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Encyclopedia of
Aluminum and
Its Alloys
Encyclopedia of
Aluminum and
Its Alloys
Edited by
George E. Totten, Murat Tiryakioğlu, and
Olaf Kessler
CRC Press
Taylor & Francis Group
6000 Broken Sound Parkway NW, Suite 300
Boca Raton, FL 33487-2742
This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been
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v
vi Brief Contents
Volume I (cont’d.)
Friction Stir Processing: Effect on Melt-Stirring Method: Influence on Ingot Purity
Microstructure and Mechanical Properties in During Ohno Continuous Casting . . . . . . . . . . 1446
Cast Aluminum Alloys . . . . . . . . . . . . . . . . . . . . 1037 Metal Casting Research: Application to
Friction Welding of Al2O3P/6061 Aluminum Aluminum Alloy Casting . . . . . . . . . . . . . . . . . . 1456
Alloy Composite to 5052 Aluminum Alloy . . . 1049 Metallic Coatings for Brazing Aluminum
Grain Refinement and Strengthening of Alloys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461
Aluminum Alloys: Cold Severe Plastic
Deformation Model . . . . . . . . . . . . . . . . . . . . . . 1054
Grain Refinement of Cast Aluminum by Volume II
Heterogeneous Nucleation Sites . . . . . . . . . . . . 1069
Graphene-Reinforced Aluminum Matrix Metallography of Aluminum Alloys: Atlas of
Nanocomposites: Structure and Properties . . . 1085 Microstructures . . . . . . . . . . . . . . . . . . . . . . . . . 1465
Hall–Heroult Process . . . . . . . . . . . . . . . . . . . . . . . 1099 Metallurgy of Continuous Hot Dip
Hall–Petch Relationship in Aluminum and Aluminizing . . . . . . . . . . . . . . . . . . . . . . . . . . 1486
Aluminum Alloys . . . . . . . . . . . . . . . . . . . . . . . . 1104 Metallurgy of Quenching Aluminum Alloys . . . . 1511
Hardening, Annealing, and Aging . . . . . . . . . . . . 1123 Microgravity Crystallization for High-Tech
Hardness–Yield Strength Relationships in Castings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1535
Al-Zn-Mg(-Cu) Alloys . . . . . . . . . . . . . . . . . . . . 1149 Micromachining of Aluminum Alloys . . . . . . . . . 1557
Heat-Treatable Aluminum Alloys: Three-Point Microstructural Changes During Annealing of
Bending . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1155 Aluminum Alloy: Modeling . . . . . . . . . . . . . . . 1592
High-Pressure Die-Cast AlSi9Cu3 (Fe) Alloys: Microstructural Evolution During Solution
Models for Casting Defects and Mechanical Treatment of ADC12 (A383) Alloy Die
Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1162 Castings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1605
High-Speed Computer Tomography: Pressure Microstructure and Microhardness of
Die Casting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1173 AlZnMnMg Alloys during Heat Treatment . . 1613
Hipping Evaluation in Cast Aluminum Alloys: Microstructure and Properties of Friction Stir
Quality Index-Based Approach . . . . . . . . . . . . 1186 Welded Aluminum Alloys . . . . . . . . . . . . . . . . . 1621
Early History of Aluminum Metallurgy . . . . . . . . 1194 Microstructure and Yield Strength Evolution of
Homogeneous Modifier-Treated AlSi10Mg Alloy: Aluminum Alloys . . . . . . . . . . . . . . . . . . . . . . . . 1627
Microstructure and Mechanical Properties . . . 1206 Microstructure Imaging, Precipitation
Honeycomb Composite Structures of Aluminum: Formation and Mechanical Properties: Al–Li
Aerospace Applications . . . . . . . . . . . . . . . . . . . 1213 and Al–Mg–Zn Alloys . . . . . . . . . . . . . . . . . . . . 1648
Hot Stamping of Complex-Shaped High- Microstructure of Al-Cu, Al-Zn, Al-Ag-Zn,
Strength Aluminum Components . . . . . . . . . . . 1244 and Al-Zn-Mg Alloys . . . . . . . . . . . . . . . . . . . . . 1659
Hot Tear Nucleation During Solidification of Microstructure of Aluminum Alloys: Effect of
Aluminum and Its Alloys . . . . . . . . . . . . . . . . . . 1263 Hardening Conditions . . . . . . . . . . . . . . . . . . . . 1675
Hypoeutectic Al–Fe Alloys: Formation and MIG Welding of Aluminum Alloys . . . . . . . . . . . . 1685
Characterization of Intermetallics by Molten Aluminum: Inductive Technique for
Dissolution of the Al Matrix . . . . . . . . . . . . . . . 1270 Electrical Conductivity Measurements . . . . . . 1689
Image Processing for Fault Detection in Molten Metal Processing . . . . . . . . . . . . . . . . . . . . 1698
