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peau @® CODE-A PX Aakash C=) Medicall IIT-JEE| Foundations Corporate Office: Aakash Tower, 8, Pusa Road, New Dethi-t 10008, Ph.011-47623456 AIM - 720 (Advanced INTENSE astery for 720) MM : 720 csT-7 Time : 3 Hrs. 20 Min. 1 @ 41. 4) at. (1) 121. (1) 161. (3) 2 @) 42. (3) 82 (3) 122. (4) 162. (3) 3 (1) 43. (4) 83. (2) 423. (2) 163. (3) 4. 3) 44. (2) 84. (1) 124. (3) 164. (2) 5 (8) 45. (1) 85. (2) 425. (4) 165. (2) & 2) 46. (2) 86. (1) 426. (1) 166. (4) 7 (1) 47. (4) 87. (2) 127.1) 167. (3) 8) 48. (3) 88. (3) 128. (3) 168. (4) 8. (2) 49. (1) 89. (2) 129. (4) 169. (2) 10. @) 50. (4) 90. (3) 130-(1) 470. (2) 11. @) 51. (2) st. (3) 431. (4) 471.2) 12. (t) 52. (1) 92. (1) 192. (1) 472. (2) 13. (2) 53. (2) 93. (3) 433. (2) 473. 2) 1a. Q) 54. (3) 94. (2) 134. (2) 174. 3) 18. (8) 55. (1) 95. (1) 135. (2) 175. (1) 16. (4) 56. (2) 96. (4) 136. (3) 476. (4) 17.) 57. (3) 97. (1) 137. (2) 47.(1) 18. (1) 58. (2) 98. (2) 138. (1) 178. (2) 19. (1) 59. (2) 99. (4) 439. (3) 179.(1) 20. (3) 60. (1) 100. 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(2) (ay CST-7_(Code-A) (Answers & Solutions) AIM. 720 13/04/2024 MM : 720 i) Aakash Medical] IIT-JEE| Foundations AIM - 720 CODE-A Co) (Aduanced INTENSE Wastery for 120) csT-7 Time : 3 Hrs. 20 Min, SECTION-A Answer (3) Genetic diversity of a species shows high diversity. at the genetic level over its distributional range. The genetic variation shown by Reuwolfia vomitoria grow in different Himalayan ranges, might be in terms potency and concentration of the active chemical. Answer (2) In the test cross, an individual with homozygous recessive genotype is crossed with individual with dominant phenotype. This cross is done to identify the genotype of organism with dominant phenotype. In snapdragon plant, flower colour show incomplete dominance, So for this plant, if plant is showing red coloured flowers it means plant is homozygous dominant for red colour. Answer (1) Drosophila and garden pea both have short life span. Both of them can produce large number of progenies in a single mating, Answer (3) Endemic species are confined to a particular geographical area and not found anywhere else, Answer (4) In lactic acid fermentation, no carbon dioxide is, released, Answer (2) Sickle cell anaemia is caused due to transversion mutation, 7. 10. " 12 13. Answer (1) ‘AB blood groups in human is a good example of co-dominance, When both !* and I? are present in @ person, both enzymes or sugars thus both antigens A and B are produced ‘Answer (1) Lactose is the substrate for the enzyme beta- galactosidase and it regulates switching on and off of the operon. ‘Answer (2) Initiator t-RNA will recognize the codon 5'AUG3" with the help of anticodon 3’UACS’ Answer (3) A+T+G+C= 100% 20+20+x+x=100 [As A=T and G=C] 40 + 2x = 100 2x=60 x=30 Answer (2) The genetic material should be chemically and structurally stable, provide the scope for slow changes and be able to express itself in the form of Mendelian characters, Answer (1) In both Cs and Cs plants primary COe fixation ‘occurs in mesophyll cells, Answer (2) Light reaction produces ATP, O2 and NADPHtH’. (2) AIM - 720 CST-7_(Code-A)_(Answers & Solutions) 14. Answor (2) 22. Answer (1) Sclereids are spherical, oval or cylindrical cells The arrangement of sepals or petals in floral bud with highly thickened cell wall and are also the with respect to other member of same whor is dead cells. The gity texture of guava and pear is known as aestivation, Main types of aestivation due to the presence of sclereids in ther pulp. are valvate, twisted, imbricate and vexilary. 