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CHEM PP2 KCSE 2024 PREDICTION TRIALS with answers
CHEM PP2 KCSE 2024 PREDICTION TRIALS with answers
CHEMISTRY PAPER 2
KCSE 2024 TOP PREDICTION TRIALS 1-10
CLASS OF KCSE 2024 NOVEMBER
The set Comprises of 10 Prediction Trials prepared
by a panel of Top KNEC Writers Nairobi HQ
Kenya Educators Consultancy is proud to announce that in KCSE 2023 National
Examinations, more than 57% of our predictions from the same panelists appeared in
the national exam (KCSE 2023)
All KCSE 2024 November Candidates are advised to take the questions in this
package of predictions serious as they prepare for the national exams!
Confidential!!!
All the best to all KCSE 2024 Candidates as they prepare for the national Exams
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
INSTRUCTIONS TO CANDIDATES.
o Write your name and index number in the spaces provided above.
o Answer ALL the questions in the spaces provided.
o Mathematical tables and silent electronic calculators may be used.
o All working MUST be clearly shown where necessary.
o Ensure that all pages are printed as indicated.
FOR EXAMINER’S USE ONLY.
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
b) The half life of sodium -20 is 0.3 seconds. P grams of sodium -20 decays to 6 grams in 0.9
seconds.
i. Calculate the initial mass P, of the isotope. (2mks)
ii. With reference to sodium -20, give one use of radio isotopes in medicine. (1mk)
c) In the Down’s process, (used to manufacture sodium) a certain salt is added to lower the
melting point of sodium chloride from 8000c to 6000c.
i. Name the salt that is added. (1mk)
d) Explain why aqueous sodium chloride is not suitable as an electrolyte for the manufacture of
sodium in Down’s process. (2mks)
2. The grid below shows part of the periodic table. Use it to answer the question that follows.
(Letters are not actual symbols of elements.)
E F
G H I J K
ii. L
b) Give the formula of one stable ion with an electron arrangement of 2:8 which is;
(1mk)
i. Negatively charged.
c) The oxide of H reacts with both hydrochloric acid and sodium hydroxide to form a
salt. What is the nature of the oxide? (1mk)
g) 60cm3 of gas E diffused through a porous partition in 50 seconds. How long would it
take 60cm3 of sulphur IV oxide gas to diffuse through the same partition, under the
same conditions? (3mks)
(0=16, s=32)
b) Study the flow chart below and answer the questions that follow.
IV -
ii. State the reagent and condition necessary for steps II (1mk)
Reagent -
Condition -
A sample of this polymer is found to have a molecular mass of 750. Determine the number of
monomers is the polymer. (2mks)
(Cl=35.5, C=12, H=1)
ii) State why the polymer above should not be thrown away. (1mk)
4. The flow chart below represents preparation and properties of oxygen gas. Study it and
answer the questions that follow.
c) i)What observation is made when excess ammonia solution is added to solution M. (1mk)
ii) Write an ionic equation for the reaction in C (i) above. (1mk)
d) 1.68g of hot copper metal completely reacted with oxygen gas. Calculate the volume of
oxygen gas used (molar gas volume= 24dm3 Cu=63.5) (3mks)
b) i) Use the reduction potentials below to draw a labeled diagram of an electrochemical cell that
can be constructed to measure the electromotive force between magnesium and copper. (2mks)
Mg2++2e-→Mg(s) EӨ=-2.38V
Cu2++2e-→Cu(s) EӨ=+0.34v
6. a) Chlorine can be prepared using the following reagents; concentrated hydrochloric acid,
potassium manganate VII and concentrated sulphuric VI acid.
i. What is the role of each of the following?
Potassium manganate VII. (1mk)
ii. Name the bleaching agent formed when chlorine gas is passed through cold, dilute
sodium hydroxide solution. (1mk)
iii. Name one other use of the compound formed in (ii) above other than bleaching.
(1mk)
b) State and explain observations that would be made if a moist blue litmus paper was placed in a
gas jar full of chlorine gas. (2mks)
c) 1.9g of magnesium chloride was dissolved in distilled water. Silver nitrate solution was added
until in excess. Calculate the mass of silver nitrate that was used for complete reaction. (3mks)
(RMM MgCl2=95, N=14, O=16, Ag=108)
7. The table below gives the solubility of ammonium phosphate at the stated temperatures.
Temp 0c 10 18 26 34 42 50
Solubility g/100g H2 21 28 38.5 51 68.5 98
iv. Use an equation to explain how temporary water hardness is removed. (1mk)
c. Study the information in the table below and answer the question that follows.
Salt Solubility (g/100g H2O) at
45 0c 60 0c
i. Na2Co3 35 80
ii. Pb(no3)2 77 101
A mixture containing 90g of sodium carbonate and 72g of lead II nitrate in 100g of water at 60 0c
was cooled to 45 0c.
i. Identify the salt that crystallized out. (1mk)
ii. Calculate the mass of the salt that crystallized out. (1mk)
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
INSTRUCTIONS TO CANDIDATES.
o Write your name and index number in the spaces provided above.
o Answer ALL the questions in the spaces provided.
o Mathematical tables and silent electronic calculators may be used.
o All working MUST be clearly shown where necessary.
o Ensure that all pages are printed as indicated.
