.
Increasing the energy on the IP section will lower the crossover temperature, but it will also impact the cycle
efficiency, increase the number of IP stages, or the loading of the IP stages, increase the height of the final
IP bucket, increase the size of the crossover, or increase the pressure drop through the crossover.
LP inlet temperature can be adjusted by both reheater pressure and crossover pressure.
To lower the crossover temperature, the reheater pressure has to be increased or the crossover pressure
has to be decreased.
Crossover temperature is increased when a HARP is employed because it choose lower reheater pressure
to increase the thermal efficiency of plants.
T
Feedwater heater (m)
FWH
condenser
Condenser (1-m)
pump2 pump1
s
The Rankine cycle can be used with a feedwater heater to heat the high pressure subcooled water at the
pump exit to the saturation temperature.
The cycle efficiency can be increased, if the feedwater is heated by extracted steam from turbine. In this
case the temperature of the feedwater becomes higher. This cycle is called as a regenerative cycle.
Heating of the feedwater is accomplished by using small amounts of extracted steam having high enthalpy at
various points in the expansion through the turbine.
If a large number of heaters is used, the process of feedwater heating is more reversible.
For this reason, the regenerative cycle improves the thermal efficiency of the power plant.
The feedwater heater arrangement has to be designed to obtain the best heat rate for a given set of USC
steam conditions.
In general, the selection of higher steam conditions will result in additional feedwater heaters and a higher
final feedwater temperature.
The higher final feedwater temperature will have an impact on the boiler cost.
This then requires a system level optimization to determine the best economical solution for the increase in
final feedwater temperature.
In many cases, the selection of a heater above reheat point (HARP) is recommended.
Employment of a HARP has a strong influence on the design of both turbine and boiler.
The use of separate de-superheater ahead of the top heater for unit with a HARP can results in additional
performance gain.
In order to maximize the efficiency with USC steam conditions, a HARP is employed for a optimal higher
feedwater temperature.
7 No Base Case
Single Reheat
8 No +0.2%
(4500 psig, 1100F/ 1100
8 Yes +0.6%
F)
9 Yes +0.7%
8 No Base Case
Double Reheat
9 No +0.3%
(4500 psig, 1100F/ 1100
9 Yes +0.2%
F/1100F)
10 Yes +0.5%
Stage
balance
piston
The basic design characteristics of HP turbine is the barrel type outer casing design and has an inner casing.
This design can enable 300 bar and 600C.
This rotation-symmetric design has minimum deformation during steady-state and transient operation and a
consequence minimum clearances i.e. minimum leakage losses are achieved.
The barrel type outer casing has an axial split casing which can handle highest pressure loadings by
adopting the wall thickness. This gives an optimal thermal deformation behavior because there is no
horizontal flange. The benefit is small radial clearances between inner casing and blades, that means best
turbine efficiency.
Advanced sealing technologies such as brush seals and abradable coatings reduce steam leakages even
further.
In order to remove this restriction, an internal bypass cooling system has been developed.
Basically, a small amount of cooling steam passes through radial bores into the small annulus between the
inner and outer HP casing.
The cooling steam is lead through the inner casing towards the balance piston.
Thus, the surface temperature is reduced, creep stresses are reduced, and customers’ lifetime requirements
are met.
The internal bypass cooling also effectively protects the inner surface of the outer casing, which would be
exposed to main steam temperature without the internal bypass cooling.
As a consequence, it was possible to reduce the wall-thickness of the outer casing and thus enable
faster start-up of the casing.
An improved starting performance is the main customer benefit of this innovative concept.
3DV technology (3-dimensional design with variable reaction levels) is applied for HP and IP blades.
Therefore, GE chose to implement a full arc 1st stage design, which is much higher reaction and lower
aspect ratio to a traditional control stage.
This enables the first stage design to rival the efficiency of other stages.
To allow this, however, changes need to be made to allow the turbine quickly and efficiently respond to load
swings.
Therefore, GE will utilize an overload valve that will bypass the first stage and allow additional flow/load
response.
An overload admission was added for frequency control and capacity margin.
Elimination of the nozzle box required that two inner shells be used.
In this arrangement, the inlet #1 inner casing is subject to adjacent stage steam conditions on its inner
surfaces and a downstream stage’s steam pressure on its outer surface.