15. Answer (4) 23, Answer (2) + _Alltissues on the inner side ofthe endodermis In monocotyledons the leaf base expand into a such as pericycl, vascular bundles and pith sheath covering tho stom partaly or wholly. constitute the stele. Flowers with bracts-reduced leaf found atthe base «+ Endodermis in rots comprises a single layer of pedicel are called bracteate and those without of barrel shaped cells having suberin bracts are termed as ebracteate. thickenings in their radial as well as tangential | 24. Answer (1) wals, called casparian strips. The plumule are enclosed in sheaths which are 16. Anewer (4) caled coleoptle while radicle are enclosed in + FW. Went isolated the plant hormone ‘Auxin’ coleorhiza. from the tips of coleopties of oat seedlings. | 25: Answer (4) + Charles and Francis Darwin observed that the Algae may be filamentous and colonial. Solooptiog of eanery ase sesponded te Filamentous algae are Ulothrix, Spirogyra. ec. unilateral illumination by growing towards light Volvox is a.colonial algae. source 26. Answer (4) 17. Answer (1) In pteridophytes antherozoids represents motile Hilum is the junction between ovule and funicle male gametes produced in antheridia found on ‘One or more protective envelopes surrounding the lparnetophyte. body of ovule are integuments. Micropyle is the | 27. Answer (1) pore present at the tip of ovule where integument Greater the BOD of waste water, more is its is absent. Nucellus isthe parenchymatous mass polluting potential of tissue enclosed within integuments, 28. Answer (3) 18. Answer (1) In commensalism one species is benefited and + Barley plant has albuminous seeds. ather is neither harmed nor benefted, Bamacles +The wall of the ovary forms the wall of fruit Growing on the beck of whale benef nthe form Wich calles pce of shelter where whale remains unatfecte + Cashew is a false fruit. 29. Answer (4) Most productive ecosystem are coral reef, tropical 19. Answer (1) rain forest, sugarcane field etc. Glass is a group of related orders for example, | 39. Answer (1) plans order lke Sapindales and Polymoniales are Senet ‘ow ch , included in class Dicotyledonae. ometimes a few chromosomes Nave non. staining secondary constrictions at a constant 20. Answer (3) location, gives the appearance of small fragment Lichen is @ mutualistic association between a caled satelite fungal partner (mycobiont) and an algal partner | 31, answer (4) (phycobiont) Nucleolus is the site for active ribosomal RNA 21. Answer (2) synthesis. In ascomycetes ascus is the site of karyogamy | 32. Answer (2) and meiosis where 4 to 8 haploid meiospores named ascospores are produced endogenously in each ascus. Eg — Claviceps Cell membrane is a mosaic or composite of diverse lipids and proteins and it shows fluid behaviour. @) CST-7_(Code-A) (Answers & Solutions) AIM. 720 33, 34. 36. 36. a7. 38, 39, 40. 41. ‘Answer (2) M phase is the most dramatic period of cell cycle Answer (1) Prophase is marked by the initiation of chromosomal material. Decondensation of chromosomal material and reformation of ER and nucleolus occur in telophase. ONA duplication occur in S-phase of interphase. ‘Answer (4) In oocytes of some vertebrates, diplotene can last for months or years. ‘SECTION-B ‘Answer (3) Formula to calculate number of different types of gametes produced is = 2° Here n= , where n = number of heterozygote Hence, 2°= 23= The given genotype will produce eight different types of gametes. Answer (3) Fermentation can occur in both prokaryotes and, eukaryotes. Answer (2) Post transcriptional modifications include capping, tailing and splicing. Aminoacylation of {RNA occurs during translation ‘Answer (3) All the genes that are expressed as RNA are referred to as EST. ‘Answer (2) + Meristematic cells have dense cytoplasm with conspicuous nucleus. + Lateral meristems appear later in life and are cylindrical meristems which is responsible for increase in girth of stem and produces secondary tissues. + Interfascicular cambium is an example of lateral meristem, Answer (4) 2, 4-D (2, 4-Dichlorophenoxyacetic acid) is a synthetic auxin, widely used to kill dicotyledonous weeds and does not affect mature monocotyledonous plants. 