SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.

C-120_Jee-Main_WTM-44_Key & Sol's

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr. C-120 JEE-MAIN Date: 09-08-2025
Time: 09.00Am to 12.00Pm WTM -44 Max. Marks: 300
KEY SHEET
MATHEMATICS
1 4 2 1 3 3 4 3 5 2
6 1 7 3 8 3 9 1 10 3
11 3 12 2 13 2 14 2 15 4
16 2 17 3 18 3 19 3 20 3
21 5 22 1 23 39 24 4 25 19

PHYSICS
26 3 27 2 28 2 29 4 30 2
31 2 32 1 33 1 34 2 35 2
36 3 37 3 38 2 39 1 40 1
41 1 42 4 43 2 44 3 45 3
46 250 47 1 48 36 49 40 50 27

CHEMISTRY
51 4 52 1 53 2 54 4 55 4
56 1 57 3 58 2 59 1 60 4
61 2 62 2 63 4 64 1 65 3
66 1 67 3 68 2 69 1 70 1
71 6 72 3 73 6 74 3 75 4

Sec: Sr. C-120 Page 1

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

SOLUTION
MATHEMATICS
1
r 3/ 2
n
2  2
Lt  5/2    x 3/ 2  dx   x 5/2  
1
1.
n 
r 1 n
0
5 0 5
 /3  /3
sec 2 x 3 3
2. I  sec 2/ 3 x cos ec 4/3 xdx   / 6 sec4/ 3 x cos ec x dx  31/ 6  31/ 6  3  3
4 /3 7/6 5/ 6

 /6
 /2
sin 2 x
3. I  dx ____ 1
0 sin x  cos x
 
 /2 sin 2   x 
2  dx   a  x  prop 
     
0 sin   x   cos   x 
2  2 
 /2
cos 2 x
  dx ____  2 
0 cos x  sin x
 /2
cos 2 x
  dx ____  2 
0 cos x  sin x
 /2
1 1

2
  
dx
0 sin  x  
 4
 /2
1  x  
  log tan    
2  2 8  0
1  3 
  logtan  logtan 
2 8 8


1 
2

log 2  1  log 2  1 
   
 2I 
2
2
log 2  1  
2024
4.  g  x  dx  2024  2023 1  0  1 .  2023  2024
2024

dx( period of x   x  is 1)
1000 x  x 1
  x  x 
5.  0
e dx  1000 e
0
1
= 1000 0ex dx  1000  e  1
1 2x   2x  1  2x   2x  1 π
cos 1 
3 2 
 tan 1  2  3 cot 1  2 
 tan 1  2  3
1 x   1  x  dx  1 x   1  x  dx 
6. I 
1 ex  1 
1 ex  1 1 e x 2 1 dx
3 3 3
1 1
3 b b 3 1
π 1 π ex π
 1 e x  1 dx( a f ( x) dx  a f (a  b  x) dx)  2 1 1  e x dx  2 log 1  e  31
x

2 3
3 3

Sec: Sr. C-120 Page 2

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

π    
1 1
 
 log  1  e 3   log  1  e 3   
2   



 2 3

1  2x   2x 
cos 1 
3 2 
 tan 1  2 
 1  x   1  x  dx
I 
1 ex  1
3
1

  1
3
ex  
I     dx 
2 0  e 1 e 1
x x
2 3
7.
 /2dx 1
 5  3sin x
0
  tan 1  
2
x 2dt
Put t  tan then dx 
2 1 t2
2t
and sin x 
1 t2
2 1 dt
 
5 0  3 2  4  2
t     
 5 5
1
 3
2 1 t 
  tan 1  5 
5 4  4 
5  5 0
1  1  3 
 tan  2   tan 1   
2   4 
 3 
 2 
1 4 
 tan 1 
2  1 2 3  
  
 4
1 1
 tan 1  
2  2
1
By comparision we get  
2
2 2
 x 1  x 1 x 1 x 1 x
8. Let f  x       2    f  x  4 2
 x 1  x 1 x 1 x 1 x 1
∵ f(−x)=f(x),i.e., f(x) is an even function
1 1 1
2 2 2 1
x x 2 x dx
I  2   4 2 dx  8  0 1  x 2 dx  4 0 1  x 2  4 log e 1  x  0 2
2

