TO STUDY ABOUT

CEMENT
A PROJECT WORK SUBMITTED FOR THE PARTIAL FULFILLMENT OF
THE REQUIREMENT FOR THE GRADE 12 SCIENCE IN CHEMISTRY

Submitted By

PRAKRITI REGMI

Grade:12

Roll no: 23

Batch:2080

Submitted to

Motherland Secondary School

National Education Board(NEB)

Pokhara, Kaski, Nepal

 CERTIFICATE OF APPROVAL

The project work entitled “ TO STUDY ABOUT CEMENT” by Ms. “Prakriti Regmi” under the
supervision of Mr. “Narayan Poudel”, Motherland Secondary School, Kaski, Nepal, is hereby
submitted for the partial fulfillment of the requirement to any other institution previously for the
award of Grade 12.

Supervisors

Name; Narayan Poudel

Signature;

Department of chemistry

Motherland Secondary School

 ACKNOWLEDGEMENT

Being a part of Motherland Secondary School, I got the opportunity to work to my full potential.
Moreover, the practical knowledge provided to me in hand with the theoretical knowledge is
paving the path for my success. Observing every scenario around me in the language of
chemistry has been fascinating to me, and providing me one more opportunity to be involved in
the project has made me learn from a different genre of learning and has made learn and think
more critically than before.

So, I would like to extend my deep awe towards Mr Narayan Baral, Mr Narayan Acharya, Mr Vi
Mr Narayan Poudel for providing me with such a golden opportunity to extend my knowledge
beyong the horizon of theoretical knowledge and look from a different perspective.

This project would not have been complete without the support of my family and my friends. I
would like to thank them for helping me in this survey regarding cement. I would like to thank
all the indirect supporters who helped me in this project.

Prakriti Regmi
 Table of Content

Title page ……………………………………………………………. I

Certificate of Approval …………………………………………….. II

Acknowledgement……………………………………………………. III

Table of contents ……………………………………………………... IV

CHAPTER 1: INTRODUCTION

- History
- Background
- Types of cement

CHAPTER 2: PROCESS OR METHODOLOGY

- Raw materials
- Methods
- Chemistry Insights

CHAPTER 3: RESULT AND DISCUSSION

 RESULT – Types
- Properties
- Chemistry
 DISCUSSION

CHAPTER 4: CONCLUSION

CHAPTER 5: SUGGESTION FOR FUTURE USE

CHAPTER 6: REFRENCES
INTRODUCTION

Joseph Aspdin, an enterprising 19th-century British stonemason, who heated a mix of ground
limestone and clay in his kitchen stove, then pulverized the concoction into a fine powder,
discovered cement in England in 1924. The result was the world's first hydraulic cement: one
that hardens when water is added. Aspdin dubbed his creation Portland cement due to its
similarity to a stone quarried on the Isle of Portland, off the British coast. Cement, the unsung
champion of construction, is brought to life by a remarkable blend of nature’s finest ingredients:
limestone, clay, and a touch of iron-rich flair. It’s this magical blend that forms the essence of
our structures, providing the backbone of our modern world. Cement come in various forms, but
two of its most prominent forms are Portland and Pozzolanic cement.

OPC (ORDINARY PORTLAND CEMENT): This is the most widely used type of cement in the
construction industry. OPC is manufactured by grinding a mixture of limestone, clay, and other
materials at very high temperature. It comes in different grades: OPC 33, OPC 43, and OPC 53.
OPC 53 is the strongest and most commonly used variety for construction.

PPC (PORTLAND POZZOLANA CEMENT): PPC is a more environment friendly alternative

to OPC. It is made by blending OPC with materials like fly ash, which is a waste product from
coal combustion, or calcined clay. This combination not only reduces the environmental impact
but also enhances certain properties of the cement.
PROCESS OR METHOLOGY

Cement, one of the most essential materials in the construction industry, is created through a
fascinating chemical process. Let's explore the production process with a focus on its chemistry
while keeping it suitable for high school-level understanding.

Raw Material Preparation:

Limestone and Clay Extraction: The journey of cement production begins with the extraction of
two key raw materials: limestone and clay. Limestone, primarily composed of calcium carbonate
(CaCO3), is sourced from quarries, while clay, with its silica (SiO2), alumina (Al2O3), and iron
(Fe2O3) components, is obtained from clay pits.

Raw Material Processing:

Crushing and Mixing: The extracted limestone and clay must be transformed into a homogenous
blend. To achieve this, they are crushed into small pieces and thoroughly mixed. This step is
crucial as it ensures a consistent composition of the raw materials.