42, 43, 44, 45, 46. 47. 48, 49, 50, Answer (3) Wind pollination is quite common in grasses, for example— Maize, Wheat. Wind pollinated flowers have light and non-sticky pollen grains, large feathery stigma and single ovule in each ovary but not mucilaginous covering in pollen grains. + Light, unwettable pollen grains surrounded by mucilaginous covering which protects from wetting found in water-pollinated flowers. Answer (4) ‘Mycoplasma completely lacks cell wall and are the ‘smallest living cells known and can survive without oxygen ie., facultative anaerobe. Many ‘mycoplasmas are pathogenic in animals and plants. Answer (2) ‘The floral formula of Poaceae (gress family) is 466 Phezestammn Abus S Answer (1) Selaginella, Lycopodium belong to the class Lycopsida: Answer (2) Cyclosporin A is used as immunosuppressive agent in organ-transplant patients. It is produced by fungus Trichoderma polysporum. ‘Answer (4) Um-shaped age-pyramid shows a declined growth (negative growth) as there are fewer individuals in pre-reproductive group, the population size will decline with time. ‘Answer (3) Decomposition is the breakdown of complex organic matter to inorganic raw material like COz, H20 and various nutrients by decomposers. Humus is dark colored, amorphous substances Which is slightly acidic and function as reservoir of nutrients. Answer (1) Ribosomes are the sites of protein synthesis and have subunits 50S and 30S in prokaryotes. ‘Answer (4) Bivalent appears as tetrad in pachytene stage. Daughter cells produced after equational division are same to each other and as well as the parent cell (4) AIM - 720 CST-7_(Code-A)_(Answers & Solutions) SECTION-A 57. Answer (3) 51, Answer (2) Biopiracy is the term used to refer to the use of bio- resources by multinational companies and other Endocrine glands lack ducts and are hence, caled | rsisatons without proper authorisation from | the countries and people concemed without hormones. Hormones are non-nutrient chemicals the counties and pe which act as intercellular messengers and are Ps ry Dey produced in trace amounts. 58. Answer (2) 52. Answer (1) 8. thuringiensis forms protein crystals during a paricular phase of their growth. These crystals DNA RNA Contain a toxic insecticidal protein. These proteins Purines Adenine, Adenine, are called Bt toxins. Guarine Guanine 59. Answer (2) Fossils discovered in Java in 1891 revealed Homo Pyrimidines | Thymine, Uracil, Cytsine nr Gyosine, 1 ove erectus. Homo erectus had a large brain around yosine grectu 53. Answer (2) 60. Answer (1) Glucosamine - Amino sugar Pnoumotaxic contre present in the pons region of the brain can moderate the functions of the Secondary _~ Oni right handed helices are, respiratory thythm centre. Noural signals from this structure of observed centre can reduce the duration of inspiration and proteins thereby alter the respiratory rate. Inulin = Polymer of fructose 61, Answer (4) Colagen «Most abundant p Steinatf Bobcat is a placental mammal while wombat, Snimals bandicoot and sugar glider are Austr marsupials. 