9724219216

DEV Institute, Gandhinagar

Chapter : 3 Std 12 : Chemistry Date : 08/02/25
Total Marks : 100 MCQs Practice Time : 1 Hour
//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [100]
1. The role of a catalyst is to change ..........
(A) Gibbs energy of reaction. (B) enthalpy of reaction.
(C) activation energy of reaction. (D) equilibrium constant.
2. In the presence of a catalyst, the heat evolved or absorbed during the reaction....
(A) increases (B) decreases
(C) remains unchanged (D) may increase or decrease
3. Activation energy of a chemical reaction can be determined by....
(A) determining the rate constant at standard temperature.
(B) determining the rate constants at two temperatures.
(C) determining probability of collision.
(D) using catalyst.
4. Consider figure below and mark the correct option.
Activated complex

E1

Products
Energy

E2

Reactants

Reaction coordinate
(A) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.
(B) Activation energy of forward reaction is E1 + E2 and product is more stable than reactant.
(C) Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable
than product.
(D) Activation energy of backward reaction is E1 and product is more stable than reactant.
5. Consider a first order gas phase decomposition reaction given below :
A(g) ® B(g) + C(g)
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure
of the system increased by x units and became ‘pt’. The rate constant k for the reaction is given as .........
2.303 pi 2.303 pi
(A) k = log (B) k = log
t pi – x t 2pi – pt
2.303 pi 2.303 pi
(C) k = log (D) k = log
t 2pi + pt t pi + x
6. According to Arrhenius equation rate constant k is equal to A e–Ea /RT. Which of the following options
1
represents the graph of ln k vs ?
T

(A) ln k Wish You - All The

(B)Best
ln k

1 1
T
 According to Arrhenius equation rate constant k is equal to A e–Ea /RT. Which of the following options
9724219216
1
represents the graph of ln k vs ?
T

(A) ln k (B) ln k
1 1
T T

ln k ln k
(C) (D)
1 1
T T
7. Consider the Arrhenius equation given below and mark the correct option.
k = A e–Ea/RT
(A) Rate constant increases exponentially with increasing activation energy and decreasing
temperature.
(B) Rate constant decreases exponentially with increasing activation energy and decreasing
temperature.
(C) Rate constant increases exponentially with decreasing activation energy and decreasing
temperature.
(D) Rate constant increases exponentially with decreasing activation energy and increasing
temperature.
8. A graph of volume of hydrogen released Vs time for the reaction between zinc and dil. HCl is given in
figure below. On the basis of this mark the correct option.

V5
V4
V3

V2
V1

O 20 30 40 50
V3 – V2 V3 - V2
(A) Average rate upto 40 seconds is (B) Average rate upto 40 seconds is
40 40 - 30
V3 V3 - V1
(C) Average rate upto 40 seconds is (D) Average rate upto 40 seconds is
40 40 - 20
9. Which of the following statements is not correct about order of a reaction ?
(A) The order of a reaction can be a fractional number.
(B) Order of a reaction is experimentally determined quantity.
(C) The order of a reaction is always equal to the sum of the stoichiometric coefficients of reactants
in the balanced chemical equation for a reaction.
(D) The order of a reaction is the sum of the powers of molar concentration of the reactants in the
rate law expression.
10. Consider the graph given in Figure. Which of the following options does not show instantaneous rate of
reaction at 40 s ?

V5
V4
V3 Wish You - All The Best

V2
 Consider the graph given in Figure. Which of the following options does not show instantaneous rate of
reaction at 40 s ? 9724219216

V5
V4
V3

V2
V1

O 20 30 40 50
V5 – V2 V4 – V2 V3 – V2 V3 – V1
(A) 50 – 30 (B) (C) 40 – 30 (D) 40 – 20
50 – 30
11. Which of the following statements is correct ?
(A) The rate of a reaction decreases with passage of time as the concentration of reactants decreases.
(B) The rate of a reaction is same at any time during the reaction.
(C) The rate of a reaction is independent of temperature change.
(D) The rate of a reaction decreases with increase in concentration of reactant(s).
12. Which of the following expressions is correct for the rate of reaction given below ?
5Br –(aq) + BrO–3(aq) + 6H+(aq) ® 3Br2(aq) + 3H2O(l)
D[Br - ] D[H + ] D[Br - ] 6 D[H + ]
(A) =5 (B) =
Dt Dt Dt 5 Dt
D[Br - ] 5 D[H + ] D[Br - ] D[H+ ]
(C) = (D) = 6
Dt 6 Dt Dt Dt
13. Which of the following graphs represents exothermic reaction ?
Activated complex
Activated complex Activated complex
Energy