0 x 1
1
4  log e    4log e 2  log e 16
2
9 log3 x 2 9 log3x 2
9.  5 log3x 2  log  588  84 x  3x 2  dx   5 log3x 2  log3 196  28 x  x 2  dx
Sec: Sr. C-120 Page 3
 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

9 log 3x 2 1
 dx   9  5   2
5 log3 x  log3(14  x)
2 2
2
1
  1   22   n 2   n
10. Given lim  1  2  1  2   1  2    k
n 
  n   n   n  
Apply log on both sides
1
 n  r2  n
log k  log  lim  1  2  

n  r 1
 n 
1 n r 2 
 .lim log    1  2  
n n    n 
r 1

1 n  r2 
log k  lim . log 1  2 
n  n
r 1  n 
1

log k   log 1  x 2  dx  log 2  2
0 2
1  sin x
11. Given f  x   and g  x   log e x
1  sin x
 1  sin x 
Now g  f  x    n  f  x    n  
 1  sin x 
 1  sin x   1  sin x 
g  f  x   dx  
π/2  /2
Now  n   dx( n   is odd function)
π/ 2  / 2
 1  sin x   1  sin x 
0
 log e 1
π/4 dx π/4 dx
12. I  
π/6
sin 2x  tan x  cot x 
5 5 π / 6 2 tan x
cot 5 x  tan10 x  1
1  tan 2 x
1 π/4 tan 4 xsec 2 x
I  dx
2 π/6 tan10 x  1
put tan 5 x  t  5 tan 4 xsec 2 xdx  dt
1 1 dt
 
10 (1/ 3 ) t  1
5 2

1
  tan 1  t   1 5
1

10 
 3


1 π 1 
   tan 1 
10  4 9 3

1 1
13. 3 f  x   2 f     10 ........ 1
 x x
1 1
Put x   3 f    2 f  x   x  10 ....... 2 
x x
Solving (1) & (2) we get

Sec: Sr. C-120 Page 4

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

1 3 
 f  x     2 x  10 
5x 
1 
2
2 x2
1 f  x  dx   3log x   10 x 
5 2 
1 2 3 13
 3log x  x 2  10 x   log 2 
5 1 5 5
14.

Sub 4, 4 3  a  3 
2  3
t1  , t2 
3 2
9 
Q   , 3 3 
 4 
1
Area   MN  PM  QN 
2
1
  MN  PS  QS 
2
1
  MN  PQ 
2
1
 7 3  
2
  49 
 4 

343 3

8

15.
2ae  42 ae  2
a b  4
2 2
a2 3
b  a 4
2 2
 12  4  8
b2  8
2b 2 2 A2 32
 
a B 3

Sec: Sr. C-120 Page 5

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

A2  2 B
1 B 2  A2 1 1  2B
 2
 
3 B 3 B2
2 2
 B3 A2  6
3 B
x2 y2 x2 y 2
E1    1 E2   1
12 8 6 9
y2 x2 2 3
 1 8  x2  9  x2
8 12 3 2
 3 2  2 6
   x 1 a 
2

 2 3  5
6 6
x y
5 5
 6 6    6 6    6 6   6 6 
A   ,  , B  , ,C  , , D  , 
 5 5  5 5   5 5   5 5 
4 6 6 24 6
Area of ABCD =  
5 5 5
16.
2 2
Giventhat foci   5,0  and  50

5 2
  e  5,  2 
2
5 2
  2   2 1  e2 ) 
2
5 2
  1  e 2  
2
5 5 2
 1  e 2  
e 2
 2e  e  2  0
2


 e 2  
2e  1  0
1
 e   2  rejected so, e 
2
5
   5 2 and  2  25
1
2
 2 2
Noweccentricity of hyperbola  e1   1   51
2
2b 2 a 4
17. Giventhat  9 and     1
a e 3
Equation of tan gent is y  3 x  3
where m  3, c   3