54. Answer (3) Rap arcuesos * The alimentary canal ofa frog is short because Inhumans, each testicular lobule contains one to they are camivores. three highly coiled seminiferous tubules. So, the + Qesophagus isa short tube that opens into the approximate number of seminferous tubules in stomach which in tum continues as tho 100 testicular lobules is 100 to 300, intestine, rectum and finally opens outside by | 63 angwer (2) the cloaca ‘ ‘An alarming increase in growth rate of human + Parially digested food called chyme is passed population could lead to an absolute scarcity of from stomach to the first part of the small even the basic requirements, i.¢., food, shelter and intestine. clothing, in spite of significant progress made in + Final digestion takes place inthe intestine. those areas 55. Answer (1) 64. Answer (2) Hydra belongs to the phylum Coelenterata and Pills, injactions and implants contain progestogens has only tissue level of body organisation. It has only or progestogen-estrogen combinations. The neural tissue composed of a network of neurons. mode of action of pils, injections and implants are The vertebrates have a well developed neural similar. They inhibit ovulation and implantation as system well as alter the quality of cervical mucus to 56. Answer (2) prevent/retard the entry of sperms. 65. Answer (3) ‘The testes are situated outside the abdominal cavity within a pouch called scrotum. The scrotum helps in maintaining the low temperature of the testes (2-2.5°C lower than the normal internal body temperature) necessary for spermatogenesis Vasectomy and tubectomy are surgical methods of contraception for human male and female respectively. Condoms are barriers used by both males and females. Multiload-375 is a copper releasing IUD, (6) CST-7_(Code-A) (Answers & Solutions) AIM. 720 66. 67. 68. 69, 70. nm 72. 73, 74, ‘Answer (3) The human immune system consists of lymphoid ‘organs which are of two types, primary and secondary lymphoid organs. ‘After maturation in primary lymphoid organs, the lymphocytes migrate to secondary lymphoid organs like spleen, tonsils, Peyer's patches of ‘small intestine, lymph nodes and appendix. ‘Answer (2) Recognition sites for BamH 1, Sal and Pvu Il are present in pBR322. Hind Il is the first discovered restriction enzyme. ‘Answer (3) Skeletal muscle fibres are present in biceps while cardiac muscle fibres are present in heart Cardiac muscle fibres are uninucleated ‘They both are striated muscles. ‘Answer (3) Erythroblastosis foctalis has been observed between the Rh-ve blood of a pregnant mother with Rh +ve blood of the foetus Blood group A represents presence of Rh antigen whereas blood group A- represents absence of Rh antigen ‘Answer (2) Areolar tissue is a loose connective tissue. It is present beneath the skin. It often serves as a support framework for epithelium. ‘Answer (4) Frogs respire on land and in the water by two different methods. In water, skin acts as aquatic. respiratory organ (cutaneous respiration) Dissolved oxygen in the water is exchanged through the skin by diffusion. ‘Answer (3) The maximum volume of air a person can breathe ‘out after a forced inspiration is called vital capacity. Itincludes ERV, TV and IRV. ‘Answer (3) Zinc is a co-factor for the proteolytic enzyme, carboxypeptidase, ‘The essential chemical components of many coenzymes are vitamins, eg. co-enzyme nicotinamide adenine dinucleotide (NAD) and NADP contain the vitamin niacin, ‘Answer (4) The smooth muscle fibres taper at both ends (fusiform) and do not show striations. The wall of internal organs such as the blood vessels, stomach and intestine contains this type of muscle. Cell junctions hold them together and they are bundled together in a connective tissue sheath. 75. 76. 77. 78. 