Section – 2
Chemistry
1. 'A' is an organic compound which can reduce Tollen's reagent, reduces mercuric
chloride giving black precipitate, decolourises acidified KMnO 4 and can
reduce Fehling solution also. Compound 'A' is
(a) HCOOH (b) CH≡CH (c) CH3CHO (d) CH2=CH2
2. One gram of a monobasic acid when dissolved in 100 g of water lowers the
freezing point by 0.186oC. Now, 0.25 g of the same acid are dissolved and titrated
with 15.1 mL of N alkali. The degree of dissociation of the acid is (kf (H20) =
1.86)
(a) 1.66 (b) 0.66 (c) 0.11 (d) 0.060
3. If the shortest wavelength of hydrogen atom in Lyman series is x, then longest
wavelength in Balmer series of He is
(a) (b) (c) (d)
4. Alkali metals dissolve in liquid NH3, then which of the following statements
about the
solution obtained is incorrect?
(a) Solution has high electrical conductivity due to ammoniated electron
(b) Solution imparts blue colour due to greater polarization of metal ion
(c) Solution is quite stable, which is considered as a dilute metal
(d) On the addition of substance like iron, oxide, solution decomposes and
releases
hydrogen gas
5. Which of the following does not represent the correct order of properties
indicated?
(a) NH3 < PH3 < AsH3 (acidic character)
(b) Ni2+ < Co2+ <Fe2+ < Mn2+ ( unpaired electrons)
(c) Al2O3 < MgO < Na2O < K2O (basic nature)
(d) Li < Be < B < C (IE1)
6. During the test for halogens, sodium extract is heated with conc. HNO 3. The
reason for
this is
(a) to decompose NaCN and Na2S (b) Na2S is soluble in HNO3
(c) NaCN is soluble in HNO3 (d) silver halides are insoluble in HNO 3
7. A gas is heated in such a way so that its pressure and volume both becomes
double.
Again by lowering temperature, one fourth of initial number of moles of air has
been
taken in, to maintain the double volume and pressure. By what fraction the
temperature
must have been raised finally?
(a) times (b) times (c) times (d) times
19g/kg of sea water. The volume of earth's ocean is 1.4 × 1021L.
8. The most abundant element dissolved in sea water is chlorine at a
concentration of
How many gram- atoms of chlorine are potentially available from the oceans?
(density of sea water is 1 g/cc)
(a) 1.4 x 1024 (b) 2.7x 1022 (c) 4.5 x 1021 (d) 7.6 x
20
10
9. Which of the following is the strong acid?
10. 'A' is a blue coloured hydrated salt giving white ppt. 'B' with BaCl2. 2.495 g of 'A'
gave
2.33 g of white ppt. 'B'. 'A' gives deep reddish-brown solution on reaction with
KI but after addition of hypo, reddish-brown solution appears in the form of white ppt.
V. 'B' and 'C' are respectively
(a) BaSO4 ,CuCN (b) CuSO4 ,Cu2I2 (c) BaSO4, Cu2I2 (d) BaSO4 ,CuI2
11. When the concentration of 'A' is 0.1M, it decomposes to give 'X' by a first order
process with;, a... rate constant of 6.93 x 10 –2 min–1. The reactant 'A' in the
presence of catalyst gives 'Y' by a second order mechanism with a rate constant
of 0.2 min-1M-1. In order that half-life of both the processes is 10 mm, one should
start with an initial concentration of 'A' as
(a) 0.01M (b) 5.OM (c) 10.OM (d) 0.5M
12. 4.5 g of PCl5 was completely vaporised at 252° C, vapour occupying 1700 mL at
1.0 atm. The degree of dissociation is (Given V. = 104.175)
(a) 60% (b) 22% (c) 82% (d) 30%
13. Compound A and B are treated with dil. HCl separately. The gases liberated are
Y and Z
respectively. Y turns acidified dichromate paper green while Z turns lead
acetate paper
black. - The compound A and B are respectively
(a) Na2SO3 and Na2S (b) NaCl and Na2CO3
(c) Na2S and Na2SO3 (d) Na2SO3 and Na2SO4
14. E-1-chloro-2-methyl cyclohexane product. Predominant product is
15. Which of the following statements is wrong?
(a) van der Waals' radius of iodine is more than its covalent radius
(b) All isoelectronic ions belong to same period of the periodic table
(C) IE1 of N is higher than that of 0 while IE 2 of 0 is higher than that of N
(d) The electron gain enthalpy of N is zero while that of P is 74.3 kJ mol -1.
