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Renewable Energy
journal homepage: www.elsevier.com/locate/renene
Effects of blending crude Jatropha oil and heavy fuel oil on the soot
behavior of a steam atomizing burner
Kazuki Tainaka*, Yong Fan 1, Nozomu Hashimoto 2, Hiroyuki Nishida
Central Research Institute of Electric Power Industry, 2-6-1, Nagasaka, Yokosuka-shi, Kanagawa, 240-0196, Japan
a r t i c l e i n f o a b s t r a c t
Article history: The aim of this study is to investigate the detailed soot formation characteristics of crude Jatropha oil
Received 16 May 2018 (CJO) and heavy fuel oil (HFO) blends (lower heating value (LHV) basis: 50%/50%) in a 550 kW-class
Received in revised form combustion test furnace equipped with an industry-scale steam atomizing burner using optical mea-
9 October 2018
surement systems. In the present study, time-resolved flame images through the high-speed photog-
Accepted 30 December 2018
raphy, flame radiation intensity through Hottel & Broughton (H&B) two-color method, instantaneous
Available online 7 January 2019
soot volume fraction and the velocity field around the fuel nozzle through laser induced incandescence
(LII) and particle image velocimetry (PIV), and the soot absorbance through the dust analyzer were
Keywords:
Crude Jatropha oil
obtained. The results of this study show that soot volume fraction around the fuel nozzle became lower
Heavy fuel oil with blending CJO in HFO, thereby the flame radiation intensity decreasing. This seems to be caused by
Spray combustion fewer polycyclic aromatic hydrocarbons (PAHs) in the CJO. By the exhaust gas recirculation (EGR), a
Laser induced incandescence larger soot volume fraction around the fuel nozzle and a lower soot volume fraction in the downstream
Particle image velocimetry region were obtained, which are probably due to a decrease in oxygen concentration slowing the soot
Soot oxidation rate around the fuel nozzle and the increase in oxygen concentration behind overfire air holes,
respectively.
© 2019 Elsevier Ltd. All rights reserved.
1. Introduction fact, Japan has already set a target of 80% reduction in CO2 emis-
sions of 1990 by 2050 [3].
After the Great East Japan Earthquake of 2011, all nuclear power The use of carbon-neutral and renewable biofuels has been
plants in Japan were shut down. Most of the electric power deficit recognized as an effective way to reduce the CO2 emission. How-
due to the shutdown of nuclear power plants was compensated by ever, plant-derived biofuels have several problems that interfere
the thermal power generation using liquefied natural gas (LNG) and with their wide adoption. These problems include price instability,
oil. The share of thermal power generation in total electric power market competition between food and fuel usage of crop plants,
generation in Japan remains as high as 90% in 2013. On the other diversion of cultivable land that could be used to grow edible plants
hand, the ever-increasing carbon dioxide (CO2) emissions from the in food deficit countries, and increases in CO2 emissions due to fuel
combustion of fossil fuels are major concerns [1]. processing steps such as esterification. Recently, as a non-edible
It was reported in the 5th assessment report of the Intergov- biofuel to solve these problems, Jatropha oil extracted from the
ernmental Panel on Climate Change (IPCC) that the global surface Jatropha curcas seed has drawn considerable attention.
temperature has a strong correlation with cumulative anthropo- Jatropha curcas is a genus of flowering plants in the spurge
genic CO2 emissions since 1870 [2]. Regulations of CO2 emissions family (Euphorbiaceae). It is a drought-resistant perennial that can
are likely to be stricter in the near future according to this report. In even be planted in land unsuited for cultivation such as deserts [4].
Jatropha curcas seed is toxic and thus cannot be used as human
food or animal feed. Therefore, the price has no direct influence on
the food price. Crude Jatropha oil (CJO) is the direct product from oil
* Corresponding author. 2-6-1 Nagasaka, Yokosuka, Kanagawa 240-0196, Japan.
E-mail address: tainaka@criepi.denken.or.jp (K. Tainaka).
extraction of the Jatropha curcas seed before its esterification to
1
(Currently) The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, produce the biodiesel. CJO has a lower heating value (LHV) com-
Japan. parable to that of heavy fuel oil (HFO; heavy fuel oil C JIS (Japanese
2
(Currently) Hokkaido University, N13-W8, Kita-ku, Sapporo-shi, Hokkaido, 060- Industrial Standards) K2205). Because of these advantages, CJO is
8628, Japan.
https://doi.org/10.1016/j.renene.2018.12.113
0960-1481/© 2019 Elsevier Ltd. All rights reserved.