79, 80, at 82, 83, ‘Answer (2) Class Osteichthyes include both marine and fresh water fishes with bony endoskeleton. Their body is streamlined. They have four pairs of gills which are: covered by an operculum on each side. Mouth is ventral in cartilaginous fishes. Answer (3) A special coronary system of blood vessels is present in our body exclusively for the circulation of blood to and from the cardiac musculature. ‘Answer (1) Introduction of sex education in schools should be. encouraged to provide right information to young children so as to discourage them from believing in myths and having misconceptions about sex- related aspects. Answer (2) ‘The separated bands of DNA are cut out from the agarose gel and extracted from the gel piece. This step is known as elution, DNA spooling is a method of obtaining DNA in a form of spool over a glass rod. Answer (4) Prawn is an aquatic arthropod Hydra is a fresh water cnidarian, Nereis is an aquatic annelid Answer (3) ‘The autonomic nervous system (part of PNS) is divided into sympathetic and parasympathetic, neural system, ‘Sympathetic nervous system predominates during emergency conditions. Answer (1) Tumor cells have been shown to avoid detection and destruction by immune system. Therefore, the patients are given substances called biological response modifiers such as a-interferons which activate their immune system and help in destroying the tumor. Answer (3) Epididymis leads to vas deferens that ascends to the abdomen and loops over the urinary bladder. Rete testis and vasa efferentia are present inside testis. Answer (2) Sap ee caer TaaiOw 7K Deestor” Fey TOK Tho After gel electrophoresis, two bands will be seen, as two same fragments of 7 kb will form only one band (6) AIM - 720 84, 86. 86. 87. 88, 89. 90. ot. Answer (1) After completion of the biosynthetic stage, the product has to be subjected through a series of processes before it is ready for marketing as a finished product. ‘The processes include separation and purification. ‘The product has to be formulated with suitable preservatives. ‘Answer (2) Liver is the largest gland of human body which secretes bile-containing substances like bilirubin, biiverdin, cholesterol, degraded steroid hormones, vitamins and drugs. ‘SECTION-B Answer (1) Earthworm and leeches are monoecious. Bombyx and Periplaneta (Arthropod), Ancylostoma (Aschelminth) are dioecious. ‘Answer (2) Morphine is extracted from the latex of poppy plant, Papaver somniferum. Its receptors are opioid receptors which are present in our central nervous system and gastrointestinal tract. Acetylation of morphine produces smack/heroin Morphine is an effective painkiller and sedative, ‘Answer (3) Lungs do not collapse between breaths and some air always remains in the lungs which can never be expelled. There is a negative intrapleural pressure puling at the lung walls ‘Answer (2) Oxytocin ~ Milk ejection rom mammary gland Melatonin - Influences metabolism, pigmentation and our defense capability Thyroxine - Controls metabolism of carbohydrates, proteins and fats Cortisol - Maintains the cardio-vascular system as well as kidney functions ‘Answer (3) Nitrogenous base when found attached to a sugar, then they are called nucleosides. If a phosphate ‘group is also found esterified to the sugar, itis called nucleotide, Adenylic acid, thymidylic acid, guanylic acid are examples of nucleotides. ‘Answer (3) * Golden rice is vitamin-A enriched, with gene from daffodil 92, 93, 94, 95, 96. 97, 98. 