Sec: Sr. C-120 Page 6

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

condition of tan gency is c   a 2 m 2  b 2

  3  3a 2  b 2
 2a 2  3a  2  0
1
 a  2 or 
2
 a  2 b  9
2

x2 y2
 Equationof hyperbola is  1
4 9

e
13
2
and point of contact of tan gent  h, k   4,3 3  
Now m   a  ex1  a  ex1   48
18.
x2  9  x  9
2 2
 x 
f  g  x      9 
 x 9   x  9
2

f  g 10    100  9  109  a 2  109

x2  9 x2  9
g  f  x   
x2  9  9 x2
99
g  f  3    2  b2  2
9
x2 y2 109  2 107 107
 1 e    e2 
109 2 109 109 109
2
2b 2x2 16
   2 
a 109 109
8 107  16 872
8e 2   2   8
109 109
19.
9π 9π
dx cos x
 22
π
11 1  tan x
  22
π
11 cos x  sin x
dx

b f x ba
Using formula  f  x   f  a  b  x  dx 
a 2
9π
dx 7π
 22
π
11

1  tan x 44
20.
 /2  sin n x
A) I  dx  i 
 sin n x  cos n x
 
sin n   x 
I 
 / 2 2  dx
n   n  

sin   x   cos   x 
2  2 
n
 / 2 cos x
I  dx .  ii 
 cos x  sin n x
n

Sec: Sr. C-120 Page 7

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

Adding eqs.(i) and (ii), then

 2  
2I   1dx   2
 2

I  
4
sin 2 x

B) I   dx  i 
 1   x

 sin   x    sin x
2 x 2
I 
 1    x
dx   1   x dx  ii 
Adding Eqs.(i) and (ii), then
 
2 I   sin 2 xdx  2  sin 2 xdx
 0
  /2
 I   sin 2 xdx  2 sin 2 xdx
0 0

1  
2. . 
2 2 2
C) Removal property
D) Kings property
21.
 (x  π)  cos 2  x  3π   dx
 π/2
Given I   3
3π/2

Put , x  π  t  dx  dt

t  cos 2 t  dt  
π/2 π/2 π/ 2
I 3
t 3d
  cos

2
t
dt
 π/2  π /2  π/2
odd function even function

π/2 π π
 2  cos 2 t.dt  2   
0
4 2
22.
 /2
dx
Let I  
/4 
cos x tan x  1  2 tan x  tan x cos 2 x
 /2
sec2 xdx
I 
1  
2
 /4 tan x tan x
put tan x  t 2  sec 2 xdx  2t dt

2t dt
I 
 t  1
2
1 .t

 1   1
I  2    2 0    1
 t  1 1  2
23.
I    x11  x 7  x 3  2 x12  3 x8  6 x 4  dx
1 1/4

Put 2 x12  3 x8  6 x 4  t
11
 
 t 5/4  1
 11
5/4
I 
5 30
 24. 
 4 0
Sec: Sr. C-120 Page 8
 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

24.
 xsec 2 x  tanx 
 x2   dx
  xtanx  12 
 
 1  2x
 x2    dx
 xtanx  1  xtanx  1
x2 xcosx
  2 dx
xtanx  1 xsinx  cosx
x2
  2ln  xsinx  cosx   c
xtanx  1
I  0  0  c  0
π π2 π4
I   2 ln
4 4  π  4 4 2
25.
1
 1 1  3 1  23
  2  4   3  dx
x x  x x 
3 1  1 1 
U sin g t=  3  dt  3  2  4  dx
x x  x x 
1/23 24/23
t dt t
  C
3  24 
   3 
 23 
 α  23,β  1, γ  3
 α  β  γ  19

Sec: Sr. C-120 Page 9

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

PHYSICS

26.
i i
di   Rd ; di   d
R π
μ 0 di
 dB  
2π R
μ i μi
 dB  0   d  02  d
2 R π 2π R
π/2 μi
 B0   2dB sin θ  2B0  20
0 πR
27. Conceptual
 0i
B
28. 2R
dq dq
i  
dt 2
29. The magnetic field intensity at a distance r from centre on the axis of a coil of radius a
carrying current i is given by
μ 0 2 ia 2
Baxis  ...  i 
4π  a 2  r 2 3/2

The magnetic field intensity at the centre of the coil is given by

μ 0 2 i
Bcentre  ...  ii 
4π a
According to question, the fractional change in the magnetic field intensity is given by
B B
 1  axis ...  iii 
B Bcentre
Substituting the values of Baxis and Bcentre from Eqs. (i) and (ii) respectively in Eq. (iii), we
get
μ 0 2 ia 2
B 4π  a 2  r 2 3/ 2 a3 a3  r2 
3/ 2

1 1 1  1  1  2 

μ 0 2 i
a  r2 
3/ 2 3/ 2
B 2
 r2   a 
4π a a 1  2 
3

 a 
Given that, r < a, applying Binomial expansion,
2x 2 3  2x 3
(1  x)  n  1  x   (1) n x n  1  nx 
2! 3!