16. The solubility product of Ca(OH) 2 at 25° C is 4.42 ×10–5. A 500 mL of saturated
solution
of Ca(OH)2 is mixed with equal volume of 0.4 M NaOH. Now the amount of
Ca(OH)2
precipitated is (in mg)
(a) 0.0223 (b) 0.01115 (c) 0.010045 (d) 0.001105
17. Positive Beilstein's test for halogens shows that
(a) a halogen is definitely present (b) a halogen may be present
(C) a halogen is absent (d) None of the above
18. A major alkene (A) obtained in the following reaction undergo ozonolysis to give
the
product.
The product obtained is/are identified as
(a) ethanal only (b) methanal and propanal
(c) methanal and acetone (d) acetone only
19. Which of the following is correct comparison of the stability of the molecules ?
(a) (b) (c) (d)
20. Product
Predominant product is
(a) polyacrylate (b) polymethylmethacrylate
(c) latex (d) perspex
Directions : Question nos. 21, 22 and 23 are based on the following paragraph. When
a system is taken from state A to state B along the path ACB as shown, 80 J of heat
flows into the system and the system does 30 J of work.
21. How much heat flows into the system along path A.DB if the work done is 10 J?
(a) 80J (b) -50J (c) 50J (d) 30J
22. When the system is returned from state B to A along the curved path, work
done on the
system is 20 J. Does the system absorb or liberate heat, and how much?
(a) System liberates heat, -70 J (b) System absorbs heat, 70 J
(c) System absorbs heat, 90 J (d) System liberates heat, - 90 J
23. If HD HA = 40J, heat absorbed in the process DB is
(a) +50J (b) +30J (c) +60 J (d) +10 J
Directions : Question nos. 24 and 25 are Assertion-Reason type questions. Each of
these
questions contains two statements Statement I (Assertion) and Statement II (Reason).
Each
of these questions also has four alternative choices, only one of which is the correct
answer. You have to select the correct choice.
(a) Statement I is true; Statement II is true; Statement II is not a correct
explanation
of statement I.
(b) Statement! is true; Statement II is false.
(c) Statement I is false; Statement II is true.
(d) Statement I is true; Statement II is true; Statement II is the correct
explanation of Statement I.
24. Statement I : NF is a weaker ligand than N (CH3)3.
–
Statement II: NF3 ionises to give F ions in aqueous solution.
25. Statement I : Photochemical smog is produced by nitrogen oxides.
Statement!!: Vehicular pollution is a major source of nitrogen oxides.
– –
26. The radius ratio of Cs + to Cl is 0.90Å. If the radius of Cl ion is 1.80 Å, the false
statement regarding the CsCl structure is
–
(a) The distance between the centres of Cl ions is greater than 3.60 Å
–
(b) The distance between the centres of two Cl ions is 3.60 Å
–
(c) The distance between Cs+ ion and Cl ion is 3.42 Å
(d) The distance between two Cs+ ion is greater than 3.24 Å
27. In the ground state of Cu+, the number of shells occupied, subshells occupied,
filled orbital’s unpaired electrons respectively, are
(a) 4,8,15,0 (b) 3,6,15,1 (c) 3,6,14, 0 (d) 4,7,14,2
28. [Co(NH3)4 (NO2)2] Cl exhibits
(a) linkage isomerism, ionization isomerism and optical isomerism.
(b) linkage isomerism, geometrical isomerism and optical isomerism
(c) linkage isomerism, ionization isomerism and geometrical isomerism
(d) ionization isomerism, geometrical isomerism and optical isomerism
29. 100 mL each of two sols of Agl, one obtained by adding AgNO 3, to slight excess
of KI and
another obtained by adding KI to slight excess of AgNO 3, are mixed together.
Then,
(a) the two sols will stabilize each other
(b) the sol particles will acquire more electric charge
(c) the sols will coagulate each other mutually
(d) a true solution will be obtained
30. The hybridization states of the central atom of ClF 3, IF7, respectively,
are
(a) sp3d, sp3d3, sp3, sp3 (b) sp3d, sp3d2 , sp3d, sp3
(c) sp3, sp3d2, sp3d2, sp3 (d) sp3d2, sp3d3 , sp3, sp3
Chemistry
1.A 2.B 3.A 4.B 5.D 6.A 7.C 8.D 9.D 10.C 11.D 12.C 13.A
14.A 15.B 16.C 17.B 18.B 19.D 20.B 21.C 22.A 23.D 24.B 25.A 26.C
27.C 28.C 29.C 30.A
