Chemistry Chapter 1
Chemistry Chapter 1
🔬 States of Matter
The Universe's Building Blocks
The universe is composed of 118 known elements, some naturally occurring in stars and
others artificially created. These elements serve as the fundamental building blocks of
everything around us. What's remarkable is that:
Each atom is made up of just three subatomic particles: protons, neutrons, and
electrons
Only about a quarter of these elements are common in everyday objects
Chemistry studies how these atoms combine to form everything from trees to
skyscrapers
All matter exists in one of three states: solids, liquids, or gases. These states differ in the
arrangement, movement, and energy of their particles.
Arrangement of Particles
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This particle arrangement explains why you can't walk through a brick wall (solid), can
move through water with resistance (liquid), and can easily move through air (gas).
Gases: Fill their container completely; a small volume of liquid can expand to a much
larger volume as gas (e.g., 5 cm³ of water becomes enough steam to fill a bucket)
Changes of State
Solid ↔ Liquid
Eventually particles vibrate so much that forces can't hold them in fixed positions
Particles gain enough energy to move around each other
Occurs at the melting point
Releases energy
Liquid ↔ Gas
There are two different processes for this change:
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Cooling causes gas particles to move slowly enough for attractive forces to form
Solid ↔ Gas
Key Point: Evaporation occurs at any temperature (like puddles drying at 5°C), while
boiling only occurs at one specific temperature (water boils at 100°C).
🧪 States of Matter
Sublimation
Sublimation is the process where a solid turns directly into a gas without passing through the
liquid state.
Solid carbon dioxide (dry ice) turns directly from solid to gas at -78.5°C
When dry ice sublimes, it creates a white cloud as the cold carbon dioxide gas causes
water vapor in the air to condense (the carbon dioxide gas itself is invisible)
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Key Point: In science, room temperature is typically considered to be between 20°C and
25°C. Because there isn't a single fixed value, we must be careful when making
comparisons for substances that change state near room temperature.
Below Below
Room temperature is above
Oxygen room room Gas
oxygen's boiling point
temp temp
Above Above
Room temperature is below
Lithium room room Solid
lithium's melting point
temp temp
Diffusion
Definition: Diffusion is the spreading out of particles from where they are at a high
concentration to where they are at a low concentration.
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Diffusion in Gases
When a gas like ammonia is released in a lab:
Despite this speed, it takes time for the smell to spread throughout the room
This is because gas particles don't travel in straight lines but bounce off other air
particles
In the time it takes for the smell to reach all corners of the lab, each ammonia particle
may have traveled 30+ kilometers!
When lids are removed, the brown color diffuses upward until both jars are uniformly
brown
Air particles also diffuse downward, resulting in an even mixture
Example 2: Ammonia and Hydrogen Chloride This demonstration shows that particles of
different gases travel at different speeds:
Cotton wool soaked in concentrated ammonia solution is placed at one end of a glass
tube
Cotton wool soaked in concentrated hydrochloric acid is placed at the other end
The gases diffuse along the tube and react to form white solid ammonium chloride:
The white ring forms closer to the hydrochloric acid end because:
Ammonia particles (relative molecular mass 17) are lighter than hydrogen chloride
particles (relative molecular mass 36.5)
Lighter particles move faster
Diffusion in Liquids
Diffusion in liquids is much slower than in gases:
If a small jar of colored solution (e.g., potassium manganate(VII)) is placed in a gas jar
of water, it can take days for the color to diffuse throughout
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For the color to be visible, each drop must contain at least one "particle" of potassium
manganate(VII)
This suggests there must be at least 200,000 particles in 0.01g
Solubility of Solids
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In other words, solubility is the maximum mass of solute that can dissolve in 100g of solvent
at a specific temperature.
For example, the solubility of sodium chloride (common salt) in water at 25°C is about 36 g
per 100 g of water.