FOR EXAMINER’S USE ONLY.
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
(i) (a)Which curve shows the variation in temperature for the pure solid? Explain.
(2mks)
……………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………..
(ii) State the effect of impurities on the melting and boiling points of a pure substance.
I. Melting points (1/2 mk)
………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………….
II. Boilling points (1/2 mk)
………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………..
(b)The diagram below shows the relationship between the physical states of matter.
A
B C
Solid Liquid Gas
E D
B………………………………………………
D…………………………………………….
CHAMBER 4
Heated magnesium
Escaping gases powder
…………………………………………………………………………………………………………………..
II. Chamber 3
………………………………………………………………………………………………………………….
III. Chamber 4
…………………………………………………………………………………………………………………..
………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………
I. chamber 1 (1mk)
……………………………………………………………………………………………………………………………
e) State and explain the observation made in chamber 3 during reaction (2mks)
……………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………
f) Name one gas which escapes from the scheme above (1mk)
……………………………………………………………………………………………………………………………………..
U H2O Substance Y
O2 Heat Sodalime
Process K Process J
CH2BrCH2 CH2CH2 CH3CH3
Nickel Catalyst
Process T Cl2
H H W + HCl
C C
H H
Substances S
J- ……………………………………………………………..
K- …………………………………………………………….
T- …………………………………………………………….
4. The grid below shows a part of the periodic table. The letters do not represent the actual
symbols. Study it and answer the questions that follow.
C T
U
X K M Q W
Y P Z
J
f) Identify an element whose oxide reacts with both acids and alkalis (1mk)
………………………………………………………………………………………………………………………………
g) i. Write down the chemical formular of the compound formed between elements K and
W (1mk)
……………………………………………………………………………………………………………………………………
Gas M
I Air
II
Ammonia Catalyst P Absorption
rower
Air 7000C
IV
a) Catalyst P (½ mk)
…………………………………………………………………………………………………………………………………..
b) Gas M (½ mk)
……………………………………………………………….…………………………………………………………………
c) Liquid F (½mk)
…………………………………………………………………………………………………………………………………..
……………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………….
…………………………………………………………………………………………………………………………………..
6. Study the reaction scheme below and answer the questions that follow
Sodium White precipitate
White NaOH (aq) Lead (II) nitrate Suplhate
P
precipitate solution Solution
Few drops
Process 3
Colourlesssol
ution Z
i) P ………………………………………….
b) Write an ionic equation for the process that produces white precipitate P (1mk)
…………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………
P ………………………………………..
Q …………………………………………
e) Write a balanced chemical equation for the formation of white precipitate L. (1mk)
………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………
i) Write the formula of the complex ion present in colourless solution Y (1mk)
…………………………………………………………………………………………………………………………………………
7. Below is a set of apparatus that was used to obtain a dry sample of sulphur(iv)oxide gas
a) Name;
i) Solid W (1mk)
………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………..
C) Complete the diagram to show how the gas could have been collected (1mk)
………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………
e) 50cm3 of 2M Hydrochloric acid was used during the above experiment. Determine the
volume of sulphur(iv)oxide gas produced at r.t.p (molar gas volume = 24dm3)
…………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………
ii) Use the graph to determine the concentration in moles per litre of the hydrochloric
acid (2mks)
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
INSTRUCTIONS TO CANDIDATES.
o Write your name and index number in the spaces provided above.
o Answer ALL the questions in the spaces provided.
o Mathematical tables and silent electronic calculators may be used.
o All working MUST be clearly shown where necessary.
o Ensure that all pages are printed as indicated.
FOR EXAMINER’S USE ONLY.
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
K L M N P
Q R S T V
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
c) With a reason, identify elements in period 3 with the largest atomic radius (2mks )
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
d) Write the formula of the compound formed between Q and M (1mk )
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
e) State two uses of element R and for each use , state property of element R that makes lts possible for
the use
(i) Use ( 1mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
Property (1mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
(ii) Use (1mk)
…………………………………………………………………………………………………………………
g) In terms of structure and bonding explain why the oxides of element Thas relatively low boiling
points (2mks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
2. (a) name the following compounds (3mks)
(i) CH3CH2CH2COOH
…………………………………………………………………………………………………………………
(ii)
…………………………………………………………………………………………………………………
(iii)CH3CH2OOCCH2CH3
…………………………………………………………………………………………………………………
i)
Name the above process used to obtain sulphur from the underground deposits
(1mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
b) Chamber T (1mk)
…………………………………………………………………………………………………………………
c) Substance R (1mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
ii) Write the chemical equation occurring in the dilution chamber (1mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
5. (a) Calamine is one of the ores from which zinc can be extracted from
(i) Name any other ore from which zinc can be extracted from (1mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
(ii) The calamine is usually decomposed by heating to obtain substance M as shown
below
ZnCO3 M+ CO2
(i) Which letter represents the, strongest reducing agent? give a reason (2mks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
(ii) Which two letters represent elements whose half cells would form an electrochemical cell
with the largest e.m.f? (1mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
(iii) Calculate the e.m.f of the cell formed in (ii) above (2mks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
(ii) Charge carried by the ions of metal Q given that R.A.M of metal Q is 84 (3mks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
7 (a) starting with magnesium oxide, describe how you can obtain a dry sample of magnesium
Carbonate (3mks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
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************END***********
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
INSTRUCTIONS TO CANDIDATES.
o Write your name and index number in the spaces provided above.
o Answer ALL the questions in the spaces provided.
o Mathematical tables and silent electronic calculators may be used.
o All working MUST be clearly shown where necessary.
o Ensure that all pages are printed as indicated.