The buckets of the first four stages are made of nickel-based material due to the high temperature creep
requirements. The remaining buckets are conventional 12Cr material.
All 10 stages will utilize integral cover buckets with advanced tip seals.
The wheel spaces of the first two stages are cooled using external cooling steam.
A combination of brush, variable clearance, and conventional shaft seals are used in the HP section.
The corresponding outer casing inner surface is subjected to steam conditions at the same downstream
steam pressure.
Full admission design alleviated the mechanical challenges associated with partial admission design and the
control stage.
Two feedwater heater extractions are taken from the lower half.
The buckets of the first three stages are made of nickel-based material due to the high temperature creep
requirements. The remaining buckets are conventional 12Cr material.
All 8 stages will utilize integral cover buckets with advanced tip seals.
The wheel spaces of the first two stages are cooled using cooling steam, from HP section.
A combination of variable clearance and conventional shaft seals are used in the HP section.
Packing
Head
LP Casing
LP Inner Casing
Comparison of Parameters
Parameters Subcritical Supercritical 1100F USC 1290F A-USC
Main steam, F/psia 1005/2600 1080/3800 1120/4000 1290/5100
Net efficiency, % (HHV) 36.5 38.5 39.2 43.4
Net heat rate, Btu/kWh (HHV) 9370 8880 8720 7880
Generals
A-USC (Advanced Ultra Supercritical) means a coal fired power plant design with the inlet steam
temperature of 700C to 760C (1292F to 1400F).
The higher the inlet steam temperature, the higher the efficiency of a plant.
The higher the efficiency of a plant, the less fuel consumption, and fewer emission are produced during
electricity generation.
Therefore, the purposes of A-USC plants are reducing the emission of CO2 and its capture cost, and fuel
consumption by increasing the efficiency of power plants.
When the heat is supplied at 760C, the Carnot cycle efficiency is 69.9%, while the expected A-USC net
plant efficiency is 52.7% (6825 kJ/kWh, or 6475 Btu/kWh).
USC uses ferritic and stainless steels, while A-USC requires nickel alloy materials.
The costs of the higher priced nickel alloys must be balanced with the savings in less fuel consumption,
lower weight and size of equipment, and cost avoidance for emission allowance requirements.
TPC(Total Plant Cost) for 1290F A-USC is 11% higher than for SC unit, but potential to halve the difference
because the cost of high temperature materials is getting lower.
A-USC plants have the potential for lower cost of electricity especially when combined with the requirements
to capture carbon for sequestration (CCS).
The plant production costs per megawatt-hour are the lowest for A-USC w/CCS based on plant economic
studies for coal firing. Combining CCS with A-USC plants will provide lower cost of electricity generation with
90% CO2 capture.
Currently, A-USC studies have been focused on 50Hz machines. This is because the rotating components of
60Hz machines require reduced steam temperatures by 40F to meet strength requirements.
Throttle pressure for the desired throttle temperature of 700 to 760C will most feasible in the range of 5000
to 5500 psi.
Considering a single reheat cycle, the optimum available energy peaks at about 2500 psia for 1000F, about
4000 psia for 1200F, and at about 5000 psia for 1400F.
Because higher pressure results in higher component costs, the optimum available energy should be
investigated.
Higher steam pressure can help to reduce the flow path pipe size delivering the energy flow.
The more compact plant equipment will help with cost savings as long as pressure vessel thickness and
material costs are at the optimum.
Due to concerns that very thick parts will require a very limited rate of load change and longer start up times,
the throttle pressure should be determined with optimum properties and cost.
Setting the HP throttle pressure, the IP inlet pressure and the LP exhaust pressure is important for the
optimization and meeting acceptable operating conditions.
It has been reported that the double reheat cycle would only provide 0.7% advantage above single reheat
turbine with inlet conditions of 35 MPa/680C/700C (5075 psig /1256F/1292F).
High temperature of the second reheat steam requires nickel alloy for its larger diameter piping. Thus, piping
cost should be considered.
Operation of a double reheat cycle was considered more difficult because of controlling the differential
between the HP, IP 1 and IP 2 steam temperatures.
The first A-USC plants will more likely be single reheat and double reheat may be adopted later.