Investigating Solubility
3. Add the solid (potassium nitrate) until no more dissolves (excess solid remains)
4. Cool to exactly the target temperature (40°C)
5. Pour off some solution into the evaporating basin (without any undissolved solid)
Safety Note:
Calculating Solubility
The formula for calculating solubility:
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mass of solute
solubility (g/100 g) = × 100
mass of solvent
Example calculation:
Therefore:
Solubility Curves
Solubility curves show how the solubility of a substance changes with temperature. For most
solids:
10 31.2
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30 37.2
40 40.0
70 48.5
90 53.9
General formula:
For a solution with 51.0 g KCl in 100 g water, crystals appear when temperature drops
below 80°C
Important Notes
Always quote temperature with solubility since solubility varies with temperature
When a solution becomes saturated and cools further, excess solute "crystallizes out" or
"precipitates out" of the solution
Supersaturated solutions contain more dissolved solid than expected at a particular
temperature (not required for International GCSE)
Classification of Matter
Matter can be classified into three main categories:
1. Elements: Substances that cannot be split into anything simpler by chemical means
2. Compounds: Formed when two or more elements chemically combine
3. Mixtures: Various substances mixed together without chemical reactions occurring
Elements
Elements are substances that can't be split into anything simpler by chemical means. An
element contains only one type of atom.
Contain only one type of atom (with the same atomic number)
There are 118 elements shown in the Periodic Table
Examples include:
Gold
Important note: While elements consist of one type of atom, most elements consist of
mixtures of isotopes, which have the same atomic number but different mass numbers due
to different numbers of neutrons.
Compounds
Compounds are formed when two or more elements chemically combine. The elements
always combine in fixed proportions.
Water (H₂O)
Silicon dioxide (SiO₂)
Sodium chloride (NaCl)
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Mixtures
In a mixture, the various substances are mixed together and no chemical reaction
occurs.
1. Proportions
Compounds:
Example: In water (H₂O), every molecule has exactly two hydrogen atoms combined with
one oxygen atom
Mixtures:
2. Properties
Compounds:
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Example: Iron sulfide (FeS) reacts with acids to produce hydrogen sulfide gas, unlike
either iron or sulfur alone
Mixtures:
Example: In a mixture of iron and sulfur, iron remains grey and magnetic while sulfur
remains yellow
3. Ease of Separation
Compounds:
Mixtures:
Mixtures:
Impurities lower the melting point and raise the boiling point
Example: Adding 10g of salt to 1 liter of water lowers the melting point to about -0.6°C and
raises the boiling point to about 100.2°C
Important application: Melting point can be very useful in determining whether a substance
is pure.
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When synthesizing compounds like aspirin, melting point determination is a crucial method
to assess purity:
A wide melting range and a melting point below the expected value indicate impurities in
the sample.
Separation of Mixtures
Separation techniques are fundamental in chemistry with applications in:
Filtration
Filtration separates a solid from a liquid using filter paper.
Components:
Terminology:
Applications:
Crystallisation
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Process:
3. Turn off heat and allow crystals to form as solution cools and more water evaporates
Equipment needed:
Evaporating basin
Heat source
Glass rod for testing
This method works for separating any mixture of two solids where one is water-soluble
and the other is not.
Simple Distillation
Simple distillation separates components of a solution, collecting both the solvent and
solute.
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Equipment:
Side-arm flask
If distillation continues, the salt solution becomes concentrated enough that salt will
crystallize out.
Fractional Distillation
Fractional distillation separates miscible liquids with different boiling points.
Both liquids vaporize, but careful temperature control causes water to condense in the
fractionating column
Equipment:
Condenser
Collection vessel
Water is always fed into the lower end of the condenser to ensure it fills the condenser
jacket properly.
Note: The ethanol produced is approximately 96% pure, as it's impossible to remove the last
4% of water by distillation.
Paper Chromatography
Paper chromatography separates mixtures of substances, particularly colored inks or food
colorings.
