Page 1 of 2 CCP - SANKALP_GOC-6-PH-IV

CPP
GENERAL ORGANIC CHEMISTRY - SHEET – 6
LEVEL - 1
Q. Classify the following into substitution, addition elimination and rearrangement reactions:
1. CH3Br + OH ⎯⎯→ CH3OH + Br −
Br CH3
2. CH3CH = CHCH3 ⎯⎯⎯⎯→ Br2 / CCl4

H3C Br
3. ROTs ⎯⎯⎯
→ ROHOH

CH3
C3 H7
4. H3C CH2 CH2 C3H7 ⎯⎯⎯⎯⎯
→ H3C OH / CH3OH
50o C
CH2 CH2
C3 H7
C3H7
C6H5 CH CH2 SiMe 3 ⎯⎯
HF
⎯→ C6H5 − CH = CH2 + Me3SiF
5.
OH
CH3 NO 2 CH3
SO2 SO2H
⎯⎯⎯⎯
CH3ONa
→ NO 2
6.
OH NO 2

NO 2
CH3 CH3
7. CH2
H3C OH ⎯⎯⎯⎯⎯
conc. H2SO4

→ H3C
Br
CH3 CH3
8. C6H5 CH C + HBr ⎯⎯→ C6H5 CH
CH3 CH3
Cl
Cl Cl

9. + 3Cl2 ⎯⎯⎯
UV
500 K
→
Cl Cl
Cl
H+
10. ⎯⎯→

LEVEL - 2

11. Which one of the following species behaves as electrophile as well as nucleophile?

(a) C6H5 — CH2 (b) CH3 — CH2

(c) PCl5 (d) CH3 — N = C

12. Which of these species is/are electrophile/s;

(a) CO2 (b) CCl4
(c) AlCl3 (d) All of these
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Page 2 of 2 CCP - SANKALP_GOC-6-PH-IV

13. Which of these species is/are electrophile/s

(a) C Cl2 (b) BF3

(c) NO2 (d) All of these

14. Which among the following species is an ambident nucleophile?

(a) Ethene (b) Benzene
(c) Cyanide ion (d) Acetone

15. Which one of the compound behaves as an electrophile as well as nucleophile?

(a) Acetone (b) Cyanide ion
(c) Nitrite ion (d) sulphite ion

16. Which one of the nitrogen containing compounds can act as an electrophile?
(a) NH2—NH2 (b) NH2—OH
(c) NF3 (d) NH3

17. Which one of the following species is a nucleophile:

(a) NF3 (b) PCl3
(c) NH2OH (d) OF2

18. Which one of the following statements is not correct for electrophile?
(a) Electron deficient species are electophile
(b) Electrophiles are Lewis acids
(c) All +ve charged species are electrophiles
(d) AlCl3, SF6, IF7 and SO3 are electrophiles

19. Which of the following statements are correct for nucleophile?

(a) All negatively charged species are nucleophile
(b) Nucleophiles are Lewis bases
(c) Alkenes, alkynes, benzene and pyrrole are nucleophiles
(d) All are correct

20. Classify the following into polar protic, polar aprotic and non polar solvents:
H2O, CH3CH2OH, DMSO, CCl4, DMA, HMPA, cyclohexane, benzene, DMF, THF, Crown ether,
CH2Cl2, Xylene

——

ANSWER KEY – GENERAL ORGANIC CHEMISTRY - SHEET – 6

11. D
12. D
13. D
14. C
15. A
16. C
17. C
18. C
19. D
20. Polar protic : H2O, CH3CH2OH
Polar aprotic: DMSO, DMA, HMPA, DMF, crown ether
Non-polar: CCl4, cyclohexane, benzene, THF
——

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