FOR EXAMINER’S USE ONLY.
Questions Maximum score Candidates score
1 12
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
c) Study the scheme given below and answer the questions that follow.
i) Write an equation for the reaction between propan – 1 –ol and potassium metal.
(1mk)
II
iii) Identify the products A and B (2mks)
A
v) Draw the structural formula of the repeating unit in the polymer C. (1mk)
2. (a) The following diagrams show the structures of two allotropes of carbon. Study
them and answer the questions that follow
(b) In an experiment, carbon (IV) oxide gas was passed over heated charcoal and the
gas produced collected as shown in the diagram below
(i) Write an equation for the reaction that took place in the combustion tube (1mk)
(ii) Name another substance that can be used instead of sodium hydroxide ((1mk)
3. a) Fraction distillation of liquid air usually produces nitrogen and oxygen as the
major products.
i) Name one substance that is used to remove carbon (IV) oxide from the air before
it is changed into liquid. (1mk)
ii) Describe how nitrogen gas is obtained from the liquid air. (2mk)
(Boiling points nitrogen = - 196oC, oxygen = -183oC)
(b)Study the flow chart below and answer the questions that follow.
52
4. (a) An atom Q can be represented as Q.
24
(i) Write the formula of the compound formed when N reacts with P.
(Atomic numbers are N = 20; P = 17) (1mk)
(ii) Identify the elements which belong to the third period of the periodic table. Explain
(2mks)
(iii) Which of the element identified in b (ii) above comes last in the third period? Explain
(2mks)
(c) The table below gives some properties of substances I, II, III, and IV.
Study it and answer the questions that follow
II
5. (a) Below is a simplified diagram of the Downs Cell used for the manufacture of
sodium. Study it and answer the questions that follow
(i) What material is the anode made of? Give a reason (2mks)
(i) What precaution is taken to prevent chlorine and sodium from re-
combination? ( 1mks)
(iii) Write an ionic equation for the reaction in which chlorine gas is formed
(1mk)
(c) Explain why aqueous sodium chloride is not suitable as an electrolyte for the
manufacture of sodium in the Downs process (2mk)
(d) Sodium metal reacts with air to form two oxides. Give the formulae of two oxides
(1mk)
(ii) How could it have been shown that the liquid was pure water? (1mk)
(c) It was confirmed that magnesium sulphate was present in the tap water
(i) What type of hardness was present in the water? (1mk)
(ii) Explain one method that can be used to remove the water hardness.
(2mks)
(ii) At the end of the experiment, the solution in the beaker was found to be a weak
base. Explain why the solution is a weak base. (2 marks)
(iii) Give one laboratory use of the solution formed in a beaker. (1 mark)
Step 4
(b) The table below gives the percentages of a radioactive isotope of Bismuth that
remains after decaying at different times.
II. Original mass of the Bismuth isotope given that the mass that remained
after 70 minutes was 0.16g (2mks)
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
A
B G H E
J I L C
D M
Y
(i) What name is given to the family of elements to which A and C belong? ( 1 mark )
(a) Metal
(b) Non-metal
(iv) Name the bond formed when B and H react. Explain your answer. ( 2 marks )
(vi) Ionic radius of element E is bigger than the atomic radius. Explain.
( 2 marks )
(viii) The oxide of G has a lower melting point than the oxide of L. Explain.
( 1 mark )
(x)Explain the trend in the 1st ionization energies of the elements J, I and L.(1mark )
Y 15 20 35 45 65 80
i. On the grid provided, plot a graph of solubility (vertical axis) against temperature.
(4mks)
X ……………………………………………………….. (1mk)
iii. At what temperature was the solubility of both salts equal. (1mk)
3. The flow chart below illustrates two industrial processes. Haber and contact processes each
with air as one of the starting materials and other chemical reactions.
AIR Nitrogen B D
Harber
process
Oxygen Hydrogen
Sulphur C Sulphuric
A dioxide acid
Water
Contact
process
(iii) Explain the role of the catalyst in both the Haber and contact process. (2 mks)
………………………………………………………………………………………………………
……
4. A student set-up the arrangement below to prepare and collect dry hydrogen gas
(c) (i) Explain why hydrogen was collected by the method shown above
(1mk)
………………………………………………………………………………………………
…………………………………………………………………………………………
(ii) Write a balanced chemical equation for the reaction that takes place when
hydrogen gas is burnt in air.
(1mk)
………………………………………………………………………………………………
………………………………………………………………………………………………
………………
(e) Determine the relative atomic mass of zinc, given that when 6.54g of zinc was
used, 2.4litres of hydrogen gas was produced. (Molar gas volume = 24 litres)
(3mks)
a) Name one condition that is missing in the set up that must be present if the experiment to
proceed.