Aluminum Castings . . . . . . . . . . . . . . . . . . . . . . 1287 Nanocomposites with Aluminum Matrix:
Intermetallics of Aluminum . . . . . . . . . . . . . . . . . 1312 Preparation and Properties . . . . . . . . . . . . . . . . 1725
Introduction to Aluminum . . . . . . . . . . . . . . . . . . . 1327 Nanoparticle Aluminum Preparation . . . . . . . . . . 1738
Ionic Liquids in Surface Protection of Aluminum Nanostructured Aluminum Films: Deep
and Its Alloys . . . . . . . . . . . . . . . . . . . . . . . . . . . 1346 Ultraviolet Absorption from Glancing Angle
Iron: Removal from Aluminum . . . . . . . . . . . . . . 1356 Physical Vapor Deposition . . . . . . . . . . . . . . . . . 1763
Machining . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1390 Nanostructured Ni/Al2O3 Interlayer: Transient
Master Alloys for Grain Refinement . . . . . . . . . . . 1417 Liquid Phase Diffusion Bonding of
Al6061-MMC . . . . . . . . . . . . . . . . . . . . . . . . . . . 1767
Melt Quality Assessment . . . . . . . . . . . . . . . . . . . . 1430
Brief Contents vii
Welding Parameters for Aluminum Alloys . . . . . 2835 X-Ray Diffraction Analysis of the
Welding Technology: Gas Chromatography in . . . 2856 Microstructure of Precipitating Aluminum-
Welding: Particulate and Gaseous Emissions . . . 2860 Based Alloys . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2883
Wrought Aluminum Alloy: Reinforcement,
Alloy Addition, and Deformation Effects on
Mechanical Responses . . . . . . . . . . . . . . . . . . . . 2871
Encyclopedia of Aluminum and Its Alloys
Editor-in-Chief
George Totten
Portland State University
Murat Tiryakioğlu
University of North Florida
Olaf Kessler
Materials Science, Faculty of Mechanical Engineering and Marine Technology
Universitat Rostock
I.S. Jawahir
Xinjin Cao James F. Hardymon Chair in Manufacturing
Structures, Materials and Manufacturing Systems
Laboratory Director, Institute for Sustainable Manufacturing
National Research Council Canada – (ISM)
Aerospace
Laurens Katgerman
Namas Chandra Materials Science & Engineering (MSE)
Department of Biomedical Engineering Delft University of Technology
Newark College of Engineering
Joseph W. Newkirk
X. Grant Chen Missouri University of Science and Technology
University of Quebec at Chicoutimi
ix
x Editor-in-Chief
Valery Rudnev
Director, Science and Technology
Inductoheat, Inc
Contributors xi
Contributors
Pramod Koshy / School of Materials Science and Engineering, University of New South
Wales, Sydney, Australia
Jure Krolo / Faculty of Electrical Engineering, Mechanical Engineering and Naval
Architecture, University of Split, Split, Croatia
Lenka Kuchariková / Department of Materials Engineering, University of Žilina, Žilina,
Slovakia
Howard A. Kuhn / Scienda Building Sciences, Orangeburg, South Carolina, U.S.A.
Katrin Kuhnke / Metallurgical and Material Engineering, Yildiz Technical University,
Istanbul, Turkey
Mukul Kumar / Industrial Systems Engineering, October University for Modern Sciences
and Arts, 6 October City, Egypt
Daniel Larouche / Department of Mining, Metallurgy and Materials Engineering,
Université Laval, Québec, Canada
T. Latouche / Ecole Nationale Supérieure Maritime (ENSM), France
Branimir Lela / Faculty of Electrical Engineering, Mechanical Engineering and Naval
Architecture, University of Split, Split, Croatia
Janos Lendvai / Department of Materials Physics, Eotvos Lorand University, Budapest,
Hungary
Xiuhui Li / Beijing Institute of Aeronautical Materials, Beijing, China
Jinbo Li / Huazhong University of Science and Technology, Wuhan, Hubei, China
Heng Li / Northwestern Polytechnical University, Xi’an, Shaanxi, China
Kai Li / State Key Laboratory of Powder Metallurgy, Central South University, Changsha,
China
Hyun-Kyu Lim / Korea Institute of Industrial Technology, Incheon, Republic of Korea
Jianguo Lin / Department of Mechanical Engineering, Imperial College London, London,
U.K.
Zuoming Lin / Aviation Industry Corporation of China, Beijing, China
Frank Liou / Department of Mechanical and Aerospace Engineering, Missouri University
of Science and Technology, Rolla, Missouri, U.S.A.
Tomasz Lipiński / Faculty of Technical Sciences, University of Warmia and Mazury in
Olsztyn, Olsztyn, Poland
Jun Liu / Department of Mechanical Engineering, Imperial College London, London,
U.K.