Sec: Sr. C-120 Page 10

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

B  3 r2 
we get  1  1  2 
B  2a 
B 3 r2
 11 
B 2 a2
B 3 r 2
 , which is the required expression.
B 2 a2
30. When a point source is moving towards right, the spherical wave fronts of sound waves
will have wavelength compressed towards right and wavelength gets expended towards
left.
31. As the electric field is switched on, positive ion will start to move along positive x-
direction and negative ion along negative x-direction. Current associated with motion of
both types of ions is along positive x-direction. According to Fleming's left hand rule
force on both types of ions will be along positive y-direction.
32. Conceptual
   
 
q V  B  qE  0
  
 V  B  E
    
33.  
 V  B  B  E  B
         
   
 V  B B  B  B V  E  B V  B  0
 
 
 EB
V 2
B
h

2 Em
1
34. 
m
e  p  n  
35.

      0i i i
     B   B 
B0  B0  B0
1 2
0
3
0
4 R
4
sin 900  sin 450    0   0  sin 450  sin 900  

2R 4 R
  0i  1   0i  0i  1  i  1 1 
 1      1   0  1   2   1 
4 R  2  2 R 4 R  2  4 R  2 2 
i i  1 
 0  2  2    0  
4 R 2 R  2 

Sec: Sr. C-120 Page 11

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

mv v
36. In magnetic field, the radius of circular path, r= =
Bq q
B 
m
i.e,r∝1/q/m
37. The charge will distribute itself such that the potential energy of the system is minimized.
When a charge is placed on a conductor, it will naturally redistribute itself to minimize
the potential energy of the system. This means the charge will concentrate on the surfaces
of the object, especially at points with sharp curvature, where the electric field is
strongest.
μ0 1 μ 2I
38. B  π  0
4π R 4π R
μ I  2
 0 1   outward i.e., away from page.
4R  π 
 
μ 0i net  ∮B  d l
39.  
i net  1A; ∮B  d l  μ 0
40. Conceptual
41. Force by magnetic field on e  is centripetal in nature.
mv 2
Hence BeV 
r
E  2iˆ  ˆj  3kˆ

 
A  16  ˆj  16 ˆj
 
42. 1  E. A
 2iˆ  ˆj  3kˆ . 16 ˆj 
1  16Vm
43. Magnetic field can change the direction of motion of charged particle. Since the force by
magnetic field is centripetal, no work is done by it.
44. Since the magnetic force is always perpendicular to the velocity of the charged particle
so, work done is always zero.
45. Field at outside and empty space is zero. Field inside the core of the toroid

μ 0 Ni r1  r2 
B  where r  
2 r
 2 
4 10 7  2000  11 4 107  22000
B   2  102 T
2  0.22 0.44
2 m
46. Since time period of a revolving charge is
qB
Where B = magnetic field
due to a solenoid = 0 nI
2 m
T 
q  0 nI 

9
 2   9 1031 
75 10 
1.6  1019  4  107  n 1.5
N  250

Sec: Sr. C-120 Page 12

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

R
Resistance per unit length   0.01Ω m 1 ,
l
r  1.0cm Total turns  400,   20cm,
400
B  1102 T, n  turns / m
20 102
47. E E E
i  
R 0 R  2 r  400
  0.01 2  π  0.01 400
l
B  μ 0 ni
400 E
 102  4π  107  2

20  10 400  2π  0.01 102
102  20 10 2  400  2π 102  0.01
E  1V
4π  107  400
23
Req   2.8  4
23
6
i   1.5 A
4
48. VR  2.8  1.5  4.2V
VC  1.8V
q  CVC  0.2 1.8  0.36 C
μi μ e μ e
B  0  0   0  ω
2r 2r T 2r 2π
μ e v
B 0  
49. 2r 2π r
4π  107  1.6 10 19  6.76  106
B
4π  0.52  0.52 1020
B  40
m   ZmP   A  Z  m n   M AC
 13 1.00726  14  1.00866   27.18846
50.  27.21562  27.18846
 0.02716u
E  27.16x 103 J