1mark
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………
b) If the experiment was carried out properly. What observation would be made in the
combustion tube?
1mark
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………
d) Give an equation for the reaction that takes place as gas x burns.
1 marks
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………
e) Why is it necessary to burn gas x?
1mk
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………
f) Name the reducing and oxidizing agent.
2marks
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………………………………………………………………………………
………………………………………
…………………………………………………………………………………………………
b) State one property of chlorine gas which facilitates this method of collection.
1mark
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………
d) Chlorine gas was bubbled through distilled water. With aid of an equation show the
formation of chlorine water.
(1mark)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………..…….
e) Write the formula of the compounds formed when chlorine gas reacts with warm dry
phosphorous.
(2marks)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………
f) Chlorine gas is mixed with moist hydrogen sulphide gas, state and explain the observations
(2marks)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
g) Give one use of chlorine gas.
1mark
…………………………………………………………………………………………………
……………………………………………………………………………………
Ai
r A B M
Substance T
Dry air
Sodium Compressor
Carbonate
solution
X
Nitrogen boiling D
point- 1960C
Fractional
distillation
Argon boiling
point -1860C R
Oxygen boiling
point - 1960C
A…………………………………………………………………………………………..…….
.
B…………………………………………………………………………………………….
M……………………………………………………………………………………………..…
.
b) Name;
……………………………………………………………………………………….……….…
(ii) Substance T(1mk)
…………………………………………………………………………….…….………………
c) Explain why part Y in chamber D is curved?
1mark
…………………………………………………………………………………………………
………………………………………………………………………………………………
d) Give two industrial uses of oxygen gas?
(2marks)
…………………………………………………………………………………………………
……………………………………………………………………………………………
e) In the laboratory preparation of oxygen, manganese (iv) oxide and hydrogen peroxide are
used. Write an equation to show how oxygen gas is formed.
1mark
…………………………………………………………………………………………………
…………………………………………………………………………………………………
R T
S
Air Air
Air
Nail
Oil
Water
Anhydrous
Nail calcium Boiled water
chloride Nail
(i) State and explain what will happen in the three test-tubes R, S and T after seven days.
2marks
…………………………………………………………………………………………………
……………………………………………………………………………………
(ii) Give one reason why some metals are electroplated.
1mark
…………………………………………………………………………………………………
……………
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
INSTRUCTIONS TO CANDIDATES.
o Write your name and index number in the spaces provided above.
o Answer ALL the questions in the spaces provided.
o Mathematical tables and silent electronic calculators may be used.
o All working MUST be clearly shown where necessary.
o Ensure that all pages are printed as indicated.
FOR EXAMINER’S USE ONLY.
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
Green
Blue
Red
A B C D E
(b) What conditions are required to separate the chromatograms present in a dye? (2 mks)
(c) What is meant by the term solvent front? Indicate its position in the diagram. (1 ½ mks)
(h) How can one obtain the extract of the blue dye? (2 mks)
(i) The results showed that dye E contained unwanted colour. Identify the colour. (2 mks)
Compressor
A
Fractionating
column
Nitrogen C (-183oC)
Argon
(196oC
(-106oC)
(a) Write an equation for the reaction which takes place in the chamber with.
(i) Concentrated Sodium hydroxide. (1 mk)
(iv) Name one gas which escapes from the chamber containing magnesium powder. Give a
reason for your answer. (2 mks)
(iii) Nitrogen gas collected using this method is not pure. Explain. (1 mk)
(iv) Give a reason why liquid nitrogen is used for storage of semen for artificial
insemination. (1 mk)
3. Use the grid below to answer the questions that follow. The letters do not represent actual
symbols of the elements.
F
Q
O B P R S A
T E C U
V Z
(a) (i) Which element form ions with a charge of -2? Explain. (2 mks)
(iv) Select the element with the largest atomic radius. Give a reason. (2 mks)
Sugar solution
Process X
Crude ethanol
Process Y
Substance B Polymer G
B–
C–
D–
Y-
(ii) A sample of the polymer was found to have relative molecular mass of 3952. Determine
the volume of n. (H = 1.0, C = 12.0) (2 mks)
(iii) State one demerits of this kind of polymer as a synthetic fibre. (1 mk)
(b) Give the purpose of the solution that passes through pipe 2. (2 mks)
(c) The following equation is the reaction of Sulphur (iv) oxide and oxygen gas. Use it to answer
the questions below.
(ii) Explain briefly how Sulphur (vi) oxide is converted to Sulphuric (VI) acid in the contact
process. (2 mks)
(ii) When ammonia is passed through concentrated Sulphuric acid, ammonium sulphate
fertilizer is produced.
I. Write an equation for the reaction. (1 mk)
II. Calculate the mass in kg of Sulphuric acid required to produce 250kg of the
ammonium sulphate fertilizer (S = 32.0 O = 16.0, N = 14.0, H = 1.0) (3 mks)
6. A sample of hydrated Iron (II) sulphate weighing 6.8g was dissolved in water and the solution
made up to 250cm3. 25cm3 of the solution was titrated against a solution of 0.02 molar acidified
potassium manganite (VII). The titre volumes obtained were 22.8cm3, 22.4cm3 and 22.5cm3 for
the first, second and third titrations.