Energy
Energy

(ii) Products (iii)

(i)
Reactants Reactants Products
Products Reactants
Reaction coordinate
(A) only (i) (B) only (ii) (C) only (iii) (D) (i) and (ii)
14. Rate law for the reaction A + 2B ® C is found to be Rate = k [A][B] Concentration of reactant ‘B’
is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be...
(A) the same (B) doubled (C) quadrupled (D) halved
15. Which of the following statements is incorrect about the collision theory of chemical reaction ?
(A) It considers reacting molecules or atoms to be hard spheres and ignores their structural features.
(B) Number of effective collisions determines the rate of reaction.
(C) Collision of atoms or molecules possessing sufficient threshold energy results into the product
formation.
(D) Molecules should collide with sufficient threshold energy and proper orientation for the collision
to be effective.
16. A first order reaction is 50% completed in 1.26 × 1014 s. How much time would it take for 100%
completion ?
(A) 1.26 × 1015 s (B) 2.52 × 1014 s (C) 2.52 × 1028 s (D) infinite
17. Compounds ‘A’ and ‘B’ react according to the following chemical equation.
A(g) + 2B(g) ® 2C(g)
Wish You - All The Best
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants
constant and rates were measured as a function of initial concentration. Following results were
 Compounds ‘A’ and ‘B’ react according to the following chemical equation. 9724219216
A(g) + 2B(g) ® 2C(g)
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants
constant and rates were measured as a function of initial concentration. Following results were
obtained. Choose the correct option for the rate equations for this reaction.
Experiment Initial Initial Initial
concentration concentration concentration
of [A] mol L–1 of [B] mol L–1 of [C] mol L–1s–1
1 0.30 0.30 0.10
2 0.30 0.60 0.40
3 0.60 0.30 0.20

(A) Rate = k [A]2[B] (B) Rate = k [A][B]2 (C) Rate = k [A][B] (D) Rate = [k][A]2[B]0
18. Which of the following statement is not correct for the catalyst ?
(A) It catalyses the forward and backward reaction to the same extent.
(B) It alters DG of the reaction.
(C) It is a substance that does not change the equilibrium constant of a reaction.
(D) It provides an alternate mechanism by reducing activation energy between reactants and
products.
19. The value of rate constant of a pseudo first order reaction...
(A) depends on the concentration of reactants present in small amount.
(B) depends on the concentration of reactants present in excess.
(C) is independent of the concentration of reactants.
(D) depends only on temperature.
20. ) Which of the following is correct differential rate equation for given reaction.
5Br–(aq) + BrO–3(aq) + 6H+(aq) ® 3Br2(aq) + 3H2O(l)
–1 d[Br – ] –d[BrO3– ] –1 d[H+ ] 1 d[Br2 ] 1 d[H 2O]
(A) Rate= = = = =
5 dt dt 6 dt 3 dt 3 dt
1 d[Br – ] d[BrO3– ] 1 d[H+ ] 1 d[Br2 ] 1 d[H 2O]
(B) Rate= = = = =
5 dt dt 6 dt 3 dt 3 dt
–1 d[Br – ] – d[BrO3– ] –1 d[H + ] –1 d[Br2 ] –1 d[H 2O]
(C) Rate= = = = =
5 dt dt 6 dt 3 dt 3 dt
1 d[Br – ] d[BrO3– ] 1 d[H + ] –1 d[Br2 ] –1 d[H2O]
(D) Rate= = = = =
5 dt dt 6 dt 3 dt 3 dt
21. ) What will be the slope, when a graph is plotted between log10[R] ® t for a first order reaction ?
k –k
(A) k (B) –k (C) (D)
2.303 2.303
22. ) What would be the unit of rate constant for third order reaction ?
(A) mol–1 L S–1 (B) mol L–1 S–1 (C) mol–2 L2 S–1 (D) mol–2 L2 S–1
166) For R ® P reaction, following graph is given.
23.