Kejia Liu / School of Metallurgy and Materials, Northeastern University, Shenyan, China
Alsten Clyde Livingstone / School of Civil and Environmental Engineering, University of
Technology Sydney, Ultimo, Australia; Perfect Engineering Pty. Ltd., Henley, Australia
Chris Loader / Defence Science and Technology, Fishermans Bend, Australia
Ana López-Oyama / CICATA-Altamira, IPN, Altamira, Mexico
Enrique Louis / Centre for Engineered Coatings, International Advanced Research Centre
for Powder Metallurgy and New Materials, Hyderabad, Telangana, India
Diego Lozano / División de Extensión, Consultoría e Investigación, Universidad de
Monterrey, San Pedro Garza García, Mexico
Wei Hua Lu / Institute of Materials Science and Engineering, Donghua University
Yan’anlu Campus, Shanghai, China
Xingmei Lu / Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key
Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase
Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences,
Beijing, China
Contributors xvii
Xiangping Zhang / Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key
Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase
Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences,
Beijing, China
Xiaoyan Zhang / Beijing Institute of Aeronautical Materials, Beijing, China
Kun Zhao / School of Metallurgy and Materials, Northeastern University, Shenyan, China
Shuangzan Zhao / Beijing Institute of Aeronautical Materials, Beijing, China
M. I. Zotov / E 0 Paton Welding Institute, Academy of Sciences of the Ukrainian SSR,
Ukraine
Contents
Contributors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xi
Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxxi
About the Editors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxxiii
Volume I
6XXX Alloys: Chemical Composition and Heat Treatment / Grażyna Mrówka-Nowotnik . . . . . . 1
Additive Manufacturing of Aluminum Alloys / Sriram Praneeth Isanaka, Sreekar Karnati, and
Frank Liou . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Aerospace Fasteners: Use in Structural Applications / George Nadim Melhemt . . . . . . . . . . . . . . . 30
Aircraft Structural Integrity: Corrosion Effects / Bruce Crawford, Chris Loader, and Timothy
J. Harrison . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
Al-Mg-Si: Microstructural Analysis / Marcello Cabibbo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60
Analytical Techniques for Aluminum / Alexis Deschamps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Anisotropic Yield Criteria for Aluminum Alloy Sheets / Dorel Banabic, Dan Sorin Comsa, and
Tudor Balan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
Anodic Oxides: Applications and Trends in Nanofabrication / W.J. Stepniowski . . . . . . . . . . . . . 107
Arc-Welding: Lithium-Containing Aluminum Alloys / V. I. Ryazantsev and V. A. Fedoseev . . . . . 130
As-Cast Grain Size of Aluminum Alloys Refined by Al-Ti-B Master Alloys / Mark Easton,
David St John, and Arvind Prasad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135
Atom Probe Characterization of Nanoscale Precipitates in Aluminum Alloys / K. Hono . . . . . . . 146
Bayer Process / Diego Lozano, Gabriela M. Martínez-Cázares, and Miguel Bocanegra . . . . . . . . . . 163
Brazing Aluminum in Low Vacuum / B. N. Perevezentsev, N. M. Sokolova, and G. A. Telitsyna . . 168
Brazing of Aluminum Alloys / Y. Sugiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171
Bulk Metallic Glasses: Aluminum-Based / B.J. Yang, J.H. Yao, J.Q. Wang, Y.S. Chao, and E. Ma . . 183
Calcium-Containing Aluminum Alloys / Torgom Akopyan, Nikolay Belov, and Evgenia Naumova . . . 192
Carbothermic Reduction Methods for Alumina / Efthymios Balomenos and Dimitrios Gerogiorgis . . . 207
Cast Al-Si-Cu Alloys: Effect of Modification on Thermal and Electrical Conductivities / Carlos
Huitrón, Eduardo Valdés, Salvador Valtierra, and Rafael Colás . . . . . . . . . . . . . . . . . . . . . . . . . . . 220
Casting Designs / Henry W. Stoll . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227
Castings / Rafael Colás, Eulogio Velasco, and Salvador Valtierra . . . . . . . . . . . . . . . . . . . . . . . . . . . 248
Castings: Ten Rules for Good Castings / John Campbell . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275
Chemical Milling of Aluminum / Bruce M. Griffin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 280
Computer Vision for Fault Detection in Aluminum Castings / Domingo Mery . . . . . . . . . . . . . . . 332
Control Principle of Thermal Spray Process / Masahiro Fukumoto . . . . . . . . . . . . . . . . . . . . . . . . . 378
Corrosion and Wear Protection through Micro Arc Oxidation Coatings in Aluminum and Its
Alloys / L. Rama Krishna and G. Sundararajan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 386
Corrosion Inhibitors: Effect on Aluminum Alloys / Feyisayo Victoria Adams, Mbali Mokgatla,
Abubakar Ishak, Chukwuma Valentine Onwujiuba, Pwafureino Reuel Moses, and Utseoritselaju
Okorodudu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 400
Corrosion of Aluminum and Its Alloys / T. David Burleigh . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 410
Corrosion Protective Coatings: Fabrication of Sputtered CeO2-La2O3 and La2O3 -CeO2
Bilayers / Miguel Antonio Dominguez-Crespo, Silvia Brachetti-Sibaja, Aide Torres-Huerta,
Edgar Onofre, Ana Lopez-Oyama, and Sandra Rodil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 434
xxv
xxvi Contents
Volume I (cont’d.)