(b) Determine the number of moles of manganese (VII) ions used. (2 mks)
(e) An indicator is not required for this titration. How can the end point be determined?
(2 mks)
P A
Ammoniated brine
A
Solvey Towers
Ammonioum chloride
Heat Q By-product E
R
F
D
Roaster Slaker T
S G
Soda ash (Na2CO3
(b) Write equations for the reactions taking place at Q and S. (2 mks)
Q–
S–
(c) Name recycled substances and include equations for the reactions. (2 mks)
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
o Write your name and index number in the spaces provided above.
o Answer ALL the questions in the spaces provided.
o Mathematical tables and silent electronic calculators may be used.
o All working MUST be clearly shown where necessary.
o Ensure that all pages are printed as indicated.
FOR EXAMINER’S USE ONLY.
Questions Maximum score Candidates score
1 12
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
A B C D
E F
G
H
(a) Give the name of the family to which element F belongs. (1mk)
(d) Using dot(.) and cross(x) diagram, show the bonding in the compound formed between E
and C. (2mks)
(g) 0.081g of element A reacts with 20cm3 of dilute hydrochloric acid. Calculate the molarity of
the hydrochloric acid. (R.A.M = 27) (3mks)
(h) The graph below shows the trend of the melting points and the boiling points of the family
to which element G belongs. Explain the trend in the melting points. (2mks)
(ii) Calculate the heating value of propane, C3H8, given that its molar enthalpy of
combustion is 2200 kJ mol-1. . (2 mks)
(C=12, H=1)
(ii) Use the information provided by the thermochemical equations below to calculate the
molar enthalpy of combustion of ethyne. (3 mks)
(c) Study the data given below and answer the questions that follow.
(ii) Draw an energy level diagram for the dissolution of calcium chloride in water.
(3 mks)
3. (a) The diagram below shows the preparation of an oxide of nitrogen. Study the diagram and
answer the questions that follow.
Flask M
Mixture of
ammonium
sulphate Heat
and solid D Gas jar
Oxide of nitrogen
(Gas L)
(ii) Write the equation for the reaction in the flask M (1mk)
(iii) Burning magnesium ribbon was lowered into the gas jar containing gas L. State and
explain the observations made. (2mks)
(iv) Write the two equations for the reactions taking place in (iii) above. (2mks)
I.
II.
(v) A drop of water was added to the product formed in (iii) above. A colourless gas K with
a choking smell was produced. Write the chemical equation for the production of gas K
(1mk)
(b) (i) Give two uses for nitric (V) acid. (2mks)
4. A group of form four students of Cockelbet Secondary School carried out an experiment to
determine the solubility of potassium chlorate. The table below shows the results obtained.
(ii) The temperature at which the solubility of KClO3 is 35g/100g water. (1mk)
5. (a) Use the standard reduction potentials for elements P, Q, R, S and T given below to answer
the questions that follow. (The letters do not represent the actual symbols of the elements).
Eθ (Volts)
P2+ (aq) + 2e P (s) - 2.90
Q2+(aq) + 2e Q (s) -2.36
R+ (aq) + e ½R2 (g) 0.00
S2+ (aq) + 2e S (s) + 0.33
½ T2 (g) + e T- (aq) +2.86
(i) Which element is likely to be hydrogen? Give a reason for your answer.
(1½mks)
(iii) A form four student chose S2+(aq) / S(s) as the reference half-cell. Use the space at the
right side of Eθ Volts) to rewrite the Eθ values of the above half-cells. (2½mks)
(iv) In the space provided below draw a labeled diagram of the electrochemical cell that
would be obtained when half-cells of elements Q and S are combined. (3mks)
(b) An iron spoon is placed in an electrochemical cell with AuCl3 solution to be gold plated. How
long must the spoon be in the electrolytic cell if the spoon is to be plated with 0.293 g of Au and the
current of the cell is 1.03A. ( RAM of Au =197; 1F = 96,485 C). (3mks)
Charge
mixture
L Tuyere
s
A
B
A…………………………………………………………………………………………….
B…………………………………………………………………………………………….
(g) Write an equation for the reaction between heated iron and chlorine. (1mk)
(h) Iron-60 is a radioisotope of iron (half-life 2.6 x 106 years). Its ultimate decay product is
nickel-60. Write a nuclear equation for this process.
(Atomic numbers: Fe= 26, Ni= 28) (1mk)
(c) Chlorofluorocarbons have a wide range of uses. However they have been linked to depletion
of ozone.
(i) Explain the problem caused by depletion of ozone layer. (1mk)
(d) Study the flow chart below and use it to answer the questions that follow.
Conc. H3PO4
Propanol Gas A
Heat
Process W
NaOH(aq) NaOH(s)
Propanoic acid B C
Heat
I: Process W (½mk)
A:
B:
C:
(e) Explain how a sample of propan-1-ol could be distinguished from a sample of propanoic acid by
means of a chemical reaction (2mks)
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
INSTRUCTIONS TO CANDIDATES.
o Write your name and index number in the spaces provided above.
o Answer ALL the questions in the spaces provided.
o Mathematical tables and silent electronic calculators may be used.
o All working MUST be clearly shown where necessary.
o Ensure that all pages are printed as indicated.