270
Potential energy ® kJ

R
150
P
100

Reaction coordinate ®
What will be enthalpy change for the given reaction ?
(A) –50 kJ (B) 50 kJ Wish You - All The
(C)Best
120 kJ (D) 170 kJ
 Po
Reaction coordinate ® 9724219216
What will be enthalpy change for the given reaction ?
(A) –50 kJ (B) 50 kJ (C) 120 kJ (D) 170 kJ
24. ) What will be the unit of rate constant for following reaction ?
C2H4(g) + H2(g) ® C2H6(g)
(A) mol–1 L S–1 (B) S–1 (C) mol L–1 S–1 (D) mol–2 L2 S–1
25. ) Which of the following is bimolecular reaction ?
(A) N2 + 3H2 ® 2NH3 (B) 2NH3 ® N2 + 3H2
(C) NH4NO2 ® N2 + 2H2O (D) 2NO + O2 ® 2NO2
26. ) Identify the reaction order for which rate constant K = 2.3 × 10–5 L mol–1 s–1
(A) Zero (B) First (C) Second (D) Third
1
27. ) What is the slope of graph of ln k ® ?
r
E – 2.303 Ea R – 2.303R
(A) – a (B) (C) – (D)
R R Ea Ea
28. ) What is the unit of rate constant of the second order reaction ?
(A) mol L–1s–1 (B) mol–1 Ls–1 (C) s–1 (D) mol–2 L+2s–1
29. ) What is the wrong equation of rate constant for zero order reaction ?
[R] - [R]0 [R]0 - [R]
(A) [R] = – Kt + [R]0 (B) - K = (C) K = (D) [R]0 + [R] = – Kt
t t
30. ) A first order reaction is found to have a rate constant, K = 5.5 ´ 10–14 s–1. The half life of reaction
is ........ .
(A) 1.26 ´ 1014 s (B) 6.93 ´ 1014 s (C) 1.26 ´ 1013 s (D) 12.6 ´ 1015 s
31. ) The order of reaction for following value of rate constant is.....
[K = 2.3 ´ 10–5 L mol–1 sec–1]
(A) Zero order (B) Second order (C) First order (D) Third order
32. ) The rate constants of a reaction at 500K is 0.02 S–1. Its activation energy (Ea) is 18.230 kJ. Calculate
Arrhenius constant.
(A) 1.2 (B) 1.3 (C) 1.4 (D) 1.6
33. ) Which of the following graph is correct for a first order reaction ?
conc. of R ®

[R]0 ­
slope = –k t1
2
(A) (B)

time ® [R]0 ®
k
conc. P ®

slope =
2.303
[R]0
molar

[R]
log

(C) (D)

time ® time ®
34. ) A reaction is second order with respect to a reactant. How is the rate of reaction affected if the
concentration of the reactant is reduced to half ?
1 1
(A) 2 times (B) 4 times (C) times (D) times
2 4
35. ) The role of catalyst is to change ..........
(A) Gibbs energy of reaction. (B) Enthalpy of reaction.
(C) Equilibrium constant of the reaction. (D) Activation energy of the reaction.
36. ) The decomposition of NH3 on platinum surface is zero order reaction. What is the rate of production of
N2 if K = 2.5 ´ 10–4 mol L–1 S–1 ?
(A) 2.5 ´ 10–4 mol L–1 s–1 (B) 8.3 ´ 10–5 mol L–1 s–1
(C) 7.5 ´ 10–4 mol L–1 s–1 (D) 5 ´ 10–4 mol L–1 s–1
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 N2 if K = 2.5 ´ 10–4 mol L–1 S–1 ?
(A) 2.5 ´ 10–4 mol L–1 s–1 (B) 8.3 ´ 10–5 mol L–1 s–1 9724219216
(C) 7.5 ´ 10–4 mol L–1 s–1 (D) 5 ´ 10–4 mol L–1 s–1
1
37. ) Which of the following graph for ln k ® is correct ?
T