Corrosion-Induced Hydrogen Embrittlement in AA2024 / G.N. Haidemenopoulos and Helen
J. Kamoutsi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 454
Creation of Master Alloys for Aluminum / Michael M. Gasik and Vladislav I. Mazur . . . . . . . . . . 468
The Crystallography of Aluminum and Its Alloys / Philip N.H. Nakashima . . . . . . . . . . . . . . . . . . 488
Defects in Aluminum Alloy Castings / John Campbell . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 587
Design of Aluminum Rolling Processes for Foil, Sheet, and Plate / Julian H. Driver and Olaf Engler . . . . 593
Design of Forming Processes: Sheet Metal Forming / T. Wanheim . . . . . . . . . . . . . . . . . . . . . . . . . 633
Designing for Aluminum / Howard A. Kuhn . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 655
Designing with Aluminum Alloys / Nack J. Kim . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 674
Die Casting Process Design / Frank E. Goodwin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 702
Diesel Engine: Applications of Aluminum Alloys / Mihriban Pekguleryuz, Erol Ozbakir, and
Amir Rezaei Farkoosh . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 743
Diffusion Bonding of A2017 Aluminum Alloys / T. Latouche, M. Cailler, B. Sander, and S.K. Marya . . . 763
Dispersoid Precipitation in Aluminum Alloys / Joseph D. Robson . . . . . . . . . . . . . . . . . . . . . . . . . . 770
Ductility–Fatigue Life Relationships in Aluminum Alloy Castings: Role of Structural
Quality / Murat Tiryakioğlu and Hüseyin Özdeş . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 778
Electrical Conductivity of Aluminum Alloy A2011 / Sayavur Bakhtiyarov and Ruel Overfelt . . . . 784
Electrical Resistivity of Al-Cast Alloys in the Range of Solidification / Mitja Petric, Jožef
Medved, Sebastjan Kastelic, Maja Vončina, and Primož Mrvar . . . . . . . . . . . . . . . . . . . . . . . . . . . . 793
Electrochemical Study of Potassium Fluoride in a Cryolite-Aluminum Oxide Molten
Salt / Shaohu Tao, Jianping Peng, Yuezhong Di, Kejia Liu, Kun Zhao, and Naixiang Feng . . . 801
Electrodeposition of Aluminum in Ionic Liquids / Qian Wang, Suojiang Zhang, Xingmei Lu, and
Xiangping Zhang . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 808
Electron Backscatter Diffraction / David P. Field and Mukul Kumar . . . . . . . . . . . . . . . . . . . . . . . . 823
Electron Beam Welding of Aluminum Alloys / Mohamed Sobih and Zuhair Elseddig . . . . . . . . . . 859
Electron-Beam Welding of Thick Components of Steels, Aluminum, and Titanium
Alloys / V.N. Martynov, A.S. Khokhlovskii, and A.P. Sliva . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 870
Entrainment Defects / J. Campbell . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 873
Extractive Metallurgy of Aluminum / Fathi Habashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 893
Extrudable Al-Si-Mg Alloys: Simulation of Microsegregation and Homogenization /
G.N. Haidemenopoulos and Panagiota Sarafoglou . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 919
Extrusion / Sigurd Stvren and Per Thomas Moe . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 931
Fatigue Endurance under Torsion Testing: 6061-T6 and 6063-T5 Aluminum Alloys / Jorge
L. Avila Ambriz, Erasmo Correa Gómez, Julio C. Verduzco Juárez, Gonzalo M. Dominguez
Almaraz, and Aymeric E. Dominguez . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 992
Fatigue Lifetime Improvement of Aluminum Alloys / Patiphan Juijerm and Berthold Scholtes . . 1000
Field Trials of Aerospace Fasteners in Mechanical and Structural Applications / George Nadim
Melhem, Paul Richard Munroe, Charles Christopher Sorrell, and Alsten Clyde Livingstone . . . . . 1007
Forging / Kichitaro Shinozaki and Kazuho Miyamoto . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1022
Friction Stir Processing: Effect on Microstructure and Mechanical Properties in Cast Aluminum
Alloys / Murat Tiryakioglu and Nelson Netto . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1037
Friction Welding of Al2O3P/6061 Aluminum Alloy Composite to 5052 Aluminum Alloy /
K. Kato and H. Tokisue . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1049
Grain Refinement and Strengthening of Aluminum Alloys: Cold Severe Plastic Deformation
Model / Xiao Guang Qiao, Nong Gao, and Marco Starink . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1054
Grain Refinement of Cast Aluminum by Heterogeneous Nucleation Sites / Yoshimi Watanabe
and Hisashi Sato . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1069
Contents xxvii
Volume II
Metallography of Aluminum Alloys: Atlas of Microstructures / S.V.S. Narayana Murty, Sushant
K. Manwatkar, and P. Ramesh Narayanan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1465
Metallurgy of Continuous Hot Dip Aluminizing / R. W. Richards, H. Clarke, R. D. Jones, and
P. D. Clements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1486
xxviii Contents
Volume II (cont’d.)