Turbine Cycle
The capacity of the steam turbine under studying is 750 MW.
The steam turbine throttle conditions are 35 MPa/732C/760C (5000 psig /1350F/1400F) with 2 in.Hga
condenser pressure.
An additional new requirement of an A-USC boiler is to deliver cooling steam from a source such as the
primary superheater at 1.5% of main steam flow rate to the HP outer casing.
1.5% cold reheat steam is retained at the turbine for IP turbine outer casing cooling.
Feedwater temperature to the economizer has ranged from 630F to 649F at MCR. Reducing the
economizer gas outlet temperature is a little more difficult because of the higher final feedwater temperature
of A-USC.
A-USC steam turbine section efficiencies are expected to lie in the following range depending on offered by
various vendors; HP: 89.2~93.3%, IP: 90.5~96.6%, LP: 90.6~95.8%.
CCS will affect net plant efficiency because total auxiliary power for CCS will be about 20.5% of gross power
generation.
Oxy-combustion A-USC plant efficiency with Ohio coal is estimated to be 38.1% (HHV) with 90% capture of
carbon dioxide.
Steam Turbine
Major characteristics
• HP turbine may have two stage because of limited use of nickel alloy
• Start up time longer because of higher temperature, but frequency control not expected to be affected
• BFW extractions are similar, but final feedwater temperature will become higher
Same availability
• A-USC steam turbines should have same availability as conventional turbines.
AD 700 Cycle
AD 700 is an advanced 700C PF power plant has being developed in European Union.
Fuel saving and CO2 emission reduction of up to 15% compared with the best available technology of today.
In recent years, costs associated with CO2 emissions have attracted more attention because of global
warming.
Carbon capture and storage (CCS) and capture ready power plant designs are becoming increasingly
important for the evaluation of investments into new power plants and in addition retrofit solutions for the
existing power plants are required.
Efficiency improvement is a means for reducing emission of CO2, the costs of carbon capture, water use,
particulates, sulfur dioxides (SO2) and nitrogen oxides (NOx) emissions, and fuel consumption.
As coal is more abundant in many parts of the world, coal price is more stable than natural gas price.
However, greater CO2 emissions increase the need for more efficient coal-fired power plants.
USC steam power plants meet notably the requirements for high efficiency to reduce both fuel costs and
emissions as well as for a reliable supply of electric energy at low cost.
Recent developments in steam turbine technologies and high-temperature materials allowed for significant
efficiency gains.
Due to CO2 emission limits and corresponding penalties, the conventional coal-fired power plant with the
efficiency lower than 40% become less cost-effective.
NETL and EPRI studies show that current CCS technologies have CO2 removal costs of $50 to 70/ton.
1200
1000
CO2 Emission, g/kWh
800
600
400
200
0
28 32 36 40 44 48 52 56
Net Plant Efficiency, % (LHV)
0.90 30
0.80 20
CO2 Reduction, %
0.75 15
0.70 10
Subcritical
PC plant
0.65 Ultrasupercritical 5
PC plant range
0.60 0
37 38 39 40 41 42 43 44 45 46 47 48 49 50
Net Plant Efficiency, %
Every 28C (50F) increase in throttle and reheat temperature results in approximately 1.5% improvement in
heat rate.
Every 1% improvement in plant efficiency results in approximately 2.5% reduction in CO2 emission.
An increase in plant efficiency from 30% to 50% reduce CO2 emissions about 40%.
A-USC plants having net plant efficiency of 45%, without CCS(Carbon Capture and Sequestration), will
produce about 22% less CO2 than the average subcritical plants that include the majority of units currently in
service and operating at about 35% net plant efficiency.
Combining CCs with A-USC plants will provide lower cost of electricity generation with 90% carbon capture.
A-USC will lower the CO2 per kWh, thus reducing the size of the CCS equipment.
Oxy-combustion CCS plant that achieve 90% carbon capture use about 20.5% auxiliary power which
includes the compression purification unit (CPU), additional cooling tower, air separation unit (ASU), and
polishing scrubber.
The efficiency penalty associated with CO2 capture based on Siemens advanced process is 9.2%.