­ ­
­ ­
ln k ln k
ln k ln k
(A) (B) (C)
(D)
1 ® 1 ®
1 ® 1 ®
T T
T T
38. ) Which of the following relation is correct for first order reaction ?
(A) Reaction order = molecularity (B) Reaction order £ molecularity
(C) Reaction order > molecularity (D) Reaction order < molecularity
1
39. ) What is the value of slope of graph log10K ® ?
T
k Ea Ea
(A) – (B) – (C) – (D) – k
2.303 2.303R R
40. ) The units for the rate constant and the rate of reaction are same for a reaction. What will be the order
of the reaction ?
(A) Second (B) Zero (C) First (D) Third
d[A] d[B]
41. ) For the reaction 2A + B ® product, – = K [A]2[B]. What will be the rate equation for – ?
dt dt
1 1
(A) K[2A]2[B] K[A]2[B] (B) (C) K[A][B]2 (D) K[A][B] 2
2
42. ) Which of the following relation is correct for zero order reaction ?
1
(A) t 1 µ (B) t 1 µ [R]0
2 [R]0 2
1
(C) t 1 µ (D) t 1 is independent of [R]0
2 [R]02 2
1
43. ) For a reaction, the value of slope of a plot in ln K ® = .......... .
T
Ea Ea Ea
(A) – (B) – (C) –Ea (D) –
2.303 R 2.303R
44. ) What is the value of intercept for the graph of log [R] ® time for the first order reaction ?
K K
(A) (B) ln [R]o (C) – (D) log [R]o
2.303 2.303
144) 3ClO– ® ClO–3 + 2Cl
45.
The rate of reaction of above reaction is given by ......... .
(A) K1[ClO–] (B) K1[Cl–]2 (C) K1[ClO2–] (D) K1[ClO–]2
46. ) The decomposition reaction of SO2Cl2 is the first order reaction. It’s concentration gets halved in
60 minutes what is its rate constant value ?
(A) 0.01155 min–1 (B) 0.07676 min–1 (C) 0.7676 min–1 (D) 0.1155 minute–1
47. ) The order of following reaction is .........
hv
H 2(g) + Cl 2(g) ¾¾® 2HCl(g)
(A) 2 (B) 1 (C) 1.5 (D) 0
48. ) The unit of rate constant for third order reaction is .........
(A) mole–3 lit3 s–1 (B) mo1e–2 lit2 s–1 (C) mole lit–1 s–1 (D) mole2 lit–2 s–1
- Ea
49. ) According to collision theory Rate = P · ZAB e RT what does P indicate in the equation ?
(A) Pressure (B) Collision frequency (C) Arrhenius constant (D) Probability factor
50. ) Which is correct relation for half life period (t½) and Initial concentration of reactant [R]0 for fourth
order reaction.
1 1 1
(A) t 1 µ (B) t 1 µ Wish You - All The
(C)Best
t1 µ (D) t 1 µ [R]0
2 [R]0–3 2 [R]0 2 [R]03 2
 ) Which is correct relation for half life period (t½) and Initial concentration of reactant [R]0 for fourth
order reaction. 9724219216
1 1 1
(A) t 1 µ (B) t 1 µ (C) t 1 µ (D) t 1 µ [R]0
2 [R]0–3 2 [R]0 2 [R]03 2

