EXPERIMENT NO. 5 Aim:- To determine the kineties of the reaction bet tween ethyl acetate and sodium hydroxid: at room temperature by the differential method of analysis. es Apparatus: - Beaker Stop watch Conical Flask Pipette Burette Chemicals: - Ethyl acetate (0.2 M) NaOH (0.2 M) Std. HCI (0.1 N) Theory:- ‘The differential method of analysis deals directly with the differential rate equation to be tested, evaluating all terms in the equation including the derivative dCy/di, and testing the goodness of fit of the equation with experiment. Procedure: 1. Take 150 ml of ethyl acetate in a beaker, which serves as the batch reactor 2. To this add 150 ml of NaOH solution and the contents are kept well stirred. 3. Soon after adding NaOH a stopwatch is started. 4 Invall samples each of 10 ml volume are taken from the renetant contents as per the following time schedule. Sample No. Time ; 12,3 For every 2 min 4,5,6 For every 3 min 78,9 For every 5 min Observation: : f ‘Ca, moviit adinj Sr.No. Burette Readis Guns L $3 0.03% | Calculations:- to represent } 1. Plot the Ca vs. time data, and then By ee caret obo sone points | the data, Tis curve most likely Will Ot PAS ee concentration values. These 2 Determine the slope of this curve at suitably selec slopes dCyfdt= rare the rates of reaction at these ‘compositions. Now for n order rate equation ala m at ws kG a logk + nlogCaSr.No. | Ca, molflit Log Ca =dCa/dt Jog (-dCa/ dt) ‘ 2.045 =134¢ 2.0045 234 z waa That 19.0936 a4 Plot log (-dC,/dt) logC data, which will be a straight line. \ 4. Calculate the order of reaction and the rate constant from the slope and the intercept of the graph. Result:- Conclusion:-Ose vation table + BR. Ca Cold 4. 3. 3.1 23 26 2.3 2.2 aa 2 V.V.P. ENGG. COLLEGE - RAJKOT _ STUDENT STORE-S cee-! Exp