Metallurgy of Quenching Aluminum Alloys / Ralph T. Shuey and Murat Tiryakioğlu . . . . . . . . . . 1511
Microgravity Crystallization for High-Tech Castings / Hans M. Tensi . . . . . . . . . . . . . . . . . . . . . . 1535
Micromachining of Aluminum Alloys / Ann Rumsey and Muhammad Jahan . . . . . . . . . . . . . . . . . 1557
Microstructural Changes During Annealing of Aluminum Alloy: Modeling / Soheila
Shabaniverki and S. Serajzadeh . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1592
Microstructural Evolution During Solution Treatment of ADC12 (A383) Alloy Die
Castings / Gil-Yong Yeom, Ghasem Eisaabadi Bozchaloei, Hyun-Kyu Lim, Shae Kwang Kim,
Young-Ok Yoon, Soong-Keun Hyun, Nelson Netto, and Murat Tiryakioğlu . . . . . . . . . . . . . . . . . . . 1605
Microstructure and Microhardness of AlZnMnMg Alloys during Heat Treatment / S. Valdez-
Rodríguez, B. Campillo, and J. Islas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1613
Microstructure and Properties of Friction Stir Welded Aluminum Alloys / Izabela Kalemba
and Stanisław Dymek . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1621
Microstructure and Yield Strength Evolution of Aluminum Alloys / Kai Li, Yong Du, and Min
Song . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1627
Microstructure Imaging, Precipitation Formation and Mechanical Properties: Al–Li and Al–Mg–
Zn Alloys / Wilfried Wunderlich, Janos Lendvai, and Hans-Joachim Gudladt . . . . . . . . . . . . . 1648
Microstructure of Al-Cu, Al-Zn, Al-Ag-Zn, and Al-Zn-Mg Alloys / Stanko Popović and Željko
Skoko . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1659
Microstructure of Aluminum Alloys: Effect of Hardening Conditions / Hülya Demirören . . . . . 1675
MIG Welding of Aluminum Alloys / K. Yasuda . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1685
Molten Aluminum: Inductive Technique for Electrical Conductivity Measurements / Sayavur
Bakhtiyarov and Ruel Overfelt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1689
Molten Metal Processing / Ryotatsu Otsuka . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1698
Nanocomposites with Aluminum Matrix: Preparation and Properties / Jacopo Fiocchi,
Riccardo Casati, and Maurizio Vedani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1725
Nanoparticle Aluminum Preparation / Soma Venugopal Rao, Krishnamurthi Muralidharan, and
Anuj A. Vargeese . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1738
Nanostructured Aluminum Films: Deep Ultraviolet Absorption from Glancing Angle Physical
Vapor Deposition / Stephen Stagon and Ryan Scherzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1763
Nanostructured Ni/Al2O3 Interlayer: Transient Liquid Phase Diffusion Bonding of Al6061-
MMC / Kavian Cooke and Tahir Khan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1767
Nodular Silicon Al–(12–30) % Si Alloys: Microstructure, Mechanical Properties and Fracture
Behaviors / Ruyao Wang and Wei Hua Lu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1779
Non-Heat Treatable Al-Alloys: Development of Intermetallic Particles during Solidification and
Homogenization / Olaf Engler, Katrin Kuhnke, and Jochen Hasenclever . . . . . . . . . . . . . . . . . 1797
Open-Cell Foam Metal Production and Characterization by Aluminum Solid Mold Investment
Casting / Kerem Altug Guler . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1816
Optical Microstructures of Aluminum Alloys / S.V.S. Narayana Murty, Sushant Manwatkar, and
Ramesh Narayanan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1822
Plasma Electrolytic Oxidation (PEO) Coatings on Aluminum Alloys: Kinetics and Formation
Mechanism / Alex Lugovskoy and Lyubov Snizhko . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1903
Plasma Surface Treatment: Effects on Mechanical and Corrosion Protection Properties of Hybrid
Sol–Gel Coatings / R. Subasri . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1922
Plastic Flow of Aluminum in Explosive Welding / V. G. Petushkov, M. I. Zotov, and L. D.