51. ) With the help of which graph the value of Arrhenius constant can be obtained from Arrhenius
- Ea /RT
equation : K = A · e
1 1 1
(A) log K versus (B) K versus (C) log K versus (D) K versus T
log T log T T
52. ) An elementary reaction occurs in a closed vessel.
2CO(g) + O2(g) ¾® 2CO2(g)
If the volume of the reaction vessel is made one third of its original volume at constant temperature,
the order of the reaction ......... of its original rate.
(A) becomes twenty seven times. (B) becomes nine times.
(C) becomes three times. (D) becomes eighteen times.
53. ) For the given reaction, find the order of the reaction with respect to [H+]
-
5Br(aq) + BrO -3(aq) ‡ˆ
ˆˆ†
ˆ 3Br2(aq) + 3H 2O(l )
(A) 3 (B) 2 (C) 1 (D) 4
54. ) Which of the following statements is true regarding molecularity and order of reaction ?
(A) Order of the reaction can be determined from stoichiometry of the reaction.
(B) For the complex reaction, the fastest step decides order of the reaction.
(C) Molecularity cannot be defined for the reactions occurring in more than one step.
(D) The order of the reaction for trimolecular reaction is always 2.
55. ) Activation energy of forward and backward non catalysed reactions are x and x' respectively. If they
are done using catalyst the activation energy of forward and backward reactions are y and y'
respectively, then which of the following relation is true ?
(A) x – x' = y – y' (B) x – x' < y – y' (C) x – x' > y – y' (D) x – x' £ y – y'
56. ) Which of the following methods are used to determine rate of the reactions containing more than one
type of reactants ?
(P) Integrated rate equation method.
(Q) Half life time method.
(R) Ostwald’s isolation method.
(A) Only R (B) Q and R (C) P and Q (D) P, Q and R
d[ A]
57. ) For the reaction A + B ® Products, -
-E a /RT
= x·e , what is x ?
dt
(A) Collision frequency (B) Molecularity (C) Avogadro number (D) Rate constant
58. ) The half life period of the reaction H2 + I2 ® 2HI is proportional to.....
(A) initial concentration. (B) the square of initial concentration.
(C) inverse of initial concentration. (D) independent of initial concentration.
59. ) For which of the following reactions, Oswald’s isolation method is useful for determination of order
of the reaction ?
1 1
(A) N2O5(g) ® 2NO2(g) + O (B) H2O2(l) ® H2O(l) + O
2 2(g) 2 2(g)
K
(C) – + BrO –3(aq) + 6H(aq)
+
® 3Br2(aq) + 3H2O(l ) (D) All the three given options.
2.303
60. ) The unit of K for pseudo first order reaction is
(A) minute–1 (B) mol–1 lit minute–1 (C) mol lit–1 minute–1 (D) mol–2 lit2 minute–1
61. ) The negative value for slope of the graph of concentration of reactant [R] ® t indicates....
(A) zero order reaction.
(B) first order reaction.
(C) instantaneous rate.
(D) both zero order reaction and instantaneous rate.
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 (B) first order reaction.
(C) instantaneous rate. 9724219216
(D) both zero order reaction and instantaneous rate.
62. ) For the first order reaction, the time required for completion of 50% reaction is 100 seconds. Then
the rate constant will be....
(A) 6.93 ´ 10–3 mol2 lit–2 s–1 (B) 6.93 ´ 10–3 s–1
(C) 6.93 ´ 10–3 mol lit–1 s–1 (D) 6.93 ´ 10–2 s–1
63. ) Which of the following statement is not appropriate ?
(A) Activated complex is short lived molecule.
(B) Activated complex breaks due to its oscillation motion.
(C) Activated complex possesses very weak bonds.
(D) Activated complex possesses minimum potential energy.
64. ) In elementary reaction : 2SO2(g) + O2(g) ® product. If pressure of SO2 gas is doubled and pressure
of O2 gas is halved, then what will be the increase in rate of reaction ?
(A) Sixteen times (B) Two times (C) Four times (D) Eight times
1
65. ) For any chemical reaction, value of slope of ln K ® graph will be.....
T
Ea Ea Ea
(A) – (B) – (C) – 2.303 R (D) – Ea
2.303 R