K. Tainaka et al. / Renewable Energy 136 (2019) 358e364 359
more attractive than other biofuels. Tsuchiya et al. [5] conducted and soot absorbance in the exhaust gas. Soot behavior around the
the assessment of the energy balance of Jatropha plantations in fuel nozzle was examined through simultaneous measurements of
Palawan, the Philippines. They estimated that CO2 emissions from the soot volume fraction and the flow velocity field by laser induced
CJO was 20 g(CO2)/MJ, with a low negative environmental impact. incandescence (LII) and particle image velocimetry (PIV), respec-
Desmira et al. [6] conducted combustion experiments with CJO to tively. Discussions are made on the influence of soot behavior on
develop a monitoring technique for the flame. Fan et al. [7] inves- the heat transport around the burner and the soot aerosol con-
tigated spray characteristics of CJO using a pressure-swirl atomizer centration in the exhaust gas.
with assist air. Spray visualization employing the pulse-laser
backlight illumination and droplet size distribution measurement 2. Experimental apparatus
by a laser diffraction spray analyzer were carried out, although not
in the combustion field. A local minimum of the Sauter mean Fig. 1 shows a schematic diagram of the experimental apparatus
diameter (SMD), a measure of average droplet size, in the SMD vs. used in the present study. The apparatus consists of the fuel supply
liquid viscosity curve was observed in the transitional region where system, the air supply system, the combustion furnace, the steam
the transition of spray shape from a twisted jet to a hollow cone atomizing burner, and the exhaust-gas treatment system.
happens. Martínez et al. [8] reported fuel properties of Jatropha The fuel supply system has two oil tanks capable of supplying a
methyl ester (JME), which is the product from esterification of CJO. mixture of two types of oils in arbitrary proportions. A heater is
Considering the difficulty in stable CJO supply, CJO shall be used attached to the fuel line to the burner in order to control the oil
as an additive to oil blends of the fossil fuel in thermal power temperature, thereby controlling the kinematic viscosity.
plants. Chhetri et al. [9] reported fuel properties of CJO/diesel oil Three fans: a forced draft fan (FDF), an overfire air fan (OFAF),
blend. Farfan-Cabrera et al. [10] posed the damage to automotive and a gas recirculating fan (GRF) are used for the supply of primary
seals by the exposure of CJO/diesel oil blend. Combustion charac- and secondary air to the combustor and EGR, respectively. The
teristics of CJO/liquid fuel blends in diesel engines have been overfire air is vertically introduced at 2575 mm from the burner
investigated by many researchers. In most of the studies, CJO/diesel top. The exhaust gas is recirculated back to the burner (primary air)
oil blend was used as fuel [11e17]. Agarwal et al. [12] conducted and the overfire air port (secondary air) at equal EGR ratios. The
combustion experiments on CJO/diesel oil blends employing a purpose of two-stage combustion and EGR employed in this
diesel engine. They reported that, at an equal engine load, the apparatus is to reduce the thermal nitrogen oxides (NOx) by
concentrations of CO2, carbon monoxide (CO), and hydrocarbons decreasing the flame temperature, as in many industry-scale low-
(HC) in the exhaust gas increased with the proportion of CJO in the NOx boilers [32]. A fuel-rich primary zone and a fuel-lean second-
oil blends. They also claimed that the composition of emissions ary zone are formed in the combustor. In both zones, the flame
from burning the oil blend became close to that from burning the temperature is lowered by the off-stoichiometric combustion. On
pure diesel oil when the kinematic viscosity of CJO was lowered by the other hand, the decrease in flame temperature by applying EGR
preheating. Singh et al. [17] overviewed the performance and is a combined result of a decrease in O2 concentration and an in-
emission characteristics of CJO and the other biofuels. In other crease in heat capacity of combustion air due to the EGR dilution.
research, CJO was used, mixed with methanol [18e21], producer The combustion furnace is a horizontal cylinder with an inner
gas [22], and hydrogen peroxide [23]. Co-combustion experiments diameter of 1000 mm and length of 8500 mm. The furnace has one
with reformed CJO also were conducted [24e28]. burner section and four furnace sections as shown in Fig. 1. The
While most previous studies of CJO were conducted in diesel furnace sections were numbered starting at 1 in order away from
engines where the combustion is intermittent, studies in contin- the burner section. Each section has a jacket water cooling system.
uous combustion fields were limited to simple laboratory-scale The heat balance of each section is examined using measured flow
setups [29,30]. Rehman et al. [29] tested JME and diesel oil rate and temperature rise of the cooling water. The furnace had
blends in a Rover IS/60 gas turbine combustor. It was found that CO quartz windows for optical measurements.
and HC concentrations decreased, but nitrogen monoxide (NO) Figs. 2 and 3 respectively show respectively a schematic diagram
concentration increased in the exhaust gas with increasing the JME of the burner section and a closeup view of the fuel nozzle. The
blending ratio because the high oxygen content of JME improves present burner has a water steam atomizer in common oil-fired
the combustion and thereby increases the gas temperature. Spray boilers. In such a burner, liquid fuel is atomized through the mix-
combustion in an industrial oil-fired boiler is a highly complex ing of the water steam in the mixing chamber. Combustion air is
phenomenon where the fuel atomization, dispersion of droplets, supplied through swirl vanes. As a result, spray combustion with a
evaporation, fuel-air mixing, and combustion reaction take place swirling flow takes place in the furnace.