1400 USC
1300 USC w/PCC (3)
40 1300 USC w/PCC (2)
Net Plant Efficiency, % (HHV)
35
1100 USC
w/PCC
30
25
(1) Back-end heat recovery (2) Double reheat
(3) 1350F with back-end heat recovery and double reheat
Lignite: 980~1,230
Oil: 890
NG: 640
Solar 80~160
• Post-combustion separates CO2 from the flue gases produced by combustion of a fuel in air.
• Oxy-fuel combustion uses oxygen instead of air for combustion, producing a flue gases that contains
mainly H2O and CO2. Therefore, CO2 is easily separated by condensing the water vapor.
• Pre-combustion technology processes the primary fuel in a reactor to produce separate stream of CO2 for
storage and H2, which is used as a fuel.
Post-combustion capture
• chemical absorption process
• gas-fired power plant in Malaysia
• constructed by MHI
Pre-combustion capture
• physical solvent process
• coal gasification plant in US
N2,O2
Coal
Post- CO2
Gas Power & Heat
combustion Separation
Biomass CO2
Air
Air/O2
Coal Steam
Biomass CO2
Pre- Gasification Reformer
combustion H2
Gas, Oil +CO2 Sep. Power & Heat
N2, O2
CO2 Compression
Air
& Dehydration
Coal CO2
Gas Power & Heat
Oxy- Biomass
combustion O2 N2
Air Air Separation
Air/O2
Industrial Coal CO2
processes Gas Process + CO2 Sep.
Biomass
Remove
90% of
CO2
Remove
85-90% of
NOx
Chimney
Remove Remove
Capture
Flue Gas
Cooling
CO2
99.7% of 90-95% of
Fly Ash SO2
DeNOx
Continuous
Emission
FGD
Monitoring
EP
System
The most common method for separating CO2 from a gas stream in use today is the chemical absorption
using alkaline solvents.
The flue gas passes through an aqueous alkaline solvent, and since CO2 is acidic it is bound to the solvent.
The flue gas enters at the bottom of the absorber, while the solvent is pumped to the top of the absorber.
After the reaction and CO2 absorption, the rich- CO2 solvent drops to the bottom of the absorber and then it is
pumped to the separation unit (CO2 stripper).
In CO2 stripper the rich-CO2 solvent is heated up depending on the solvent type to 100-140C.
This reverses the absorption process and releases most of the CO2 in a pure stream for compression and
transport. The lean- CO2 solvent is transported back to the absorber for reuse.
A variety of solvents could be used in the absorption/regeneration process and each has its advantages and
disadvantages.
Choosing the right solvent is important to reduce the energy penalty of the capture process.
In oxy-fuel combustion capture technology nearly pure oxygen is used for combustion instead of air.
If fuel is burnt in pure oxygen, the flame temperature is exceedingly high. Therefore, CO2 and /or H2O-rich
flue gas is recirculated to the combustor to moderate the temperature.
The steam can easily be removed by condensation, leaving a rich- CO2 stream ready for compression and
storage.
Oxygen is usually produced in cryogenic air separation unit which is the major demanding component in the
process.
In the EU, a capture ready assessment is mandatory for all new fossil power plants 300 MW, in other
regions capture ready programs are already implemented or still under discussion.
The aim of building power plants that are capture ready is to reduce the risk of space and connections.
The capture process consumes LP steam for solvent regeneration and electrical energy for the solvent
pumps and the CO2 compressors.
The mass and energy flow rates at the interfaces depend on the capture process.
Optimizing the heat integration between the power plant and the CO2 capture unit including CO2
compression will be a decisive factor for the competitiveness of a steam power plant with CO2 capture.
3) Steam extraction
• A significant amount of the available LP steam (approx. 40%) needs to be extracted from the steam
turbine and has to be supplied to the capture unit for solvent regeneration. (2.7 GJ/ton CO2 captured,
approximately 40% of LP steam)
• Avoiding thermodynamic inefficiencies associated with throttling at full and partial load as well as keeping
the capital costs low are the main challenges.
• In addition, the different solvents and capture processes under competition vary in demand and properties
of LP steam.