66. ) If energy of activation of a reaction is 2303 Joule, then what is the value of slope of graph log K ®
1
?
T
(A) –12195.12 Joule (B) –503.27 Joule (C) –120.28 Joule (D) –239.0 Joule
67. ) What is the value of slope of graph of concentration of R versus time for zero order reaction ?
K Ea Ea
(A) (B) – (C) –K (D) – 2.303 R
2.303 R 2.303
68.
121) What will be the theoretical rate of elementary reaction if pressure of O2 is increased by three times ?
2SO2(g) + O2(g) ® 2SO3(g)
(A) 27 times increase (B) 9 times increase (C) 18 times increase (D) 3 times increase
69. ) The half reaction time of a first order required to decrease initial concentration from 40% to 20% is 20
minute. What time will be taken to decrease initial concentration from 10% to 5% ?
(A) 20 minute (B) 5 minute (C) 10 minute (D) 60 minute
119) AB ® A + B is a zero order reaction, if K = 4 ´
70. 10–1 molelitre–1 second–1, then how much will be
the production rate in mole litre–1 second–1 for A ?
(A) 2 ´ 10–1 (B) 4 ´ 10 (C) 1.6 ´ 10–3 (D) 2 ´ 10–2
71. ) For one first order reaction 60 minutes are required to decrease the initial concentration from 0.8 M
to 0.1 M, determine the half reaction time (t½).
(A) 20 min. (B) 30 min. (C) 40 min. (D) 15 min.
1
117) If graph log K ®
72. is plotted, a straight line is obtained then what will be value of slope ?
T
Ea –Ea –2.303R –Ea
(A) (B) (C) (D)
2.303R 3.203R Ea 2.303R
73. ) The unit of rate constant of second order reaction is....
(A) litre · mole–1, second–1 (B) mole–1 litre second–1
(C) mole/litre. (D) (mole/litre)–1 second–1
74. ) Mention the unit of K for zero order reaction.
(A) mole litre–1 second–1 (B) second–1
(C) (mole/litre)–1 second–1 (D) (mole/litre)1–n second–1
75. ) What is the correct formula for R ® P reaction rate ?
– D[R] – D[P] – D[R] D[P] –[R] D[P] – D[R] Dt
(A) = (B) = (C) = (D) =
t t Dt Dt t Dt Dt D[P]
76. ) In a first order reaction the time required for the concentration to decrease from 6 moles to 3 moles
is 40 minutes, in such a reaction what time will be taken for the conversion reactant from 12 moles
to 6 moles ? Wish You - All The Best
(A) 20 minutes (B) 40 minutes (C) 80 minutes (D) 160 minutes
 ) In a first order reaction the time required for the concentration to decrease from 6 moles to 3 9724219216
moles
is 40 minutes, in such a reaction what time will be taken for the conversion reactant from 12 moles
to 6 moles ?
(A) 20 minutes (B) 40 minutes (C) 80 minutes (D) 160 minutes
77. ) A reaction is first order in terms of A and second order in terms of B. What will be the rate of
reaction, if concentration of B is increased two times ?
(A) 8-Times (B) 4-Times (C) 2-Times (D) 16-Times
1 3
78. ) Which will be the unit of rate constant for the reaction having Rate = K [ A ] 2 [B ] 2 ?
(A) Mol–1 · lit. (B) sec–1 (C) Mol/lit. (D) (Mol/lit)2 · sec–1
79. ) For which of the following graph of first order reaction the value of slope will be K
2.303 ?
[R]0 [R]0 [R] [R]
(A) ln ® t(Time) (B) log ® t(Time) (C) log ® t(Time) (D) ln ® t(Time)
[R] [R] [R]0 [R]0
80.
109) A reaction is first order with respect to reactant A and second order with respect to reactant B. What
is the effect of rate when concentration of A and B are doubled ?
(A) Doubled (B) Quadrupled (C) Eight times (D) Sixteen times
81. ) The rate constant for a first order reaction is 60 s–1. How much second will it take to reduce the
1
initial concentration of the reactant to its th value ?
16
(A) 2.3 × 10–2 (B) 4.6 × 10–2 (C) 9.5 × 10–2 (D) 6.9 × 10–2
[R]0
82. ) For first order reaction, the value of slope for graph of log ® t is ......
[R]
K 2.303 K
(A) (B) –K (C) (D) –
2.303 K 2.303
83. ) For a reaction, K = 4.5 × 10–4 L mol–1 s–1. What is order of reaction ?
(A) Zero (B) First (C) Second (D) Third
84. ) Time required to decompose SO2Cl2 to half of its initial amount is 40 minutes. If the decomposition