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Process:
2. Place a spot of mixture on the line using a teat pipette or capillary tube
6. Remove paper when solvent nears top and mark the solvent front
7. Let paper dry
Results interpretation:
Substances that don't move have high affinity for paper or low solubility
Substances that move with solvent front have low affinity for paper or high solubility
The pattern produced is called a chromatogram
If a dye doesn't move from the pencil line, it's insoluble in the chosen solvent. If it moves
with the solvent front, it's too soluble. In both cases, a different solvent should be tried.
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4. Allow the solvent to travel up the paper, carrying the components at different rates
5. Compare the spots from the unknown mixture with those of the known dyes
Example Analysis:
In the example shown in Figure 2.13, a mixture (m) was analyzed alongside four known dyes
(d1, d2, d3, and d4). The mixture showed spots that corresponded to dyes d1, d3, and d4 in
both color and distance traveled.
Example Calculation:
For dye d3 in Figure 2.13:
2.9 cm
Rf = = 0.81
3.6 cm
Component Rf Value
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Component Rf Value
Dye d1 0.56
Dye d2 0.36
Dye d3 0.81
Dye d4 0.25
Important: When measuring spots for Rf calculation, measure to the center of the spot.
The mixture contains dyes d1, d3, and d4 because their Rf values match those of spots in
the mixture
Dye d2 is not present in the mixture because its Rf value (0.36) doesn't match any spot in
the mixture
An atom is the smallest piece of an element that can still be recognized as that element.
If you divide copper into smaller and smaller pieces, you would eventually reach an
individual copper atom. While an atom can be further split into protons, neutrons, and
electrons, the resulting particles would no longer be recognizable as copper.
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Molecules
A molecule consists of two or more atoms chemically bonded together (by covalent bonds).
Molecules can be formed from:
Examples:
A hydrogen (H₂) molecule consists of 2 hydrogen atoms chemically bonded together
A water (H₂O) molecule consists of 2 hydrogen atoms and 1 oxygen atom chemically
bonded together
Protons
Neutrons
Electrons
Proton 1 +1
Neutron 1 0
Electron 1/1836 -1
Note: Most of an atom's mass is concentrated in the nucleus because electrons have a
much smaller mass than protons and neutrons.
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Atomic number (or proton number) is the number of protons in an atom's nucleus. This
determines which element the atom is.
Atomic Structure
The mass number (also called the nucleon number) counts the total number of protons and
neutrons in the nucleus:
mass number
atomic number Element
symbol
59
For example: 27 Co
Therefore:
Atomic Model
Important note about atomic models: While atoms are sometimes depicted with electrons
orbiting the nucleus like planets around the sun, this is misleading. Electrons are constantly
moving, and we cannot know their exact position at any moment. Instead, we can only
identify:
Electrons with different energies are found at different distances from the nucleus.
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Isotopes
Isotopes are atoms of the same element (same atomic number) but with different mass
numbers due to different numbers of neutrons.
Despite having different numbers of neutrons, isotopes of the same element have identical
chemical properties because:
Chlorine consists of two isotopes, 35 Cl and 37 Cl, with the former being more abundant (since
the relative atomic mass is closer to 35 than to 37).
Example Calculation:
Boron contains 20% 10 B and 80% 11 B. To calculate its relative atomic mass:
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Electrons in Atoms
Since atoms are electrically neutral, the number of negatively charged electrons must equal
the number of positively charged protons:
For example:
The atomic number is defined by the number of protons (not electrons) because the
number of electrons can change during chemical reactions, such as when atoms form ions.
The Periodic Table arranges atoms in order of increasing atomic number. When using the
Periodic Table:
The atomic number is the smaller number shown with each element
The other number is either the mass number of the most common isotope or the relative
atomic mass
Example:
For uranium shown as 238
92 U:
Important Reminders
When writing element symbols with two letters:
The numbers in the International GCSE Periodic Table are relative atomic masses, not mass
numbers (with chlorine at 35.5 and copper at 63.5 being exceptions to the general pattern).
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