99, 100. CST-7_(Code-A)_ (Answers & Solutions) © Single strand of nucleic acid tagged with radioactive molecule is known as probe. ‘* Adenosine deaminase enzyme deficiency will lead to a disease called SCID. Answer (1) In gout, there is inflammation of joints due to accumulation of uric acid crystals. ‘Answer (3) Man has bred selected plants and animals for agriculture, horticulture, sport and security. Man has domesticated many wild animals and crops. This intensive breeding programme has created breeds that differ from other breeds (e.g., dogs) but stil are of the same group. Answer (2) Inner cell mass contains stem calls for formation and development of embryo. Delivery of child is called parturition. Relaxin is secreted from ovary in the later phase of pregnancy. Cleavage is a special type of mitotic cell division Answer (1) Neutrophils are granulocytes, nucleated and constitutes 60-65% of the total WBCs. These are phagocytes. Basophils secrete histamine, heparin Answer (4) Ovaries are considered as primary sex organs and vagina is considered as secondary sex organ in human female, External genitalia in human females include mons pubis, labia majora, labia minora, clitoris and hymen, Answer (1) According to Darwin, the organic evolution is due to natural selection of small and directional variations, ‘Answer (2) Reptiles, birds, land snails and insects excrete nitrogenous wastes such as uric acid in the form of pellet or paste with a minimum loss of water and are called uricotelic animals. ‘Answer (4) ‘Troponin and tropomyosin are regulatory proteins in the muscle contraction while actin and myosin are contractile proteins, serotonin and ‘Answer (1) Selection of recombinants due to inactivation of antibiotic resistance gene is a cumbersome process because it requires simultaneous plating of two different antibiotics. m7 CST-7_(Code-A) (Answers & Solutions) AIM. 720 101 102 103. 104, ‘SECTION-A. ‘Answer (2) The correct representation of FBD will be as shown, w NOOSA ‘Answer (2) 2 Hyg =O ang = g ‘According to question, wsin?0_ u?sin20 2g g Sindxsind _ 9, sinoxcos0 2 = tang =4 = 0= tar) Answer (1) > 10 ms” >2ms~ A 8 i—_,-— 40m Aral = -2 ms Vea = 10 ms“ Sq =10t—Jx2nt2 +40 af Answer (3) => Sua For minimum > t=5s “ v 2g +a) from (i) and (ii) gah *<(o+a) Ai) during the downward mation, liga) h-Ka-alf 105. 106. 107 108 109. 110. 2h g-a bot Answer (3) PV=nRT, n> same, R-> Constant, V > same = Pot => New pressure = 2P Answer (1) (from 4 kg) We know, ge 810) 6 my 446 Answer (2) We know, 1 loom * MR? MR? MR? R= 80007 R=20r Surface energy of small drop E: = S* 4x7 Surface energy of larger drop Ey = S x (200)? x 4n* 400% &41 E400 Answer (1) Ya= tango° 1 3 8 3 Yo=3¥s Answer () Speed in a medium s given by and Ya = tan60* Yan and ¥q = V3 % y,-8-%8 3 ce v (8) Aim = 720 CST-T_(Code-A) (Answers & Solutions) 111. Answer (1) IF 0 is 0° or 180°, then the magnetic force on a 2 2 charged parlicle is zero. = (Uh Vi) = (Wat + Vat)? = 261 ana tar prone = (Ves) = Waar) =1 Maximum magnetic field due to a cylindrical wire is on ts surface. 112, Answer (1) wl Current through load resistance oR 30 =3.75 mA 5 _4axt07 xi 10" 105 = 8x10 2x10" 1 + i-ta 5 + 3.75 20 1= 28.75 mA 118, Answer (1) Voltage drop across R = IR Domains are present in ferromagnetic material. = 28.75 x 102 x 400 = 11.5V 119. Answor(8) Input voltage needed = Va + Vi a 211.5 +30=415V o-te 113, Answer (3) 2 Magnifying power when image is formed at infinity = Tier. D 2 Se = 2) 114. Answer (2) 120. Answer (1) 116. 116. Itcan be observed in the given circuit that potential difference between points A and Gis zero, hence thy ar at same pated 2 Ve tet 2-(242)40-(2eTe Mg Vy-10+10-Vy = V4=V5 Answer) oR R,=8, R= 8 ‘When resistors are connected in series, then Reg = Ry + Re aoolid + Answer (4) Formula of magnetic force on a charged particle is given by F=qlvx6) Fl = qvBsino 121 122 123. 