Sec: Sr. C-120 Page 13

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

CHEMISTRY
51. According to Faraday's second law,
5600
WAg WO2 WAg  32
 or  22400
E Ag EO2 108 8
WAg 8
or   WAg  108 g
108 8
52. Time, t=1.608 min or 96.5 s
z i t 27 10  96.5
Formula, WAl   WAl    WAl  0.09 g
96500 3 96500
53.
K  1000 K  1000 8  105  103
Λ eq  N N
N Λ eq 400
N  2  104
2  104
 1  104 M  K sp  S2  1  104   1  10 8 M 2
2
Solubility M 
2
1 R
54. G*    R  ρ  G*  1
a ρ
55.

56. Given for 0.2 M solution

R=50 Ω
K  1.4 sm 1  1.4  102 scm 1
1  
Now K     R  K
R a a
l
 50  1.4  102 cm 1  70  102 cm 1
a
For 0.5 M solution
R=280 Ω
K=?
1  1
So K     70  102
R a 280
k  2.5  103 Scm 1c
K  1000 2.5  103  1000
Now  m  
M 0.5
 m  5 S cm m01
2 1

Or

Sec: Sr. C-120 Page 14

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

 m  5 104 sm 2 mo11
1m  100cm
1m 2  104 cm 2
1 cm 2  10 4 m 2
57. strong electrolyte undergoes complete ionisation, when compared to weak electrolyte.
58. At cathode H 2 gas is liberated
Ect 1 4825  20
m   1
F 1 96500
59. During electrolysis of CuSO4 aq  solution, the resulting solution is acidic  H 2 SO4 
Hence pH<7
60. Generally few drops of H 2 SO4 is added before crystallization to prevent the oxidation of
ferrous sulphate to ferric sulphate.

61.
It is β- elimination reaction (Dehydrohalogenation) which follows saytzeff rule
i.e., a more substituted alkene is formed as a major product.

62.
Jones reagent is a mild oxidising agent, oxidizes ethyl alchohol to acetaldehyde, which on
oxidation with KMnO4 forms Acetic acid, Acetic acid undergoes decarboxylation in
presence of sodalime (NaOH+CaO) to form alkane containing one carbon atom less than
acid used.
63.

KCN H3O 
64. C2 H 5Cl  C2 H 5CN  C2 H 5COOH
65. HVZ reaction.
66. LiAlH 4 reduces-COOH group to - CH 2OH and does not attack C=C bond.
67. Acidic strength of carboxylic acids ∝ Stability of carboxylate ion
68. The direction of electric dipole is towards negative pole in case of N-H the negative pole
of N-H while in case of N-F the negative pole is F as order of electro negativity is
F>N>H.
69. Except Cu in 3d series all other elements have negative reduction potential values

Sec: Sr. C-120 Page 15

 SRI CHAITANYA IIT ACADEMY, INDIA 09-08-2025_Sr.C-120_Jee-Main_WTM-44_Key & Sol's

ETi0 2 /Ti  1.63V

0
ECr 2
/ Cr
 0.91V
EV0 2 /V  1.18V
70.
TiCl4  Ti 4  3d 0  eg0t20g
MnO4  Mn 7  3d 0  eg0 t20g
 FeO4   Fe6  3d 2  eg2t20g
2

 FeCl4   Fe3  3d 5  eg2t23g



CoCl4   Co2  3d 7  eg4t23g

2

Only, TiCl4 , MnO4  ,  FeO4  complexes have no e- in

2
t2 g orbital
λM
 n  factor
71. λE
Ca3  PO4 2  3Ca 2  2 PO43
n -factor = 3×2=6; total positive charge on all cations=6
72.
λ m of NH 4Cl  185
λ 
m NH 
4
  λ m 
Cl 
 185

λ 
m NH 
4
 185  70  115Scm 2 mol 1

λ 
m NH OH
4
  λ m 
NH 4
  λ m 
OH 

 115  170
λ 
m NH OH
4
 285Scm 2 mol 1

 λ m  NH OH
degree of dissociation  4

 λm  NH 4OH

85.5
  0.3  3  10–1
285
73. n – factor – 6
74. H  COOH ;C6 H 5  COOH ; F  CH 2  COOH
75. β−keto acids evolved CO2 gas

Sec: Sr. C-120 Page 16