FOR EXAMINER’S USE ONLY.
Questions Maximum score Candidates score
1 12
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
ii)an equation of the reaction that led to the formation of white precipitate W
(1mk)
e) State the observations that would be made if the product of step III is added ammonia solution
drop wise till in excess.
(1mk)
f) 100cm3 of the blue solution formed in step III was placed in a plastic beaker, its initial
temperature was recorded. Excess magnesium powder was then added and the mixture stirred and
the highest temperature attained recorded. State and explain the observation made in the above
reaction apart from the change in temperature.
(2mk)
2. a) The set up below was used on a sample of an iron iii oxide. Study it and answer the questions
that follow.
iii) Write equations for the two reactions that take place in the combustion tube (2mk)
b) Diamond and graphite are both allotropes of carbon explain using structure and bonding why
diamond is hard while graphite is soft. (2mk)
c) The diagram below was used by a form I student from Rami secondary school to prepare a
certain gas. Study it and answer the questions that follow.
ii) Identify one of its physical properties apart from its solubility in water and one of its uses
(1mk) (1mk)
Property-
d) A student was supplied with a colourless liquid suspected to be water describe one chemical
test that could have been used to show that the liquid was water
(1½ mk)
3. a)Study the set-up below and answer the questions that follow.
vi) Name the process that formed salt K as shown in the diagram. (1mk)
vii) Both blue and red litmus papers had been placed in the water in the trough, state and explain
the observations made at the end of the experiment. (1 ½ mk)
c)A mixture of 70cm3 of chlorine gas and 110cm3 of hydrogen gas were exploded. Calculate the
total volume of the resulting gaseous mixture.
(2mk)
4.The following is an extract of the periodic table. Study it and answer the questions that
follow.(The letters are not the actual symbols of the elements.
b) i)Write the formulae of the compound formed when elements Y and J reacts. ( ½ mk)
c) Compare
i)The atomic radius of elements Z and E (1 ½ mk)
ii)The reactivity of element J with magnesium metal and that of V with magnesium ( 1 ½ mk)
d) The melting point the chloride of G is much higher than that of the chloride of D. Explain this
observation
(2mk)
f) An element M with a relative atomic mass of 15.2 was found to have 2 isotopes, M- 16 and M-
12. Calculate the percentage abundance of each isotope.
(2mk)
i) Draw an energy cycle diagram linking the above enthalpy changes and the enthalpy of
combustion of ethanol
(2mk)
(ii) The sketch below was obtained when the temperature of the mixture were plotted against time.
Study and answer the questions that follow.
iii). If the heat change in the above reaction was 10,500Joules, and the initial temperature for both
solutions was 22.50C calculate;
I) The highest temperature attained by the mixture.(specific heat capacity of the solution = 4.2Jg -
1 -1
K and the density of the solution = 1.0g/cm3 ) (2mk)
III) Explain how the value of the molar heat of neutralization obtained in this experiment would
compare with the one that would be obtained if the experiment was repeated using 100cm3 of 2M
ethanoic acid instead of hydrochloric acid. (2mk)
6. The following are reduction potentials of some elements, study them and answer the questions
that follow.
c) i)Draw a well labelled diagram for the electrochemical cell that would be formed when elements
G and S are combined . (3mk)
d)During the electrolysis of dilute sodium chloride solution using graphite electrodes, a current of
0.8 ampheres was passed through the cell for two and a half hours.
i)Write an ionic equation for the reaction that occurred at cathode (1mk)
ii)Calculate the volume of the gas produced at anode in cm3 .(1F= 96500coulombs,1 mole of gas
at RTP=24dm3) (3mk)
8. A student reacted excess dilute hydrochloric acid with 12.5grams of an impure calcium
carbonate. The volume of carbon (iv) oxide produced was recorded after every thirty seconds .The
data obtained was recorded in the table below. Study it and answer the questions that follow.
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
(i) Select two elements, whose oxides have giant ionic structure (2 marks)
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
(iii) Explain why the melting point of the oxide of A is lower than that of the oxide of C
(2 marks)
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
(iv) State the nature of the solution formed when oxide of D, D2O5 dissolves in water.
(1 mark)
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
(c) When a piece of calcium is placed in cold water, it sinks to the bottom and a colourless gas
that extinguishes a burning splint with a pop sound is produced. Use a simple diagram to
illustrate how this gas can be collected during this experiment. (3 marks)
..............................................................................................................................................................
..............................................................................................................................................................
..............................................................................................................................................................
.............................................................................................................................................................
................................................................................................................................................
................................................................................................................................................
.................................................................................................................................................
.................................................................................................................................................
.................................................................................................................................................
.................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
....................................................................................................................................................
(b) State and explain how propan-1 –ol could be distinguished from propanoic acid (2 marks)
.................................................................................................................................................................
..................................................................................................................................................................
..................................................................................................................................................................