Dobrushin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1929
Polyphase Eutectics of Aluminum Alloys: Effect of Phase Composition / Malgorzata Warmuzek . . 1932
Porosity Development and Modification in Al-Si Alloys: Effect of P and Sr / J. Campbell and
Murat Tiryakioğlu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1951
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Before the workmen from the United States arrived here a large
part of the bridge material was already in Mombasa. The Americans
left one man there to see that additional materials were forwarded
promptly, and came at once to the scene of action. They put up the
bridges at the rate of something like one a week, and constructed
the longest viaduct in sixty-nine and one half working hours.
What they did forms one of the wonders of civil and mechanical
engineering. The bridge material was so made that its pieces fitted
together like clockwork, notwithstanding the fact that it was put into
shape away off here, thousands of miles from the place of
construction and in one of the most uncivilized parts of the world.
The materials in the viaducts included about half a million feet of
southern pine lumber and over thirteen million pounds of steel. The
steel was in more than one hundred thousand pieces and the
heaviest piece weighed five tons. The average weight was about one
hundred pounds. The greatest care had to be taken to keep the parts
together and in their own places. Every piece was numbered and
those of different bridges were painted in different colours. At that, it
was hard to keep all the parts together, for, since most of the natives
here look upon steel as so much jewellery, it was all but impossible
to keep them from filching some of the smaller pieces for ear bobs
and telegraph wire to make into bracelets.
Besides all the other tremendous difficulties in building this road,
there were the wild beasts. There are a hundred places along it
where one might get off and start up a lion. Rhinoceroses have
butted the freight cars along the track, and infest much of the country
through which it goes. I was shown a station yesterday where
twenty-nine Hindus were carried off by two man-eating lions. Night
after night the man-eaters came, taking away each time one or two
of the workmen from the construction camp. They were finally killed
by an English overseer, who sat up with his gun and watched for
them.
It was not far from this station of Nairobi that a man was taken out
of a special car while it stopped overnight on the side track. The
windows and doors of the car had been left open for air, and the
three men who were its only inmates had gone to sleep. Two were in
the berths while the other, who had sat up to watch, was on the floor
with his gun on his knees. As the night went on he fell asleep, and
woke to find himself under the belly of a lion. The beast had slipped
in through the door, and, jumping over him, seized the man in the
lower berth and leaped out of the window, carrying him along. The
other two men followed, but they failed to discover the lion that night.
The bones of the man, picked clean, were found the next day.
An interesting “by-product” of the construction of the Uganda road
has been the development of the native labourer. Twenty years ago
the saying was: “Native labour is of little value, no dependence can
be placed upon it, and even famine fails to force the tribesmen to
seek work.” To-day that opinion has yielded to the belief that, if he is
properly trained and educated to it, the native can supply labour,
skilled and unskilled, for all manufacturing and industrial enterprises
of Kenya Colony. Remarkable progress in industrial education is
shown by the nine thousand African workers on the Uganda line.
CHAPTER XXXI
THE CAPITAL OF KENYA COLONY
In Nairobi the popular way to travel is in jinrikishas much like those of Japan but
sometimes made in America. Two good-natured Negroes man each one and sing
a monotonous song as they trot uphill and down.
The African smell is everywhere. It burdens the air of the market
places, and I verily think it might be chopped up into blocks and sold
as a new kind of phosphate. The natives cover themselves with hair
oil and body grease, and the combination of this when it turns rancid
with the natural effluvia which exhales from their persons is
indescribable. Some of the blacks smear their faces with a mixture of
grease and red clay, and cover their hair with the same material, so
that they look more like copper Indians than Africans.
These Africans do all the hard work of Nairobi. They are hewers of
wood and drawers of water. I see scores of them, carrying baskets of
dirt on their heads and bundles of wood on their backs and pushing
and pulling carts and wagons through the streets. Most of my trips
from one place to another are made in two-wheeled carts hauled by
wire-bedecked natives.
The retail business is done by East Indians, as is also the case at
Mombasa. I am told this is so in every settlement on this part of the
continent. The Hindus have made their way along all the travelled
routes, until their little stores may be found in every large African
village. They have trading stations upon Lakes Victoria and
Tanganyika. They are very enterprising, and as they live upon almost
nothing they can undersell the whites. They sell cotton of bright
colours and of the most gorgeous patterns, wire for jewellery, and all
sorts of knickknacks that the African wants. They deal also in
European goods, and one can buy of them almost anything from a
needle to a sewing machine. Here at Nairobi there is an Indian
bazaar covering nine acres which is quite as interesting as any
similar institution in Tunis, Cairo, Bombay, or Calcutta. The stores
are all open at the front, and the men squat in them with their gay
goods piled about them. These Hindus dress in a quaint costume not
unlike that of the English clergyman who wears a long black coat
buttoned up to the throat. The only difference is that the Hindu’s
trousers may be of bright-coloured calico, cut very tight, and his
head may be covered with a flat skullcap of velvet embroidered in
gold. Moreover, his feet are usually bare.