Clinker Formation:

Heating in Kiln: The mixed raw materials are introduced into a rotary kiln, a high-temperature
furnace. This is where the chemistry of cement production really comes into play. There are two
key reactions at this stage:

a. Decomposition of Limestone: At the elevated temperatures inside the kiln, limestone

undergoes thermal decomposition:

CaCO3 (s) → CaO (s) + CO2 (g)

This reaction releases carbon dioxide gas, which is one of the environmental concerns associated
with cement production.
b. Formation of Clinker: The calcium oxide (CaO) produced from the decomposition of
limestone reacts with the silica (SiO2) from clay to create calcium silicate compounds,
commonly referred to as clinker. While the actual chemical reactions in the kiln are more
complex, a simplified version can be represented as:

CaO (s) + SiO2 (s) → CaSiO3 (s)

Cooling of Clinker: After the clinker formation, it must be rapidly cooled to prevent further
reactions. The resulting clinker is the primary building block of cement.

Cement Production:

Clinker Grinding: The clinker, once cooled, is ground into a fine powder. In this step, gypsum
(calcium sulfate, CaSO4) is added to control the setting time of the cement. The addition of
gypsum retards the hydration process, which affects the time it takes for the cement to set.

CaSO4 + 2H2O → CaSO4 · 2H2O (s)

Packaging: The finely ground powder, now cement, is packaged for distribution and use in
construction.

Chemistry Insights:

The fundamental chemical reaction in cement production is the formation of clinker through the
reaction between calcium oxide (CaO) and silica (SiO2).

The addition of gypsum is crucial to control the setting time of the cement, ensuring it can be
used effectively in construction.

Cement production is not only a chemical process but also an industry undergoing significant
changes to address environmental and sustainability concerns. Efforts are ongoing to reduce
carbon emissions and develop more eco-friendly cement production methods, making it a
captivating area of study within the field of chemistry.
RESULT AND DISCUSSION

Cement, a versatile construction material, comes in various forms, with Ordinary Portland
Cement (OPC) and Portland Pozzolana Cement (PPC) being two of the most prominent varieties.
Understanding the properties and characteristics of these cements is vital for their effective use in
the construction industry.

1. Ordinary Portland Cement (OPC):

Grades: OPC is available in different grades, including OPC 33, OPC 43, and OPC 53. Among
these, OPC 53 is the most widely used variety for construction due to its superior strength.

Strength: OPC 53 possesses high compressive strength, making it suitable for structural
applications where strength is a primary consideration.

Production Process: The production of OPC involves heating a mixture of limestone, clay, and
other materials at high temperatures. The critical chemical reactions include the decomposition
of limestone to form calcium oxide (CaO) and carbon dioxide (CO2) and the subsequent
formation of calcium silicate compounds (clinker). Gypsum is added during the clinker grinding
stage to regulate the setting time.

2. Portland Pozzolana Cement (PPC):

Environment-Friendly: PPC is recognized for its environmental benefits. It is created by

blending OPC with materials like fly ash or calcined clay, which are waste products from coal
combustion. This combination not only reduces the environmental impact but also enhances
certain properties of the cement.

Properties: PPC offers improved workability and reduced heat of hydration compared to OPC. It
is often used in applications where long-term strength development is more critical than initial
strength.
Chemistry: The incorporation of pozzolanic materials, such as fly ash or calcined clay, leads to
supplementary chemical reactions within the cement matrix. These reactions result in the
formation of additional calcium silicate compounds, contributing to the enhanced properties of
PPC.

Discussion:

The choice between OPC and PPC depends on the specific requirements of a construction
project. While OPC is favored for structures demanding high initial strength, PPC is preferred for
applications where sustainability, reduced heat generation, and long-term strength development
are crucial.

The chemical processes involved in cement production, as outlined earlier, are critical to
understanding the properties of the final cement products. The reaction between limestone and
clay to form calcium silicate compounds, known as clinker, is at the heart of the cement-making
process.

The addition of gypsum in cement production is crucial for controlling the setting time. It retards
the hydration process, ensuring that the cement can be used effectively in construction by
allowing sufficient time for handling and placement.

The environmental impact of cement production is a growing concern. Efforts are ongoing to
reduce carbon emissions and explore alternative raw materials, like pozzolanic materials, to
create more sustainable cement varieties.
CONCLUSION

In conclusion, cement, a cornerstone of modern construction, is the result of a remarkable blend

of nature's finest ingredients, including limestone, clay, and a touch of iron-rich flair. The
journey of cement production is a captivating fusion of chemistry and industry, each step
carefully orchestrated to yield various types of cement, each with its unique properties and
applications.

Two prominent types of cement, Ordinary Portland Cement (OPC) and Portland Pozzolana
Cement (PPC), cater to a range of construction needs. OPC, available in different grades, is
known for its high compressive strength, making it ideal for structural applications. Its
production process involves critical chemical reactions, including the decomposition of
limestone and the formation of calcium silicate compounds. The addition of gypsum regulates
the setting time of OPC.