124, Equipotential surface for line charge is cylindrical. Answer (1) a=t0% at x=0, v= vm and a=0 Answer (4) ¥ = Asin(ot — kx) represents simple harmonic progressive wave. Answer (2) AP =[F(thdt =P, -P PP 3x3 2m 2x1 ‘Answer (3) 1 Jam? 2 KE =45 J (@) CST-7_(Code-A) (Answers & Solutions) 126. 126. 127. 128. 129. etn 64 = Fx (2aR)x2 32=Fxanx2 p82 _4y err 2 SB -s2ms* = 4¥ aoe a= \(2) +(a2y =4)4 +64 + 64x? ~4ee A 6a? ms? Answer (4) There will be induced emf but no induced current to oppose the magnetic field of bar magnet. So the acceleration of bar magnet remains constant. ‘Answer (1) The current should be equal to rms current. Answer (1) When i= . 8 volt E-ir=Ofori=2A Also, =2"r=05r=40 Current through battery will be maximum when E8 load resistance is zero, and imax 2A ‘Answer (3) Knox = hf- 6, hence KEnax varies linearly with frequency. Also, intensity of radiation doesn't affect the KE of photoelectrons Answer (4) L=mvr om . aa 130. 131 132 133, 134. 136. 136. 137, 138, AIM. 720 GM 2M r a GM _GMm L=nw-Sh- vo ‘Answer (1) When A=0,8=Oand C=0 y=(0+0)0=0 When A=1,B=1andC=1 y Answer (4) For forward biased diode, P-junction should be at high potential as compared to N junction. Answer (1) P Slope of PV graph for adiabatic = 7 Ratio = 7 Answer (2) As ag > ct, 80 strip B will bend outer side. Answer (2) Force acting on the base F=PxA=pghA = 109 x 10 * 1.6 «2% 109=32N ‘Answer (2) For isobaric process P = constant SECTION-B Answer (3) For escape, KE + PE = = Mechanical energy = 0 Answer (2) B20 and y= 3a Answer (1) Fog ar = = |rmyj— mv r Fag => _ 2 Fig 2 a Ft 2 _ amv = Figg ay (10) AIM - 720 CST-7_(Code-A)_ (Answers & Solutions) 139. Answer (3) We know, 600 = 120.4 a= 5 radis? Now, 0 = oo + at 200 = St t= 202 _ 40 seconds 5 140. Answer (3) power = ENCDY 205.101.6310" yy Time 1 = 3.28 « 108 W 144. Answer (3) For H-lke element 1 pf 11 Re Re, Rone for 1 line of Lyman series 4 af 1 1 (4-4) (4) a? @) for 2% line of Lyman series 1 _ppf 11) -| (2) dg (a?) y= Zi 22 27 == «062 32, 222052 142. Answer (3) 5=(u-1)Aand peak ab yt = 8- maximum 143. Answer (3) Fundamental quantities can't be derived from each other. 144. Answer (2) 145. Answer (4) 146. ‘Answer (2) By the principle of homogeneity (8) = [A] = (84) = [C} = (Ly) Hence unit of AC 147. Answer (2) tano=" > n=0 f= 50% 102% 2% 105 f= 100 x 10° m n= 1mm 148, Answer (3) When light is incident at polarizing angle, then angle between reflected and refracted light is 90°. (11) CST-7_(Code-A) (Answers & Solutions) 149. 151 152 153. 164. 165. r=90°=1 Answer (3) —10_ 2 R 5a z-Po-100 ReexP =z? AIM «720 xXp=2?-R® XP =102 8 -75.0 xX, =530 2nxSOL = 5V3 sv3 8 1002 20n 4 150. Answer (3) In steady state: Ldi at 0 CHEMISTRY SECTION-A Answer (3) Orthoboric acid (HsB0s) has a basicity of one. It does not lose H” ions while it accepts one lone pair of electrons from HO, ‘Answer (2) () Ammonium phosphomolybdate ~ Yellow (ii) Silver sulphide — Black (ii) Sodium thionitroprusside - Violet (iv) Ferriferrocyanide ~ Prussian blue ‘Answer (1) Answer (4) ANHa(g) + 502(g) > 4NO(Q) + 6H:0(9) 4 moles of NHs reacts with 5 moles of Oz. 1 mole of NHs reacts with moles of O. 1.25 moles of O: are required. So, O2 is the limiting reagent and consumed completely. Moles of NO(g) formed = 0.8 Moles of H2O(g) formed = 1.2 ‘Answer (3) Molar mass of COz = 44 g mot? Mass of CO, Number of moles of CO, - Mass of CO, _ Imber of moles of Molar mass of CO, 22-005 mole 156. 157. 