But Nairobi is a British city, notwithstanding its African and Asiatic
inhabitants; the English form the ruling class. They are divided into
castes, almost as much as are the East Indians. At the head are the
government officials, the swells of the town. They dress well and
spend a great deal of time out of office hours playing tennis and golf,
which have already been introduced into this part of the black
continent. They also ride about on horseback and in carriages, and
manage to make a good show upon very low salaries. Allied to them
are the sportsmen and the noble visitors from abroad. A scattering
element of dukes, lords, and second sons of noble families has
come out to invest, or to hunt big game. They are usually men of
means, for the prices of large tracts of land are high and it also costs
considerable money to fit out a game-shooting expedition. In
addition, there are land speculators, who are chiefly young men from
England or South Africa. Dressed in riding clothes, big helmet hats,
and top boots, they dash about the country on ponies, and are
especially in evidence around the bars of the hotels. There are but
few white women here. Some of the government officials have their
wives with them, and now and then a titled lady comes out to hunt
with her friends. I met three women who had themselves shot lions.
Nairobi has English doctors, dentists, and lawyers. It has one
photographer and two firms which advertise themselves as safari
outfitters. These men supply sportsmen with tents, provisions, and
other things for shooting trips, as well as porters to carry their stuff
and chase the lions out of the jungles so that the hunters may get a
shot at them.
It seems strange to have newspapers under the shadow of Mt.
Kenya, and within a half day’s ride on horseback to lion and
rhinoceros hunting. Nevertheless, Nairobi has three dailies, which
also issue weekly editions. They are all banking on the future of the
town and all claim to be prosperous. They are good-sized journals,
selling for from two to three annas, or from four to six cents each.
They have regular cable dispatches giving them the big news of the
world, and they furnish full reports of the local cricket, polo, tennis,
and golf matches. As for the advertisements, most of them come
from the local merchants and some are odd to an extreme. One of
to-day’s papers carries an advertisement signed by a well-known
American circus company which wants to buy a white rhinoceros, a
giant hog, some wild dogs, a wild-tailed mongoose, and a bongo.
Another advertisement, one made along farming lines, is that of the
Homestead Dairy, and others state that certain merchants will outfit
hunters for shooting. There are many land sales advertised, as well
as machinery, American wagons, and all sorts of agricultural
implements.
Nairobi has several hotels, the accommodations in which are
comfortable. I am stopping at the Norfolk at the upper end of the
town. It is a low one-story building with a wide porch in front,
separated from the dirt street by a picket fence, and shaded by
eucalyptus trees through which the wind seems to be ever sighing
and moaning. The charges are three dollars and thirty-three cents a
day, including meals, but I have to have my own servant to make my
bed and run my errands. I have a room at the back with a fine view
of the stable. A German sportsman next door has a little cub lion,
about as big as a Newfoundland dog, tied in a box outside his
window. During a part of the day he lets the baby lion out, and ties
him by a rope to one of the pillars of the porch. The animal seems
harmless, but its teeth are sharp, and it is entirely too playful to suit
me. Besides, it roars at night.
To be a Swahili, a professing Mohammedan, and boy to a white man give three
strong claims to distinction in African society. This chap is proud of his white men’s
clothes and will steal soap to wash them.
Many Europeans have taken up farms in the vicinity of Naivasha, where the flat,
grassy land is suitable for sheep. Though almost on the Equator, the altitude of
more than 6,000 feet makes the climate tolerable for white men.
John Bull designs his public buildings in Africa with a view to making an
impression on the native. His Majesty’s High Court of Kenya Colony, sitting at
Mombasa, administers both British and Koranic laws.
The horses are fairly good here, but the charges for them are
steep. When I ride out on horseback it costs me a dollar and sixty-
five cents an hour, and the carriage rates are still higher. The best
way to get about is in the jinrikishas, using the natives as beasts of
burden, but for a long ride over the plains horses are necessary.
The heavy hauling of this part of East Africa is done mostly by the
sacred cattle of India. I mean the clean-cut animals with great humps
on their backs. They are fine-looking and are apparently well-bred.
Some of these beasts are hitched to American wagons brought out
here from Wisconsin. I saw such a team hauling a Kentucky plough
through the streets of Nairobi yesterday.
Indeed, I find that American goods are slowly making their way
into these wilds. American axes and sewing machines, and
American sowers and planters are sold by the East Indians. The
drug stores carry our patent medicines and every market has more
or less American cottons. The wood cutters are using American
axes, but they complain of the flat or oval holes made for the
handles. They say that a round hole would be better, as the natives
who do the wood cutting are very clumsy and the handles snap off at
the axe. If round holes were used, heavier handles could be put in
and the Negroes could make them themselves.