In contrast, PPC is an environment-friendly alternative that blends OPC with materials like fly
ash or calcined clay, reducing the environmental footprint and enhancing certain properties of the
cement. This variety offers improved workability and reduced heat of hydration, making it
suitable for projects where long-term strength development is essential.

Understanding the choice between OPC and PPC is vital, as it hinges on the specific
requirements of a construction project. While OPC is favored for applications demanding high
initial strength, PPC is chosen for its sustainability and long-term strength development
characteristics.

Moreover, the environmental impact of cement production is a growing concern. Efforts are
underway to reduce carbon emissions and explore alternative raw materials, such as pozzolanic
materials, to create more sustainable cement varieties.

In essence, cement production is not merely a building material but a testament to human
innovation, rooted in the chemistry of clinker formation and the careful engineering of properties
to meet construction needs. This industry continues to evolve, addressing environmental and
sustainability challenges, making it a compelling area of study within the field of chemistry.
Understanding the nuances of these cement types empowers builders and engineers to make
informed decisions, striking a balance between strength, sustainability, and environmental
responsibility in the world of construction.

SUGGESTION FOR FUTURE USE

As we contemplate the future applications and developments in the world of cement and
construction materials, several suggestions emerge that can further enhance the utility and
sustainability of these essential building components.

Green Cement Innovation: Future research and development efforts should focus on creating
greener alternatives to traditional cement. This includes exploring carbon capture and utilization
technologies, the use of alternative raw materials, and the reduction of carbon emissions in the
cement production process. By investing in the development of low-carbon and carbon-neutral
cements, we can significantly reduce the environmental impact of construction.

Nanotechnology in Cement: The incorporation of nanotechnology in cement offers exciting

prospects. By engineering cement particles at the nanoscale, researchers can improve properties
such as strength, durability, and even self-healing capabilities. Nanotechnology can also enhance
the efficiency of concrete in terms of resistance to environmental stressors and reducing
maintenance costs.

3D Printing with Cement: The use of 3D printing technology for construction is a promising
avenue. 3D-printed structures made with cement-based materials can significantly speed up
construction processes and reduce material waste. Research and investment in this field can
revolutionize the construction industry.

Smart Cement and Sensor Integration: The integration of smart technologies and sensors within
cement can provide real-time data on the structural integrity and health of buildings and
infrastructure. Such innovations can lead to improved maintenance and safety, allowing for
proactive interventions before issues become critical.

Recycled and Sustainable Aggregates: Utilizing recycled materials and sustainable aggregates as
partial replacements for traditional raw materials can reduce the environmental footprint of
cement production. Research into new materials and processing techniques that promote
sustainability is essential.

Carbon Sequestration through Concrete: Investigate the potential of using concrete as a means of
carbon sequestration. Innovative concrete formulations could absorb and store atmospheric
carbon dioxide, contributing to carbon reduction efforts.

Biological Cement: Research into biological cement or biocement, produced by bacteria or

microorganisms, has the potential to create self-healing concrete. Biocement can potentially
repair cracks in structures and enhance longevity.

Alternative Construction Methods: Explore alternative construction methods that reduce the need
for traditional cement and concrete. Innovative designs, lightweight materials, and sustainable
building practices can lead to eco-friendly construction techniques.

Education and Awareness: Educate the construction industry, builders, and consumers about the
benefits and challenges of new cement technologies. Awareness and knowledge-sharing can
drive the adoption of more sustainable practices.

In conclusion, the future of cement and construction materials holds great promise, marked by a
shift towards sustainability, innovation, and a reduced environmental footprint. The construction
industry, in collaboration with researchers and innovators, has the potential to shape a future
where our structures are not only strong and durable but also environmentally responsible and
adaptive to evolving needs. By embracing these suggestions and focusing on research and
development in these areas, we can pave the way for a more sustainable and resilient built
environment.
REFERENCES

- Cement Products | Construction Materials - CEMEX USA - CEMEX. (n.d.).

[Link]
- How cement is made. (n.d.). [Link]
made#:~:text=Cement%20is%20manufactured%20through%20a,silica%20sand%2C%20and
%20iron%20ore./
- Enotes, N. (2022, June 29). Class 12 Chemistry Cement Notes. Nepal Enotes.
[Link]
- Wikipedia contributors. (2023, October 14). Cement. Wikipedia.
[Link]
- Lea, F. M., & Mason, T. O. (2023, October 15). Cement | Definition, Composition, Manufacture,
History, & Facts. Encyclopedia Britannica. [Link]
building-material/
- Admin. (2023, March 8). Emerging trends in cement manufacturing technology. AGICO Cement
Plant. [Link]
manufacturing-technology/
- Leetham, D., & Leetham, D. (2015, August 20). The cement manufacturing process. Advancing
Mining. [Link]
- How cement is made. (n.d.-b). [Link]
- Mishra, G. (2020, June 9). 13 Types of Cement [PDF]: Properties, and Applications in Concrete
Construction. The Constructor.
[Link]