Exhaust ducts Flue gas fan Steam turbine building Steam turbines
• Consider p from CO2 • Upgradable design sufficient space/foundation for • Extraction of approximately 40% of
absorption unit • or additional space for • Modification of turbines LP crossover steam
• Later flue gas connection installation of second • Steam and condensate pipes • Options for modification of turbines
to capture unit (T-branch) fan downstream of FGD • Installation of heat exchangers expand on operation modes (part
load, full load capability without
CO2 capture other plant and site
conditions)
Cooling system
FGD Air heating sufficient space for
• Either consider capacity Optional: space for • Additional circulation pumps
extension in column installation of heat • Service water system
design exchanger(s) for lowest • Sufficient cooling capacity of
• or provide space for grade heat utilization cooling tower
enlarged FGD unit
Condensate system
sufficient space for Raw water & cooling water
• Heat exchangers for low grade supply / Waste water
heat utilization treatment
• Additional piping routes with
• Sufficient space for enlargement
supporting structure/racks
• Secure water utilization rights
The varying flow will change the last stage loading and may turn the stage into turn-up mode.
In this case, windage heat is generated near the hub region because rotating LSBs feed energy into the
trapped steam. Thus, water spray nozzles are installed at the exhaust section to cool the high temperature
steam.
Typically, large coal-fired power plants have two- or three LP turbines. Therefore, one could be removed from
operation when the plant is operated in capture mode.
However, plants have one LP turbine may have lower performance when the plant is operated in capture
mode because of turn-up loss. Therefore, a true capture ready plant is not feasible in this case, and the plant
has to be modified when changed for capture operation.
Generals
Substantial reduction in emissions from coal-fired power plants can be achieved only by employing most
advanced and highly efficient modern power generation technologies.
The most direct and economical method for this is the evolutionary advance of increasing steam
temperatures and pressures at the steam turbine inlet well beyond the critical point of water.
To allow this increases, advanced materials are needed that are able to withstand the higher temperatures
and pressures in terms of strength, creep, and oxidation resistance.
USC power plants have faced particular challenges for maintaining equipment reliability and flexible
operation at more advanced throttle steam conditions.
Most of the efficiency increase results from increased temperature, not pressure.
As a consequence, material requirements, in terms of high temperature strength and steam side oxidation,
could lead to the use of lower pressures (than the goal of 38.5 MPa) to make USC turbine economical, and
yet still beneficial in terms of efficiency increases.
Since ferritic steels are capable of meeting the strength requirements up to of approximately 620C, there is
no obstacle for USC technology within this temperature range.
As the steam condition moved to A-USC, ferritic and stainless steels will be replaced by nickel based alloys
because those have higher material strength and corrosion resistance.
Advanced material application, especially of titanium for LSB with lower density allows longer blades to be
used and thus the exhaust annulus area to be increased.
Alloy Strength
50
Austenitic
45
Ferritic Nickel Alloys
40
H282
35 IN740
H230
Allowable Stress, ksi
TP310HCbN
30
IN617
S304H
25 T24
T92
TP347H
20
T22
T12
15
10
5
0
700 800 900 1000 1100 1200 1300 1400 1500 1600
Temperature, F
Thermal expansion coefficients, hardness, toughness and other mechanical properties are important to the
design and fabrication of materials. In addition, welds and weldments for both thick sections and tubes should
be tested. To achieve 1400F (760C) steam temperatures, longer creep rupture strength test at higher
temperatures is very important to the A-USC design.
200
Carbon Steel
100 CrMo Low Alloy Steel
9-12% Cr Steel Ni-Base
18%Cr-8%Ni Steel Alloys
50
15%Cr-8%Ni Steel
20-25% Cr Austenitic Steel
Relative Material Cost
10
5
1
Material Validation
Alstom
USC Materials
Hitachi
Steam Temperature
H-IP Combined Type 600゚C / 600C to 620゚C
Main steam inlet 9Cr-1Mo Protection of No.s 1,2 Overlay coating
flange elbow steel journal thrust bearing
Cooling structure with Rotor cooling for IP section
main steam leading pipe (Protection of aged bending)
12Cr No.1 IP 12Cr
Nozzle box cast steel internal casing cast steel
HP IP
HP internal 12Cr
casing cast steel
질의 및 응답
작성자: 이 병 은 (공학박사)
작성일: 2015.02.11 (Ver.5)
연락처: ebyeong@daum.net
Mobile: 010-3122-2262
저서: 실무 발전설비 열역학/증기터빈 열유체기술