Compound J
Acidified
potassium Step II
dichromate (VI)
Burn
Ethanol Products
Hydrogen
gas Step III
Step I
Step IV
Ethene
Bromine
water Step VI H2/Nickel catalyst/200ºC
Step V
Compound K
Substance L
.....................................................................................................................................
.......................................................................................................................................
(ii) Give the name of the reaction which occurs in step V (1 mark)
.....................................................................................................................................................
(iii) Write the equation for the chemical reaction in step III (1 mark)
......................................................................................................................................................
(iv) Name the reagent(s) and conditions necessary for the reaction step IV
Reagent(s) (1 mark)
..........................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
(d) The two reactions below show how a long chained alkanoic acid can be converted into
detergent M.
Step I
CH2 — C17H35COOH
|
CH — C17H35COOH +3H2O 3C17H35COOH + C3H8O3
|
CH2 — C17H35COOH
Step II
..................................................................................................................................................
(ii) When detergent M is added to a beaker containing hard water a scum is formed. Write
the formula of the scum. (1 mark)
.................................................................................................................................................
.................................................................................................................................................
Gas N Hydrogen
Purifier
Compressor
unreacted gases
Condenser Heat
Exchanger
10%
Liquid ammonia
ammonia
Catalytic
chamber
.........................................................................................................................................
.........................................................................................................................................
(ii) Carbon (IV) oxide, sulphur (VI) oxide and dust are the impurities in this process. Give
a reason why these impurities are removed. (1 mark)
......................................................................................................................................................
......................................................................................................................................................
(iii) Other than iron catalyst, state two optimum conditions for this process (2 marks)
. ..................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
(b) Urea, (CO(NH2)2) is prepared by reacting carbon (IV) oxide and ammonia.
(i) Write an equation for the reaction which occurs. (1 mark)
......................................................................................................................................................
......................................................................................................................................................
(ii) 20 kilograms of urea was applied to a farm and 25 kilograms of ammonium nitrate
applied to another farm. Determine the farm enriched with nitrogen.
(C=12, N = 14, O=16, H =1) (4 marks)
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
......................................................................................................................................................
(c) State and explain what would be observed when aqueous ammonia is added dropwise until in
excess to a solution of copper (II) chloride. (2 marks)
...............................................................................................................................................................
..............................................................................................................................................................
..............................................................................................................................................................
..............................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
Br2 (aq) + H2O (l) OBr - (aq) +Br- (aq) +2H+ (aq)
(Yellow) (colourless)
State and explain the effect of adding sodium hydroxide to the above equilibrium
(2 marks)
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
(b) Colloidal sulphur may be formed by reacting sodium thiosulphate and dilute hydrochloric
acid shown in the equation below.
(i) State and explain the effect of increase in temperature on the rate of the reaction
above. (2 marks)
....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
(ii) Other than temperature name one factor that can alter the rate of the reaction in
b (i) (1 mark)
......................................................................................................................................................
(c) 2.50 grams of a calcium carbonate was reacted with excess 1.8 M hydrochloric acid. The
volume of carbon (IV) oxide evolved measured and recorded at 10 second intervals. The
results were recorded as shown in the table below.
Time (seconds) 0 10 20 30 40 50 60 70 80
volume of gas ( cm3) 0 150 295 420 525 580 600 600 600
(i) (I) On the grid provided, plot a graph of volume (vertical axis) against time.
(3 marks)
(II) From your graph, determine the rate of reaction at 37th second.
(3 marks)
.........................................................................................................................................
.........................................................................................................................................
5. (a) The table below shows the standard reduction potentials for four half cells. Study it and
answer the questions that follow.
…………………………………………………………………………………………………
(ii) Explain why it’s not advisable to store a solution of silver nitrate in a container made
of lead (2 marks)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
(iii) In the space provided, draw a labeled diagram of the electrochemical cell that
would be obtained when half-cell of copper and iron are combined.
(3 marks)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
(b) During the electrolysis of aqueous copper (II) sulphate using copper electrodes, a current
of 0.75 A was passed through the cell for 3 hours and 45 minutes.
(i) Write an ionic equation for the reaction that took place at the anode. (1 mark)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
ii) Determine the change in mass of the anode which occurred as a result of the
electrolysis process. (Cu=63.5 1 F = 96,500C) (3 marks)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………………………………………………………………………………
Oxygen
gas
Limestone Reduction
Chamber
Molten Zinc
(i) Give the formula of the ores;
I zinc blende (1 mark)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
II Calamine (1 mark)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
(iii) Write a chemical equation for the reaction that produces Zinc metal (1 mark)
…………………………………………………………………………………………………
(iv) What is the purpose of adding limestone in the reduction chamber? (1 mark)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
(v) Give two uses of zinc metal other than galvanizing iron (2 marks)
…………………………………………………………………………………………………
(vi)
Name two other industries that can be established alongside the zinc extraction plant
(2 marks)
…………………………………………………………………………………………………………
………………………………………………………………………………………….........................
(vii) State one way in which the extraction of zinc causes air pollution (1 mark)
………………………………………………………………………………………………………….
………………………………………………………………………………………………………….
7 (a) Study the flow chart below and answer the questions that follow.
3 drops of aqueous
Step II
sodium hydroxide
White precipitate T
Colourless solution U
(i) Identify
I Solid Q (1 mark)
........................................................................................................................................