is a first order reaction, what will be the rate constant of the reaction ?
(A) 1.73 ´ 10–2 s–1 (B) 2.88 ´ 10–2 s–1 (C) 2.88 ´ 10–4 s–1 (D) 1.73 ´ 10–4 s–1
85. ) Which of the following graph has intercept equal to zero ?
[R] 1
(A) log[R] ® t (B) log 0 ® t (C) log K ® (D) [R] ® t
[R] T
86. ) In the presence of a catalyst, the heat evolved or absorbed during the reaction...
(A) Decreases (B) Increases
(C) May decrease or increase (D) Remains unchanged
87. ) Which statement is incorrect for collision theory ?
(A) The collision between the reacting molecules is essential.
(B) The collision of the reactant molecules should be from any direction.
(C) There must be certain minimum kinetic energy for the reactant experiencing collision.
(D) The reactant experiencing fruitful collisions are converted to products.
101) In a reaction A ® B, if the concentration of reactant is increased by 9 times then rate of reaction
88.
increases 3 times. What is the order of reaction ?
1 1
(A) 2 (B) 3 (C) (D)
2 3
89. ) Instantaneous rate of reaction for the reaction 3A + 2B ® 5C is .........
1 d[A] 1 d [B ] 1 d [C ] 1 d[A] 1 d [B] 1 d [C ]
(A) + = - =+ (B) - = - =+
3 dt 2 dt 5 dt 3 dt 2 dt 5 dt
1 d[A ] 1 d [ B] 1 d [C ] 1 d[A] 1 d [ B] 1 d [C ]
(C) + = + =- (D) + = - =-
3 dt 2 dt 5 dt 3 dt 2 dt 5 dt
90. At 27°C temperature, time required for 75% completion of a first order reaction 20 seconds. What will
be its rate constant ?
(A) 0.693 s–1 mol–1 lt (B) 0.0693 s–1 (C) 0.693 s–1 (D) 0.0693 s–1 mol–1 lt
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 At 27°C temperature, time required for 75% completion of a first order reaction 20 seconds. What will
be its rate constant ? 9724219216
(A) 0.693 s–1 mol–1 lt (B) 0.0693 s–1 (C) 0.693 s–1 (D) 0.0693 s–1 mol–1 lt
91. The values of slope and intercept in the graph of Freundlich adsorption isotherm at 25oC
temperature are 0.5 and 0.4771 respectively. What will be the propertion of adsorption at 4 bar
pressure ?
(A) 6 (B) 3 (C) 24 (D) 12
92. The half life period for a radioactive substance is 15 minutes. How many gms of this radioactive
substance is decayed from 50 gm of substance after one hour ?
(A) 25 (B) 46.875 (C) 43.75 (D) 37.5
93. The rate constant value for a reaction is 1.75 ´ 102 L2 mol–2 sec–1. The half life period t1/2 a .......... .
(A) [Ro]–2 (B) [Ro] (C) [Ro]2 (D) [Ro]–1
94. At 298 K temperature the activation energy for the reaction X2 + Y2 ® 2XY + 20 kJ is 15 kJ. What will
be the activation energy for the reaction 2XY ® X2 + Y2 ?
(A) +35 kJ (B) –35 kJ (C) –5 kJ (D) –15 kJ
95. What is the unit for rate constant for pseudo first order reaction ?
(A) L mol–1 sec–1 (B) sec–1 (C) mol lt–1 sec–1 (D) L2 mol–2 sec–1
96. Time taken for consumption of half of the initial concentration is 20 seconds for a first order
reaction. What will be the time taken by the same reaction to get the concentration of reactant from
0.125 M to 0.0625 M.
(A) 5 sec. (B) 20 sec. (C) 10 sec. (D) 40 sec.
97. How much time is required for completion of a zero order reaction ?
2[R o ] [R o ] [R o ] K
(A) (B) (C) (D) [R ]
K 2K K o
98. Reaction 3ClO– ® ClO–3 + 2Cl– occurs in following two steps.

(i) ClO - + ClO - ¾¾ - -

K
1
® ClO 2 + Cl (Slow step)
- - K - -
(ii) ClO 2 + ClO ¾¾ 2
® ClO 3 + Cl (Fast step)
then the rate of given reaction = .........
(A) K1[ClO–]2 (B) K1[ClO–] (C) K2[ClO–2] [ClO–] (D) K2[ClO–]3
Step-I Step-II
99. X ¾¾¾® Y ¾¾¾¾
® Z is a complex reaction. Total order of reaction is 2 and Step-II is slow step..
What is molecularity of Step-II ?
(A) 1 (B) 2 (C) 3 (D) 4
100. Total order of reaction X + Y ® XY is 3. The order of reaction with respect to X is 2. State the
differential rate equation for the reaction.
d[X] d[X] d[X] d[X]
(A) – = K[X]3[Y]0 (B) – = K[X]0[Y]3 (C) – = K[X]2[Y] (D) – = K[X][Y]2
dt dt dt dt

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