EXPERIMENT NO. 4 Aim:-To determine the activation energy and frequency factor for reaction between ethyl acetate and sodium hydroxide. Apparatus: - + Beaker * Stop wateh © Conical Flask © Pipette + Burette Chemical ‘© Ethyl acetate (0.2 M) NaOH (0.2 M) «Std. HCI (0.1 N) Procedure:. Repeat the procedure of experiment no. 2 at room temperature and two different elevated temperatures. (room temp+ 10°C and room temp+ 20°C). Observations: - + For room temperature: - Time (t), Burette Na Ca Xa min__ | Reading, ml (Normality of NaOH) | (Conc. Of NaOH) | =(1- Ca/Cao) z og 2. 008 é oN 4 05 0205 “9.028 20.35 6 oO} 29°F 9 909 oS 7 ot 9202 9-092 04d * For room temperature + 10°C. Time(t), | _ Burette Na mes Xa min | Reading, ml | (Normality of NaOH) | (Conc. OfNaOH) | =(1- Cx/Ca0) 7 2 0.00 4 2.004 Bay 4 i 0.002% 9.002%, DAE 6 5 0-2 0.002 04% i of 0. O2Nb, 9-00 oA * For room temperature + 20°C ‘Time (t), Burette Na Ca min__| Reading, ml_| (Normality of NaOH) | (Conc. Of NaOH) Le 2.0932 2. 007 “ on 0. FAG D. 901% |_ 6 oF 3.aNG AG ig oF 0.004 3.00\GCalculatior 1, Plot a graph of Xa/(1-X,) Vs time, Since the the reaction is of second order the data fits on a straight line passing through origin, and the slope gives the value of Caok. ‘Thus find k for all three temperatures, Sr.No ‘Temperature Ce) Rate Constant K { 23, 5373 z 33 aia 3 43 a5 2. Using Arrhenius equ 3. ion plot graph of Ink Vs IT, From slope and intercept find the activation energy and frequency fictor. Result:- zi Ky 2 53.3, Wye Mee by 299 Conelusion:- By pevfowming Mhig exp. we uvdlewstand the effect of keme, ew giveK veaction, So, os temp. iw-Cveases pute Of wearklon 9X0 incwoages,exp-4 CAE-I Orsewvation i At bene, ukuve 23°C Tivee @.R. Na Co xr Fo) Kris) Cea OF oc 10.00% 0.96 0.5 0.005 oNFs 0.3 9.003 2-995 °o.2 6.002 ong 0.2 0.002 2.99 At tempevatuve 33°C i 2 2.004 __0.00+ | LG 0,002¢ O16 G 4 6 t 9.002 £002 z ~ oF 9.0015/ O00l¢ ° oF en 9.001 4 L3'e ie 1.6 — 0.0032 0.0032 09 asary 0.0015 o.g 0. Cole 0.0916 O_O. 0.00\4 0.6 0.12 0.0012vc teme, DS FoR Len oS Normality of Naor, Na> Na - olyo.g = 0.00% Va Yo R= \- Gy s!-9.00¥ 20.96 Cro are XA = 0.96 \-% ron) 2 > Value of k Spats Nae Croka= (4.2% Choks = 19 z Wr = kee ze. os Fh gy ls 53.3, Te 7 Maz 95 Jen = 3.99 ae Jen by = 485,= fC CRI a4 gees exp a&