..........................................................................................................................................
...............................................................................................................................................
(iii) Write the ionic equation for the reaction in step II (1 mark)
...................................................................................................................................................
...................................................................................................................................................
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
(b) Calculate the number of sulphate ions present in 24.0 cm3 of 0.25 M aluminium sulphate
solution. (L = 6.0 × 1023) (3 marks)
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
………………………………………………………………………………………………………….
………………………………………………………………………………………………………….
SCHOOL…………………………………………………….. SIGNATURE……………..
233/2
CHEMISTRY
Theory
Paper 2
Time: 2 Hours
INSTRUCTIONS TO CANDIDATES.
o Write your name and index number in the spaces provided above.
o Answer ALL the questions in the spaces provided.
o Mathematical tables and silent electronic calculators may be used.
o All working MUST be clearly shown where necessary.
o Ensure that all pages are printed as indicated.
FOR EXAMINER’S USE ONLY.
Questions Maximum score Candidates score
1 12
2 12
3 10
4 11
5 13
6 11
7 11
Total score 80
A B C D
E F
G
H
(a) Give the name of the family to which element F belongs. (1mk)
(d) Using dot(.) and cross(x) diagram, show the bonding in the compound formed between E
and C. (2mks)
(g) 0.081g of element A reacts with 20cm3 of dilute hydrochloric acid. Calculate the molarity of
the hydrochloric acid. (R.A.M = 27) (3mks)
(h) The graph below shows the trend of the melting points and the boiling points of the family
to which element G belongs. Explain the trend in the melting points. (2mks)
(ii) Calculate the heating value of propane, C3H8, given that its molar enthalpy of
combustion is 2200 kJ mol-1. . (2 mks)
(C=12, H=1)
(ii) Use the information provided by the thermochemical equations below to calculate the
molar enthalpy of combustion of ethyne. (3 mks)
(i) Determine the molar enthalpy of solution of calcium chloride in water. (2 mks)
(ii) Draw an energy level diagram for the dissolution of calcium chloride in water.
(3 mks)
Flask M
Mixture of
ammonium
sulphate Heat
and solid D Gas jar
Oxide of nitrogen
(Gas L)
(ii) Write the equation for the reaction in the flask M (1mk)
(iii) Burning magnesium ribbon was lowered into the gas jar containing gas L. State and
explain the observations made. (2mks)
(iv) Write the two equations for the reactions taking place in (iii) above. (2mks)
I.
II.
(b) (i) Give two uses for nitric (V) acid. (2mks)
(ii) A factory uses nitric (V) acid and ammonia gas as the only reactants for the preparation of
ammonium nitrate. If the daily production of the ammonium nitrate is 4800kg, calculate the
mass of ammonia gas used daily in kg. (N=14.0, O = 16.0 H= 1.0) (3 mks)
4. A group of form four students of Cockelbet Secondary School carried out an experiment to
determine the solubility of potassium chlorate. The table below shows the results obtained.
(ii) The temperature at which the solubility of KClO3 is 35g/100g water. (1mk)
5. (a) Use the standard reduction potentials for elements P, Q, R, S and T given below to answer
the questions that follow. (The letters do not represent the actual symbols of the elements).
Eθ (Volts)
P2+ (aq) + 2e P (s) - 2.90
Q2+(aq) + 2e Q (s) -2.36
R+ (aq) + e ½R2 (g) 0.00
S2+ (aq) + 2e S (s) + 0.33
½ T2 (g) + e T- (aq) +2.86
(i) Which element is likely to be hydrogen? Give a reason for your answer.
(1½mks)
(iii) A form four student chose S2+(aq) / S(s) as the reference half-cell. Use the space at the
right side of Eθ Volts) to rewrite the Eθ values of the above half-cells. (2½mks)
(iv) In the space provided below draw a labeled diagram of the electrochemical cell that
would be obtained when half-cells of elements Q and S are combined. (3mks)
(b) An iron spoon is placed in an electrochemical cell with AuCl3 solution to be gold plated. How
long must the spoon be in the electrolytic cell if the spoon is to be plated with 0.293 g of Au and the
current of the cell is 1.03A. ( RAM of Au =197; 1F = 96,485 C). (3mks)
Charge
mixture
L Tuyere
s
A
B
B…………………………………………………………………………………………….
(d) Write an equation for the reaction that occurs in region L. (1mk)
(g) Write an equation for the reaction between heated iron and chlorine. (1mk)
(h) Iron-60 is a radioisotope of iron (half-life 2.6 x 106 years). Its ultimate decay product is
nickel-60. Write a nuclear equation for this process.
(Atomic numbers: Fe= 26, Ni= 28) (1mk)
(c) Chlorofluorocarbons have a wide range of uses. However they have been linked to depletion
of ozone.
(i) Explain the problem caused by depletion of ozone layer. (1mk)
NaOH(aq) NaOH(s)
Propanoic acid B C
Heat
(i) Name:
I: Process W (½mk)
A:
B:
C:
(e) Explain how a sample of propan-1-ol could be distinguished from a sample of propanoic acid by
means of a chemical reaction (2mks)