Nairobi promises to become one of the railroad centres of this part
of the world. It is the chief station between the Indian Ocean and
Lake Victoria, and a road is now proposed from here to Mt. Kenya.
The Uganda Railway goes through some of the poorest country in
the colony, and the Mt. Kenya road will open up a rich agricultural
region which is thickly populated by tribes more than ordinarily
industrious. The railroad shops are here, and the employees have a
large collection of tin cottages for their homes. The headquarters of
the railroad, where the chief officers stay, are one-story tin buildings.
The telegraphic offices are connected with them.
Both railroad and telegraph are run by the government. The
telegraphic rates are comparatively low. Far off here in the jungles of
Africa one can send messages much more cheaply than in the
United States. A message of eight words from here to Uganda costs
thirty-three cents, and one can telegraph to London about as cheaply
as from New York to San Francisco. This is so notwithstanding the
difficulty which the linemen have to keep up the wires, which the
jewellery-loving natives steal. During the Nandi rebellion, forty-odd
miles of it were carried away and never recovered, and in one of the
provinces adjoining Uganda, above Lake Victoria, the natives are so
crazy after the copper wire there used that it is almost impossible to
keep the lines in shape.
Another serious danger to the telegraph is the big game. The
giraffes reach up and play with the brackets and pull the wire this
way and that. At Naivasha the hippopotami have once or twice
butted down the poles, and I hear they have been doing
considerable damage to the lines along the coast near the Tana
River. In the heart of Uganda the monkeys have a way of swinging
on the wires and twisting them together, which stops the
transmission of messages, so that the way of the lineman is indeed
hard.
CHAPTER XXXII
JOHN BULL IN EAST AFRICA
I have just had a long talk with Mr. Frederick J. Jackson, the acting
governor and commander-in-chief of this big territory which John Bull
owns in the heart of East Africa. Mr. Jackson came out here to hunt
big game years ago, and he has been on the ground from that time
to this. He has long been employed by the British Government in the
administration of Uganda and of the protectorate of East Africa, and
he is now lieutenant-governor in the absence of Colonel Sadler, the
acting governor of the country.
Let me give you some idea of this vast region which the British are
opening up in the midst of the black continent. This country
altogether is larger than the combined states of Ohio, Indiana,
Illinois, and Wisconsin. It has a population of four million natives,
most of whom not so long ago were warring with one another. Some
of the tribes made their living by preying upon their neighbours.
Slavery was everywhere common, and one of the great slave routes
to the coast was not far from the line where the Uganda railway now
runs. To-day all these evils have been done away with. The warlike
tribes have been conquered, and are turning their attention to stock
raising and farming. Slavery has been practically abolished, and
peace prevails everywhere. The whole country is now kept in good
order by only about eighteen hundred police and less than two
thousand English and East Indian soldiers. A large part of the region
along the line of the railroad has been divided into ranches and
farms. Small towns are springing up here and there, and in time the
greater part of the plateau will be settled.
There is no doubt that white men can live here. The children I see
are rosy with health, and the farmers claim that, with care, they are
as well as they were when back home in England. There are some
Europeans here who have had their homes on the highlands for over
twelve years, and they report that the climate is healthful and
invigorating. They are able to work out of doors from six until ten
o’clock in the morning and from three to six o’clock in the afternoon,
and during a part of the year all the day through. As a rule, however,
the sun is so hot at midday that one should not go out unless his
head is well protected. The heat here is dry. The nights are usually
so cool that a blanket is needed. Notwithstanding the fact that we are
almost on the Equator, at any altitude above eight thousand feet ice
may be found in the early morning. Nearer the coast the land drops
and the climate is tropical. For two hundred miles back from the
Indian Ocean there are practically no white settlers, except at
Mombasa, for it is only on this high plateau that they are as yet
attempting to live.
But let me continue my description in the words of the man who
governs the country. My conversation took place in a long, blue, iron-
roofed building known as the Commissioner’s office, situated on the
hill above Nairobi. I had asked as to the colony’s future. Mr. Jackson
replied:
“It is all problematical. We have an enormous territory and millions
of people. We have not yet prospected the country, nor have we
dealt long enough with the natives to know what we can do with the
people. We have really no idea as yet as to just what our resources
are, or the labour we can secure to exploit them.”
Not long ago the great plateau of Kenya Colony was inaccessible and unknown
and its four million blacks were in continual war with one another. Now, besides the
railway, it is being opened up with roads permitting the use of motor transport.
Each group of huts is usually surrounded by a thatched wall, making an
inclosure into which cattle, sheep, and goats are driven at night. Some of the tribes
are practically vegetarians, living mostly on corn, beans, sweet potatoes, millet,
and milk.