158. Number of molecules of CO2 = 0.05 x Na Number of oxygen atoms is COz = 2 * 0.05 x Na, = 0.4 x 6,023 « 10% = 6.023 x 102 NH, NCI ee t Benzoic acid (c) B--CRCRO oo and aryl halide gives an alkylarene when treated with sodium in dry ether and is called Wurtz-Fittig reaction, es oe (12) AIM - 720 CST-7_(Code-A)_(Answers & Solutions) 159. Answer (2) 165. Answer (2) Outer electronic configuration of Eu (Z = 63) = - 0.0591, (101) aes? a= Egg og TO | Outer electronic configuration of Gm (Z = 96) = Bfedt7s2 Eca= 051-2 FP tieg(t0) + Europium and curium have half filed fautehell Econ = 0.51 ~ 0.02955 160. Answer (1) Eo = 0.48 V The species in intermediate oxidation state can | 6° ree cHhcOO™ shits th hi undergo disproportionation (simultaneous ition of CHsCOO- shifts the equilibrium in uidelion and reduction eth) backward direction, so [H'] will decrease and pH will increase. Jn CIO;, Cis in #3 oxidation state and can | 167. Answer (3) disproportionate as follows: + When Ke is very large the reaction proceeds Oxidation to completion. + When Kc is very smal, reactants predominate clo, —> cr 4 clo, over products and reaction proceeds rarely, ies Reduction 168. Answer (4) while § in in ©140%-(6) and Mn in Minimum two a-Hydrogens are required for aldol ile S in. SOZ-(46), Cr in Cr,0F (+6) and Mi eS MnO;(+7) is in it highest oxidation state and can | 169. Answer (2) not undergo disproportionation. cryenHM°_,cH,cooH 161. Answer (3) [CrINHs)eP* = Cr = 308 4s? Torres THT This is second order reaction for which unit of rate — oa constant is moh" L s~ oP 471, Answer (2) Geometry = Octahedral gS, S4CH,0OONH, - (NG) PHCHCOCD| Hybridisation = dsp? {Soib\) +(NH)80« Magnetic moment = yiin-+2) ‘ i 172. Answer (2) =\8G+2) = 36) = Vis Hydrated oxalic acid is =3878M CiHoO42H:0 162, Answer (3) To prepare 0.1 molar 100 mL CoH0«2H.0(aq) Molarity is an intensive property. = 10 mili mol (Independent of amount of substance) een tors = 1.269 Extensive Property Aso Intensive property = Deensive Property Property =F tonsive Property 173. Answer (2) Mes we Volume “ 163. Answer (3) Zris.a block element Aor 164. Answer (2) 2=47-9Ag Ag» IKri4a""5s* Group -» 11 and Period -» 5 (13) CST-7_(Code-A) (Answers & Solutions) AIM. 720 174. 176. 176. 177. 178, 179. 180. 181. 182 183, Answer (3) Electron donating group (-CHs) attached with benzene increases the reactivity of benzene nucleus towards electrophilic aromatic substitution reaction. Answer (1) Ors OH O+O-* ‘Answer (4) Proparation of ether from alkoxide and alkyl halide is called Williamson synthesis. Answer (1) Lactose is a reducing sugar hence it reduces Tolls reagents. Answer (2) 2 RPG 0. Ss 1 Ser: 022 Sal Answer (1) The volume of hypertonic solution increases till concentration of hypertonic and hypotonic solution becomes equal Answer (2) 1000 xk; x we MxW, = 1000%1.8623 46% 1000 =0.93 AT, =Ty Tyson o At Thao) = 0-093 =0.93°C Answer (2) XeF, and CO: are non-polar. NHs, NF3 and HzO are polar. Answer (1) Hybridisation of XeOs is sp” 9 Xe s, Bare ° ‘Answer (2) Kinetic energy = h( —v) = 6.6 x 10 Js (1 10"°—7 x 104) s+ = 6.6 x 10 (10°) (10-7) = 6.6 « 10-9 (3) = 19.8 x 10-9 = 1.98 x 10-9 J 22x10? J of 184. 185. 186. 187, 188, 189. 190. 191 Answer (1) Order of bond energy for halogens is, Cle > Bre> Fa> lz Answer (3) Reactivity depends upon stability of carbocation. gis 2 2 © go >(Oy-8, > CH,-CH,> CH CH, CH; SECTION-B ‘Answer (4) lon 2218 om? mol H 349.6 on 199.1 Nat 50.1 K 735 Answer (3) HOH +O” for pure water [H'] = [OH] [H'] [OH] = Kw [Hy = 105 ‘Answer (2) 142%15%0.5 % of Nitrogen = "4 100 = 42 > 1000%0.5 % % of Carbon = 100 - (42 + 10) = 48% Answer (2) HCOOH 5 CH,CH,OH Answer (2) a tye se 2 2k _ 1100 9 10?2 2 Answer (3) 1. Change in entropy is negative 8 Ang <0, aS<0 2. Since by polymerising molecules together, number of freely moving particles gets reduced = AS <0 When a gas expands at constant temperature, the constituent particles move freely of AS > 0 When a liquid crystallizes into a solid, it obtains more ordered state. as

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