simultaneously and interact with each other in a swirling flow field. The exhaust-gas treatment system is composed of a NOx
Such complexity suggests that the results obtained from simple removal equipment and a bag filter. The exhaust gas passes through
laboratory-scale burners may not be completely applicable to the treatment system first, and then the induced draft fan (IDF).
industry-scale burners. In addition, it is difficult to apply laser After that, the exhaust gas is desulfurized in an alkaline scrubber.
measurements to industry-scale combustion fields, and such
studies are few Therefore, our research group investigated the ef- 3. Measurement methods
fect of blending CJO in HFO on soot emissions and heat absorption
balance characteristics with an industry-scale burner [31]. How- The combustion characteristics were evaluated through time-
ever, it is not clear how overfire air and exhaust gas recirculation resolved images of the flame, the flame radiation intensity, the
(EGR) effect on the soot behavior. soot volume fraction and the velocity field in furnace section 1, and
In the present study, investigation on the effect of blending CJO the soot absorbance in the outlet of the furnace section 2.
in HFO was carried out in combustion experiments using a liquid- Time-resolved images of the flame were captured using a high-
fuel test facility at Central Research Institute of the Electric Power speed camera (nac Image Technology. Inc., GX-8F) with the peak
Industry (CRIEPI) in Japan. A steam atomizing burner commonly spectral sensitivity in 400e700 nm. Nearly instantaneous images
used in industry-scale oil-fired boilers was employed in this facility. were taken at an exposure time of 2.7 ms and a frame rate of 10 kHz.
Rated heat input is 550 kW. The combustion characteristics were Flame radiation intensity was measured using the Hottel &
evaluated through the measurement of flame radiation intensity Broughton (H&B) two-color method [33] with a second camera
360 K. Tainaka et al. / Renewable Energy 136 (2019) 358e364
kL
εl ¼ 1 exp a ; (2)
l
C
Ebl ¼ 1 : (3)
l5 exp C2
lT 1
8 9la1 8 9la2
Fig. 2. Schematic diagram of the burner section [31].
< l51 El1 exp lC12T 1 = < l52 El2 exp lC22T 1 =
1 1 ¼ 0:
: C1 ; : C1 ;
(4)
4. Experimental conditions
Tables 1 and 2 show the properties of CJO and HFO and the
experimental conditions, respectively. Both a pure HFO and a CJO/
HFO blend (LHV basis: 50%/50%) were used as the two fuels. The
fuel before entering the fuel nozzle was preheated using the electric
heater. The temperature of the pure HFO was kept at 140 C, while
Table 1
Properties of CJO and HFO.
CJO HFO
3
Density [g/cm ] @30 C 0.908 0.963
Dynamic viscosity [Pa$s] @30 C 0.048 0.378
Kinematic viscosity [mm2/s] @30 C 52.6 392.0
Lower heating value [MJ/kg] 37.0 40.5
Water content [wt. ppm] 1100 300
Carbon content [wt. %] 76.5 86.9
Hydrogen content [wt. %] 11.7 10.7
Oxygen content [wt. %] 11.1 <0.5
Nitrogen content [wt. ppm] 35 2000
Fig. 4. Schematic diagram of the simultaneous LII/PIV measurement system.
Sulfur content [wt. ppm] 3 23000
combustion field were also used as tracer particles in the PIV EGR ratio [wt. %] 0.0 15.0 0.0 15.0
measurement. The soot particles were illuminated by double laser Outlet O2 conc. [vol. %] 4.0 4.5 4.0 4.5
Heat input [kW] 550.0
pulses at an interval of 10 ms. A pair of two images showing the
Kinematic viscosity of fuel [mm2/s] 6.5
scattering intensity distribution were captured by a sCMOS camera Overfire air ratio [wt. %] 15.0
(LaVision GmbH., Imager sCMOS) with a band-pass filter at a center
wavelength of 532 nm and an FWHM of 3 nm. In this area, fuel
droplets had already evaporated; thus, the light scattering came
only from the soot particles. The imaging area in the PIV mea-
surement were made the same as in the LII measurement through
the use of a half-silvered mirror. 500 image pairs are taken in each
case. The velocity field was estimated using the Adaptive PIV
method [39]. The accuracy for this measurement value is 1.2 m/s.
Fig. 5 shows a schematic diagram of the soot absorbance mea-
surement using the dust monitor (SICK AG, T200). Intensities of LED
Fig. 5. Schematic diagram of the dust analyzer. Fig. 6. Direct images of the flame.
362 K. Tainaka et al. / Renewable Energy 136 (2019) 358e364
Fig. 8. Velocity field and distribution of soot volume fraction from simultaneous LII/PIV measurement.
K. Tainaka et al. / Renewable Energy 136 (2019) 358e364 363